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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (4E)-4-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]-5-methyl-2-phenylpyrazol-3-one —— C22H21N5OS
    (4E)-4-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]-5-methyl-2-phenylpyrazol-3-one
    —— 1-[(3R)-2,3-dihydro-1,4-benzoxathiin-3-yl]ethanone —— C10H10O2S
    1-[(3R)-2,3-dihydro-1,4-benzoxathiin-3-yl]ethanone
    —— (3R)-2,3-dihydro-1,4-benzoxathiine-3-carboxylic acid —— C9H8O3S
    (3R)-2,3-dihydro-1,4-benzoxathiine-3-carboxylic acid
    —— (6E)-6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]-2-nitrocyclohexa-2,4-dien-1-one —— C18H16N4O3S
    (6E)-6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]-2-nitrocyclohexa-2,4-dien-1-one
    —— (1Z)-1-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]naphthalen-2-one —— C22H19N3OS
    (1Z)-1-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]naphthalen-2-one
    —— N-[(Z)-[4-(diethylamino)phenyl]methylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C19H25N5OS
    N-[(Z)-[4-(diethylamino)phenyl]methylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— (2S)-N-[(Z)-(4-bromophenyl)methylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylpropanamide —— C16H17BrN4OS
    (2S)-N-[(Z)-(4-bromophenyl)methylideneamino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylpropanamide
    —— N-[(Z)-(3-bromophenyl)methylideneamino]-2-pyrimidin-2-ylsulfanylacetamide —— C13H11BrN4OS
    N-[(Z)-(3-bromophenyl)methylideneamino]-2-pyrimidin-2-ylsulfanylacetamide
    —— (2Z,5R)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-furan-2-ylmethylidenehydrazinylidene]-1,3-thiazolidin-4-one —— C16H13F2N3O2S2
    (2Z,5R)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-furan-2-ylmethylidenehydrazinylidene]-1,3-thiazolidin-4-one
    —— 4-[(Z)-(4-bromophenyl)methylideneamino]-6-tert-butyl-3-methylsulfanyl-1,2,4-triazin-5-one —— C15H17BrN4OS
    4-[(Z)-(4-bromophenyl)methylideneamino]-6-tert-butyl-3-methylsulfanyl-1,2,4-triazin-5-one
    —— (6E)-6-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-2-ethyl-5-imino-5,6-dihydro-7H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one —— C18H13ClN4O2S2
    (6E)-6-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-2-ethyl-5-imino-5,6-dihydro-7H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one
    —— (NZ)-N-[[4-bromo-5-(4-methylphenyl)sulfanylfuran-2-yl]methylidene]hydroxylamine —— C12H10BrNO2S
    (NZ)-N-[[4-bromo-5-(4-methylphenyl)sulfanylfuran-2-yl]methylidene]hydroxylamine
    —— (Z)-1-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]-N-(1,2,4-triazol-4-yl)methanimine —— C13H8BrClN4OS
    (Z)-1-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]-N-(1,2,4-triazol-4-yl)methanimine
    —— phenyl (1E)-1-dimorpholin-4-ylphosphoryl-N-hydroxymethanimidothioate —— C15H22N3O4PS
    phenyl (1E)-1-dimorpholin-4-ylphosphoryl-N-hydroxymethanimidothioate
    —— phenyl (1Z)-1-dimorpholin-4-ylphosphoryl-N-hydroxymethanimidothioate —— C15H22N3O4PS
    phenyl (1Z)-1-dimorpholin-4-ylphosphoryl-N-hydroxymethanimidothioate
    —— N'-[(Z)-(2-Bromophenyl)methylidene]-2-[(4,6-dimethylpyrimidin-2-YL)sulfanyl]acetohydrazide —— C15H15BrN4OS
    N'-[(Z)-(2-Bromophenyl)methylidene]-2-[(4,6-dimethylpyrimidin-2-YL)sulfanyl]acetohydrazide
    —— (Z)-1-[4-bromo-5-(4-methylphenyl)sulfanylfuran-2-yl]-N-(1,2,4-triazol-4-yl)methanimine —— C14H11BrN4OS
    (Z)-1-[4-bromo-5-(4-methylphenyl)sulfanylfuran-2-yl]-N-(1,2,4-triazol-4-yl)methanimine
    —— N-[(Z)-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]acetamide —— C13H10BrClN2O2S
    N-[(Z)-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]acetamide
    —— N'-[(Z)-{2-[(4,6-dimethylpyrimidin-2-yl)sulfanyl]-5-nitrophenyl}methylidene]pyridine-4-carbohydrazide —— C19H16N6O3S
    N'-[(Z)-{2-[(4,6-dimethylpyrimidin-2-yl)sulfanyl]-5-nitrophenyl}methylidene]pyridine-4-carbohydrazide
    —— (5Z)-5-[[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-1-(2-methoxyphenyl)-2-sulfanylidene-1,3-diazinane-4,6-dione —— C22H15ClN2O4S2
    (5Z)-5-[[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-1-(2-methoxyphenyl)-2-sulfanylidene-1,3-diazinane-4,6-dione
    —— 2-cyano-N-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]acetamide —— C14H11N3O2S
    2-cyano-N-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]acetamide
    —— N-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]acetamide —— C13H12N2O2S
    N-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]acetamide
    —— N-[(E)-[4-bromo-5-(4-methylphenyl)sulfanylfuran-2-yl]methylideneamino]acetamide —— C14H13BrN2O2S
    N-[(E)-[4-bromo-5-(4-methylphenyl)sulfanylfuran-2-yl]methylideneamino]acetamide
    —— N-[(Z)-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]-2-cyanoacetamide —— C14H9BrClN3O2S
    N-[(Z)-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]-2-cyanoacetamide
    —— 2-[3-cyano-4-(methoxymethyl)-6-methyl-2-oxopyridin-1-yl]-N-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]acetamide —— C22H20N4O4S
    2-[3-cyano-4-(methoxymethyl)-6-methyl-2-oxopyridin-1-yl]-N-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]acetamide
    —— (6E)-5-imino-6-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methylidene]-2-propyl-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one —— C20H18N4O2S2
    (6E)-5-imino-6-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methylidene]-2-propyl-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one
    —— (2R)-2-(cyclopropylamino)-4-[(5-oxo-4-propan-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]butanenitrile —— C12H19N5OS
    (2R)-2-(cyclopropylamino)-4-[(5-oxo-4-propan-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]butanenitrile
    —— (2S)-2-(cyclopropylamino)-4-[(5-oxo-4-propan-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]butanenitrile —— C12H19N5OS
    (2S)-2-(cyclopropylamino)-4-[(5-oxo-4-propan-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]butanenitrile
    —— (2S)-4-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]-2-(propan-2-ylamino)butanenitrile —— C12H21N5OS
    (2S)-4-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]-2-(propan-2-ylamino)butanenitrile
    —— (2R)-2-(cyclopropylamino)-4-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]butanenitrile —— C12H19N5OS
    (2R)-2-(cyclopropylamino)-4-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]butanenitrile
    —— (2S)-2-(cyclopropylamino)-4-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]butanenitrile —— C12H19N5OS
    (2S)-2-(cyclopropylamino)-4-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]butanenitrile
    —— (2R)-4-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-2-(propan-2-ylamino)butanenitrile —— C10H17N5OS
    (2R)-4-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-2-(propan-2-ylamino)butanenitrile
    —— (2R)-4-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]-2-(propan-2-ylamino)butanenitrile —— C12H21N5OS
    (2R)-4-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]-2-(propan-2-ylamino)butanenitrile
    —— (2S)-2-(ethylamino)-4-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]butanenitrile —— C10H17N5OS
    (2S)-2-(ethylamino)-4-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]butanenitrile
    —— (2S)-2-amino-4-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]butanenitrile —— C7H11N5OS
    (2S)-2-amino-4-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]butanenitrile
    —— (2R)-2-(ethylamino)-4-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]butanenitrile —— C10H17N5OS
    (2R)-2-(ethylamino)-4-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]butanenitrile
    —— (2S)-4-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-2-(propan-2-ylamino)butanenitrile —— C10H17N5OS
    (2S)-4-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-2-(propan-2-ylamino)butanenitrile
    —— (2R)-2-amino-4-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]butanenitrile —— C7H11N5OS
    (2R)-2-amino-4-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]butanenitrile
    —— (2S)-4-(3-bromophenyl)sulfanyl-2-(cyclopropylamino)butanenitrile —— C13H15BrN2S
    (2S)-4-(3-bromophenyl)sulfanyl-2-(cyclopropylamino)butanenitrile
    —— (NE)-N-[(1S,2S,5S)-2-[4-(difluoromethyl)-6-methylpyrimidin-2-yl]sulfanyl-6,8-dioxabicyclo[3.2.1]octan-4-ylidene]hydroxylamine —— C12H13F2N3O3S
    (NE)-N-[(1S,2S,5S)-2-[4-(difluoromethyl)-6-methylpyrimidin-2-yl]sulfanyl-6,8-dioxabicyclo[3.2.1]octan-4-ylidene]hydroxylamine
    —— (2S)-4-(3-chlorophenyl)sulfanyl-2-(propan-2-ylamino)butanenitrile —— C13H17ClN2S
    (2S)-4-(3-chlorophenyl)sulfanyl-2-(propan-2-ylamino)butanenitrile
    —— (2S)-2-amino-4-(4-methylpyrimidin-2-yl)sulfanylbutanenitrile —— C9H12N4S
    (2S)-2-amino-4-(4-methylpyrimidin-2-yl)sulfanylbutanenitrile
    —— (2R)-2-amino-4-(4-methylpyrimidin-2-yl)sulfanylbutanenitrile —— C9H12N4S
    (2R)-2-amino-4-(4-methylpyrimidin-2-yl)sulfanylbutanenitrile
    —— (2R)-2-amino-4-(4,6-dimethylpyrimidin-2-yl)sulfanylbutanenitrile —— C10H14N4S
    (2R)-2-amino-4-(4,6-dimethylpyrimidin-2-yl)sulfanylbutanenitrile
    —— (2S)-2-amino-4-(4,6-dimethylpyrimidin-2-yl)sulfanylbutanenitrile —— C10H14N4S
    (2S)-2-amino-4-(4,6-dimethylpyrimidin-2-yl)sulfanylbutanenitrile
    —— (2S)-2-amino-4-(3-chlorophenyl)sulfanylbutanenitrile —— C10H11ClN2S
    (2S)-2-amino-4-(3-chlorophenyl)sulfanylbutanenitrile
    —— (2R)-4-(3-bromophenyl)sulfanyl-2-(cyclopropylamino)butanenitrile —— C13H15BrN2S
    (2R)-4-(3-bromophenyl)sulfanyl-2-(cyclopropylamino)butanenitrile
    —— (2S)-4-(2,5-dimethylpyrazol-3-yl)sulfanyl-2-(propylamino)butanenitrile —— C12H20N4S
    (2S)-4-(2,5-dimethylpyrazol-3-yl)sulfanyl-2-(propylamino)butanenitrile
    —— (2S)-2-(cyclopropylamino)-4-(2,5-dimethylpyrazol-3-yl)sulfanylbutanenitrile —— C12H18N4S
    (2S)-2-(cyclopropylamino)-4-(2,5-dimethylpyrazol-3-yl)sulfanylbutanenitrile
    —— (2S)-2-amino-4-(2,5-dimethylpyrazol-3-yl)sulfanylbutanenitrile —— C9H14N4S
    (2S)-2-amino-4-(2,5-dimethylpyrazol-3-yl)sulfanylbutanenitrile