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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (1S,2S)-2-(4-methylsulfanylanilino)cyclohexane-1-carbonitrile —— C14H18N2S
    (1S,2S)-2-(4-methylsulfanylanilino)cyclohexane-1-carbonitrile
    —— 6-[2-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]-3-prop-2-enylsulfanyl-2H-1,2,4-triazin-5-one —— C23H20N6O2S
    6-[2-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]-3-prop-2-enylsulfanyl-2H-1,2,4-triazin-5-one
    —— 3-hydroxyimino-1-benzothiophen-2-one —— C8H5NO2S
    3-hydroxyimino-1-benzothiophen-2-one
    —— 4-[5-(2-methylpropylsulfanyl)-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]morpholine —— C15H26N4O2S
    4-[5-(2-methylpropylsulfanyl)-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]morpholine
    —— 1-[5-[(E)-3-chloroprop-2-enyl]sulfanyl-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]-4-methylpiperidine —— C16H25ClN4OS
    1-[5-[(E)-3-chloroprop-2-enyl]sulfanyl-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]-4-methylpiperidine
    —— (2S)-N-[4-(1-methylimidazol-2-yl)sulfanylphenyl]oxolane-2-carboxamide —— C15H17N3O2S
    (2S)-N-[4-(1-methylimidazol-2-yl)sulfanylphenyl]oxolane-2-carboxamide
    —— (2S)-N-[4-(1-methylimidazol-2-yl)sulfanylphenyl]-2-(4-nitrophenyl)sulfanylpropanamide —— C19H18N4O3S2
    (2S)-N-[4-(1-methylimidazol-2-yl)sulfanylphenyl]-2-(4-nitrophenyl)sulfanylpropanamide
    —— 2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[3-(furan-2-yl)prop-2-enylideneamino]acetamide —— C18H15ClN4O2S3
    2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[3-(furan-2-yl)prop-2-enylideneamino]acetamide
    —— (3S)-6-chloro-N-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]phenyl]-3,4-dihydro-2H-chromene-3-carboxamide —— C19H17ClN4O2S
    (3S)-6-chloro-N-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]phenyl]-3,4-dihydro-2H-chromene-3-carboxamide
    —— 2-(3-bromophenoxy)-N-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]phenyl]acetamide —— C17H15BrN4O2S
    2-(3-bromophenoxy)-N-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]phenyl]acetamide
    —— (2R)-5-chloro-N-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]phenyl]-2,3-dihydro-1-benzofuran-2-carboxamide —— C18H15ClN4O2S
    (2R)-5-chloro-N-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]phenyl]-2,3-dihydro-1-benzofuran-2-carboxamide
    —— 3-(4-methylphenyl)sulfanyl-N-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]phenyl]propanamide —— C19H20N4OS2
    3-(4-methylphenyl)sulfanyl-N-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]phenyl]propanamide
    —— 2-[(1R,2R,4S)-2-bicyclo[2.2.1]heptanyl]-N-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]phenyl]acetamide —— C18H22N4OS
    2-[(1R,2R,4S)-2-bicyclo[2.2.1]heptanyl]-N-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]phenyl]acetamide
    —— 5-[2-[[3-(4-chlorophenyl)pyrazol-4-ylidene]methyl]hydrazinyl]-3-methylsulfanyl-1,2-thiazole-4-carbonitrile —— C15H11ClN6S2
    5-[2-[[3-(4-chlorophenyl)pyrazol-4-ylidene]methyl]hydrazinyl]-3-methylsulfanyl-1,2-thiazole-4-carbonitrile
    —— N'-hydroxy-2-[(1S,3S)-3-methylcyclohexyl]sulfanylbenzenecarboximidamide —— C14H20N2OS
    N'-hydroxy-2-[(1S,3S)-3-methylcyclohexyl]sulfanylbenzenecarboximidamide
    —— 1,3-dimethyl-5-[(1R,3R)-3-methylcyclohexyl]sulfanylpyrazol-4-amine —— C12H21N3S
    1,3-dimethyl-5-[(1R,3R)-3-methylcyclohexyl]sulfanylpyrazol-4-amine
    —— 5-amino-2-[(1R,3S)-3-methylcyclohexyl]sulfanylpyridine-3-carbonitrile —— C13H17N3S
    5-amino-2-[(1R,3S)-3-methylcyclohexyl]sulfanylpyridine-3-carbonitrile
    —— 4-[(1S,3R)-3-methylcyclohexyl]sulfanyl-1H-pyrazol-5-amine —— C10H17N3S
    4-[(1S,3R)-3-methylcyclohexyl]sulfanyl-1H-pyrazol-5-amine
    —— [3-[(1S,3R)-3-methylcyclohexyl]sulfanylpyrazin-2-yl]methanamine —— C12H19N3S
    [3-[(1S,3R)-3-methylcyclohexyl]sulfanylpyrazin-2-yl]methanamine
    —— [3-[(1R,3S)-3-methylcyclohexyl]sulfanylpyrazin-2-yl]methanamine —— C12H19N3S
    [3-[(1R,3S)-3-methylcyclohexyl]sulfanylpyrazin-2-yl]methanamine
    —— (1R,3S)-1-(2-azidoethylsulfonyl)-3-methylcyclohexane —— C9H17N3O2S
    (1R,3S)-1-(2-azidoethylsulfonyl)-3-methylcyclohexane
    —— butyl 2-[(1R,3R)-3-methylcyclohexyl]sulfonylacetate —— C13H24O4S
    butyl 2-[(1R,3R)-3-methylcyclohexyl]sulfonylacetate
    —— [2-[(1S,3R)-3-methylcyclohexyl]sulfanyl-6,7-dihydro-5H-cyclopenta[b]pyridin-3-yl]methanamine —— C16H24N2S
    [2-[(1S,3R)-3-methylcyclohexyl]sulfanyl-6,7-dihydro-5H-cyclopenta[b]pyridin-3-yl]methanamine
    —— [3-[(1S,3S)-3-methylcyclohexyl]sulfanylpyrazin-2-yl]methanamine —— C12H19N3S
    [3-[(1S,3S)-3-methylcyclohexyl]sulfanylpyrazin-2-yl]methanamine
    —— 5-amino-2-[(1S,3R)-3-methylcyclohexyl]sulfanylpyridine-3-carbonitrile —— C13H17N3S
    5-amino-2-[(1S,3R)-3-methylcyclohexyl]sulfanylpyridine-3-carbonitrile
    —— 2-(1,3-benzothiazol-2-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-4-[1-(2-phenylsulfanylanilino)ethylidene]pyrazol-3-one —— C31H23ClN4OS3
    2-(1,3-benzothiazol-2-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-4-[1-(2-phenylsulfanylanilino)ethylidene]pyrazol-3-one
    —— N'-hydroxy-2-[(1S,3R)-3-methylcyclohexyl]sulfanylbenzenecarboximidamide —— C14H20N2OS
    N'-hydroxy-2-[(1S,3R)-3-methylcyclohexyl]sulfanylbenzenecarboximidamide
    —— 1,3-dimethyl-5-[(1S,3R)-3-methylcyclohexyl]sulfanylpyrazol-4-amine —— C12H21N3S
    1,3-dimethyl-5-[(1S,3R)-3-methylcyclohexyl]sulfanylpyrazol-4-amine
    —— 1,3-dimethyl-5-[(1S,3S)-3-methylcyclohexyl]sulfanylpyrazol-4-amine —— C12H21N3S
    1,3-dimethyl-5-[(1S,3S)-3-methylcyclohexyl]sulfanylpyrazol-4-amine
    —— 4-[(1R,3S)-3-methylcyclohexyl]sulfanylpyridin-3-amine —— C12H18N2S
    4-[(1R,3S)-3-methylcyclohexyl]sulfanylpyridin-3-amine
    —— [3-[(1R,3R)-3-methylcyclohexyl]sulfanylpyrazin-2-yl]methanamine —— C12H19N3S
    [3-[(1R,3R)-3-methylcyclohexyl]sulfanylpyrazin-2-yl]methanamine
    —— N'-hydroxy-2-[(1S,3R)-3-methylcyclohexyl]sulfanylpyridine-3-carboximidamide —— C13H19N3OS
    N'-hydroxy-2-[(1S,3R)-3-methylcyclohexyl]sulfanylpyridine-3-carboximidamide
    —— 3-[(1S,3S)-3-methylcyclohexyl]sulfonylpropanoic acid —— C10H18O4S
    3-[(1S,3S)-3-methylcyclohexyl]sulfonylpropanoic acid
    —— 3-[(1S,3S)-3-methylcyclohexyl]sulfanylpropan-1-amine —— C10H21NS
    3-[(1S,3S)-3-methylcyclohexyl]sulfanylpropan-1-amine
    —— [2-[(1R,3R)-3-methylcyclohexyl]sulfanyl-6,7-dihydro-5H-cyclopenta[b]pyridin-3-yl]methanamine —— C16H24N2S
    [2-[(1R,3R)-3-methylcyclohexyl]sulfanyl-6,7-dihydro-5H-cyclopenta[b]pyridin-3-yl]methanamine
    —— 2-[(1S,3R)-3-methylcyclohexyl]sulfanylpyrimidin-5-amine —— C11H17N3S
    2-[(1S,3R)-3-methylcyclohexyl]sulfanylpyrimidin-5-amine
    —— (1R)-1-[3-fluoro-4-[(1R,3R)-3-methylcyclohexyl]sulfanylphenyl]ethanamine —— C15H22FNS
    (1R)-1-[3-fluoro-4-[(1R,3R)-3-methylcyclohexyl]sulfanylphenyl]ethanamine
    —— 2-[(1R,3S)-3-methylcyclohexyl]sulfonylacetic acid —— C9H16O4S
    2-[(1R,3S)-3-methylcyclohexyl]sulfonylacetic acid
    —— methyl (2S)-2-methyl-3-[(1R,3R)-3-methylcyclohexyl]sulfonylpropanoate —— C12H22O4S
    methyl (2S)-2-methyl-3-[(1R,3R)-3-methylcyclohexyl]sulfonylpropanoate
    —— 2-[(1R,3S)-3-methylcyclohexyl]sulfonylethanamine —— C9H19NO2S
    2-[(1R,3S)-3-methylcyclohexyl]sulfonylethanamine
    —— 5,6-dimethyl-3-[(1R,3S)-3-methylcyclohexyl]sulfanylpyridazine-4-carbonitrile —— C14H19N3S
    5,6-dimethyl-3-[(1R,3S)-3-methylcyclohexyl]sulfanylpyridazine-4-carbonitrile
    —— butyl 2-[(1R,3S)-3-methylcyclohexyl]sulfonylacetate —— C13H24O4S
    butyl 2-[(1R,3S)-3-methylcyclohexyl]sulfonylacetate
    —— 3-[(1R,3S)-3-methylcyclohexyl]sulfanylpropan-1-amine —— C10H21NS
    3-[(1R,3S)-3-methylcyclohexyl]sulfanylpropan-1-amine
    —— (1S,3R)-1-(2-chloroethylsulfanyl)-3-methylcyclohexane —— C9H17ClS
    (1S,3R)-1-(2-chloroethylsulfanyl)-3-methylcyclohexane
    —— 4-[(1R,3R)-3-methylcyclohexyl]sulfanylpyridin-3-amine —— C12H18N2S
    4-[(1R,3R)-3-methylcyclohexyl]sulfanylpyridin-3-amine
    —— methyl (2S)-2-methyl-3-[(1S,3S)-3-methylcyclohexyl]sulfonylpropanoate —— C12H22O4S
    methyl (2S)-2-methyl-3-[(1S,3S)-3-methylcyclohexyl]sulfonylpropanoate
    —— (2R)-N-tert-butyl-2-ethyl-4-ethylsulfonyl-2-methylbutan-1-amine —— C13H29NO2S
    (2R)-N-tert-butyl-2-ethyl-4-ethylsulfonyl-2-methylbutan-1-amine
    —— (2S)-2-(2-ethylsulfonylethyl)-2-methyl-N-(2-methylpropyl)pentan-1-amine —— C14H31NO2S
    (2S)-2-(2-ethylsulfonylethyl)-2-methyl-N-(2-methylpropyl)pentan-1-amine
    —— (2R)-2-ethyl-2-(2-ethylsulfonylethyl)-N-propan-2-ylhexan-1-amine —— C15H33NO2S
    (2R)-2-ethyl-2-(2-ethylsulfonylethyl)-N-propan-2-ylhexan-1-amine
    —— 6-[2-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]-3-propylsulfanyl-2H-1,2,4-triazin-5-one —— C23H22N6O2S
    6-[2-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]-3-propylsulfanyl-2H-1,2,4-triazin-5-one