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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— tert-butyl N-[(1R,2R)-1-[5-[(4-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutyl]carbamate —— C19H26FN3O3S
    tert-butyl N-[(1R,2R)-1-[5-[(4-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutyl]carbamate
    —— tert-butyl N-[(1R,2S)-1-[5-[(4-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutyl]carbamate —— C19H26FN3O3S
    tert-butyl N-[(1R,2S)-1-[5-[(4-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-2-methylbutyl]carbamate
    —— tert-butyl N-[(1R,2S)-2-methyl-1-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butyl]carbamate —— C20H29N3O3S
    tert-butyl N-[(1R,2S)-2-methyl-1-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]butyl]carbamate
    —— (Z)-N-[[5-(4-bromophenyl)sulfanyl-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]methoxy]-1-(2,6-dichlorophenyl)methanimine —— C19H13BrCl2F3N3OS
    (Z)-N-[[5-(4-bromophenyl)sulfanyl-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]methoxy]-1-(2,6-dichlorophenyl)methanimine
    —— N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-1-methyl-3-(trifluoromethyl)thieno[2,3-c]pyrazole-5-carboxamide —— C21H13ClF3N5O3S2
    N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-1-methyl-3-(trifluoromethyl)thieno[2,3-c]pyrazole-5-carboxamide
    —— [2-(benzylamino)-2-oxoethyl] 4-(4-chlorophenyl)sulfanylbutanoate —— C19H20ClNO3S
    [2-(benzylamino)-2-oxoethyl] 4-(4-chlorophenyl)sulfanylbutanoate
    —— (NZ)-N-(2-pyrimidin-2-ylsulfanylcyclooctylidene)hydroxylamine —— C12H17N3OS
    (NZ)-N-(2-pyrimidin-2-ylsulfanylcyclooctylidene)hydroxylamine
    —— [2-[4-amino-1-methyl-3-(2-methylpropyl)-2,6-dioxopyrimidin-5-yl]-2-oxoethyl] 4-(4-chlorophenyl)sulfanylbutanoate —— C21H26ClN3O5S
    [2-[4-amino-1-methyl-3-(2-methylpropyl)-2,6-dioxopyrimidin-5-yl]-2-oxoethyl] 4-(4-chlorophenyl)sulfanylbutanoate
    —— N'-[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]-N,N-dimethylmethanimidamide —— C12H13ClN4S2
    N'-[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]-N,N-dimethylmethanimidamide
    —— 2-(2-methylphenyl)sulfanyl-N-[(Z)-3-phenylprop-2-ynylideneamino]acetamide —— C18H16N2OS
    2-(2-methylphenyl)sulfanyl-N-[(Z)-3-phenylprop-2-ynylideneamino]acetamide
    —— 2-Butenethioamide,3-amino- —— C4H8N2S
    2-Butenethioamide,3-amino-
    —— (Z)-3-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)-2-pyridin-2-ylprop-2-enenitrile —— C18H11N5O2S
    (Z)-3-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)-2-pyridin-2-ylprop-2-enenitrile
    —— 2-[(E)-1,2-Dichloro-2-(2-hydroxy-ethanesulfonyl)-ethenesulfonyl]-ethanol 130920-03-5 C6H10Cl2O6S2
    2-[(E)-1,2-Dichloro-2-(2-hydroxy-ethanesulfonyl)-ethenesulfonyl]-ethanol
    —— 4-bromo-N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]aniline —— C19H13BrClN3O2S
    4-bromo-N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]aniline
    —— [(E)-4-amino-3-cyano-2-oxopent-3-enyl] 2-(2-cyanophenyl)sulfanylbenzoate —— C20H15N3O3S
    [(E)-4-amino-3-cyano-2-oxopent-3-enyl] 2-(2-cyanophenyl)sulfanylbenzoate
    —— 2-N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-6-morpholin-4-yl-4-N-phenyl-1,3,5-triazine-2,4-diamine —— C26H23ClN8O3S
    2-N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-6-morpholin-4-yl-4-N-phenyl-1,3,5-triazine-2,4-diamine
    —— (5E)-5-{4-[(4-chlorophenyl)sulfanyl]-3-nitrobenzylidene}-3-methyl-2-thioxo-1,3-thiazolidin-4-one —— C17H11ClN2O3S3
    (5E)-5-{4-[(4-chlorophenyl)sulfanyl]-3-nitrobenzylidene}-3-methyl-2-thioxo-1,3-thiazolidin-4-one
    —— methyl 2-({5-[(1Z)-(methoxyimino)methyl]imidazo[2,1-b][1,3]thiazol-6-yl}sulfanyl)benzoate —— C15H13N3O3S2
    methyl 2-({5-[(1Z)-(methoxyimino)methyl]imidazo[2,1-b][1,3]thiazol-6-yl}sulfanyl)benzoate
    —— Methyl 2-({5-[(hydroxyimino)methyl]imidazo[2,1-b][1,3]thiazol-6-yl}sulfanyl)benzenecarboxylate —— C14H11N3O3S2
    Methyl 2-({5-[(hydroxyimino)methyl]imidazo[2,1-b][1,3]thiazol-6-yl}sulfanyl)benzenecarboxylate
    —— ethyl 5-[[(2S)-2-[4-ethoxycarbonyl-5-(4-ethoxycarbonylthiadiazol-5-yl)sulfanyltriazol-1-yl]propyl]amino]thiadiazole-4-carboxylate —— C18H22N8O6S3
    ethyl 5-[[(2S)-2-[4-ethoxycarbonyl-5-(4-ethoxycarbonylthiadiazol-5-yl)sulfanyltriazol-1-yl]propyl]amino]thiadiazole-4-carboxylate
    —— 2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-1-(furan-2-yl)ethylideneamino]acetamide —— C17H15ClN4O2S3
    2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-1-(furan-2-yl)ethylideneamino]acetamide
    —— (2R)-2-[[4-amino-5-[(2-fluorophenyl)methyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-methylpropanamide —— C17H22FN5O3S2
    (2R)-2-[[4-amino-5-[(2-fluorophenyl)methyl]-1,2,4-triazol-3-yl]sulfanyl]-N-[(3R)-1,1-dioxothiolan-3-yl]-N-methylpropanamide
    —— (2R)-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-morpholin-4-ylpropan-1-one —— C15H20N4O3S
    (2R)-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-1-morpholin-4-ylpropan-1-one
    —— (2R)-N-benzyl-2-[[4-benzyl-5-(5-bromofuran-2-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C23H21BrN4O2S
    (2R)-N-benzyl-2-[[4-benzyl-5-(5-bromofuran-2-yl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— (4S)-4-phenyl-4-phenylsulfanylbutan-1-ol —— C16H18OS
    (4S)-4-phenyl-4-phenylsulfanylbutan-1-ol
    —— (2R)-2-(5-nitropyridin-2-yl)sulfanylcyclohexan-1-one —— C11H12N2O3S
    (2R)-2-(5-nitropyridin-2-yl)sulfanylcyclohexan-1-one
    —— tert-butyl N-[(1R)-2-methyl-1-(5-methylsulfanyl-1,3,4-oxadiazol-2-yl)propyl]carbamate —— C12H21N3O3S
    tert-butyl N-[(1R)-2-methyl-1-(5-methylsulfanyl-1,3,4-oxadiazol-2-yl)propyl]carbamate
    —— tert-butyl N-[(1R)-1-[5-[(2-chloro-6-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]ethyl]carbamate —— C16H19ClFN3O3S
    tert-butyl N-[(1R)-1-[5-[(2-chloro-6-fluorophenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]ethyl]carbamate
    —— (3R)-N-(2,4-difluorophenyl)-1-[6-(4-methylphenyl)sulfanylpyridazin-3-yl]piperidine-3-carboxamide —— C23H22F2N4OS
    (3R)-N-(2,4-difluorophenyl)-1-[6-(4-methylphenyl)sulfanylpyridazin-3-yl]piperidine-3-carboxamide
    —— (3S)-N-(2,4-difluorophenyl)-1-[6-(4-methylphenyl)sulfanylpyridazin-3-yl]piperidine-3-carboxamide —— C23H22F2N4OS
    (3S)-N-(2,4-difluorophenyl)-1-[6-(4-methylphenyl)sulfanylpyridazin-3-yl]piperidine-3-carboxamide
    —— (3S)-N-(3-chloro-4-fluorophenyl)-1-[6-(4-methylphenyl)sulfanylpyridazin-3-yl]piperidine-3-carboxamide —— C23H22ClFN4OS
    (3S)-N-(3-chloro-4-fluorophenyl)-1-[6-(4-methylphenyl)sulfanylpyridazin-3-yl]piperidine-3-carboxamide
    —— N-[(1R)-1-phenylbutyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C20H21N3O2S
    N-[(1R)-1-phenylbutyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— (2S)-N-[(1R)-1-phenylbutyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C21H23N3O2S
    (2S)-N-[(1R)-1-phenylbutyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— N-[(Z)-(3-fluorophenyl)methylideneamino]-2-(4-methylphenyl)sulfanylacetamide —— C16H15FN2OS
    N-[(Z)-(3-fluorophenyl)methylideneamino]-2-(4-methylphenyl)sulfanylacetamide
    —— 2-[(3R)-3-(2-hydroxyethylsulfanyl)butyl]sulfanylethanol —— C8H18O2S2
    2-[(3R)-3-(2-hydroxyethylsulfanyl)butyl]sulfanylethanol
    —— (2R)-N-[(1R)-1-phenylbutyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C21H23N3O2S
    (2R)-N-[(1R)-1-phenylbutyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— (2S)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclohexylpropanamide —— C17H20ClN3O2S
    (2S)-2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-cyclohexylpropanamide
    —— N-[(S)-(4-fluorophenyl)-thiophen-2-ylmethyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C19H19FN4OS2
    N-[(S)-(4-fluorophenyl)-thiophen-2-ylmethyl]-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— N-[(1R)-1-cyano-1-cyclopropylethyl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C16H19N5O2S
    N-[(1R)-1-cyano-1-cyclopropylethyl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— (2S)-N-(cyclohexylmethyl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide —— C18H23N3O2S
    (2S)-N-(cyclohexylmethyl)-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]propanamide
    —— (2R)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-cyclohexylpropanamide —— C18H24N4OS2
    (2R)-2-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-cyclohexylpropanamide
    —— (2S)-2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-methylpropanamide —— C6H11N5OS
    (2S)-2-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanyl]-N-methylpropanamide
    —— 2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-3-methylbutan-2-yl]acetamide —— C10H16F3N5OS
    2-[[4-amino-5-(trifluoromethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-3-methylbutan-2-yl]acetamide
    —— 2-[[4-[(Z)-cyclohexylmethylideneamino]-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C16H20N4O3S
    2-[[4-[(Z)-cyclohexylmethylideneamino]-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— tert-butyl N-[(1R)-1-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-3-methylsulfanylpropyl]carbamate —— C19H27N3O3S2
    tert-butyl N-[(1R)-1-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-oxadiazol-2-yl]-3-methylsulfanylpropyl]carbamate
    —— ethyl (6R,7R)-3-methyl-6-phenyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate —— C14H16N4O2S
    ethyl (6R,7R)-3-methyl-6-phenyl-6,7-dihydro-5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazine-7-carboxylate
    —— (2R)-2-(1-tert-butyltetrazol-5-yl)sulfanyl-N-(2-methylpropyl)propanamide —— C12H23N5OS
    (2R)-2-(1-tert-butyltetrazol-5-yl)sulfanyl-N-(2-methylpropyl)propanamide
    —— N-[(1R)-1-(4-chlorophenyl)ethyl]-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H21ClN4O2S
    N-[(1R)-1-(4-chlorophenyl)ethyl]-2-[[5-oxo-4-(2-phenylethyl)-1H-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[(2R)-heptan-2-yl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C15H21N3O2S2
    N-[(2R)-heptan-2-yl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— 1-(6-Methoxypyridin-3-yl)-3-(2-phenylsulfanylethyl)thiourea —— C15H17N3OS2
    1-(6-Methoxypyridin-3-yl)-3-(2-phenylsulfanylethyl)thiourea