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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-Ethylsulfanyl-1,2-thiazole —— C5H7NS2
    5-Ethylsulfanyl-1,2-thiazole
    —— ethyl(methanethioyloxymethyl)carbamothioic S-acid —— C5H9NO2S2
    ethyl(methanethioyloxymethyl)carbamothioic S-acid
    —— 7-Ethylsulfanyl-1,1,1-trifluorohept-2-yne —— C9H13F3S
    7-Ethylsulfanyl-1,1,1-trifluorohept-2-yne
    —— 1-Hydroxy-1lambda6-thia-2-azacyclohexa-2,4,6-triene 1-oxide —— C4H5NO2S
    1-Hydroxy-1lambda6-thia-2-azacyclohexa-2,4,6-triene 1-oxide
    —— 1-Ethylsulfanyl-4,4,5,5,5-pentafluoro-3-methylpent-2-ene —— C8H11F5S
    1-Ethylsulfanyl-4,4,5,5,5-pentafluoro-3-methylpent-2-ene
    —— N-[(1S,2R,4R)-7-azabicyclo[2.2.1]heptan-2-yl]-4-thiophen-2-ylsulfanylbenzonitrilium —— C17H17N2S2+
    N-[(1S,2R,4R)-7-azabicyclo[2.2.1]heptan-2-yl]-4-thiophen-2-ylsulfanylbenzonitrilium
    —— 1,4-Bis(tert-butylsulfanyl)cyclohexane —— C14H28S2
    1,4-Bis(tert-butylsulfanyl)cyclohexane
    —— 1-Cyclopropyl-6-fluoro-8-methyl-7-(3-methylphenyl)sulfanylquinazoline-2,4-dione —— C19H17FN2O2S
    1-Cyclopropyl-6-fluoro-8-methyl-7-(3-methylphenyl)sulfanylquinazoline-2,4-dione
    —— 3-(2-ethylphenyl)sulfanyl-5-fluoro-2-methyl-1H-indole —— C17H16FNS
    3-(2-ethylphenyl)sulfanyl-5-fluoro-2-methyl-1H-indole
    —— 3-(2-ethylphenyl)sulfanyl-7-methoxy-1H-indole —— C17H17NOS
    3-(2-ethylphenyl)sulfanyl-7-methoxy-1H-indole
    —— 1-(Amino-hydroxy-oxo-lambda6-sulfanylidene)-2,2-dimethylbutane —— C6H15NO2S
    1-(Amino-hydroxy-oxo-lambda6-sulfanylidene)-2,2-dimethylbutane
    —— 5H-pyridazino[3,4-b][1,4]thiazine —— C6H5N3S
    5H-pyridazino[3,4-b][1,4]thiazine
    —— 1,2,3-Tris(docosylsulfanyl)-5-methylbenzene —— C73H140S3
    1,2,3-Tris(docosylsulfanyl)-5-methylbenzene
    —— 5-[3-methoxy-4-(2-methylpropoxy)phenyl]-3-[4-(trifluoromethyl)phenyl]sulfanyl-1H-pyrazin-2-one —— C22H21F3N2O3S
    5-[3-methoxy-4-(2-methylpropoxy)phenyl]-3-[4-(trifluoromethyl)phenyl]sulfanyl-1H-pyrazin-2-one
    —— propan-2-yl N-[(2-methylphenyl)sulfanylmethyl]carbamate —— C12H17NO2S
    propan-2-yl N-[(2-methylphenyl)sulfanylmethyl]carbamate
    —— [Formyl(methyl)amino] methylsulfanylformate —— C4H7NO3S
    [Formyl(methyl)amino] methylsulfanylformate
    —— Hexyl phenylsulfanylformate —— C13H18O2S
    Hexyl phenylsulfanylformate
    —— 1-Ethylsulfanyl-4-(2-methylsulfanylethyldisulfanyl)butane —— C9H20S4
    1-Ethylsulfanyl-4-(2-methylsulfanylethyldisulfanyl)butane
    —— 15-Methylsulfanylhexadec-1-ene —— C17H34S
    15-Methylsulfanylhexadec-1-ene
    —— 1,3-Bis(octacosylsulfanyl)benzene —— C62H118S2
    1,3-Bis(octacosylsulfanyl)benzene
    —— 4,4,5,5,6,6,6-Heptafluoro-1-propylsulfanylhex-2-ene —— C9H11F7S
    4,4,5,5,6,6,6-Heptafluoro-1-propylsulfanylhex-2-ene
    —— Butylsulfonyl-[diethyl(2-oxopropyl)-lambda4-sulfanyl]oxidanium —— C11H25O4S2+
    Butylsulfonyl-[diethyl(2-oxopropyl)-lambda4-sulfanyl]oxidanium
    —— N-cyclooctyl-2-(4-methylpentanoyl)-5-propan-2-ylsulfanyl-1,3,4-oxadiazol-3-ium-3-carboxamide —— C20H34N3O3S+
    N-cyclooctyl-2-(4-methylpentanoyl)-5-propan-2-ylsulfanyl-1,3,4-oxadiazol-3-ium-3-carboxamide
    —— N-thionitrosomethanethioamide —— CH2N2S2
    N-thionitrosomethanethioamide
    —— 8-[(6-Bromo-1,3-benzodioxol-5-yl)sulfanyl]-9-[3-(oxan-4-yl)propyl]purin-6-amine —— C20H22BrN5O3S
    8-[(6-Bromo-1,3-benzodioxol-5-yl)sulfanyl]-9-[3-(oxan-4-yl)propyl]purin-6-amine
    —— 1,4-Bis(butylsulfanyl)cyclohexane —— C14H28S2
    1,4-Bis(butylsulfanyl)cyclohexane
    —— N-cyclohexyl-5-(1,3-dioxolan-2-ylmethylsulfanyl)-2-(4-methylpentanoyl)-1,3,4-oxadiazol-3-ium-3-carboxamide —— C19H30N3O5S+
    N-cyclohexyl-5-(1,3-dioxolan-2-ylmethylsulfanyl)-2-(4-methylpentanoyl)-1,3,4-oxadiazol-3-ium-3-carboxamide
    —— 4-(4-Methylsulfanylphenyl)butyl formate —— C12H16O2S
    4-(4-Methylsulfanylphenyl)butyl formate
    —— 2-((3-Nitro-2-pyridinyl)sulfanyl)-4-styrylpyrimidine —— C17H12N4O2S
    2-((3-Nitro-2-pyridinyl)sulfanyl)-4-styrylpyrimidine
    —— [Diethyl(2-oxohexyl)-lambda4-sulfanyl]-(trifluoromethylsulfonyl)oxidanium —— C11H22F3O4S2+
    [Diethyl(2-oxohexyl)-lambda4-sulfanyl]-(trifluoromethylsulfonyl)oxidanium
    —— 4-(6-oxo-5H-pyridazino[3,4-b][1,4]thiazin-3-yl)-5H-pyridazino[3,4-b][1,4]thiazin-6-one —— C12H8N6O2S2
    4-(6-oxo-5H-pyridazino[3,4-b][1,4]thiazin-3-yl)-5H-pyridazino[3,4-b][1,4]thiazin-6-one
    —— 2,4-Dichloro-6-(methylthio)pyrimidin-5-amine —— C5H5Cl2N3S
    2,4-Dichloro-6-(methylthio)pyrimidin-5-amine
    —— (5Z)-5-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-3-(3,4-dichlorobenzyl)-1,3-thiazolidine-2,4-dione —— C21H12Cl3NO3S2
    (5Z)-5-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-3-(3,4-dichlorobenzyl)-1,3-thiazolidine-2,4-dione
    —— 6-[5-bromo-2-[[(Z)-(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methyl]amino]phenyl]-3-prop-2-enylsulfanyl-2H-1,2,4-triazin-5-one —— C23H19BrN6O2S
    6-[5-bromo-2-[[(Z)-(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methyl]amino]phenyl]-3-prop-2-enylsulfanyl-2H-1,2,4-triazin-5-one
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-N-[(E)-1-pyridin-4-ylethylideneamino]triazole-4-carboxamide —— C16H16N12O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]-N-[(E)-1-pyridin-4-ylethylideneamino]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-(phenylsulfanylmethyl)-N-[(Z)-pyridin-4-ylmethylideneamino]triazole-4-carboxamide —— C18H15N9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-(phenylsulfanylmethyl)-N-[(Z)-pyridin-4-ylmethylideneamino]triazole-4-carboxamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(4-bromophenyl)ethylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C20H17BrN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(4-bromophenyl)ethylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— 3-((2,6-dichloro-1-(1-propyl-1H-pyrazol-4-yl)-1H-indol-3-yl)thio)benzoic acid —— C21H17Cl2N3O2S
    3-((2,6-dichloro-1-(1-propyl-1H-pyrazol-4-yl)-1H-indol-3-yl)thio)benzoic acid
    —— (E)-1-[2-[[5-(3-chlorophenyl)-4-ethyl-1,2,4-triazol-3-yl]sulfanyl]-5-nitrophenyl]-N-(1,2,4-triazol-4-yl)methanimine —— C19H15ClN8O2S
    (E)-1-[2-[[5-(3-chlorophenyl)-4-ethyl-1,2,4-triazol-3-yl]sulfanyl]-5-nitrophenyl]-N-(1,2,4-triazol-4-yl)methanimine
    —— (Z)-2-amino-3-[[2-(4-chlorophenyl)sulfanylphenyl]methylideneamino]but-2-enedinitrile —— C17H11ClN4S
    (Z)-2-amino-3-[[2-(4-chlorophenyl)sulfanylphenyl]methylideneamino]but-2-enedinitrile
    —— N-[3-(2-methyl-1H-imidazol-1-yl)-1-phenylpropyl]-2-(pyridin-2-ylthio)acetamide —— C20H22N4OS
    N-[3-(2-methyl-1H-imidazol-1-yl)-1-phenylpropyl]-2-(pyridin-2-ylthio)acetamide
    —— N-{2-[(4-methyl-6-oxo-1,6-dihydropyrimidin-2-yl)amino]ethyl}-2-[(4-methyl-1,3-thiazol-2-yl)thio]acetamide —— C13H17N5O2S2
    N-{2-[(4-methyl-6-oxo-1,6-dihydropyrimidin-2-yl)amino]ethyl}-2-[(4-methyl-1,3-thiazol-2-yl)thio]acetamide
    —— 2-(4-acetyl-3,5-dimethyl-1H-pyrazol-1-yl)-N-[2-(1H-1,2,3-triazol-5-ylthio)ethyl]acetamide —— C13H18N6O2S
    2-(4-acetyl-3,5-dimethyl-1H-pyrazol-1-yl)-N-[2-(1H-1,2,3-triazol-5-ylthio)ethyl]acetamide
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R,5R,6S,7R)-7-pyrrolidin-1-yl-2-oxabicyclo[3.2.0]heptan-6-yl]acetamide —— C14H21N5O2S2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R,5R,6S,7R)-7-pyrrolidin-1-yl-2-oxabicyclo[3.2.0]heptan-6-yl]acetamide
    —— 2-[(3-ethyl-1H-1,2,4-triazol-5-yl)thio]-N-[2-(4-hydroxypiperidin-1-yl)ethyl]acetamide —— C13H23N5O2S
    2-[(3-ethyl-1H-1,2,4-triazol-5-yl)thio]-N-[2-(4-hydroxypiperidin-1-yl)ethyl]acetamide
    —— (4Z)-3-[(4-chlorophenyl)sulfanylmethyl]-4-(dimethylaminomethylidene)-1H-pyrazol-5-one —— C13H14ClN3OS
    (4Z)-3-[(4-chlorophenyl)sulfanylmethyl]-4-(dimethylaminomethylidene)-1H-pyrazol-5-one
    —— N-[3-(2-methyl-1H-imidazol-1-yl)-1-phenylpropyl]-2-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]acetamide —— C18H22N6OS
    N-[3-(2-methyl-1H-imidazol-1-yl)-1-phenylpropyl]-2-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]acetamide
    —— N-{cis-3-[2-(methoxymethyl)-6-oxo-1,6-dihydropyrimidin-4-yl]cyclobutyl}-2-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]acetamide —— C15H20N6O3S
    N-{cis-3-[2-(methoxymethyl)-6-oxo-1,6-dihydropyrimidin-4-yl]cyclobutyl}-2-[(4-methyl-4H-1,2,4-triazol-3-yl)thio]acetamide
    —— 2-(3-methylisoxazol-5-yl)-N-{2-[(1-methyl-1H-tetrazol-5-yl)thio]ethyl}acetamide —— C10H14N6O2S
    2-(3-methylisoxazol-5-yl)-N-{2-[(1-methyl-1H-tetrazol-5-yl)thio]ethyl}acetamide
    —— (E)-3-amino-2-[2-[[4-(oxolan-2-ylmethyl)-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]acetyl]but-2-enenitrile —— C17H19N5O2S2
    (E)-3-amino-2-[2-[[4-(oxolan-2-ylmethyl)-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]acetyl]but-2-enenitrile