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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (4S)-4-hydroxy-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]-4-phenylbutanamide —— C18H20N2O2S
    (4S)-4-hydroxy-N-[(E)-(4-methylsulfanylphenyl)methylideneamino]-4-phenylbutanamide
    —— N'-[(E)-(4-methylsulfanylphenyl)methylideneamino]-N-(pyridin-3-ylmethyl)propanediamide —— C17H18N4O2S
    N'-[(E)-(4-methylsulfanylphenyl)methylideneamino]-N-(pyridin-3-ylmethyl)propanediamide
    —— 1-[(Z)-[(E)-2-methylbut-2-enylidene]amino]-3-[(E)-[(E)-2-methylbut-2-enylidene]amino]thiourea —— C11H18N4S
    1-[(Z)-[(E)-2-methylbut-2-enylidene]amino]-3-[(E)-[(E)-2-methylbut-2-enylidene]amino]thiourea
    —— methyl (4Z)-2-methyl-1-[(4-methylphenyl)methyl]-4-[(4-methylsulfanylphenyl)methylidene]-5-oxopyrrole-3-carboxylate —— C23H23NO3S
    methyl (4Z)-2-methyl-1-[(4-methylphenyl)methyl]-4-[(4-methylsulfanylphenyl)methylidene]-5-oxopyrrole-3-carboxylate
    —— N-[(Z)-[5-(4-bromophenyl)furan-2-yl]methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide —— C19H14BrClN2O2S
    N-[(Z)-[5-(4-bromophenyl)furan-2-yl]methylideneamino]-2-(4-chlorophenyl)sulfanylacetamide
    —— (R)-3-((4-tolyl)thio)dihydrofuran-2(3H)-one —— C11H12O2S
    (R)-3-((4-tolyl)thio)dihydrofuran-2(3H)-one
    —— 1-[1-[(2R)-1-methoxypropan-2-yl]-2,5-dimethylpyrrol-3-yl]-2-(4-methylphenyl)sulfanylethanone —— C19H25NO2S
    1-[1-[(2R)-1-methoxypropan-2-yl]-2,5-dimethylpyrrol-3-yl]-2-(4-methylphenyl)sulfanylethanone
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-2-(4-methylphenyl)sulfanyl-N-propylacetamide —— C16H23NO3S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-2-(4-methylphenyl)sulfanyl-N-propylacetamide
    —— N-[(3R)-3-methyl-1,1-dioxothiolan-3-yl]-3-phenylsulfanylpropanamide —— C14H19NO3S2
    N-[(3R)-3-methyl-1,1-dioxothiolan-3-yl]-3-phenylsulfanylpropanamide
    —— [(2S)-oxolan-2-yl]methyl 2-(4-methylphenyl)sulfanylacetate —— C14H18O3S
    [(2S)-oxolan-2-yl]methyl 2-(4-methylphenyl)sulfanylacetate
    —— [(2S)-oxolan-2-yl]methyl 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C15H19N3O4S
    [(2S)-oxolan-2-yl]methyl 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-propan-2-yloxyethyl 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate —— C15H21N3O4S
    2-propan-2-yloxyethyl 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetate
    —— 2-[(R)-ethylsulfinyl]-N-methylethanamine —— C5H13NOS
    2-[(R)-ethylsulfinyl]-N-methylethanamine
    —— 2-[(S)-ethylsulfinyl]-N-methylethanamine —— C5H13NOS
    2-[(S)-ethylsulfinyl]-N-methylethanamine
    —— N-methyl-2-[(R)-methylsulfinyl]ethanamine —— C4H11NOS
    N-methyl-2-[(R)-methylsulfinyl]ethanamine
    —— (1S)-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-1-thiophen-2-ylpropan-1-ol —— C10H12N2OS3
    (1S)-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-1-thiophen-2-ylpropan-1-ol
    —— N-methyl-2-[(S)-methylsulfinyl]ethanamine —— C4H11NOS
    N-methyl-2-[(S)-methylsulfinyl]ethanamine
    —— (1S)-3-(1-methylimidazol-2-yl)sulfanyl-1-thiophen-2-ylpropan-1-ol —— C11H14N2OS2
    (1S)-3-(1-methylimidazol-2-yl)sulfanyl-1-thiophen-2-ylpropan-1-ol
    —— (1R)-1-phenyl-3-pyrimidin-2-ylsulfanylpropan-1-ol —— C13H14N2OS
    (1R)-1-phenyl-3-pyrimidin-2-ylsulfanylpropan-1-ol
    —— (1R)-3-(1-methylimidazol-2-yl)sulfanyl-1-phenylpropan-1-ol —— C13H16N2OS
    (1R)-3-(1-methylimidazol-2-yl)sulfanyl-1-phenylpropan-1-ol
    —— (1R)-3-pyridin-2-ylsulfanyl-1-thiophen-2-ylpropan-1-ol —— C12H13NOS2
    (1R)-3-pyridin-2-ylsulfanyl-1-thiophen-2-ylpropan-1-ol
    —— (1S)-3-[(4-ethyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-thiophen-2-ylpropan-1-ol —— C12H17N3OS2
    (1S)-3-[(4-ethyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-thiophen-2-ylpropan-1-ol
    —— (1R)-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-1-phenylpropan-1-ol —— C12H14N2OS2
    (1R)-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-1-phenylpropan-1-ol
    —— 3-[(5-Methyl-1,3,4-thiadiazol-2-yl)thio]-1-(2-thienyl)propan-1-one —— C10H10N2OS3
    3-[(5-Methyl-1,3,4-thiadiazol-2-yl)thio]-1-(2-thienyl)propan-1-one
    —— 3-[(4-ethyl-5-methyl-4H-1,2,4-triazol-3-yl)thio]-1-(2-thienyl)propan-1-one —— C12H15N3OS2
    3-[(4-ethyl-5-methyl-4H-1,2,4-triazol-3-yl)thio]-1-(2-thienyl)propan-1-one
    —— (1S)-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-1-phenylpropan-1-ol —— C12H14N2OS2
    (1S)-3-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-1-phenylpropan-1-ol
    —— (1S)-3-(1-methylimidazol-2-yl)sulfanyl-1-phenylpropan-1-ol —— C13H16N2OS
    (1S)-3-(1-methylimidazol-2-yl)sulfanyl-1-phenylpropan-1-ol
    —— (1R)-3-phenylsulfanyl-1-thiophen-2-ylpropan-1-ol —— C13H14OS2
    (1R)-3-phenylsulfanyl-1-thiophen-2-ylpropan-1-ol
    —— 4-[(4-chlorophenyl)thio]-N-cyclopropyl-6-methylpyrimidin-2-amine —— C14H14ClN3S
    4-[(4-chlorophenyl)thio]-N-cyclopropyl-6-methylpyrimidin-2-amine
    —— (1S)-3-pyrimidin-2-ylsulfanyl-1-thiophen-2-ylpropan-1-ol —— C11H12N2OS2
    (1S)-3-pyrimidin-2-ylsulfanyl-1-thiophen-2-ylpropan-1-ol
    —— 3-[(1-methyl-1H-imidazol-2-yl)thio]-1-(2-thienyl)propan-1-one —— C11H12N2OS2
    3-[(1-methyl-1H-imidazol-2-yl)thio]-1-(2-thienyl)propan-1-one
    —— N-cyclopropyl-4-methyl-6-(phenylthio)pyrimidin-2-amine —— C14H15N3S
    N-cyclopropyl-4-methyl-6-(phenylthio)pyrimidin-2-amine
    —— (1R)-3-[(4-ethyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-phenylpropan-1-ol —— C14H19N3OS
    (1R)-3-[(4-ethyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-phenylpropan-1-ol
    —— (1R)-1-phenyl-3-pyridin-2-ylsulfanylpropan-1-ol —— C14H15NOS
    (1R)-1-phenyl-3-pyridin-2-ylsulfanylpropan-1-ol
    —— (1R)-3-(1-methylimidazol-2-yl)sulfanyl-1-thiophen-2-ylpropan-1-ol —— C11H14N2OS2
    (1R)-3-(1-methylimidazol-2-yl)sulfanyl-1-thiophen-2-ylpropan-1-ol
    —— 2-({4-[(4-Chlorophenyl)thio]-6-methylpyrimidin-2-yl}amino)ethanol —— C13H14ClN3OS
    2-({4-[(4-Chlorophenyl)thio]-6-methylpyrimidin-2-yl}amino)ethanol
    —— (1R)-3-[(4-ethyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-thiophen-2-ylpropan-1-ol —— C12H17N3OS2
    (1R)-3-[(4-ethyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-thiophen-2-ylpropan-1-ol
    —— 2-{[4-Methyl-6-(phenylthio)pyrimidin-2-yl]amino}ethanol —— C13H15N3OS
    2-{[4-Methyl-6-(phenylthio)pyrimidin-2-yl]amino}ethanol
    —— 2-[(4-Methoxy-6-methylpyrimidin-2-yl)thio]ethanol —— C8H12N2O2S
    2-[(4-Methoxy-6-methylpyrimidin-2-yl)thio]ethanol
    —— (1S)-3-pyridin-2-ylsulfanyl-1-thiophen-2-ylpropan-1-ol —— C12H13NOS2
    (1S)-3-pyridin-2-ylsulfanyl-1-thiophen-2-ylpropan-1-ol
    —— 3-(Pyrimidin-2-ylthio)-1-(2-thienyl)propan-1-one —— C11H10N2OS2
    3-(Pyrimidin-2-ylthio)-1-(2-thienyl)propan-1-one
    —— (1S)-1-phenyl-3-pyridin-2-ylsulfanylpropan-1-ol —— C14H15NOS
    (1S)-1-phenyl-3-pyridin-2-ylsulfanylpropan-1-ol
    —— N-cyclopropyl-4-methyl-6-[(4-methylphenyl)thio]pyrimidin-2-amine —— C15H17N3S
    N-cyclopropyl-4-methyl-6-[(4-methylphenyl)thio]pyrimidin-2-amine
    —— (1S)-3-[(4-ethyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-phenylpropan-1-ol —— C14H19N3OS
    (1S)-3-[(4-ethyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-1-phenylpropan-1-ol
    —— (1S)-3-phenylsulfanyl-1-thiophen-2-ylpropan-1-ol —— C13H14OS2
    (1S)-3-phenylsulfanyl-1-thiophen-2-ylpropan-1-ol
    —— (1S)-1-phenyl-3-pyrimidin-2-ylsulfanylpropan-1-ol —— C13H14N2OS
    (1S)-1-phenyl-3-pyrimidin-2-ylsulfanylpropan-1-ol
    —— 2-[(4-Ethoxy-6-methylpyrimidin-2-yl)thio]ethanol —— C9H14N2O2S
    2-[(4-Ethoxy-6-methylpyrimidin-2-yl)thio]ethanol
    —— 2-{[4-(Phenylthio)pyrimidin-2-yl]amino}ethanol —— C12H13N3OS
    2-{[4-(Phenylthio)pyrimidin-2-yl]amino}ethanol
    —— 2-({4-Methyl-6-[(4-methylphenyl)thio]pyrimidin-2-yl}amino)ethanol —— C14H17N3OS
    2-({4-Methyl-6-[(4-methylphenyl)thio]pyrimidin-2-yl}amino)ethanol
    —— N-cyclopropyl-4-(phenylthio)pyrimidin-2-amine —— C13H13N3S
    N-cyclopropyl-4-(phenylthio)pyrimidin-2-amine