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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-N-butyl-2-ethylhexanethioamide —— C12H25NS
    (2S)-N-butyl-2-ethylhexanethioamide
    —— (2S)-N-cyclohexyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C16H21N3O3S
    (2S)-N-cyclohexyl-2-[[5-(2-methylfuran-3-yl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (2S)-N-cyclohexyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C14H24N4O2S
    (2S)-N-cyclohexyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— N-cyclohexyl-2-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C15H24N4O3S
    N-cyclohexyl-2-[[5-oxo-4-[[(2S)-oxolan-2-yl]methyl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— ethyl 2-[2-[(2R)-1-(benzylamino)-1-oxopropan-2-yl]sulfanyl-1,3-thiazol-4-yl]acetate —— C17H20N2O3S2
    ethyl 2-[2-[(2R)-1-(benzylamino)-1-oxopropan-2-yl]sulfanyl-1,3-thiazol-4-yl]acetate
    —— (2S)-N-cyclohexyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C17H24N4O2S
    (2S)-N-cyclohexyl-2-[[4-methyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— 2-(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl-N-[(1S)-1-cyclopropylethyl]-N-(2,2,2-trifluoroethyl)acetamide —— C18H22F3N3OS
    2-(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl-N-[(1S)-1-cyclopropylethyl]-N-(2,2,2-trifluoroethyl)acetamide
    —— (2S)-N-(cyclohexylmethyl)-2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C20H27N3O2S
    (2S)-N-(cyclohexylmethyl)-2-[[5-(3,5-dimethylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— 2-(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl-N-[(1R)-1-cyclopropylethyl]-N-(2,2,2-trifluoroethyl)acetamide —— C18H22F3N3OS
    2-(3-cyano-4,5,6-trimethylpyridin-2-yl)sulfanyl-N-[(1R)-1-cyclopropylethyl]-N-(2,2,2-trifluoroethyl)acetamide
    —— [(2R)-1-[2-(4-fluorophenyl)ethylamino]-1-oxopropan-2-yl] 2-phenylsulfanylacetate —— C19H20FNO3S
    [(2R)-1-[2-(4-fluorophenyl)ethylamino]-1-oxopropan-2-yl] 2-phenylsulfanylacetate
    —— (6R)-6-ethyl-[1,3]dithiolo[4,5-b][1,4]dithiine-2,5-dione —— C7H6O2S4
    (6R)-6-ethyl-[1,3]dithiolo[4,5-b][1,4]dithiine-2,5-dione
    —— N-[(Z)-1-(2-chlorophenyl)ethylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C20H19ClN4OS3
    N-[(Z)-1-(2-chlorophenyl)ethylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 4-(6,8-dimethyl-2-oxopyrido[2,3-b][1,4]thiazin-1-yl)-N-[3-[(3S,5R)-3,5-dimethylpiperidin-1-yl]propyl]butanamide —— C23H36N4O2S
    4-(6,8-dimethyl-2-oxopyrido[2,3-b][1,4]thiazin-1-yl)-N-[3-[(3S,5R)-3,5-dimethylpiperidin-1-yl]propyl]butanamide
    —— N-[(1R,2R,3R)-2,3-dimethylcyclohexyl]-4-(2-oxopyrido[2,3-b][1,4]thiazin-1-yl)butanamide —— C19H27N3O2S
    N-[(1R,2R,3R)-2,3-dimethylcyclohexyl]-4-(2-oxopyrido[2,3-b][1,4]thiazin-1-yl)butanamide
    —— (1S)-2-(1-methylimidazol-2-yl)sulfanyl-1-(4-methylphenyl)ethanol —— C13H16N2OS
    (1S)-2-(1-methylimidazol-2-yl)sulfanyl-1-(4-methylphenyl)ethanol
    —— (1S)-1-(4-methylphenyl)-2-(4-methylsulfanylphenyl)-1,5,6,7-tetrahydropyrazolo[1,2-a][1,2,4]triazol-3-one —— C19H21N3OS
    (1S)-1-(4-methylphenyl)-2-(4-methylsulfanylphenyl)-1,5,6,7-tetrahydropyrazolo[1,2-a][1,2,4]triazol-3-one
    —— tert-butyl N-[(1R,2R)-2-methyl-1-(5-methylsulfanyl-1,3,4-oxadiazol-2-yl)butyl]carbamate —— C13H23N3O3S
    tert-butyl N-[(1R,2R)-2-methyl-1-(5-methylsulfanyl-1,3,4-oxadiazol-2-yl)butyl]carbamate
    —— tert-butyl N-[(1R)-1-[5-[(2-chloro-6-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylpropyl]carbamate —— C18H23ClFN3O3S
    tert-butyl N-[(1R)-1-[5-[(2-chloro-6-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylpropyl]carbamate
    —— (2S)-3-(2-aminophenyl)sulfanyl-1,1,1-trifluoropropan-2-ol —— C9H10F3NOS
    (2S)-3-(2-aminophenyl)sulfanyl-1,1,1-trifluoropropan-2-ol
    —— (2R)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C11H12N4OS2
    (2R)-2-[(5-anilino-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— 2-(4,6-diaminopyrimidin-2-yl)sulfanyl-N-[(1R,2R,3S)-2,3-dimethylcyclohexyl]acetamide —— C14H23N5OS
    2-(4,6-diaminopyrimidin-2-yl)sulfanyl-N-[(1R,2R,3S)-2,3-dimethylcyclohexyl]acetamide
    —— (2S)-N-cyclohexyl-N-ethyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C19H25N3OS3
    (2S)-N-cyclohexyl-N-ethyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-N-benzyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C18H17N3OS3
    (2S)-N-benzyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— 2-[(6-amino-4-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(2R)-3-methylbutan-2-yl]acetamide —— C11H18N4O2S
    2-[(6-amino-4-oxo-1H-pyrimidin-2-yl)sulfanyl]-N-[(2R)-3-methylbutan-2-yl]acetamide
    —— [(4S)-4-carbamimidoylsulfanylpentyl] carbamimidothioate —— C7H16N4S2
    [(4S)-4-carbamimidoylsulfanylpentyl] carbamimidothioate
    —— (E)-[(3Z)-3-hydrazinylidene-1-[(S)-methylsulfinyl]-4-[(R)-methylsulfinyl]butan-2-ylidene]hydrazine —— C6H14N4O2S2
    (E)-[(3Z)-3-hydrazinylidene-1-[(S)-methylsulfinyl]-4-[(R)-methylsulfinyl]butan-2-ylidene]hydrazine
    —— (1R)-2-[(2-methylsulfanylpyrimidin-4-yl)amino]-1-phenylethanol —— C13H15N3OS
    (1R)-2-[(2-methylsulfanylpyrimidin-4-yl)amino]-1-phenylethanol
    —— tert-butyl N-[(1R)-1-(5-benzylsulfanyl-1,3,4-oxadiazol-2-yl)ethyl]carbamate —— C16H21N3O3S
    tert-butyl N-[(1R)-1-(5-benzylsulfanyl-1,3,4-oxadiazol-2-yl)ethyl]carbamate
    —— tert-butyl N-[(1R)-1-[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]ethyl]carbamate —— C16H20ClN3O3S
    tert-butyl N-[(1R)-1-[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]ethyl]carbamate
    —— (3R)-7-[(3,5-dimethylphenyl)methyl]-3-ethoxy-6-ethyl-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-5-one —— C19H24N2O2S
    (3R)-7-[(3,5-dimethylphenyl)methyl]-3-ethoxy-6-ethyl-2,3-dihydro-[1,3]thiazolo[3,2-a]pyrimidin-5-one
    —— tert-butyl N-[(1R,2S)-2-methyl-1-[5-[(2-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butyl]carbamate —— C20H29N3O3S
    tert-butyl N-[(1R,2S)-2-methyl-1-[5-[(2-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butyl]carbamate
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-(4-bromophenyl)methylideneamino]acetamide —— C11H10BrN5OS2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-(4-bromophenyl)methylideneamino]acetamide
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-furan-2-ylmethylideneamino]acetamide —— C9H9N5O2S2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-furan-2-ylmethylideneamino]acetamide
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-thiophen-2-ylmethylideneamino]acetamide —— C9H9N5OS3
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-thiophen-2-ylmethylideneamino]acetamide
    —— (2R)-N-benzyl-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C18H16ClN3O2S
    (2R)-N-benzyl-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— (3aR,6aS)-3a,6a-dimethyl-3,6-bis(phenylsulfanyl)-1,4-dihydropentalene —— C22H22S2
    (3aR,6aS)-3a,6a-dimethyl-3,6-bis(phenylsulfanyl)-1,4-dihydropentalene
    —— tert-butyl N-[(1R)-1-[5-[(2-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-3-methylsulfanylpropyl]carbamate —— C18H24FN3O3S2
    tert-butyl N-[(1R)-1-[5-[(2-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-3-methylsulfanylpropyl]carbamate
    —— (2S)-3-oxo-1-benzothiophene-2-carboxylic acid —— C9H6O3S
    (2S)-3-oxo-1-benzothiophene-2-carboxylic acid
    —— (2S)-N-[(2S)-4-phenylbutan-2-yl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C21H23N3O2S
    (2S)-N-[(2S)-4-phenylbutan-2-yl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-1-methanesulfonylpropan-2-ol —— C4H10O3S
    (2S)-1-methanesulfonylpropan-2-ol
    —— (2R)-2-[(2R)-1-hydroxypropan-2-yl]sulfanylpropan-1-ol —— C6H14O2S
    (2R)-2-[(2R)-1-hydroxypropan-2-yl]sulfanylpropan-1-ol
    —— 4-[[(1R)-4-methylsulfanylcyclohexa-2,4-dien-1-yl]methyl]-5-(trifluoromethyl)pyrazol-3-one —— C12H11F3N2OS
    4-[[(1R)-4-methylsulfanylcyclohexa-2,4-dien-1-yl]methyl]-5-(trifluoromethyl)pyrazol-3-one
    —— (5R)-1-benzyl-5-(3-ethylsulfanyl-1H-1,2,4-triazol-5-yl)pyrrolidin-2-one —— C15H18N4OS
    (5R)-1-benzyl-5-(3-ethylsulfanyl-1H-1,2,4-triazol-5-yl)pyrrolidin-2-one
    —— 2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-1-methoxypropan-2-yl]acetamide —— C9H14F3N5O2S
    2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-1-methoxypropan-2-yl]acetamide
    —— (3'aS,7'aR)-spiro[1,3-dithiolane-2,3'-3a,4,5,6,7,7a-hexahydro-1H-indene]-2'-one —— C11H16OS2
    (3'aS,7'aR)-spiro[1,3-dithiolane-2,3'-3a,4,5,6,7,7a-hexahydro-1H-indene]-2'-one
    —— [(2R)-2-methylbutoxy]methanedithioic acid —— C6H12OS2
    [(2R)-2-methylbutoxy]methanedithioic acid
    —— (3S)-3-phenylsulfanylthiolane 1,1-dioxide —— C10H12O2S2
    (3S)-3-phenylsulfanylthiolane 1,1-dioxide
    —— N-[(1S)-1-(4-chlorophenyl)ethyl]-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H17ClN4O2S
    N-[(1S)-1-(4-chlorophenyl)ethyl]-2-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— ethyl 2-[(S)-tert-butylsulfinyl]acetate —— C8H16O3S
    ethyl 2-[(S)-tert-butylsulfinyl]acetate
    —— 1-[(R)-[(S)-hexylsulfinyl]sulfinyl]hexane —— C12H26O2S2
    1-[(R)-[(S)-hexylsulfinyl]sulfinyl]hexane