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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [(S)-methylsulfinyl]-[(R)-methylsulfinyl]methane —— C3H8O2S2
    [(S)-methylsulfinyl]-[(R)-methylsulfinyl]methane
    —— [(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]thiourea —— C15H14N4O2S2
    [(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]thiourea
    —— 1,2-Bis(isopropylsulfonyl)-1,2-dichloroethylene —— C8H14Cl2O4S2
    1,2-Bis(isopropylsulfonyl)-1,2-dichloroethylene
    —— 2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-pyridin-4-ylmethylideneamino]acetamide —— C21H23N7OS
    2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-pyridin-4-ylmethylideneamino]acetamide
    —— (5Z)-3-(2-methoxyphenyl)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C24H18N2O4S3
    (5Z)-3-(2-methoxyphenyl)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propan-1-one —— C19H26N4O2S2
    (2S)-1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propan-1-one
    —— 2-[(4-benzyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2S)-4-phenylbutan-2-yl]acetamide —— C25H26N4OS2
    2-[(4-benzyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2S)-4-phenylbutan-2-yl]acetamide
    —— N-[(Z)-[2-methyl-5-(1-methyltetrazol-5-yl)sulfanylpyrazolo[1,5-a]quinazolin-3-yl]methylideneamino]-4-nitroaniline —— C20H16N10O2S
    N-[(Z)-[2-methyl-5-(1-methyltetrazol-5-yl)sulfanylpyrazolo[1,5-a]quinazolin-3-yl]methylideneamino]-4-nitroaniline
    —— 4-fluoro-N-[(Z)-[3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl]methylideneamino]benzamide —— C21H12FN5O5S2
    4-fluoro-N-[(Z)-[3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl]methylideneamino]benzamide
    —— 4-[(R)-methylsulfinyl]butan-2-one —— C5H10O2S
    4-[(R)-methylsulfinyl]butan-2-one
    —— 2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(R)-(4-fluorophenyl)-(1-methylimidazol-2-yl)methyl]acetamide —— C21H21BrFN3OS
    2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(R)-(4-fluorophenyl)-(1-methylimidazol-2-yl)methyl]acetamide
    —— 2-[[5-[(3R,5S)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methoxyethyl)acetamide —— C19H29N5O3S
    2-[[5-[(3R,5S)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-(2-methoxyethyl)acetamide
    —— (5Z)-3-(3-chloro-4-methoxyphenyl)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C24H17ClN2O4S3
    (5Z)-3-(3-chloro-4-methoxyphenyl)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— N-[(2R)-6-methylheptan-2-yl]-2-[[5-[(E)-2-thiophen-2-ylethenyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C18H26N4OS2
    N-[(2R)-6-methylheptan-2-yl]-2-[[5-[(E)-2-thiophen-2-ylethenyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[(Z)-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylideneamino]pyridine-4-carboxamide —— C17H14N6O3S
    N-[(Z)-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylideneamino]pyridine-4-carboxamide
    —— N-[(1R)-1-(furan-2-yl)ethyl]-2-[[5-[(E)-2-thiophen-2-ylethenyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C16H16N4O2S2
    N-[(1R)-1-(furan-2-yl)ethyl]-2-[[5-[(E)-2-thiophen-2-ylethenyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— (3S)-3-(3-aminophenyl)sulfanyl-1-methylpyrrolidine-2,5-dione —— C11H12N2O2S
    (3S)-3-(3-aminophenyl)sulfanyl-1-methylpyrrolidine-2,5-dione
    —— N-[(S)-(4-fluorophenyl)-thiophen-2-ylmethyl]-2-[[5-[(E)-2-thiophen-2-ylethenyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C21H17FN4OS3
    N-[(S)-(4-fluorophenyl)-thiophen-2-ylmethyl]-2-[[5-[(E)-2-thiophen-2-ylethenyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[(2-chlorophenyl)methyl]-2-[(3R)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetamide —— C15H14ClN3O2S
    N-[(2-chlorophenyl)methyl]-2-[(3R)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetamide
    —— 2-[(3R)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]-N-(3-phenylpropyl)acetamide —— C17H19N3O2S
    2-[(3R)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]-N-(3-phenylpropyl)acetamide
    —— 2-[(2Z)-2-[[2-(1,3-benzothiazol-2-ylsulfanyl)-9-methyl-4-oxopyrido[1,2-a]pyrimidin-3-yl]methylidene]hydrazinyl]benzoic acid —— C24H17N5O3S2
    2-[(2Z)-2-[[2-(1,3-benzothiazol-2-ylsulfanyl)-9-methyl-4-oxopyrido[1,2-a]pyrimidin-3-yl]methylidene]hydrazinyl]benzoic acid
    —— (3R)-3-[2-(4-ethylpiperazin-1-yl)-2-oxoethyl]-6,7-dimethyl-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-5-one —— C16H24N4O2S
    (3R)-3-[2-(4-ethylpiperazin-1-yl)-2-oxoethyl]-6,7-dimethyl-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-5-one
    —— N-benzyl-2-[[4-[[(2R)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H22N4O2S2
    N-benzyl-2-[[4-[[(2R)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-benzyl-2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H22N4O2S2
    N-benzyl-2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[(3R)-7-ethyl-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]-N-[(4-methylphenyl)methyl]acetamide —— C18H21N3O2S
    2-[(3R)-7-ethyl-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]-N-[(4-methylphenyl)methyl]acetamide
    —— 2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-phenylethyl]acetamide —— C21H24N4O2S2
    2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]-N-[(1R)-1-phenylethyl]acetamide
    —— (3S)-7-methyl-3-[2-(4-methylpiperazin-1-yl)-2-oxoethyl]-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-5-one —— C14H20N4O2S
    (3S)-7-methyl-3-[2-(4-methylpiperazin-1-yl)-2-oxoethyl]-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-5-one
    —— 5-chloro-1-[(4-fluorophenyl)methyl]-3-methyl-N-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]pyrazole-4-carboxamide —— C22H19ClFN5OS2
    5-chloro-1-[(4-fluorophenyl)methyl]-3-methyl-N-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]pyrazole-4-carboxamide
    —— (3S)-3-[2-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl]-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-5-one —— C14H19N3O3S
    (3S)-3-[2-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-2-oxoethyl]-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-5-one
    —— N-cyclohexyl-2-[(3R)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetamide —— C14H19N3O2S
    N-cyclohexyl-2-[(3R)-5-oxo-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-3-yl]acetamide
    —— 1-[(2R)-2-ethylhexyl]-3-propan-2-ylthiourea —— C12H26N2S
    1-[(2R)-2-ethylhexyl]-3-propan-2-ylthiourea
    —— N-[(E)-[4-(4-methylsulfanylphenyl)-3-prop-2-enyl-1,3-thiazol-2-ylidene]amino]adamantane-1-carboxamide —— C24H29N3OS2
    N-[(E)-[4-(4-methylsulfanylphenyl)-3-prop-2-enyl-1,3-thiazol-2-ylidene]amino]adamantane-1-carboxamide
    —— (2S)-2-(3,4-dimethyl-N-methylsulfonylanilino)-N-(2-phenylsulfanylphenyl)butanamide —— C25H28N2O3S2
    (2S)-2-(3,4-dimethyl-N-methylsulfonylanilino)-N-(2-phenylsulfanylphenyl)butanamide
    —— (14E)-14-[[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylidene]-11-phenyl-15-thia-12,17-diazatetracyclo[8.7.0.02,7.012,16]heptadeca-1(10),2,4,6,16-pentaen-13-one —— C32H21N3O2S3
    (14E)-14-[[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylidene]-11-phenyl-15-thia-12,17-diazatetracyclo[8.7.0.02,7.012,16]heptadeca-1(10),2,4,6,16-pentaen-13-one
    —— (2S)-2-naphthalen-2-yloxy-N-(2-phenylsulfanylphenyl)propanamide —— C25H21NO2S
    (2S)-2-naphthalen-2-yloxy-N-(2-phenylsulfanylphenyl)propanamide
    —— N-[(Z)-1-(2-hydroxyphenyl)ethylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C20H20N4O2S3
    N-[(Z)-1-(2-hydroxyphenyl)ethylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (2S)-2-(2-chlorophenoxy)-N-(2-phenylsulfanylphenyl)propanamide —— C21H18ClNO2S
    (2S)-2-(2-chlorophenoxy)-N-(2-phenylsulfanylphenyl)propanamide
    —— N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-2-phenylacetamide —— C21H16ClN3O3S
    N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-2-phenylacetamide
    —— (E)-2-(5,6-dimethyl-4-oxo-3H-thieno[2,3-d]pyrimidin-2-yl)-3-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]prop-2-enenitrile —— C21H16N6O3S2
    (E)-2-(5,6-dimethyl-4-oxo-3H-thieno[2,3-d]pyrimidin-2-yl)-3-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]prop-2-enenitrile
    —— (2R)-2-naphthalen-1-yloxy-N-(2-phenylsulfanylphenyl)propanamide —— C25H21NO2S
    (2R)-2-naphthalen-1-yloxy-N-(2-phenylsulfanylphenyl)propanamide
    —— (2E)-3-{5-[(4-chlorophenyl)sulfanyl]furan-2-yl}-2-cyano-N-(3-methylphenyl)prop-2-enamide —— C21H15ClN2O2S
    (2E)-3-{5-[(4-chlorophenyl)sulfanyl]furan-2-yl}-2-cyano-N-(3-methylphenyl)prop-2-enamide
    —— (5E)-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-3-ethyl-2-sulfanylidene-1,3-thiazolidin-4-one —— C18H13ClN2O3S3
    (5E)-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-3-ethyl-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (2S)-4-benzylsulfonyl-N-(2-phenylsulfanylphenyl)-2,3-dihydro-1,4-benzoxazine-2-carboxamide —— C28H24N2O4S2
    (2S)-4-benzylsulfonyl-N-(2-phenylsulfanylphenyl)-2,3-dihydro-1,4-benzoxazine-2-carboxamide
    —— 6-nitro-2-[(E)-2-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)ethenyl]-1,3-benzothiazole —— C19H11N5O4S2
    6-nitro-2-[(E)-2-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)ethenyl]-1,3-benzothiazole
    —— 5-{2-[(1E)-2-(4-Chlorophenyl)-1-cyanoeth-1-EN-1-YL]-1,3-thiazol-4-YL}-2-(ethylsulfanyl)-6-methylpyridine-3-carbonitrile —— C21H15ClN4S2
    5-{2-[(1E)-2-(4-Chlorophenyl)-1-cyanoeth-1-EN-1-YL]-1,3-thiazol-4-YL}-2-(ethylsulfanyl)-6-methylpyridine-3-carbonitrile
    —— 3-[2-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-oxoethyl]sulfanyl-6-methyl-4H-1,2,4-triazin-5-one —— C19H16ClN5O3S
    3-[2-[(3S)-5-(4-chlorophenyl)-3-(furan-2-yl)-3,4-dihydropyrazol-2-yl]-2-oxoethyl]sulfanyl-6-methyl-4H-1,2,4-triazin-5-one
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-[3-(dimethylamino)propyl]propanamide —— C14H21ClN2OS
    (2R)-2-(4-chlorophenyl)sulfanyl-N-[3-(dimethylamino)propyl]propanamide
    —— 4-[(2R)-2-phenylsulfanylpropanoyl]piperazine-1-carbaldehyde —— C14H18N2O2S
    4-[(2R)-2-phenylsulfanylpropanoyl]piperazine-1-carbaldehyde
    —— (3S)-1-(5-fluoro-2-methoxyphenyl)sulfonyl-N-(2-phenylsulfanylphenyl)piperidine-3-carboxamide —— C25H25FN2O4S2
    (3S)-1-(5-fluoro-2-methoxyphenyl)sulfonyl-N-(2-phenylsulfanylphenyl)piperidine-3-carboxamide
    —— (3-nitropyridin-2-yl) (2S,6S)-2,6-dimethylpiperidine-1-carbodithioate —— C13H17N3O2S2
    (3-nitropyridin-2-yl) (2S,6S)-2,6-dimethylpiperidine-1-carbodithioate