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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(2S)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide —— C15H20N4OS2
    N-[(2S)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-2-(1,3,4-thiadiazol-2-ylsulfanyl)acetamide
    —— 2,3-Dihydroxybutanedioic acid;5-[2-(4-fluorophenyl)sulfanylethyl]-2-methylpyridine —— C18H20FNO6S
    2,3-Dihydroxybutanedioic acid;5-[2-(4-fluorophenyl)sulfanylethyl]-2-methylpyridine
    —— (2S)-N-[(2R)-2-(diethylamino)-2-(furan-2-yl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide —— C17H24N4O2S
    (2S)-N-[(2R)-2-(diethylamino)-2-(furan-2-yl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide
    —— (2R)-N-[(2S)-2-(diethylamino)-2-(furan-2-yl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide —— C17H24N4O2S
    (2R)-N-[(2S)-2-(diethylamino)-2-(furan-2-yl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide
    —— (2R)-N-[(2R)-2-(diethylamino)-2-(furan-2-yl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide —— C17H24N4O2S
    (2R)-N-[(2R)-2-(diethylamino)-2-(furan-2-yl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide
    —— (2S)-N-(3-ethoxypropyl)-2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C13H23N3O3S2
    (2S)-N-(3-ethoxypropyl)-2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-2-[[4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-3-(4-methylphenyl)propanenitrile —— C17H16N4OS
    (2S)-2-[[4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-3-(4-methylphenyl)propanenitrile
    —— 4-[2-(4-Methylphenyl)sulfanylethyl]pyridine;phosphoric acid —— C14H18NO4PS
    4-[2-(4-Methylphenyl)sulfanylethyl]pyridine;phosphoric acid
    —— 3-[(1R)-1-[[5-(furan-2-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]ethyl]pyridine —— C16H16N4OS
    3-[(1R)-1-[[5-(furan-2-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]ethyl]pyridine
    —— (2R)-N-(3-ethoxypropyl)-2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C13H23N3O3S2
    (2R)-N-(3-ethoxypropyl)-2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— 3-[(1S)-1-[[5-(furan-2-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]ethyl]pyridine —— C16H16N4OS
    3-[(1S)-1-[[5-(furan-2-yl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]ethyl]pyridine
    —— ethyl (2Z)-2-[(3-bromo-4-hydroxyphenyl)methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C24H21BrN2O4S2
    ethyl (2Z)-2-[(3-bromo-4-hydroxyphenyl)methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— ethyl (2Z)-5-[4-(dimethylamino)phenyl]-7-methyl-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C26H27N3O3S2
    ethyl (2Z)-5-[4-(dimethylamino)phenyl]-7-methyl-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— ethyl (2Z)-2-[(4-fluorophenyl)methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C24H21FN2O3S2
    ethyl (2Z)-2-[(4-fluorophenyl)methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— ethyl (2E)-7-methyl-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-5-thiophen-2-yl-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C22H20N2O3S3
    ethyl (2E)-7-methyl-2-[(4-methylsulfanylphenyl)methylidene]-3-oxo-5-thiophen-2-yl-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[[(2S)-4-methylmorpholin-2-yl]methyl]propanamide —— C15H21ClN2O2S
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[[(2S)-4-methylmorpholin-2-yl]methyl]propanamide
    —— 6-methyl-2-[(1R)-1-(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)ethyl]sulfanylpyrimidin-4-amine —— C13H13N5OS2
    6-methyl-2-[(1R)-1-(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)ethyl]sulfanylpyrimidin-4-amine
    —— 1-[(2S)-1-imidazol-1-yl-3,3-dimethylbutan-2-yl]-3-[2-methyl-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]urea —— C21H27N5OS2
    1-[(2S)-1-imidazol-1-yl-3,3-dimethylbutan-2-yl]-3-[2-methyl-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]urea
    —— (2S)-2-(2-chlorophenyl)sulfanyl-N-[[(2S)-4-methylmorpholin-2-yl]methyl]propanamide —— C15H21ClN2O2S
    (2S)-2-(2-chlorophenyl)sulfanyl-N-[[(2S)-4-methylmorpholin-2-yl]methyl]propanamide
    —— N-[(E)-butan-2-ylideneamino]-2-(4-chlorophenyl)sulfanylpropanamide —— C13H17ClN2OS
    N-[(E)-butan-2-ylideneamino]-2-(4-chlorophenyl)sulfanylpropanamide
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[[(2R)-4-methylmorpholin-2-yl]methyl]propanamide —— C15H21ClN2O2S
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[[(2R)-4-methylmorpholin-2-yl]methyl]propanamide
    —— (2S)-2-(2-chlorophenyl)sulfanyl-N-[[(2R)-4-methylmorpholin-2-yl]methyl]propanamide —— C15H21ClN2O2S
    (2S)-2-(2-chlorophenyl)sulfanyl-N-[[(2R)-4-methylmorpholin-2-yl]methyl]propanamide
    —— 1-[(2R)-1-imidazol-1-yl-3,3-dimethylbutan-2-yl]-3-[2-methyl-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]urea —— C21H27N5OS2
    1-[(2R)-1-imidazol-1-yl-3,3-dimethylbutan-2-yl]-3-[2-methyl-4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]phenyl]urea
    —— 6-methyl-2-[(1S)-1-(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)ethyl]sulfanylpyrimidin-4-amine —— C13H13N5OS2
    6-methyl-2-[(1S)-1-(3-thiophen-2-yl-1,2,4-oxadiazol-5-yl)ethyl]sulfanylpyrimidin-4-amine
    —— (5E)-5-{2-[(4-chlorophenyl)sulfanyl]benzylidene}-3-(prop-2-en-1-yl)-2-thioxo-1,3-thiazolidin-4-one —— C19H14ClNOS3
    (5E)-5-{2-[(4-chlorophenyl)sulfanyl]benzylidene}-3-(prop-2-en-1-yl)-2-thioxo-1,3-thiazolidin-4-one
    —— 2-(4-chlorophenyl)sulfanyl-N-[(2S)-1-methoxypropan-2-yl]acetamide —— C12H16ClNO2S
    2-(4-chlorophenyl)sulfanyl-N-[(2S)-1-methoxypropan-2-yl]acetamide
    —— 2-((4,6-Dimethyl-2-pyrimidinyl)thio)-N'-(4-methylbenzylidene)acetohydrazide —— C16H18N4OS
    2-((4,6-Dimethyl-2-pyrimidinyl)thio)-N'-(4-methylbenzylidene)acetohydrazide
    —— 2-(4-chlorophenyl)sulfanyl-N-[(2R)-1-methoxypropan-2-yl]acetamide —— C12H16ClNO2S
    2-(4-chlorophenyl)sulfanyl-N-[(2R)-1-methoxypropan-2-yl]acetamide
    —— (2Z)-2-(anilinomethylidene)-1-benzothiophen-3-one —— C15H11NOS
    (2Z)-2-(anilinomethylidene)-1-benzothiophen-3-one
    —— N'-[(E)-(3-bromophenyl)methylidene]-2-(pyrimidin-2-ylsulfanyl)acetohydrazide —— C13H11BrN4OS
    N'-[(E)-(3-bromophenyl)methylidene]-2-(pyrimidin-2-ylsulfanyl)acetohydrazide
    —— N'-[(E)-pyridin-4-ylmethylidene]-2-(pyrimidin-2-ylsulfanyl)acetohydrazide —— C12H11N5OS
    N'-[(E)-pyridin-4-ylmethylidene]-2-(pyrimidin-2-ylsulfanyl)acetohydrazide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-3-phenylsulfanylpropanamide —— C15H21NO3S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-N-ethyl-3-phenylsulfanylpropanamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-3-phenylsulfanylpropanamide —— C15H21NO3S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethyl-3-phenylsulfanylpropanamide
    —— N'-[(2E)-butan-2-ylidene]-2-(phenylsulfanyl)propanehydrazide —— C13H18N2OS
    N'-[(2E)-butan-2-ylidene]-2-(phenylsulfanyl)propanehydrazide
    —— (2S)-N-[(2R)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide —— C18H24N4OS
    (2S)-N-[(2R)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide
    —— (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylethyl)-N-prop-2-enylpropanamide —— C17H22N4OS
    (2S)-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-(2-phenylethyl)-N-prop-2-enylpropanamide
    —— 4-[[5-[[(2S)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]butanenitrile —— C11H16N4OS2
    4-[[5-[[(2S)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]butanenitrile
    —— (2R)-N-[(2S)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide —— C18H24N4OS
    (2R)-N-[(2S)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-2-pyrimidin-2-ylsulfanylpropanamide
    —— (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methyl-2-(3-methylphenyl)sulfanylpropanamide —— C15H21NO3S2
    (2S)-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methyl-2-(3-methylphenyl)sulfanylpropanamide
    —— (2S)-2-[[5-[(2S)-1-amino-1-oxobutan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide —— C10H16N4O2S3
    (2S)-2-[[5-[(2S)-1-amino-1-oxobutan-2-yl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]butanamide
    —— 2-[(4-Chlorophenyl)sulfanyl]-N'-[(E)-(2,3,4-trimethylphenyl)methylidene]acetohydrazide —— C18H19ClN2OS
    2-[(4-Chlorophenyl)sulfanyl]-N'-[(E)-(2,3,4-trimethylphenyl)methylidene]acetohydrazide
    —— (2S)-N-[(2S)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C17H25N5OS
    (2S)-N-[(2S)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— N-[(2S)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-3-(1-methyltetrazol-5-yl)sulfanylpropanamide —— C16H24N6OS
    N-[(2S)-2-(dimethylamino)-2-(4-methylphenyl)ethyl]-3-(1-methyltetrazol-5-yl)sulfanylpropanamide
    —— (2S)-N-[(3-hydroxyphenyl)methyl]-N-methyl-2,3-dihydro-1,4-benzoxathiine-2-carboxamide —— C17H17NO3S
    (2S)-N-[(3-hydroxyphenyl)methyl]-N-methyl-2,3-dihydro-1,4-benzoxathiine-2-carboxamide
    —— N-[(2S)-2-cyanopropyl]-N-ethyl-3-phenylsulfanylpropanamide —— C15H20N2OS
    N-[(2S)-2-cyanopropyl]-N-ethyl-3-phenylsulfanylpropanamide
    —— (3R)-3-cyclopropyl-N-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]phenyl]butanamide —— C16H20N4OS
    (3R)-3-cyclopropyl-N-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]phenyl]butanamide
    —— N-[(1R)-1-phenylethyl]-2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C15H19N3O2S2
    N-[(1R)-1-phenylethyl]-2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-[(E)-(4-methylsulfanylphenyl)methylideneamino]cyclopropanecarboxamide —— C12H14N2OS
    N-[(E)-(4-methylsulfanylphenyl)methylideneamino]cyclopropanecarboxamide
    —— (2R)-2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(thiophen-2-ylmethyl)propanamide —— C13H17N3O2S3
    (2R)-2-[(5-propan-2-yloxy-1,3,4-thiadiazol-2-yl)sulfanyl]-N-(thiophen-2-ylmethyl)propanamide
    —— (2S)-N-[2-(4-fluorophenyl)ethyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C17H21FN4OS
    (2S)-N-[2-(4-fluorophenyl)ethyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanamide