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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-Methylsulfanyl-4-(sulfinoamino)but-2-yne —— C5H9NO2S2
    1-Methylsulfanyl-4-(sulfinoamino)but-2-yne
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2,5-difluorophenyl)methylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide —— C20H16F2N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2,5-difluorophenyl)methylideneamino]-5-[(4-methylphenyl)sulfanylmethyl]triazole-4-carboxamide
    —— 1-Ethenylcyclohexane-1,2-dithiol —— C8H14S2
    1-Ethenylcyclohexane-1,2-dithiol
    —— (2E)-2-[[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylidene]-3,4-dihydronaphthalen-1-one —— C21H17N3O3S
    (2E)-2-[[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylidene]-3,4-dihydronaphthalen-1-one
    —— (4E)-1-[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-5-(furan-2-yl)pyrrolidine-2,3-dione —— C26H20ClN3O4S2
    (4E)-1-[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-5-(furan-2-yl)pyrrolidine-2,3-dione
    —— 1-[2-[7-Methyl-1,3,8-tris(2-sulfanylpropylsulfanyl)octan-2-yl]sulfanylethylsulfanyl]propane-2-thiol —— C23H48S9
    1-[2-[7-Methyl-1,3,8-tris(2-sulfanylpropylsulfanyl)octan-2-yl]sulfanylethylsulfanyl]propane-2-thiol
    —— 4-Ethylsulfonylhepta-1,3,5-triene —— C9H14O2S
    4-Ethylsulfonylhepta-1,3,5-triene
    —— 2-[[7-(Furan-2-yl)-14-methylsulfanyl-8,13,15-triazatetracyclo[7.7.0.02,6.011,16]hexadeca-1,6,9,11(16),12,14-hexaen-12-yl]-(2-hydroxyethyl)amino]ethanol —— C22H24N4O3S
    2-[[7-(Furan-2-yl)-14-methylsulfanyl-8,13,15-triazatetracyclo[7.7.0.02,6.011,16]hexadeca-1,6,9,11(16),12,14-hexaen-12-yl]-(2-hydroxyethyl)amino]ethanol
    —— (4E)-1-[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-5-pyridin-4-ylpyrrolidine-2,3-dione —— C27H21ClN4O3S2
    (4E)-1-[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-5-pyridin-4-ylpyrrolidine-2,3-dione
    —— 2-(Fluoromethyl)-4-prop-2-ynylsulfanylaniline —— C10H10FNS
    2-(Fluoromethyl)-4-prop-2-ynylsulfanylaniline
    —— 1-(4-fluorophenyl)-3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine —— C20H20FN3S
    1-(4-fluorophenyl)-3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine
    —— 2-Hexylsulfonylpentane-2-sulfinate —— C11H23O4S2-
    2-Hexylsulfonylpentane-2-sulfinate
    —— 2-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]-N-(3-methylsulfanylphenyl)acetamide —— C26H21N3O5S3
    2-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]-N-(3-methylsulfanylphenyl)acetamide
    —— carbaldehyde O-3,4-dichlorobenzyl oxime —— C20H15Cl2N3OS2
    carbaldehyde O-3,4-dichlorobenzyl oxime
    —— 1,2,6-Tris(sulfanyl)hexane-3-thione —— C6H12S4
    1,2,6-Tris(sulfanyl)hexane-3-thione
    —— 2-(1,3-Benzodithiol-2-ylidene)-1,3-benzodithiole;propane —— C26H40S4
    2-(1,3-Benzodithiol-2-ylidene)-1,3-benzodithiole;propane
    —— [5-(3,5-dichlorophenyl)sulfanyl-2-methyl-4-propan-2-yl-1-(pyridin-4-ylmethyl)pyrrol-3-yl]methyl N-methylcarbamate —— C23H25Cl2N3O2S
    [5-(3,5-dichlorophenyl)sulfanyl-2-methyl-4-propan-2-yl-1-(pyridin-4-ylmethyl)pyrrol-3-yl]methyl N-methylcarbamate
    —— (4E)-1-[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-5-thiophen-2-ylpyrrolidine-2,3-dione —— C26H20ClN3O3S3
    (4E)-1-[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-5-thiophen-2-ylpyrrolidine-2,3-dione
    —— N'-[5-(cyanomethylsulfanyl)-1,3,4-thiadiazol-2-yl]-N,N-dimethylmethanimidamide —— C7H9N5S2
    N'-[5-(cyanomethylsulfanyl)-1,3,4-thiadiazol-2-yl]-N,N-dimethylmethanimidamide
    —— (4E)-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-5-(5-methylfuran-2-yl)-1-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]pyrrolidine-2,3-dione —— C28H25N3O4S2
    (4E)-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-5-(5-methylfuran-2-yl)-1-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]pyrrolidine-2,3-dione
    —— [1-Ethyl-1-(3-phenylsulfanylpropyl)pyrrolidin-1-ium-2-yl] 2-cyclohexyl-2-(furan-2-yl)-2-hydroxyacetate —— C27H38NO4S+
    [1-Ethyl-1-(3-phenylsulfanylpropyl)pyrrolidin-1-ium-2-yl] 2-cyclohexyl-2-(furan-2-yl)-2-hydroxyacetate
    —— 3-Nitrosopropanethioamide —— C3H6N2OS
    3-Nitrosopropanethioamide
    —— 8-(2,5-diethoxyphenyl)sulfanyl-3-(2-phenylethyl)-7H-purin-3-ium-6-amine —— C23H26N5O2S+
    8-(2,5-diethoxyphenyl)sulfanyl-3-(2-phenylethyl)-7H-purin-3-ium-6-amine
    —— (NZ)-N-(1-bromo-6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophen-4-ylidene)hydroxylamine —— C11H14BrNOS2
    (NZ)-N-(1-bromo-6,6-dimethyl-3-methylsulfanyl-5,7-dihydro-2-benzothiophen-4-ylidene)hydroxylamine
    —— Sulfanyl-(sulfinoamino)methane —— CH5NO2S2
    Sulfanyl-(sulfinoamino)methane
    —— 4-(2,2-Dimethylpropyl)-5-methylcyclohept-2-ene-1-thione —— C13H22S
    4-(2,2-Dimethylpropyl)-5-methylcyclohept-2-ene-1-thione
    —— 3-(1-benzothiophen-3-yl)-5-[(4-methoxyphenyl)methyl]-1H-pyrazole;5-benzyl-3-[4-(cyclohexen-1-yl)thiophen-3-yl]-1H-pyrazole;5-benzyl-3-(4-phenylsulfanylthiophen-3-yl)-1H-pyrazole —— C59H52N6OS4
    3-(1-benzothiophen-3-yl)-5-[(4-methoxyphenyl)methyl]-1H-pyrazole;5-benzyl-3-[4-(cyclohexen-1-yl)thiophen-3-yl]-1H-pyrazole;5-benzyl-3-(4-phenylsulfanylthiophen-3-yl)-1H-pyrazole
    —— 4-[2-(6-Butan-2-ylsulfanylpyridin-3-yl)ethynyl]-2-methyl-2,3-dihydro-1,3-thiazole —— C15H18N2S2
    4-[2-(6-Butan-2-ylsulfanylpyridin-3-yl)ethynyl]-2-methyl-2,3-dihydro-1,3-thiazole
    —— 3-(2-ethylphenyl)sulfanyl-5-fluoro-1H-indole —— C16H14FNS
    3-(2-ethylphenyl)sulfanyl-5-fluoro-1H-indole
    —— 4-ethenyl-2-(pyridin-3-ylmethylsulfanyl)-1H-pyrimidin-6-one —— C12H11N3OS
    4-ethenyl-2-(pyridin-3-ylmethylsulfanyl)-1H-pyrimidin-6-one
    —— (E)-2-(4-chlorophenylthio)nicotinaldehyde O-4-methylbenzyl oxime —— C20H17ClN2OS
    (E)-2-(4-chlorophenylthio)nicotinaldehyde O-4-methylbenzyl oxime
    —— (3R)-5-bromo-3-tritiooxyhex-4-enethioamide —— C6H10BrNOS
    (3R)-5-bromo-3-tritiooxyhex-4-enethioamide
    —— 1-[6-(4-Cyclopropyl-1-methylcyclohepta-2,4,6-trien-1-yl)-1,6-dimethylcyclododecyl]ethanethione —— C27H42S
    1-[6-(4-Cyclopropyl-1-methylcyclohepta-2,4,6-trien-1-yl)-1,6-dimethylcyclododecyl]ethanethione
    —— N-cycloheptyl-2-(4-methylpentanoyl)-5-(pyridin-2-ylmethylsulfanyl)-1,3,4-oxadiazol-3-ium-3-carboxamide —— C22H31N4O3S+
    N-cycloheptyl-2-(4-methylpentanoyl)-5-(pyridin-2-ylmethylsulfanyl)-1,3,4-oxadiazol-3-ium-3-carboxamide
    —— (4E)-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-5-(furan-2-yl)-1-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]pyrrolidine-2,3-dione —— C27H23N3O4S2
    (4E)-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-5-(furan-2-yl)-1-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]pyrrolidine-2,3-dione
    —— (4E)-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-1-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]-5-pyridin-4-ylpyrrolidine-2,3-dione —— C28H24N4O3S2
    (4E)-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-1-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]-5-pyridin-4-ylpyrrolidine-2,3-dione
    —— 3-Cyclohexyl-1-methyl-1-[3-[[5-(4-methylpentanoyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propyl]urea —— C19H32N4O3S
    3-Cyclohexyl-1-methyl-1-[3-[[5-(4-methylpentanoyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propyl]urea
    —— 4-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]-9-(2-hydroxy-3-morpholin-4-ylpropyl)-4,4a,6,8a-tetrahydro-1H-pyrazolo[3,4-b][1,7]naphthyridin-5-one —— C27H29N7O4S
    4-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]-9-(2-hydroxy-3-morpholin-4-ylpropyl)-4,4a,6,8a-tetrahydro-1H-pyrazolo[3,4-b][1,7]naphthyridin-5-one
    —— 5,6-dihydro-4H-thiocine —— C7H10S
    5,6-dihydro-4H-thiocine
    —— N-[(E)-[2-[(5-ethyl-4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-1-phenylethylidene]amino]acetamide —— C17H20N4O2S
    N-[(E)-[2-[(5-ethyl-4-methyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]-1-phenylethylidene]amino]acetamide
    —— Thia-3-azacyclodecane —— C8H17NS
    Thia-3-azacyclodecane
    —— 2-[(5E)-5-{[7-Methyl-4-oxo-2-(phenylsulfanyl)-4H-pyrido[1,2-A]pyrimidin-3-YL]methylidene}-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-YL]acetic acid —— C21H15N3O4S3
    2-[(5E)-5-{[7-Methyl-4-oxo-2-(phenylsulfanyl)-4H-pyrido[1,2-A]pyrimidin-3-YL]methylidene}-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-YL]acetic acid
    —— 2-[(5E)-5-{[9-Methyl-4-oxo-2-(phenylsulfanyl)-4H-pyrido[1,2-A]pyrimidin-3-YL]methylidene}-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-YL]acetic acid —— C21H15N3O4S3
    2-[(5E)-5-{[9-Methyl-4-oxo-2-(phenylsulfanyl)-4H-pyrido[1,2-A]pyrimidin-3-YL]methylidene}-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-YL]acetic acid
    —— 2-[(5Z)-5-[(7-methyl-4-oxo-2-phenylsulfanylpyrido[1,2-a]pyrimidin-3-yl)methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]acetate —— C21H14N3O4S3-
    2-[(5Z)-5-[(7-methyl-4-oxo-2-phenylsulfanylpyrido[1,2-a]pyrimidin-3-yl)methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]acetate
    —— [4-[3-[Heptyl(phenylcarbamoyl)amino]phenyl]sulfanylphenyl] butanoate —— C30H36N2O3S
    [4-[3-[Heptyl(phenylcarbamoyl)amino]phenyl]sulfanylphenyl] butanoate
    —— 5-[4-[1-(Dimethylamino)propan-2-ylsulfanyl]phenyl]-3-[(2-fluorophenyl)methylidene]pyrazin-4-id-2-amine —— C22H24FN4S-
    5-[4-[1-(Dimethylamino)propan-2-ylsulfanyl]phenyl]-3-[(2-fluorophenyl)methylidene]pyrazin-4-id-2-amine
    —— [4-[4-(3-Hydroxyphenyl)-1,3-thiazol-2-yl]-5-methylsulfanylthiophen-2-yl]-methylidene-[(2-methylpropan-2-yl)oxycarbamoyl]azanium —— C20H22N3O3S3+
    [4-[4-(3-Hydroxyphenyl)-1,3-thiazol-2-yl]-5-methylsulfanylthiophen-2-yl]-methylidene-[(2-methylpropan-2-yl)oxycarbamoyl]azanium
    —— [Dimethyl(2-oxooctyl)-lambda4-sulfanyl]-(trifluoromethylsulfonyl)oxidanium —— C11H22F3O4S2+
    [Dimethyl(2-oxooctyl)-lambda4-sulfanyl]-(trifluoromethylsulfonyl)oxidanium
    —— (5E)-3-methyl-5-[5-nitro-2-(pyridin-2-ylsulfanyl)benzylidene]-2-thioxo-1,3-thiazolidin-4-one —— C16H11N3O3S3
    (5E)-3-methyl-5-[5-nitro-2-(pyridin-2-ylsulfanyl)benzylidene]-2-thioxo-1,3-thiazolidin-4-one
    —— (4E)-1-(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-5-(5-methylfuran-2-yl)pyrrolidine-2,3-dione —— C27H23N3O4S2
    (4E)-1-(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-5-(5-methylfuran-2-yl)pyrrolidine-2,3-dione