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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanyl-7-[(E)-2-phenylethenyl]-[1,2,4]triazolo[1,5-a]pyrimidine —— C19H11ClF3N5S
    2-[3-chloro-5-(trifluoromethyl)pyridin-2-yl]sulfanyl-7-[(E)-2-phenylethenyl]-[1,2,4]triazolo[1,5-a]pyrimidine
    —— 3,4-Dimethyl-4-(3-methylphenyl)sulfanylpentan-2-ol;ethane —— C16H28OS
    3,4-Dimethyl-4-(3-methylphenyl)sulfanylpentan-2-ol;ethane
    —— [4-[3-[(2-Ethoxyphenyl)carbamoyl-(2-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate —— C33H34N2O4S
    [4-[3-[(2-Ethoxyphenyl)carbamoyl-(2-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate
    —— 2-[Methyl-[2-[2-[4-(2-methylpropyl)phenyl]sulfanylphenoxy]ethyl]amino]acetic acid —— C21H27NO3S
    2-[Methyl-[2-[2-[4-(2-methylpropyl)phenyl]sulfanylphenoxy]ethyl]amino]acetic acid
    —— Ethane;1-methyl-3-(2,3,3-trimethylbutan-2-ylsulfanyl)benzene —— C16H28S
    Ethane;1-methyl-3-(2,3,3-trimethylbutan-2-ylsulfanyl)benzene
    —— N-[4-(2-chloroethylsulfonyl)-2-oxobutyl]-2-methylpropanamide;2-methylpropane —— C14H28ClNO4S
    N-[4-(2-chloroethylsulfonyl)-2-oxobutyl]-2-methylpropanamide;2-methylpropane
    —— 1-Ethyl-4-prop-1-enylsulfanylbenzene —— C11H14S
    1-Ethyl-4-prop-1-enylsulfanylbenzene
    —— 2-[[2-chloro-5-(methylamino)phenyl]methylsulfanyl]-4-methyl-1H-pyrimidin-6-one —— C13H14ClN3OS
    2-[[2-chloro-5-(methylamino)phenyl]methylsulfanyl]-4-methyl-1H-pyrimidin-6-one
    —— S-(4-pyrazol-1-ylpyrimidin-2-yl) ethanethioate —— C9H8N4OS
    S-(4-pyrazol-1-ylpyrimidin-2-yl) ethanethioate
    —— 1,3,5-Trifluoro-2-propan-2-ylsulfanylbenzene —— C9H9F3S
    1,3,5-Trifluoro-2-propan-2-ylsulfanylbenzene
    —— Ethyl-(3-hydroperoxysulfonylpropyl)-hydroxy-methylazanium —— C6H16NO5S+
    Ethyl-(3-hydroperoxysulfonylpropyl)-hydroxy-methylazanium
    —— 3-Pentylsulfinylpropanenitrile —— C8H15NOS
    3-Pentylsulfinylpropanenitrile
    —— N'-[(1E)-1-(furan-2-yl)ethylidene]-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide —— C18H18N4O2S3
    N'-[(1E)-1-(furan-2-yl)ethylidene]-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide
    —— N-[4-[4-[(1-amino-3-iminobutylidene)amino]-6-[4-(2-hydroxypropan-2-yl)piperidin-1-yl]pyrimidin-2-yl]sulfanylphenyl]propanamide —— C25H35N7O2S
    N-[4-[4-[(1-amino-3-iminobutylidene)amino]-6-[4-(2-hydroxypropan-2-yl)piperidin-1-yl]pyrimidin-2-yl]sulfanylphenyl]propanamide
    —— 5-[(5-Nitro-2-pyridin-2-ylsulfanylphenyl)methylidene]-1-prop-2-enyl-2-sulfanylidene-1,3-diazinane-4,6-dione —— C19H14N4O4S2
    5-[(5-Nitro-2-pyridin-2-ylsulfanylphenyl)methylidene]-1-prop-2-enyl-2-sulfanylidene-1,3-diazinane-4,6-dione
    —— N-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]-4-nitroaniline —— C20H16N4O4S
    N-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]-4-nitroaniline
    —— N-[(Z)-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]-4-hydroxybutanamide —— C18H16N4O4S2
    N-[(Z)-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]-4-hydroxybutanamide
    —— 2-(Fluoromethyl)-4-(2,2,2-trifluoroethylsulfanyl)aniline —— C9H9F4NS
    2-(Fluoromethyl)-4-(2,2,2-trifluoroethylsulfanyl)aniline
    —— 3-[2-(2-Phenylethylsulfanyl)imidazol-1-yl]pyridine —— C16H15N3S
    3-[2-(2-Phenylethylsulfanyl)imidazol-1-yl]pyridine
    —— N-[1-(cyclopropanecarbonylamino)cyclohexyl]-2-(4-methylpentanoyl)-5-propan-2-ylsulfanyl-1,3,4-oxadiazol-3-ium-3-carboxamide —— C22H35N4O4S+
    N-[1-(cyclopropanecarbonylamino)cyclohexyl]-2-(4-methylpentanoyl)-5-propan-2-ylsulfanyl-1,3,4-oxadiazol-3-ium-3-carboxamide
    —— 2-(1,3-Thiazol-2-ylmethylsulfanyl)-1,3-thiazole —— C7H6N2S3
    2-(1,3-Thiazol-2-ylmethylsulfanyl)-1,3-thiazole
    —— Octan-4-ylsulfanylbenzene —— C14H22S
    Octan-4-ylsulfanylbenzene
    —— (E)-N-[(3-benzylsulfanyl-5-ethyl-1,2,4-triazol-4-yl)carbamothioyl]-3-(furan-2-yl)prop-2-enamide —— C19H19N5O2S2
    (E)-N-[(3-benzylsulfanyl-5-ethyl-1,2,4-triazol-4-yl)carbamothioyl]-3-(furan-2-yl)prop-2-enamide
    —— [Methoxysulfinyl(methyl)amino]methane;methylsulfanylmethane;1,1,3,3-tetramethylthiourea —— C10H27N3O2S3
    [Methoxysulfinyl(methyl)amino]methane;methylsulfanylmethane;1,1,3,3-tetramethylthiourea
    —— N-(4-methoxyphenyl)-2-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]acetamide —— C26H21N3O6S2
    N-(4-methoxyphenyl)-2-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]acetamide
    —— 2-methyl-3-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]quinazolin-4-one —— C23H18N4O3S
    2-methyl-3-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]quinazolin-4-one
    —— 4-(2-Hydroxyethylsulfanyl)-1,3-dithiole-2-thione —— C5H6OS4
    4-(2-Hydroxyethylsulfanyl)-1,3-dithiole-2-thione
    —— (diazonioamino)-[(1R)-1-hydroxysulfanyl-2-sulfanylethyl]azanide —— C2H6N4OS2
    (diazonioamino)-[(1R)-1-hydroxysulfanyl-2-sulfanylethyl]azanide
    —— 3-Chloropropylsulfanylbenzene;ethane —— C11H17ClS
    3-Chloropropylsulfanylbenzene;ethane
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-N'-{(E)-[4-(dimethylamino)phenyl]methylidene}-1H-1,2,3-triazole-4-carbohydrazide —— C21H20ClN9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-chlorophenyl)sulfanyl]methyl}-N'-{(E)-[4-(dimethylamino)phenyl]methylidene}-1H-1,2,3-triazole-4-carbohydrazide
    —— 1-Bromo-2-sulfonylethane —— C2H3BrO2S
    1-Bromo-2-sulfonylethane
    —— N-[3-(4-bromophenyl)sulfanyl-5-nitrophenyl]-5-(4-methylphenyl)-7-(trifluoromethyl)-1,5,6,7-tetrahydropyrazolo[1,5-a]pyrimidine-3-carboxamide —— C27H21BrF3N5O3S
    N-[3-(4-bromophenyl)sulfanyl-5-nitrophenyl]-5-(4-methylphenyl)-7-(trifluoromethyl)-1,5,6,7-tetrahydropyrazolo[1,5-a]pyrimidine-3-carboxamide
    —— propan-2-yl (2Z)-2-[[5-(4-chlorophenyl)furan-2-yl]methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C29H25ClN2O4S2
    propan-2-yl (2Z)-2-[[5-(4-chlorophenyl)furan-2-yl]methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— 2,6-Di(hexan-2-yl)-4-(2-methylheptan-2-ylsulfanyl)phenol —— C26H46OS
    2,6-Di(hexan-2-yl)-4-(2-methylheptan-2-ylsulfanyl)phenol
    —— [4-[2-[6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-7H-purin-3-ium-3-yl]ethyl]piperidin-1-yl]-cyclopropylmethanone —— C23H26BrN6O3S+
    [4-[2-[6-amino-8-[(6-bromo-1,3-benzodioxol-5-yl)sulfanyl]-7H-purin-3-ium-3-yl]ethyl]piperidin-1-yl]-cyclopropylmethanone
    —— 1-Methyl-2-(1-methylsulfanylethyl)cyclopentane —— C9H18S
    1-Methyl-2-(1-methylsulfanylethyl)cyclopentane
    —— N'-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-N-propan-2-ylpropanediamide —— C14H19N3O2S
    N'-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-N-propan-2-ylpropanediamide
    —— 2-(6-Imidazo[1,2-a]pyrimidin-3-ylsulfanyl-1,3-benzothiazol-2-yl)acetamide —— C15H11N5OS2
    2-(6-Imidazo[1,2-a]pyrimidin-3-ylsulfanyl-1,3-benzothiazol-2-yl)acetamide
    —— 3,4-Dimethyl-5-propan-2-ylsulfanylheptane —— C12H26S
    3,4-Dimethyl-5-propan-2-ylsulfanylheptane
    —— 3-(2-(4-Chlorophenylthio)-5-nitrophenyl)-2-(phenylsulfonyl)prop-2-enenitrile —— C21H13ClN2O4S2
    3-(2-(4-Chlorophenylthio)-5-nitrophenyl)-2-(phenylsulfonyl)prop-2-enenitrile
    —— 5-Methyltricyclo[5.2.1.03,9]decane-5-thiol —— C11H18S
    5-Methyltricyclo[5.2.1.03,9]decane-5-thiol
    —— Methyl 4-((3-cyano-4,6-dimethyl-2-pyridinyl)sulfanyl)-2-butenoate —— C13H14N2O2S
    Methyl 4-((3-cyano-4,6-dimethyl-2-pyridinyl)sulfanyl)-2-butenoate
    —— 4-Methyl-5,5-bis(sulfanyl)pentan-1-ol —— C6H14OS2
    4-Methyl-5,5-bis(sulfanyl)pentan-1-ol
    —— N'-[(E)-(4-bromo-5-methylfuran-2-yl)methylidene]-2-(phenylsulfanyl)propanehydrazide —— C15H15BrN2O2S
    N'-[(E)-(4-bromo-5-methylfuran-2-yl)methylidene]-2-(phenylsulfanyl)propanehydrazide
    —— 3-(2,3-Difluoropropylsulfanyl)-2,2-difluoropropane-1-thiol —— C6H10F4S2
    3-(2,3-Difluoropropylsulfanyl)-2,2-difluoropropane-1-thiol
    —— 5-[[3-Nitro-4-[5-(trifluoromethyl)pyridin-2-yl]sulfanylphenyl]methylidene]-1-prop-2-enyl-2-sulfanylidene-1,3-diazinane-4,6-dione —— C20H13F3N4O4S2
    5-[[3-Nitro-4-[5-(trifluoromethyl)pyridin-2-yl]sulfanylphenyl]methylidene]-1-prop-2-enyl-2-sulfanylidene-1,3-diazinane-4,6-dione
    —— (E)-6-(isopropylthio)imidazo[2,1-b]thiazole-5-carbaldehyde oxime —— C9H11N3OS2
    (E)-6-(isopropylthio)imidazo[2,1-b]thiazole-5-carbaldehyde oxime
    —— 3-Ethyl-1,3-dimethyl-2-methylsulfanylcyclopropene —— C8H14S
    3-Ethyl-1,3-dimethyl-2-methylsulfanylcyclopropene
    —— 1-Methylsulfanylprop-2-yn-1-amine —— C4H7NS
    1-Methylsulfanylprop-2-yn-1-amine
    —— 2-[Ethyl-[1-[2-[4-(2-methylpropyl)phenyl]sulfanylphenoxy]propan-2-yl]amino]acetic acid —— C23H31NO3S
    2-[Ethyl-[1-[2-[4-(2-methylpropyl)phenyl]sulfanylphenoxy]propan-2-yl]amino]acetic acid