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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-Benzothiophen-4(5H)-one, 6,7-dihydro-1-chloro-6,6-dimethyl-3-methylthio-, oxime —— C11H14ClNOS2
    2-Benzothiophen-4(5H)-one, 6,7-dihydro-1-chloro-6,6-dimethyl-3-methylthio-, oxime
    —— 2-{[3-Chloro-5-(trifluoromethyl)-2-pyridinyl]sulfanyl}-4-(2,4-dichlorostyryl)pyrimidine —— C18H9Cl3F3N3S
    2-{[3-Chloro-5-(trifluoromethyl)-2-pyridinyl]sulfanyl}-4-(2,4-dichlorostyryl)pyrimidine
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-(phenylsulfanylmethyl)-N-[(Z)-1-pyridin-4-ylethylideneamino]triazole-4-carboxamide —— C19H17N9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-(phenylsulfanylmethyl)-N-[(Z)-1-pyridin-4-ylethylideneamino]triazole-4-carboxamide
    —— (Z)-1-[2-(2,3-dichlorophenyl)sulfanyl-5-nitrophenyl]-N-methoxymethanimine —— C14H10Cl2N2O3S
    (Z)-1-[2-(2,3-dichlorophenyl)sulfanyl-5-nitrophenyl]-N-methoxymethanimine
    —— O-(2,2,2-trifluoroethyl) propanoylsulfanylmethanethioate —— C6H7F3O2S2
    O-(2,2,2-trifluoroethyl) propanoylsulfanylmethanethioate
    —— 2-Amino-2-methylheptane-1-thiol;3-bromo-1-oxoboranylpropan-1-imine —— C11H24BBrN2OS
    2-Amino-2-methylheptane-1-thiol;3-bromo-1-oxoboranylpropan-1-imine
    —— 3-Ethylsulfanyl-3-propylsulfanylpropane-1-thiol —— C8H18S3
    3-Ethylsulfanyl-3-propylsulfanylpropane-1-thiol
    —— 2,3,3,4,4-Pentafluorobutane-1-thiol —— C4H5F5S
    2,3,3,4,4-Pentafluorobutane-1-thiol
    —— 5-(3-Methylpentyl)-2-methylsulfanyl-1,3-thiazole —— C10H17NS2
    5-(3-Methylpentyl)-2-methylsulfanyl-1,3-thiazole
    —— (2E)-3-{5-[(4-chlorophenyl)sulfanyl]furan-2-yl}-2-cyanoprop-2-enamide —— C14H9ClN2O2S
    (2E)-3-{5-[(4-chlorophenyl)sulfanyl]furan-2-yl}-2-cyanoprop-2-enamide
    —— [2-(Cyanomethylcarbamoyl)cyclohexylidene]-[4-[2-oxo-2-(pyridin-4-ylmethylamino)ethyl]sulfanylphenyl]methanesulfinic acid —— C24H26N4O4S2
    [2-(Cyanomethylcarbamoyl)cyclohexylidene]-[4-[2-oxo-2-(pyridin-4-ylmethylamino)ethyl]sulfanylphenyl]methanesulfinic acid
    —— (Cyclopentylideneamino)oxymethanethiol —— C6H11NOS
    (Cyclopentylideneamino)oxymethanethiol
    —— 2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(1E)-1-(thiophen-2-yl)ethylidene]acetohydrazide —— C17H16N4OS4
    2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(1E)-1-(thiophen-2-yl)ethylidene]acetohydrazide
    —— Hydroxylamine;methyl 3-[2-[6-amino-8-[(6-methyl-1,3-benzodioxol-5-yl)sulfanyl]purin-9-yl]ethoxy]propanoate —— C19H24N6O6S
    Hydroxylamine;methyl 3-[2-[6-amino-8-[(6-methyl-1,3-benzodioxol-5-yl)sulfanyl]purin-9-yl]ethoxy]propanoate
    —— 2-(3,3-Dichloropropylsulfinyl)ethanimine —— C5H9Cl2NOS
    2-(3,3-Dichloropropylsulfinyl)ethanimine
    —— (5Z)-5-[[3-nitro-4-[5-(trifluoromethyl)pyridin-2-yl]sulfanylphenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C16H8F3N3O3S3
    (5Z)-5-[[3-nitro-4-[5-(trifluoromethyl)pyridin-2-yl]sulfanylphenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— N-[(Z)-(4-chlorophenyl)methylideneamino]-4-(4-phenylsulfanylphenyl)-1,3-thiazol-2-amine —— C22H16ClN3S2
    N-[(Z)-(4-chlorophenyl)methylideneamino]-4-(4-phenylsulfanylphenyl)-1,3-thiazol-2-amine
    —— [4-(thiophen-2-ylsulfanylamino)-2-(1H-1,2,4-triazol-5-ylsulfanyl)naphthalen-1-yl]methanol —— C17H14N4OS3
    [4-(thiophen-2-ylsulfanylamino)-2-(1H-1,2,4-triazol-5-ylsulfanyl)naphthalen-1-yl]methanol
    —— 2-({5-[(2-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1Z)-1-phenylethylidene]acetohydrazide —— C19H17ClN4OS3
    2-({5-[(2-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1Z)-1-phenylethylidene]acetohydrazide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(2-methylpiperidin-1-yl)methyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]triazole-4-carboxamide —— C20H25N9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(2-methylpiperidin-1-yl)methyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]triazole-4-carboxamide
    —— 2-Methyl-2,7-dihydrothionine —— C9H12S
    2-Methyl-2,7-dihydrothionine
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methylphenyl)sulfanylmethyl]-N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]triazole-4-carboxamide —— C19H18N8O2S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-methylphenyl)sulfanylmethyl]-N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]triazole-4-carboxamide
    —— 2-[5-bromo-4-(4-chlorophenyl)sulfanyl-7-ethenyl-2,3-dihydro-1H-pyrrolo[1,2-a]indol-3-yl]propanoic acid —— C22H19BrClNO2S
    2-[5-bromo-4-(4-chlorophenyl)sulfanyl-7-ethenyl-2,3-dihydro-1H-pyrrolo[1,2-a]indol-3-yl]propanoic acid
    —— 1-Chloro-4-(1-nitro-2-phenylethenyl)sulfanylbenzene —— C14H10ClNO2S
    1-Chloro-4-(1-nitro-2-phenylethenyl)sulfanylbenzene
    —— N-[(E)-1-(4-bromophenyl)ethylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C20H19BrN4OS3
    N-[(E)-1-(4-bromophenyl)ethylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— Trimethoxymethylsulfanylbenzene —— C10H14O3S
    Trimethoxymethylsulfanylbenzene
    —— 1-benzyl-3-[(Z)-[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]thiourea —— C19H16ClN3OS2
    1-benzyl-3-[(Z)-[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]thiourea
    —— (E)-2-(1H-benzimidazol-2-yl)-3-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]prop-2-enenitrile —— C23H16N4O2S
    (E)-2-(1H-benzimidazol-2-yl)-3-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]prop-2-enenitrile
    —— 2-N-[(Z)-[2-(4-chlorophenyl)sulfanylphenyl]methylideneamino]-4-N-phenyl-6-piperidin-1-yl-1,3,5-triazine-2,4-diamine —— C27H26ClN7S
    2-N-[(Z)-[2-(4-chlorophenyl)sulfanylphenyl]methylideneamino]-4-N-phenyl-6-piperidin-1-yl-1,3,5-triazine-2,4-diamine
    —— ethyl (3Z)-2-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanyl-3-methoxyiminopropanoate —— C12H12ClF3N2O3S
    ethyl (3Z)-2-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanyl-3-methoxyiminopropanoate
    —— (5E)-5-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-3-phenyl-1,3-thiazolidine-2,4-dione —— C20H12ClNO3S2
    (5E)-5-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-3-phenyl-1,3-thiazolidine-2,4-dione
    —— 1-(4-Chlorophenyl)-5-[[6-(4-methylphenyl)sulfanylpyrazolo[1,2-b]thiadiazol-4-ium-5-yl]methylidene]-2-sulfanylidene-1,3-diazinane-4,6-dione —— C23H16ClN4O2S3+
    1-(4-Chlorophenyl)-5-[[6-(4-methylphenyl)sulfanylpyrazolo[1,2-b]thiadiazol-4-ium-5-yl]methylidene]-2-sulfanylidene-1,3-diazinane-4,6-dione
    —— 6-[2-(n-Propoxycarbamoyl)phenylsulfanyl]-3-E-[2-(pyridin-2-yl)ethenyl]-1H-indazole —— C24H22N4O2S
    6-[2-(n-Propoxycarbamoyl)phenylsulfanyl]-3-E-[2-(pyridin-2-yl)ethenyl]-1H-indazole
    —— S-[3-[bis[di(propan-2-yl)amino]phosphanyloxymethoxy]propyl] N-(3-ethylpentan-3-yl)carbamothioate —— C24H52N3O3PS
    S-[3-[bis[di(propan-2-yl)amino]phosphanyloxymethoxy]propyl] N-(3-ethylpentan-3-yl)carbamothioate
    —— 4-[[2-[(4-Prop-1-ynylphenyl)methylsulfanyl]pyridin-3-yl]methyl]piperazine-1-carboximidamide —— C21H25N5S
    4-[[2-[(4-Prop-1-ynylphenyl)methylsulfanyl]pyridin-3-yl]methyl]piperazine-1-carboximidamide
    —— 4-(2,5-Dihydroxy-1-methylpyrrol-3-yl)sulfanyl-4-methyl-3-(methylamino)pentan-2-one —— C12H20N2O3S
    4-(2,5-Dihydroxy-1-methylpyrrol-3-yl)sulfanyl-4-methyl-3-(methylamino)pentan-2-one
    —— (E)-butan-2-ylidene-(3-ethenylhexyl)-methyl-lambda4-sulfane —— C13H25S+
    (E)-butan-2-ylidene-(3-ethenylhexyl)-methyl-lambda4-sulfane
    —— 9-Bromo-5-methylsulfanyl-8-thia-2,4-diazabicyclo[4.3.1]deca-1(9),2,4,6-tetraene —— C8H7BrN2S2
    9-Bromo-5-methylsulfanyl-8-thia-2,4-diazabicyclo[4.3.1]deca-1(9),2,4,6-tetraene
    —— 2,3-Diethyl-2-methylcyclobutane-1-thiol —— C9H18S
    2,3-Diethyl-2-methylcyclobutane-1-thiol
    —— 3-(5-Tert-butylsulfanyl-4-phenylmethoxypyridin-2-yl)propanoic acid —— C19H23NO3S
    3-(5-Tert-butylsulfanyl-4-phenylmethoxypyridin-2-yl)propanoic acid
    —— 3-Methoxy-5-(3-methoxypent-3-enyldisulfanyl)pent-2-ene —— C12H20O2S2+2
    3-Methoxy-5-(3-methoxypent-3-enyldisulfanyl)pent-2-ene
    —— 2-Fluoro-1,5-dimethyl-4-methylsulfonylcyclohexa-1,3-diene —— C9H13FO2S
    2-Fluoro-1,5-dimethyl-4-methylsulfonylcyclohexa-1,3-diene
    —— 2-[4-Chloro-2-(2,2-diethoxyethylsulfanyl)-2,3-dihydro-1-benzothiophene-5-carbonyl]cyclohexane-1,3-dione —— C21H25ClO5S2
    2-[4-Chloro-2-(2,2-diethoxyethylsulfanyl)-2,3-dihydro-1-benzothiophene-5-carbonyl]cyclohexane-1,3-dione
    —— 6-[3-[2-[(E)-3-(5-chloro-1,3-dimethylpyrazol-4-yl)prop-2-enoyl]pyrazolidin-1-yl]-3-oxopropyl]-3-methylsulfanyl-4H-1,2,4-triazin-5-one —— C18H22ClN7O3S
    6-[3-[2-[(E)-3-(5-chloro-1,3-dimethylpyrazol-4-yl)prop-2-enoyl]pyrazolidin-1-yl]-3-oxopropyl]-3-methylsulfanyl-4H-1,2,4-triazin-5-one
    —— (2E)-2-(5,7-dihydroxy-[1,3]dithiolo[4,5-d]pyrimidine-4,6-diium-2-ylidene)-4H-[1,3]dithiolo[4,5-d]pyrimidine-5,7-dione —— C10H6N4O4S4+2
    (2E)-2-(5,7-dihydroxy-[1,3]dithiolo[4,5-d]pyrimidine-4,6-diium-2-ylidene)-4H-[1,3]dithiolo[4,5-d]pyrimidine-5,7-dione
    —— N-methyl-6-(6-methylimidazo[1,2-a]pyridin-3-yl)sulfanyl-1,3-benzothiazol-2-amine —— C16H14N4S2
    N-methyl-6-(6-methylimidazo[1,2-a]pyridin-3-yl)sulfanyl-1,3-benzothiazol-2-amine
    —— 2-Methyl-2-methylsulfanylhept-3-yne —— C9H16S
    2-Methyl-2-methylsulfanylhept-3-yne
    —— Ethyl 2-(2-chloro-6-fluorobenzylidene)-7-methyl-5-(4-(methylthio)phenyl)-3-oxo-3,5-dihydro-2H-thiazolo[3,2-a]pyrimidine-6-carboxylate 609795-96-2 C24H20ClFN2O3S2
    Ethyl 2-(2-chloro-6-fluorobenzylidene)-7-methyl-5-(4-(methylthio)phenyl)-3-oxo-3,5-dihydro-2H-thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— 5-[[2-(4-Chlorophenyl)sulfanyl-1-methylindol-3-yl]methylidene]-1-prop-2-enyl-2-sulfanylidene-1,3-diazinane-4,6-dione —— C23H18ClN3O2S2
    5-[[2-(4-Chlorophenyl)sulfanyl-1-methylindol-3-yl]methylidene]-1-prop-2-enyl-2-sulfanylidene-1,3-diazinane-4,6-dione
    —— 5,5-dimethyl-4-[(Z)-[4-(methylsulfanyl)benzylidene](oxido)-lambda~5~-azanyl]-3-propyl-1,3-thiazolidine-2-thione —— C16H22N2OS3
    5,5-dimethyl-4-[(Z)-[4-(methylsulfanyl)benzylidene](oxido)-lambda~5~-azanyl]-3-propyl-1,3-thiazolidine-2-thione