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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— S-(1H-1,2,4-triazol-5-yl) N-[(Z)-benzylideneamino]carbamothioate —— C10H9N5OS
    S-(1H-1,2,4-triazol-5-yl) N-[(Z)-benzylideneamino]carbamothioate
    —— N-[1-[4-[4-[(Z)-N-(2,4-dinitroanilino)-C-methylcarbonimidoyl]phenyl]sulfanylphenyl]ethylideneamino]-2,4-dinitroaniline —— C28H22N8O8S
    N-[1-[4-[4-[(Z)-N-(2,4-dinitroanilino)-C-methylcarbonimidoyl]phenyl]sulfanylphenyl]ethylideneamino]-2,4-dinitroaniline
    —— (E)-[(3E)-3-hydrazinylidene-1,4-bis(methylsulfonyl)butan-2-ylidene]hydrazine —— C6H14N4O4S2
    (E)-[(3E)-3-hydrazinylidene-1,4-bis(methylsulfonyl)butan-2-ylidene]hydrazine
    —— [(1R)-3-formyl-2,4,4-trimethylcyclohex-2-en-1-yl] (3Z)-4-phenylsulfanylhexa-3,5-dienoate —— C22H26O3S
    [(1R)-3-formyl-2,4,4-trimethylcyclohex-2-en-1-yl] (3Z)-4-phenylsulfanylhexa-3,5-dienoate
    —— dimethyl (E)-2-(3-amino-5,6-dichloropyrazin-2-yl)sulfanylbut-2-enedioate —— C10H9Cl2N3O4S
    dimethyl (E)-2-(3-amino-5,6-dichloropyrazin-2-yl)sulfanylbut-2-enedioate
    —— dimethyl (E)-2-(3-amino-5,6-dichloropyrazin-2-yl)sulfanylbut-2-enedioate;methyl 2-(6,7-dichloro-3-oxo-5H-pyrazino[2,3-b][1,4]thiazin-2-ylidene)acetate —— C19H14Cl4N6O7S2
    dimethyl (E)-2-(3-amino-5,6-dichloropyrazin-2-yl)sulfanylbut-2-enedioate;methyl 2-(6,7-dichloro-3-oxo-5H-pyrazino[2,3-b][1,4]thiazin-2-ylidene)acetate
    —— N-[(Z)-2-nitroso-1,2-bis(pyridin-2-ylsulfanyl)ethenyl]hydroxylamine —— C12H10N4O2S2
    N-[(Z)-2-nitroso-1,2-bis(pyridin-2-ylsulfanyl)ethenyl]hydroxylamine
    —— Allylschwefel 16812-21-8 C3H5S
    Allylschwefel
    —— 1-[(Z)-2-butylsulfinylethenyl]sulfinylbutane —— C10H20O2S2
    1-[(Z)-2-butylsulfinylethenyl]sulfinylbutane
    —— (E)-3-(4-chlorophenyl)sulfanylprop-2-enoic acid —— C18H14Cl2O4S2
    (E)-3-(4-chlorophenyl)sulfanylprop-2-enoic acid
    —— [(3S)-1-[(2-methylsulfanylpyrimidin-5-yl)methyl]piperidin-3-yl]-(3-methylthiophen-2-yl)methanone —— C17H21N3OS2
    [(3S)-1-[(2-methylsulfanylpyrimidin-5-yl)methyl]piperidin-3-yl]-(3-methylthiophen-2-yl)methanone
    —— [(3R)-1-[(2-methylsulfanylpyrimidin-5-yl)methyl]piperidin-3-yl]-(3-methylthiophen-2-yl)methanone —— C17H21N3OS2
    [(3R)-1-[(2-methylsulfanylpyrimidin-5-yl)methyl]piperidin-3-yl]-(3-methylthiophen-2-yl)methanone
    —— (6E)-6-(nitrosomethylidene)-5H-pyrimido[4,5-b][1,4]thiazine-2,4-diamine —— C7H8N6OS
    (6E)-6-(nitrosomethylidene)-5H-pyrimido[4,5-b][1,4]thiazine-2,4-diamine
    —— dibutoxy-[(E)-2-phenylsulfanylethenyl]borane —— C16H25BO2S
    dibutoxy-[(E)-2-phenylsulfanylethenyl]borane
    —— 1, 1,1,2,3,4-Pentachloro-4-[(1-methylethyl)sulfonyl]- —— C7H7Cl5O2S
    1, 1,1,2,3,4-Pentachloro-4-[(1-methylethyl)sulfonyl]-
    —— [(Z)-1-(2-methyl-4-methylsulfanylphenyl)ethylideneamino]urea —— C11H15N3OS
    [(Z)-1-(2-methyl-4-methylsulfanylphenyl)ethylideneamino]urea
    —— [(E)-4-bromo-2,3,3-trifluorobut-1-enyl] carbamimidothioate —— C5H6BrF3N2S
    [(E)-4-bromo-2,3,3-trifluorobut-1-enyl] carbamimidothioate
    —— (3,4-Dimethyl-5-oxo-2,5-dihydro-1H-pyrrol-2-yl)-[4,4-dimethyl-5-(2,3,3-trimethyl-5-methylthio-3,4-dihydro-2H-pyrrol-2-ylmethylene)pyrrolidin-2-ylene]-thioacetic acid, S-(tert.-butyl) ester —— C27H41N3O2S2
    (3,4-Dimethyl-5-oxo-2,5-dihydro-1H-pyrrol-2-yl)-[4,4-dimethyl-5-(2,3,3-trimethyl-5-methylthio-3,4-dihydro-2H-pyrrol-2-ylmethylene)pyrrolidin-2-ylene]-thioacetic acid, S-(tert.-butyl) ester
    —— (2R)-1-ethylsulfonylpropan-2-amine —— C5H13NO2S
    (2R)-1-ethylsulfonylpropan-2-amine
    —— 1-Pyrroline, 2-[5-(3,3-dimethyl-1-pyrrolin-2-ylmethylene)-3,3-dimethyl-pyrrolidin-2-ylidenemethyl]-4,4-dimethyl-5-(4,4,5-trimethyl-5-cyano-1-pirrolin-2-ylthiomethylene —— C29H41N5S
    1-Pyrroline, 2-[5-(3,3-dimethyl-1-pyrrolin-2-ylmethylene)-3,3-dimethyl-pyrrolidin-2-ylidenemethyl]-4,4-dimethyl-5-(4,4,5-trimethyl-5-cyano-1-pirrolin-2-ylthiomethylene
    —— (2S)-1-ethylsulfonylpropan-2-amine —— C5H13NO2S
    (2S)-1-ethylsulfonylpropan-2-amine
    —— 4H-1,3-Dithiin, 2,2,6-trimethyl-4-(2,2,6-trimethyl-4H-1,3-dithiin-4-ylidene)- —— C14H20S4
    4H-1,3-Dithiin, 2,2,6-trimethyl-4-(2,2,6-trimethyl-4H-1,3-dithiin-4-ylidene)-
    —— 2,2-dimethyl-N-[(1S)-2,2,2-trichloro-1-[2-[(1R)-2,2,2-trichloro-1-(2,2-dimethylpropanoylamino)ethyl]sulfanylpyrimidin-4-yl]sulfanylethyl]propanamide —— C18H24Cl6N4O2S2
    2,2-dimethyl-N-[(1S)-2,2,2-trichloro-1-[2-[(1R)-2,2,2-trichloro-1-(2,2-dimethylpropanoylamino)ethyl]sulfanylpyrimidin-4-yl]sulfanylethyl]propanamide
    —— 2,2-dimethyl-N-[(1R)-2,2,2-trichloro-1-[2-[(1S)-2,2,2-trichloro-1-(2,2-dimethylpropanoylamino)ethyl]sulfanylpyrimidin-4-yl]sulfanylethyl]propanamide —— C18H24Cl6N4O2S2
    2,2-dimethyl-N-[(1R)-2,2,2-trichloro-1-[2-[(1S)-2,2,2-trichloro-1-(2,2-dimethylpropanoylamino)ethyl]sulfanylpyrimidin-4-yl]sulfanylethyl]propanamide
    —— 2,2-dimethyl-N-[(1R)-2,2,2-trichloro-1-[2-[(1R)-2,2,2-trichloro-1-(2,2-dimethylpropanoylamino)ethyl]sulfanylpyrimidin-4-yl]sulfanylethyl]propanamide —— C18H24Cl6N4O2S2
    2,2-dimethyl-N-[(1R)-2,2,2-trichloro-1-[2-[(1R)-2,2,2-trichloro-1-(2,2-dimethylpropanoylamino)ethyl]sulfanylpyrimidin-4-yl]sulfanylethyl]propanamide
    —— (6R,7R)-7-(4-methylphenyl)spiro[5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6,3'-oxolane]-2,2',5'-trione —— C16H13NO4S2
    (6R,7R)-7-(4-methylphenyl)spiro[5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6,3'-oxolane]-2,2',5'-trione
    —— 2,2-dimethyl-N-[(1S)-2,2,2-trichloro-1-[2-[(1S)-2,2,2-trichloro-1-(2,2-dimethylpropanoylamino)ethyl]sulfanylpyrimidin-4-yl]sulfanylethyl]propanamide —— C18H24Cl6N4O2S2
    2,2-dimethyl-N-[(1S)-2,2,2-trichloro-1-[2-[(1S)-2,2,2-trichloro-1-(2,2-dimethylpropanoylamino)ethyl]sulfanylpyrimidin-4-yl]sulfanylethyl]propanamide
    —— S-(1,1,2,3,3,3-Hexafluoro-propyl)-N-[2-(1,1,2,3,3,3-hexafluoro-propylsulfanyl)-1-methyl-vinyl]-n-propyl-thiohydroxylamine —— C12H13F12NS2
    S-(1,1,2,3,3,3-Hexafluoro-propyl)-N-[2-(1,1,2,3,3,3-hexafluoro-propylsulfanyl)-1-methyl-vinyl]-n-propyl-thiohydroxylamine
    —— (6S,7R)-1'-benzyl-7-(3,5-dibromo-2-hydroxyphenyl)spiro[5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6,3'-pyrrolidine]-2,2',5'-trione —— C22H16Br2N2O4S2
    (6S,7R)-1'-benzyl-7-(3,5-dibromo-2-hydroxyphenyl)spiro[5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6,3'-pyrrolidine]-2,2',5'-trione
    —— (6S,7S)-1'-benzyl-7-(3,5-dibromo-2-hydroxyphenyl)spiro[5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6,3'-pyrrolidine]-2,2',5'-trione —— C22H16Br2N2O4S2
    (6S,7S)-1'-benzyl-7-(3,5-dibromo-2-hydroxyphenyl)spiro[5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6,3'-pyrrolidine]-2,2',5'-trione
    —— (6S,7S)-7-(4-methylphenyl)spiro[5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6,3'-oxolane]-2,2',5'-trione —— C16H13NO4S2
    (6S,7S)-7-(4-methylphenyl)spiro[5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6,3'-oxolane]-2,2',5'-trione
    —— [4,4-Dimethyl-5-(2,3,3-trimethyl-5-methylthio-3,4(2H)-dihydropyrrol-2-ylmethylene)pyrrolidin-2-ylidene]thioacetic acid, S-tert.-butyl ester —— C21H34N2OS2
    [4,4-Dimethyl-5-(2,3,3-trimethyl-5-methylthio-3,4(2H)-dihydropyrrol-2-ylmethylene)pyrrolidin-2-ylidene]thioacetic acid, S-tert.-butyl ester
    —— Propenoic acid, 2-cyano-3-(1-methyl-5-phenylthio-2-pyrrolyl)-, methyl ester —— C16H14N2O2S
    Propenoic acid, 2-cyano-3-(1-methyl-5-phenylthio-2-pyrrolyl)-, methyl ester
    —— (6R,7S)-1'-benzyl-7-(3,5-dibromo-2-hydroxyphenyl)spiro[5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6,3'-pyrrolidine]-2,2',5'-trione —— C22H16Br2N2O4S2
    (6R,7S)-1'-benzyl-7-(3,5-dibromo-2-hydroxyphenyl)spiro[5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6,3'-pyrrolidine]-2,2',5'-trione
    —— (6R,7S)-7-(4-methylphenyl)spiro[5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6,3'-oxolane]-2,2',5'-trione —— C16H13NO4S2
    (6R,7S)-7-(4-methylphenyl)spiro[5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6,3'-oxolane]-2,2',5'-trione
    —— (6R,7R)-1'-benzyl-7-(3,5-dibromo-2-hydroxyphenyl)spiro[5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6,3'-pyrrolidine]-2,2',5'-trione —— C22H16Br2N2O4S2
    (6R,7R)-1'-benzyl-7-(3,5-dibromo-2-hydroxyphenyl)spiro[5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6,3'-pyrrolidine]-2,2',5'-trione
    —— (6S,7R)-7-(4-methylphenyl)spiro[5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6,3'-oxolane]-2,2',5'-trione —— C16H13NO4S2
    (6S,7R)-7-(4-methylphenyl)spiro[5,7-dihydro-3H-thiopyrano[2,3-d][1,3]thiazole-6,3'-oxolane]-2,2',5'-trione
    —— (2R)-2-nonylsulfonylpropanoic acid —— C12H24O4S
    (2R)-2-nonylsulfonylpropanoic acid
    —— (2S)-2-nonylsulfonylpropanoic acid —— C12H24O4S
    (2S)-2-nonylsulfonylpropanoic acid
    —— (NE)-N-(1-chloro-6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophen-4-ylidene)hydroxylamine —— C11H14ClNOS2
    (NE)-N-(1-chloro-6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophen-4-ylidene)hydroxylamine
    —— 7-(dimethylamino)-14-methyl-2-thia-4,6,9,12,13-pentazatricyclo[8.4.0.03,8]tetradeca-1(14),3,5,7,9-pentaen-11-one —— C11H12N6OS
    7-(dimethylamino)-14-methyl-2-thia-4,6,9,12,13-pentazatricyclo[8.4.0.03,8]tetradeca-1(14),3,5,7,9-pentaen-11-one
    —— (8E)-4-imino-8-(4-methyl-1,2,5-oxadiazol-3-ylidene)-[1,3,5]triazino[2,1-b][1,3,4]thiadiazin-2-amine —— C8H8N8OS
    (8E)-4-imino-8-(4-methyl-1,2,5-oxadiazol-3-ylidene)-[1,3,5]triazino[2,1-b][1,3,4]thiadiazin-2-amine
    —— 2-(N-Phenylaminomethylen)-3(2H)-benzothiophenthion 55136-27-1 C15H11NS2
    2-(N-Phenylaminomethylen)-3(2H)-benzothiophenthion
    —— 4-(methoxymethyl)-6-methyl-2-[(2Z)-2-[(4-methylsulfanylphenyl)methylidene]hydrazinyl]pyridine-3-carbonitrile —— C17H18N4OS
    4-(methoxymethyl)-6-methyl-2-[(2Z)-2-[(4-methylsulfanylphenyl)methylidene]hydrazinyl]pyridine-3-carbonitrile
    —— Benzothiophen-3(2H)-one, 2-(4-fluorobenzylidene)- —— C15H9FOS
    Benzothiophen-3(2H)-one, 2-(4-fluorobenzylidene)-
    —— 3,3-Dimethylpyrrolidin-5-ylidineacetic acid, 2-[3,4(2H)dihydro-5-(methylthio)-2,3,3-trimethylpyrrol-2-yl]methylene-, t-butyl ester —— C21H34N2O2S
    3,3-Dimethylpyrrolidin-5-ylidineacetic acid, 2-[3,4(2H)dihydro-5-(methylthio)-2,3,3-trimethylpyrrol-2-yl]methylene-, t-butyl ester
    —— (5R)-2-[(2E)-2-[(4-bromophenyl)methylidene]hydrazinyl]-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-1,3-thiazol-4-one —— C18H14BrF2N3OS2
    (5R)-2-[(2E)-2-[(4-bromophenyl)methylidene]hydrazinyl]-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-1,3-thiazol-4-one
    —— 1-Pyrroline, 2-methylthio-4,4,5-trimethyl-5-[(2-methylthio-4,4,-dimethyl-1-pyrrolinidenyl-5)methylene]- —— C16H26N2S2
    1-Pyrroline, 2-methylthio-4,4,5-trimethyl-5-[(2-methylthio-4,4,-dimethyl-1-pyrrolinidenyl-5)methylene]-
    —— [4,4-Dimethyl-5-(2,3,3-trimethyl-5-methylthio-5-pyrrolin-2-ylmethylene)-5-pyrrolin-2-ylthio]acetic acid, tert.-butyl ester —— C21H34N2O2S2
    [4,4-Dimethyl-5-(2,3,3-trimethyl-5-methylthio-5-pyrrolin-2-ylmethylene)-5-pyrrolin-2-ylthio]acetic acid, tert.-butyl ester
    —— 2,3,3-Trimethyl-5-methylthio-2-[5-allylthio-3,3-dimethyl-3,4(2H)-dihydro-2-pyrrolylidenemethyl]-3,4(2H)-dihydropyrrole —— C18H28N2S2
    2,3,3-Trimethyl-5-methylthio-2-[5-allylthio-3,3-dimethyl-3,4(2H)-dihydro-2-pyrrolylidenemethyl]-3,4(2H)-dihydropyrrole