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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-1-(4-ethylpiperazin-1-yl)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propan-1-one —— C13H22N4OS3
    (2S)-1-(4-ethylpiperazin-1-yl)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]propan-1-one
    —— (2S)-2-[(4-methyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2S)-2-phenylpropyl]propanamide —— C19H27N5O2S
    (2S)-2-[(4-methyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2S)-2-phenylpropyl]propanamide
    —— ethyl 2-[[5-[(1R)-1-amino-3-methylbutyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetate —— C11H19N3O3S
    ethyl 2-[[5-[(1R)-1-amino-3-methylbutyl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetate
    —— [(1R)-1-[5-(2-ethoxy-2-oxoethyl)sulfanyl-1,3,4-oxadiazol-2-yl]-3-methylbutyl]azanium —— C11H20N3O3S+
    [(1R)-1-[5-(2-ethoxy-2-oxoethyl)sulfanyl-1,3,4-oxadiazol-2-yl]-3-methylbutyl]azanium
    —— ethyl (1S,5R,6R)-5-hydroxy-1-(trifluoromethyl)spiro[2-oxa-7-thiabicyclo[3.2.1]octane-4,1'-cyclohexane]-6-carboxylate —— C15H21F3O4S
    ethyl (1S,5R,6R)-5-hydroxy-1-(trifluoromethyl)spiro[2-oxa-7-thiabicyclo[3.2.1]octane-4,1'-cyclohexane]-6-carboxylate
    —— N-(3-amino-3-sulfanylidenepropyl)-N-[(1S,2S)-2-methylcyclohexyl]acetamide —— C12H22N2OS
    N-(3-amino-3-sulfanylidenepropyl)-N-[(1S,2S)-2-methylcyclohexyl]acetamide
    —— N-(3-amino-3-sulfanylidenepropyl)-N-[(1S,2R)-2-methylcyclohexyl]propanamide —— C13H24N2OS
    N-(3-amino-3-sulfanylidenepropyl)-N-[(1S,2R)-2-methylcyclohexyl]propanamide
    —— N-(3-amino-3-sulfanylidenepropyl)-2,2,2-trifluoro-N-[(1R,2S)-2-methylcyclohexyl]acetamide —— C12H19F3N2OS
    N-(3-amino-3-sulfanylidenepropyl)-2,2,2-trifluoro-N-[(1R,2S)-2-methylcyclohexyl]acetamide
    —— N-(3-amino-3-sulfanylidenepropyl)-N-prop-2-enyladamantane-1-carboxamide —— C17H26N2OS
    N-(3-amino-3-sulfanylidenepropyl)-N-prop-2-enyladamantane-1-carboxamide
    —— N-(3-amino-3-sulfanylidenepropyl)-2,2-dimethyl-N-[(1S,2S)-2-methylcyclohexyl]propanamide —— C15H28N2OS
    N-(3-amino-3-sulfanylidenepropyl)-2,2-dimethyl-N-[(1S,2S)-2-methylcyclohexyl]propanamide
    —— N-(3-amino-3-sulfanylidenepropyl)-2-methyl-N-[(1S,2R)-2-methylcyclohexyl]propanamide —— C14H26N2OS
    N-(3-amino-3-sulfanylidenepropyl)-2-methyl-N-[(1S,2R)-2-methylcyclohexyl]propanamide
    —— N-(3-amino-3-sulfanylidenepropyl)-N-[(2R)-butan-2-yl]-3-cyclohexylpropanamide —— C16H30N2OS
    N-(3-amino-3-sulfanylidenepropyl)-N-[(2R)-butan-2-yl]-3-cyclohexylpropanamide
    —— methyl (2R)-2-(2-aminophenyl)sulfanylbutanoate —— C11H15NO2S
    methyl (2R)-2-(2-aminophenyl)sulfanylbutanoate
    —— 2-methylpropyl (2R)-2-(2-aminophenyl)sulfanylpropanoate —— C13H19NO2S
    2-methylpropyl (2R)-2-(2-aminophenyl)sulfanylpropanoate
    —— (8R,8aS)-6-amino-8-(4-methylsulfanylphenyl)-2-propan-2-yl-1,3,8,8a-tetrahydroisoquinoline-5,7,7-tricarbonitrile —— C22H23N5S
    (8R,8aS)-6-amino-8-(4-methylsulfanylphenyl)-2-propan-2-yl-1,3,8,8a-tetrahydroisoquinoline-5,7,7-tricarbonitrile
    —— propan-2-yl (2S)-2-(2-aminophenyl)sulfanylbutanoate —— C13H19NO2S
    propan-2-yl (2S)-2-(2-aminophenyl)sulfanylbutanoate
    —— propan-2-yl (2R)-2-(2-aminophenyl)sulfanylbutanoate —— C13H19NO2S
    propan-2-yl (2R)-2-(2-aminophenyl)sulfanylbutanoate
    —— propan-2-yl (2R)-2-(2-aminophenyl)sulfanylpropanoate —— C12H17NO2S
    propan-2-yl (2R)-2-(2-aminophenyl)sulfanylpropanoate
    —— (2S)-3-(2-aminophenyl)sulfanylpropane-1,2-diol —— C9H13NO2S
    (2S)-3-(2-aminophenyl)sulfanylpropane-1,2-diol
    —— [(2S)-butan-2-yl] (2R)-2-(2-aminophenyl)sulfanylpropanoate —— C13H19NO2S
    [(2S)-butan-2-yl] (2R)-2-(2-aminophenyl)sulfanylpropanoate
    —— propyl (2R)-2-(2-aminophenyl)sulfanylbutanoate —— C13H19NO2S
    propyl (2R)-2-(2-aminophenyl)sulfanylbutanoate
    —— (2R)-4-(4-methylphenyl)sulfanyl-3-oxo-2-[5-(trifluoromethyl)pyridin-2-yl]butanenitrile —— C17H13F3N2OS
    (2R)-4-(4-methylphenyl)sulfanyl-3-oxo-2-[5-(trifluoromethyl)pyridin-2-yl]butanenitrile
    —— (2S)-5-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-3-oxo-2-pyridin-2-ylpentanenitrile —— C17H18N4OS
    (2S)-5-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-3-oxo-2-pyridin-2-ylpentanenitrile
    —— N-[[(3S)-3-morpholin-4-ylthiolan-3-yl]methyl]-2-phenylsulfanylacetamide —— C17H24N2O2S2
    N-[[(3S)-3-morpholin-4-ylthiolan-3-yl]methyl]-2-phenylsulfanylacetamide
    —— (5R)-5-[[(4S,4aR,8aR)-2,4-diphenyl-4,4a,5,6,7,8-hexahydrothiochromen-8a-yl]sulfanylmethyl]-4,5-dihydro-1,3-thiazol-2-amine —— C25H28N2S3
    (5R)-5-[[(4S,4aR,8aR)-2,4-diphenyl-4,4a,5,6,7,8-hexahydrothiochromen-8a-yl]sulfanylmethyl]-4,5-dihydro-1,3-thiazol-2-amine
    —— (8R,8aS)-6-amino-2-ethyl-8-(4-methylsulfanylphenyl)-1,3,8,8a-tetrahydroisoquinoline-5,7,7-tricarbonitrile —— C21H21N5S
    (8R,8aS)-6-amino-2-ethyl-8-(4-methylsulfanylphenyl)-1,3,8,8a-tetrahydroisoquinoline-5,7,7-tricarbonitrile
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(2S)-2-(4-methylpiperidin-1-yl)-2-thiophen-2-ylethyl]acetamide —— C20H28N4OS2
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(2S)-2-(4-methylpiperidin-1-yl)-2-thiophen-2-ylethyl]acetamide
    —— (4S,8Z)-2-amino-6-methyl-4-(4-methylsulfanylphenyl)-8-[(4-methylsulfanylphenyl)methylidene]-4,5,6,7-tetrahydropyrano[3,2-c]pyridin-6-ium-3-carbonitrile —— C25H26N3OS2+
    (4S,8Z)-2-amino-6-methyl-4-(4-methylsulfanylphenyl)-8-[(4-methylsulfanylphenyl)methylidene]-4,5,6,7-tetrahydropyrano[3,2-c]pyridin-6-ium-3-carbonitrile
    —— ethyl (2R)-2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]-3-oxobutanoate —— C9H11N3O5S
    ethyl (2R)-2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]-3-oxobutanoate
    —— (2Z,5R)-2-[(Z)-benzylidenehydrazinylidene]-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-1,3-thiazolidin-4-one —— C18H15F2N3OS2
    (2Z,5R)-2-[(Z)-benzylidenehydrazinylidene]-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-1,3-thiazolidin-4-one
    —— (2Z,5R)-5-[[3-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-pyridin-2-ylmethylidenehydrazinylidene]-1,3-thiazolidin-4-one —— C17H14F2N4OS2
    (2Z,5R)-5-[[3-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-pyridin-2-ylmethylidenehydrazinylidene]-1,3-thiazolidin-4-one
    —— (2Z,5R)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-pyridin-4-ylmethylidenehydrazinylidene]-1,3-thiazolidin-4-one —— C17H14F2N4OS2
    (2Z,5R)-5-[[4-(difluoromethylsulfanyl)phenyl]methyl]-2-[(Z)-pyridin-4-ylmethylidenehydrazinylidene]-1,3-thiazolidin-4-one
    —— (5S,6R,7R)-5-methyl-7-(4-methylphenyl)-2-oxo-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-6-carbaldehyde —— C15H15NO2S2
    (5S,6R,7R)-5-methyl-7-(4-methylphenyl)-2-oxo-3,5,6,7-tetrahydrothiopyrano[2,3-d][1,3]thiazole-6-carbaldehyde
    —— (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]-1-[(1R)-cyclohex-3-en-1-yl]methanimine —— C19H23ClN4S
    (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]-1-[(1R)-cyclohex-3-en-1-yl]methanimine
    —— 2-[(4-fluorophenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole —— C13H15FN3OS+
    2-[(4-fluorophenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole
    —— 2-(2-methylprop-2-enylsulfanyl)-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole —— C10H16N3OS+
    2-(2-methylprop-2-enylsulfanyl)-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole
    —— 2-[(2-chlorophenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole —— C13H15ClN3OS+
    2-[(2-chlorophenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole
    —— (Z)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-[(1R)-cyclohex-3-en-1-yl]methanimine —— C17H19BrN4S
    (Z)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-[(1R)-cyclohex-3-en-1-yl]methanimine
    —— (Z)-1-[(1R)-cyclohex-3-en-1-yl]-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C17H20N4S
    (Z)-1-[(1R)-cyclohex-3-en-1-yl]-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— 2-[(4-methylphenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole —— C14H18N3OS+
    2-[(4-methylphenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole
    —— 6-methyl-5-[[5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1H-pyrimidine-2,4-dione —— C12H16N5O3S+
    6-methyl-5-[[5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazol-2-yl]sulfanylmethyl]-1H-pyrimidine-2,4-dione
    —— 2-[(3-methylphenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole —— C14H18N3OS+
    2-[(3-methylphenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole
    —— 2-[(2-methylphenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole —— C14H18N3OS+
    2-[(2-methylphenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole
    —— 2-[[5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide —— C8H13N4O2S+
    2-[[5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetamide
    —— 2-[(2-fluorophenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole —— C13H15FN3OS+
    2-[(2-fluorophenyl)methylsulfanyl]-5-[(2S)-pyrrolidin-1-ium-2-yl]-1,3,4-oxadiazole
    —— [(1S)-1-[5-[2-(dimethylamino)-2-oxoethyl]sulfanyl-1,3,4-oxadiazol-2-yl]-3-methylbutyl]azanium —— C11H21N4O2S+
    [(1S)-1-[5-[2-(dimethylamino)-2-oxoethyl]sulfanyl-1,3,4-oxadiazol-2-yl]-3-methylbutyl]azanium
    —— 2-[(2S)-3-benzylsulfonyl-2-hydroxypropyl]sulfanyl-4,6-dimethylpyridine-3-carbonitrile —— C18H20N2O3S2
    2-[(2S)-3-benzylsulfonyl-2-hydroxypropyl]sulfanyl-4,6-dimethylpyridine-3-carbonitrile
    —— (3R)-3-(4,6-diaminopyrimidin-2-yl)sulfanylbutanenitrile —— C8H11N5S
    (3R)-3-(4,6-diaminopyrimidin-2-yl)sulfanylbutanenitrile
    —— (1R,2R)-2-[(6-amino-4-oxo-1H-pyrimidin-2-yl)sulfanyl]cyclopentane-1-carbonitrile —— C10H12N4OS
    (1R,2R)-2-[(6-amino-4-oxo-1H-pyrimidin-2-yl)sulfanyl]cyclopentane-1-carbonitrile
    —— (1R,2S)-2-[(6-amino-4-oxo-1H-pyrimidin-2-yl)sulfanyl]cyclopentane-1-carbonitrile —— C10H12N4OS
    (1R,2S)-2-[(6-amino-4-oxo-1H-pyrimidin-2-yl)sulfanyl]cyclopentane-1-carbonitrile