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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(2S)-1-hydroxybutan-2-yl]-2-(4-methylphenyl)sulfanylacetamide —— C13H19NO2S
    N-[(2S)-1-hydroxybutan-2-yl]-2-(4-methylphenyl)sulfanylacetamide
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-(3-hydroxypropyl)propanamide —— C12H16ClNO2S
    (2R)-2-(4-chlorophenyl)sulfanyl-N-(3-hydroxypropyl)propanamide
    —— (2S)-2-(4-chlorophenyl)sulfanyl-N-[(E)-pyridin-3-ylmethylideneamino]propanamide —— C15H14ClN3OS
    (2S)-2-(4-chlorophenyl)sulfanyl-N-[(E)-pyridin-3-ylmethylideneamino]propanamide
    —— 1-cycloheptyl-3-[(2R)-2-ethylhexyl]thiourea —— C16H32N2S
    1-cycloheptyl-3-[(2R)-2-ethylhexyl]thiourea
    —— 1-[(2S)-butan-2-yl]-3-[(1R,2S)-2-methylcyclohexyl]thiourea —— C12H24N2S
    1-[(2S)-butan-2-yl]-3-[(1R,2S)-2-methylcyclohexyl]thiourea
    —— 1-[(2R)-butan-2-yl]-3-[(1S,2S)-2-methylcyclohexyl]thiourea —— C12H24N2S
    1-[(2R)-butan-2-yl]-3-[(1S,2S)-2-methylcyclohexyl]thiourea
    —— 1-cycloheptyl-3-[(1R,2S)-2-methylcyclohexyl]thiourea —— C15H28N2S
    1-cycloheptyl-3-[(1R,2S)-2-methylcyclohexyl]thiourea
    —— 2-(1-methylimidazol-2-yl)sulfanyl-N-[(3S)-2-methyl-4-oxopentan-3-yl]acetamide —— C12H19N3O2S
    2-(1-methylimidazol-2-yl)sulfanyl-N-[(3S)-2-methyl-4-oxopentan-3-yl]acetamide
    —— (2S)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)butanoic acid —— C11H17N3O2S
    (2S)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-ylsulfanyl)butanoic acid
    —— (4R)-N-[2-(difluoromethylsulfanyl)phenyl]-4-ethyl-4,5-dihydro-1,3-thiazol-2-amine —— C12H14F2N2S2
    (4R)-N-[2-(difluoromethylsulfanyl)phenyl]-4-ethyl-4,5-dihydro-1,3-thiazol-2-amine
    —— (2R)-2-(1,3,4-thiadiazol-2-ylsulfanyl)butanoic acid —— C6H8N2O2S2
    (2R)-2-(1,3,4-thiadiazol-2-ylsulfanyl)butanoic acid
    —— 2-(2-chlorophenyl)sulfanyl-N-[(3R)-2-methyl-4-oxopentan-3-yl]acetamide —— C14H18ClNO2S
    2-(2-chlorophenyl)sulfanyl-N-[(3R)-2-methyl-4-oxopentan-3-yl]acetamide
    —— (2S)-2-[(4-oxo-6-propyl-1H-pyrimidin-2-yl)sulfanyl]butanoic acid —— C11H16N2O3S
    (2S)-2-[(4-oxo-6-propyl-1H-pyrimidin-2-yl)sulfanyl]butanoic acid
    —— (2R)-2-[(4-oxo-6-propyl-1H-pyrimidin-2-yl)sulfanyl]butanoic acid —— C11H16N2O3S
    (2R)-2-[(4-oxo-6-propyl-1H-pyrimidin-2-yl)sulfanyl]butanoic acid
    —— (8S,8aR)-6-amino-2-ethyl-8-(4-methylthiophenyl)-1,2,3,7,8,8a-hexahydroisoquino line-5,7,7-tricarbonitrile —— C21H21N5S
    (8S,8aR)-6-amino-2-ethyl-8-(4-methylthiophenyl)-1,2,3,7,8,8a-hexahydroisoquino line-5,7,7-tricarbonitrile
    —— 2-methylsulfanyl-N-[(1R)-1-phenylethyl]aniline —— C15H17NS
    2-methylsulfanyl-N-[(1R)-1-phenylethyl]aniline
    —— [(2S)-5-(diethylamino)pentan-2-yl]thiourea —— C10H23N3S
    [(2S)-5-(diethylamino)pentan-2-yl]thiourea
    —— [(2R)-5-(diethylamino)pentan-2-yl]thiourea —— C10H23N3S
    [(2R)-5-(diethylamino)pentan-2-yl]thiourea
    —— (2R)-2-(ethylamino)-2-(4-methylsulfanylphenyl)acetonitrile —— C11H14N2S
    (2R)-2-(ethylamino)-2-(4-methylsulfanylphenyl)acetonitrile
    —— (2R)-2-[(3S)-3-methylpiperidin-1-yl]-2-(4-methylsulfanylphenyl)ethanamine —— C15H24N2S
    (2R)-2-[(3S)-3-methylpiperidin-1-yl]-2-(4-methylsulfanylphenyl)ethanamine
    —— (2S)-2-(ethylamino)-2-(4-methylsulfanylphenyl)acetonitrile —— C11H14N2S
    (2S)-2-(ethylamino)-2-(4-methylsulfanylphenyl)acetonitrile
    —— (2R)-2-(4-methylsulfanylphenyl)-2-piperazin-1-ylacetonitrile —— C13H17N3S
    (2R)-2-(4-methylsulfanylphenyl)-2-piperazin-1-ylacetonitrile
    —— (2R)-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-2-phenylacetic acid —— C12H10N2O3S
    (2R)-2-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-2-phenylacetic acid
    —— 6-amino-2-[(2R)-butan-2-yl]sulfanyl-1H-pyrimidin-4-one —— C8H13N3OS
    6-amino-2-[(2R)-butan-2-yl]sulfanyl-1H-pyrimidin-4-one
    —— [(1R,2S)-2-methylcyclohexyl]thiourea —— C8H16N2S
    [(1R,2S)-2-methylcyclohexyl]thiourea
    —— [(1R,2R)-2-methylcyclohexyl]thiourea —— C8H16N2S
    [(1R,2R)-2-methylcyclohexyl]thiourea
    —— (1R)-N,N-dimethyl-1-(4-methylsulfanylphenyl)ethane-1,2-diamine —— C11H18N2S
    (1R)-N,N-dimethyl-1-(4-methylsulfanylphenyl)ethane-1,2-diamine
    —— (1S)-N-cyclohexyl-N-methyl-1-(4-methylsulfanylphenyl)ethane-1,2-diamine —— C16H26N2S
    (1S)-N-cyclohexyl-N-methyl-1-(4-methylsulfanylphenyl)ethane-1,2-diamine
    —— (2R)-2-(4-methylpiperidin-1-yl)-2-(4-methylsulfanylphenyl)ethanamine —— C15H24N2S
    (2R)-2-(4-methylpiperidin-1-yl)-2-(4-methylsulfanylphenyl)ethanamine
    —— (1S)-N-methyl-1-(4-methylsulfanylphenyl)-N-phenylethane-1,2-diamine —— C16H20N2S
    (1S)-N-methyl-1-(4-methylsulfanylphenyl)-N-phenylethane-1,2-diamine
    —— (1S)-N,N-diethyl-1-(4-methylsulfanylphenyl)ethane-1,2-diamine —— C13H22N2S
    (1S)-N,N-diethyl-1-(4-methylsulfanylphenyl)ethane-1,2-diamine
    —— (1R)-N-methyl-1-(4-methylsulfanylphenyl)-N-propan-2-ylethane-1,2-diamine —— C13H22N2S
    (1R)-N-methyl-1-(4-methylsulfanylphenyl)-N-propan-2-ylethane-1,2-diamine
    —— (2R)-2-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-(4-methylsulfanylphenyl)ethanamine —— C15H24N2OS
    (2R)-2-[(2R,6R)-2,6-dimethylmorpholin-4-yl]-2-(4-methylsulfanylphenyl)ethanamine
    —— (2R)-2-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-2-(4-methylsulfanylphenyl)ethanamine —— C15H24N2OS
    (2R)-2-[(2R,6S)-2,6-dimethylmorpholin-4-yl]-2-(4-methylsulfanylphenyl)ethanamine
    —— (2R)-2-[(3S,5S)-3,5-dimethylpiperidin-1-yl]-2-(4-methylsulfanylphenyl)ethanamine —— C16H26N2S
    (2R)-2-[(3S,5S)-3,5-dimethylpiperidin-1-yl]-2-(4-methylsulfanylphenyl)ethanamine
    —— (1R)-N-cyclohexyl-N-methyl-1-(4-methylsulfanylphenyl)ethane-1,2-diamine —— C16H26N2S
    (1R)-N-cyclohexyl-N-methyl-1-(4-methylsulfanylphenyl)ethane-1,2-diamine
    —— (2S)-2-(4-methylpiperidin-1-yl)-2-(4-methylsulfanylphenyl)ethanamine —— C15H24N2S
    (2S)-2-(4-methylpiperidin-1-yl)-2-(4-methylsulfanylphenyl)ethanamine
    —— (2R)-2-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-(4-methylsulfanylphenyl)ethanamine —— C15H24N2OS
    (2R)-2-[(2S,6S)-2,6-dimethylmorpholin-4-yl]-2-(4-methylsulfanylphenyl)ethanamine
    —— 2-[[5-[(1S)-1-(4-methylanilino)ethyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetohydrazide —— C16H22N6OS
    2-[[5-[(1S)-1-(4-methylanilino)ethyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetohydrazide
    —— (2E)-2-[(pyridin-4-ylmethylamino)methylidene]-1-benzothiophen-3-one —— C15H12N2OS
    (2E)-2-[(pyridin-4-ylmethylamino)methylidene]-1-benzothiophen-3-one
    —— [Amino-(4-methylsulfanylphenyl)methylidene]azanium —— C8H11N2S+
    [Amino-(4-methylsulfanylphenyl)methylidene]azanium
    —— [1-Amino-2-(4-methylsulfanylphenyl)ethylidene]azanium —— C9H13N2S+
    [1-Amino-2-(4-methylsulfanylphenyl)ethylidene]azanium
    —— [Amino-[2-[amino(azaniumylidene)methyl]-3-phenylsulfanylphenyl]methylidene]azanium —— C14H16N4S+2
    [Amino-[2-[amino(azaniumylidene)methyl]-3-phenylsulfanylphenyl]methylidene]azanium
    —— (NE)-N-[1-(4-chlorophenyl)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]ethylidene]hydroxylamine —— C11H11ClN4OS
    (NE)-N-[1-(4-chlorophenyl)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]ethylidene]hydroxylamine
    —— (Z)-1-(4-chlorophenyl)-N-methoxy-3-(4-methylphenyl)sulfanylpropan-1-imine —— C17H18ClNOS
    (Z)-1-(4-chlorophenyl)-N-methoxy-3-(4-methylphenyl)sulfanylpropan-1-imine
    —— (NZ)-N-[1-(4-chlorophenyl)-3-(4-methylphenyl)sulfanylpropylidene]hydroxylamine —— C16H16ClNOS
    (NZ)-N-[1-(4-chlorophenyl)-3-(4-methylphenyl)sulfanylpropylidene]hydroxylamine
    —— N'-[(6-fluoropyridin-1-ium-2-yl)amino]-2-pyridin-2-ylsulfanylethanimidamide —— C12H13FN5S+
    N'-[(6-fluoropyridin-1-ium-2-yl)amino]-2-pyridin-2-ylsulfanylethanimidamide
    —— 2-[(2-chlorobenzyl)sulfanyl]-5-[(2S)-pyrrolidin-2-yl]-1,3,4-oxadiazole —— C13H14ClN3OS
    2-[(2-chlorobenzyl)sulfanyl]-5-[(2S)-pyrrolidin-2-yl]-1,3,4-oxadiazole
    —— 2-[(2-methylprop-2-en-1-yl)sulfanyl]-5-[(2S)-pyrrolidin-2-yl]-1,3,4-oxadiazole —— C10H15N3OS
    2-[(2-methylprop-2-en-1-yl)sulfanyl]-5-[(2S)-pyrrolidin-2-yl]-1,3,4-oxadiazole
    —— 2-[(3-methylphenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-2-yl]-1,3,4-oxadiazole —— C14H17N3OS
    2-[(3-methylphenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-2-yl]-1,3,4-oxadiazole