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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-N-[(2R)-2-(3,4-difluorophenyl)sulfanylpropyl]pentan-2-amine —— C14H21F2NS
    (2S)-N-[(2R)-2-(3,4-difluorophenyl)sulfanylpropyl]pentan-2-amine
    —— (2S)-2-(3,4-difluorophenyl)sulfanyl-N-(2,2,2-trifluoroethyl)propan-1-amine —— C11H12F5NS
    (2S)-2-(3,4-difluorophenyl)sulfanyl-N-(2,2,2-trifluoroethyl)propan-1-amine
    —— N-[(2S)-2-(2,5-dimethylpyrazol-3-yl)sulfanylpropyl]cyclopentanamine —— C13H23N3S
    N-[(2S)-2-(2,5-dimethylpyrazol-3-yl)sulfanylpropyl]cyclopentanamine
    —— (3S)-N-[2-(2-chlorophenyl)sulfanylethyl]-1,1-dioxothiolan-3-amine —— C12H16ClNO2S2
    (3S)-N-[2-(2-chlorophenyl)sulfanylethyl]-1,1-dioxothiolan-3-amine
    —— (2R)-N-methyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propan-1-amine —— C8H14N2S2
    (2R)-N-methyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propan-1-amine
    —— (2S)-N-[2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]heptan-2-amine —— C12H24N4S
    (2S)-N-[2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]ethyl]heptan-2-amine
    —— 2-(2-chlorophenyl)sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]ethanamine —— C13H18ClNOS
    2-(2-chlorophenyl)sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]ethanamine
    —— (2S)-N-methyl-2-(4-methylphenyl)sulfanylpropan-1-amine —— C11H17NS
    (2S)-N-methyl-2-(4-methylphenyl)sulfanylpropan-1-amine
    —— (2R)-N-methyl-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-2-phenylethanamine —— C12H16N4S
    (2R)-N-methyl-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-2-phenylethanamine
    —— N-[(2S)-2-(2-fluorophenyl)sulfanylpropyl]-3-methylbutan-1-amine —— C14H22FNS
    N-[(2S)-2-(2-fluorophenyl)sulfanylpropyl]-3-methylbutan-1-amine
    —— N-[(2S)-2-(3,4-dimethylphenyl)sulfanylpropyl]cyclopentanamine —— C16H25NS
    N-[(2S)-2-(3,4-dimethylphenyl)sulfanylpropyl]cyclopentanamine
    —— (2S)-N-methyl-2-(1-methylimidazol-2-yl)sulfanyl-2-phenylethanamine —— C13H17N3S
    (2S)-N-methyl-2-(1-methylimidazol-2-yl)sulfanyl-2-phenylethanamine
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]propan-1-amine —— C14H20ClNOS
    (2R)-2-(4-chlorophenyl)sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]propan-1-amine
    —— N-[(2S)-2-(2-fluorophenyl)sulfanylpropyl]cyclohexanamine —— C15H22FNS
    N-[(2S)-2-(2-fluorophenyl)sulfanylpropyl]cyclohexanamine
    —— (2S)-2-(4-chlorophenyl)sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]propan-1-amine —— C14H20ClNOS
    (2S)-2-(4-chlorophenyl)sulfanyl-N-[[(2R)-oxolan-2-yl]methyl]propan-1-amine
    —— (2S)-2-(4-fluorophenyl)sulfanyl-N-methyl-2-phenylethanamine —— C15H16FNS
    (2S)-2-(4-fluorophenyl)sulfanyl-N-methyl-2-phenylethanamine
    —— (1R)-1-[(2S)-oxolan-2-yl]-N-(2-phenylsulfanylethyl)ethanamine —— C14H21NOS
    (1R)-1-[(2S)-oxolan-2-yl]-N-(2-phenylsulfanylethyl)ethanamine
    —— (2R)-N-[(2S)-2-(3,4-dimethylphenyl)sulfanylpropyl]butan-2-amine —— C15H25NS
    (2R)-N-[(2S)-2-(3,4-dimethylphenyl)sulfanylpropyl]butan-2-amine
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-(3-methoxypropyl)propan-1-amine —— C13H20ClNOS
    (2R)-2-(4-chlorophenyl)sulfanyl-N-(3-methoxypropyl)propan-1-amine
    —— (1S)-1-[(2S)-oxolan-2-yl]-N-(2-phenylsulfanylethyl)ethanamine —— C14H21NOS
    (1S)-1-[(2S)-oxolan-2-yl]-N-(2-phenylsulfanylethyl)ethanamine
    —— (2R)-2-phenylsulfanyl-N-(thiophen-2-ylmethyl)propan-1-amine —— C14H17NS2
    (2R)-2-phenylsulfanyl-N-(thiophen-2-ylmethyl)propan-1-amine
    —— 2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(5-ethylthiophen-2-yl)methyl]acetamide —— C17H25N5O2S2
    2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(5-ethylthiophen-2-yl)methyl]acetamide
    —— (2S)-N-methyl-2-phenylsulfanylpropan-1-amine —— C10H15NS
    (2S)-N-methyl-2-phenylsulfanylpropan-1-amine
    —— N-[(2R)-2-phenylsulfanylpropyl]aniline —— C15H17NS
    N-[(2R)-2-phenylsulfanylpropyl]aniline
    —— 2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(5-ethylthiophen-2-yl)methyl]acetamide —— C14H18N4OS2
    2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-N-[(5-ethylthiophen-2-yl)methyl]acetamide
    —— N-(2-methylsulfonylethyl)-2-[(2S)-octan-2-yl]oxyethanamine —— C13H29NO3S
    N-(2-methylsulfonylethyl)-2-[(2S)-octan-2-yl]oxyethanamine
    —— 5-methyl-2-(4-methylphenyl)-4-[(2-methylsulfanylanilino)methylidene]pyrazol-3-one —— C19H19N3OS
    5-methyl-2-(4-methylphenyl)-4-[(2-methylsulfanylanilino)methylidene]pyrazol-3-one
    —— 2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-1-[(2S)-2-thiophen-3-ylpyrrolidin-1-yl]ethanone —— C15H18N4OS2
    2-(4-amino-6-methylpyrimidin-2-yl)sulfanyl-1-[(2S)-2-thiophen-3-ylpyrrolidin-1-yl]ethanone
    —— 2-[(2-methylanilino)methylidene]-1-benzothiophen-3-one —— C16H13NOS
    2-[(2-methylanilino)methylidene]-1-benzothiophen-3-one
    —— N'-[[5-(hydroxymethyl)-2-methyl-3-oxopyridin-4-ylidene]methyl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetohydrazide —— C13H15N5O3S2
    N'-[[5-(hydroxymethyl)-2-methyl-3-oxopyridin-4-ylidene]methyl]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetohydrazide
    —— N-[(S)-cyclopentyl-(4-fluorophenyl)methyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C17H20FN3OS3
    N-[(S)-cyclopentyl-(4-fluorophenyl)methyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-[2-(2,6-difluorophenyl)ethyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C13H13F2N3OS3
    N-[2-(2,6-difluorophenyl)ethyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— 1-[[4-[4-[(2-Oxonaphthalen-1-ylidene)methylamino]phenyl]sulfanylanilino]methylidene]naphthalen-2-one —— C34H24N2O2S
    1-[[4-[4-[(2-Oxonaphthalen-1-ylidene)methylamino]phenyl]sulfanylanilino]methylidene]naphthalen-2-one
    —— N-[[1-(4-fluorophenyl)cyclopentyl]methyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C17H20FN3OS3
    N-[[1-(4-fluorophenyl)cyclopentyl]methyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-[(R)-cyclopentyl-(4-fluorophenyl)methyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C17H20FN3OS3
    N-[(R)-cyclopentyl-(4-fluorophenyl)methyl]-2-[(5-methylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-cyclopentyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-propan-2-ylacetamide —— C15H26N4O2S
    N-cyclopentyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]-N-propan-2-ylacetamide
    —— N-[2-[(1S,2S)-2-methylcyclohexyl]oxyethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C15H24N2O2S2
    N-[2-[(1S,2S)-2-methylcyclohexyl]oxyethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— (2S)-2-(2-chlorophenyl)sulfanyl-N-(4-morpholin-4-ylbutyl)propanamide —— C17H25ClN2O2S
    (2S)-2-(2-chlorophenyl)sulfanyl-N-(4-morpholin-4-ylbutyl)propanamide
    —— N-[2-[(1S,2R)-2-methylcyclohexyl]oxyethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C15H24N2O2S2
    N-[2-[(1S,2R)-2-methylcyclohexyl]oxyethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— N-[2-[(1R,2S)-2-methylcyclohexyl]oxyethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide —— C15H24N2O2S2
    N-[2-[(1R,2S)-2-methylcyclohexyl]oxyethyl]-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]acetamide
    —— 2-[[4-amino-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(5-ethylthiophen-2-yl)methyl]acetamide —— C16H19N5O2S2
    2-[[4-amino-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(5-ethylthiophen-2-yl)methyl]acetamide
    —— N-cyclopentyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]-N-propan-2-ylacetamide —— C18H23N3OS3
    N-cyclopentyl-2-[(4-phenyl-5-sulfanylidene-1,3,4-thiadiazol-2-yl)sulfanyl]-N-propan-2-ylacetamide
    —— (2R)-N-[2-[(4-fluorophenyl)methylsulfamoyl]ethyl]-2-phenylsulfanylpropanamide —— C18H21FN2O3S2
    (2R)-N-[2-[(4-fluorophenyl)methylsulfamoyl]ethyl]-2-phenylsulfanylpropanamide
    —— N-[2-methyl-2-[(3S)-3-methylpiperidin-1-yl]propyl]-2-pyridin-4-ylsulfanylacetamide —— C17H27N3OS
    N-[2-methyl-2-[(3S)-3-methylpiperidin-1-yl]propyl]-2-pyridin-4-ylsulfanylacetamide
    —— 2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-cyclopentyl-N-propan-2-ylacetamide —— C19H26N4OS2
    2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-cyclopentyl-N-propan-2-ylacetamide
    —— [(2S)-6-methyl-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-(3-methyl-1,2-oxazol-5-yl)pyrrolidin-1-yl]methanone —— C18H20N2O2S
    [(2S)-6-methyl-2,3-dihydro-1-benzothiophen-2-yl]-[(2R)-2-(3-methyl-1,2-oxazol-5-yl)pyrrolidin-1-yl]methanone
    —— N'-[(2R)-3,3-dimethylbutan-2-yl]-N'-methyl-N-(2-methylsulfonylethyl)ethane-1,2-diamine —— C12H28N2O2S
    N'-[(2R)-3,3-dimethylbutan-2-yl]-N'-methyl-N-(2-methylsulfonylethyl)ethane-1,2-diamine
    —— N'-[1-(6-methyl-2,4-dioxopyran-3-ylidene)ethyl]-2-[[5-[1-[2-[1-(6-methyl-2,4-dioxopyran-3-ylidene)ethyl]hydrazinyl]-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]propanehydrazide —— C24H26N6O8S3
    N'-[1-(6-methyl-2,4-dioxopyran-3-ylidene)ethyl]-2-[[5-[1-[2-[1-(6-methyl-2,4-dioxopyran-3-ylidene)ethyl]hydrazinyl]-1-oxopropan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]propanehydrazide
    —— 3-heptylsulfanyl-6-[2-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]-2H-1,2,4-triazin-5-one —— C27H30N6O2S
    3-heptylsulfanyl-6-[2-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]-2H-1,2,4-triazin-5-one
    —— 2-[(2R,6R)-4-(3-bromophenyl)-2-(4-methylsulfanylphenyl)-1,2,5,6-tetrahydropyrimidin-6-yl]phenol —— C23H21BrN2OS
    2-[(2R,6R)-4-(3-bromophenyl)-2-(4-methylsulfanylphenyl)-1,2,5,6-tetrahydropyrimidin-6-yl]phenol