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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(E)-[(3E)-3-[[2-(4-bromo-2,5-dimethylphenyl)sulfanylacetyl]hydrazinylidene]cyclohexylidene]amino]acetamide —— C26H30Br2N4O2S2
    2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(E)-[(3E)-3-[[2-(4-bromo-2,5-dimethylphenyl)sulfanylacetyl]hydrazinylidene]cyclohexylidene]amino]acetamide
    —— (NZ)-N-[1-[4-(4-aminophenyl)sulfanylphenyl]ethylidene]hydroxylamine 7402-83-7 C14H14N2OS
    (NZ)-N-[1-[4-(4-aminophenyl)sulfanylphenyl]ethylidene]hydroxylamine
    —— 1-methyl-3-[(Z)-[5-(4-methylphenyl)sulfanylfuran-2-yl]methylideneamino]thiourea —— C14H15N3OS2
    1-methyl-3-[(Z)-[5-(4-methylphenyl)sulfanylfuran-2-yl]methylideneamino]thiourea
    —— 1-(2-methoxyethyl)-3-[(Z)-(4-methylsulfanylphenyl)methylideneamino]thiourea —— C12H17N3OS2
    1-(2-methoxyethyl)-3-[(Z)-(4-methylsulfanylphenyl)methylideneamino]thiourea
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-[(E)-2-methyl-3-phenylprop-2-enylidene]amino]triazole-4-carboxamide —— C22H19ClN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-[(E)-2-methyl-3-phenylprop-2-enylidene]amino]triazole-4-carboxamide
    —— diethyl-[(Z)-4-ethylsulfanylhex-3-en-3-yl]sulfanium —— C12H25S2+
    diethyl-[(Z)-4-ethylsulfanylhex-3-en-3-yl]sulfanium
    —— 1-butyl-3-[(Z)-(4-methylsulfanylphenyl)methylideneamino]thiourea —— C13H19N3S2
    1-butyl-3-[(Z)-(4-methylsulfanylphenyl)methylideneamino]thiourea
    —— 2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1Z)-1-(4-chlorophenyl)ethylidene]acetohydrazide —— C19H16Cl2N4OS3
    2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1Z)-1-(4-chlorophenyl)ethylidene]acetohydrazide
    —— 2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(1Z)-1-(4-bromophenyl)ethylidene]acetohydrazide —— C19H17BrN4OS3
    2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(1Z)-1-(4-bromophenyl)ethylidene]acetohydrazide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-5-(piperidin-1-ylmethyl)triazole-4-carboxamide —— C19H23N9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-5-(piperidin-1-ylmethyl)triazole-4-carboxamide
    —— (5E)-2-[2-hydroxyethyl(methyl)amino]-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazol-4-one —— C14H16N2O2S2
    (5E)-2-[2-hydroxyethyl(methyl)amino]-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazol-4-one
    —— ethyl (2Z)-2-cyano-3-[5-methyl-2-(methylsulfanyl)thiophen-3-yl]prop-2-enoate —— C12H13NO2S2
    ethyl (2Z)-2-cyano-3-[5-methyl-2-(methylsulfanyl)thiophen-3-yl]prop-2-enoate
    —— 2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-1-(furan-2-yl)ethylideneamino]acetamide —— C17H15ClN4O2S3
    2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-1-(furan-2-yl)ethylideneamino]acetamide
    —— 4-[(1E,5E,7E)-11-methoxy-8-methyltetradeca-1,5,7,13-tetraenyl]-2-(2-methylcyclopropyl)-4,5-dihydro-1,3-thiazole —— C23H35NOS
    4-[(1E,5E,7E)-11-methoxy-8-methyltetradeca-1,5,7,13-tetraenyl]-2-(2-methylcyclopropyl)-4,5-dihydro-1,3-thiazole
    —— N-[(Z)-1-(4-fluorophenyl)ethylideneamino]-2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C23H25FN6OS
    N-[(Z)-1-(4-fluorophenyl)ethylideneamino]-2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— ethyl (2E)-2-{2-[(pyrimidin-2-ylsulfanyl)acetyl]hydrazinylidene}cyclopentanecarboxylate —— C14H18N4O3S
    ethyl (2E)-2-{2-[(pyrimidin-2-ylsulfanyl)acetyl]hydrazinylidene}cyclopentanecarboxylate
    —— (3Z,5E)-1-methyl-3,5-bis[(4-methylsulfanylphenyl)methylidene]piperidin-4-one —— C22H23NOS2
    (3Z,5E)-1-methyl-3,5-bis[(4-methylsulfanylphenyl)methylidene]piperidin-4-one
    —— 2-methylpropyl (2E)-7-methyl-2-(4-methylbenzylidene)-5-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C27H28N2O3S2
    2-methylpropyl (2E)-7-methyl-2-(4-methylbenzylidene)-5-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-4-phenylbutan-2-ylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C22H22N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-4-phenylbutan-2-ylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(Z)-1-thiophen-2-ylethylideneamino]acetamide —— C14H16N4OS2
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(Z)-1-thiophen-2-ylethylideneamino]acetamide
    —— N'',N'''-bis[(2Z)-3,3-dimethylbutan-2-ylidene]thiocarbonohydrazide —— C13H26N4S
    N'',N'''-bis[(2Z)-3,3-dimethylbutan-2-ylidene]thiocarbonohydrazide
    —— 1-O-tert-butyl 5-O-methyl (E,4E)-4-(phenylsulfanylmethylidene)pent-2-enedioate —— C17H20O4S
    1-O-tert-butyl 5-O-methyl (E,4E)-4-(phenylsulfanylmethylidene)pent-2-enedioate
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]methyl}-N'-[(1Z)-1-(pyridin-4-yl)ethylidene]-1H-1,2,3-triazole-4-carbohydrazide —— C16H16N12O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-{[(4-methyl-4H-1,2,4-triazol-3-yl)sulfanyl]methyl}-N'-[(1Z)-1-(pyridin-4-yl)ethylidene]-1H-1,2,3-triazole-4-carbohydrazide
    —— (2R)-2-[(3R)-3-methylmorpholin-4-yl]-2-(4-methylsulfanylphenyl)ethanamine —— C14H22N2OS
    (2R)-2-[(3R)-3-methylmorpholin-4-yl]-2-(4-methylsulfanylphenyl)ethanamine
    —— (2E,5E)-3-(2-methylpropyl)-5-[4-(methylsulfanyl)benzylidene]-2-(phenylimino)-1,3-thiazolidin-4-one —— C21H22N2OS2
    (2E,5E)-3-(2-methylpropyl)-5-[4-(methylsulfanyl)benzylidene]-2-(phenylimino)-1,3-thiazolidin-4-one
    —— (E)-imino(phenylsulfanylmethylimino)azanium —— C7H8N3S+
    (E)-imino(phenylsulfanylmethylimino)azanium
    —— N'-[(1E)-2-(2-cyanoethyl)cyclohexylidene]-2-(phenylsulfanyl)propanehydrazide —— C18H23N3OS
    N'-[(1E)-2-(2-cyanoethyl)cyclohexylidene]-2-(phenylsulfanyl)propanehydrazide
    —— phenyl (2E)-7-methyl-2-({5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene)-3-oxo-5-phenyl-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C32H24N2O4S2
    phenyl (2E)-7-methyl-2-({5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene)-3-oxo-5-phenyl-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— (3S)-N-ethyl-5,6-difluoro-2,3-dihydro-1-benzothiophen-3-amine —— C10H11F2NS
    (3S)-N-ethyl-5,6-difluoro-2,3-dihydro-1-benzothiophen-3-amine
    —— (3S)-N-ethyl-5-fluoro-2,3-dihydro-1-benzothiophen-3-amine —— C10H12FNS
    (3S)-N-ethyl-5-fluoro-2,3-dihydro-1-benzothiophen-3-amine
    —— (3S)-N-ethyl-5,7-difluoro-2,3-dihydro-1-benzothiophen-3-amine —— C10H11F2NS
    (3S)-N-ethyl-5,7-difluoro-2,3-dihydro-1-benzothiophen-3-amine
    —— (3R)-5-fluoro-N-propyl-2,3-dihydro-1-benzothiophen-3-amine —— C11H14FNS
    (3R)-5-fluoro-N-propyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (3R)-5,7-difluoro-N-propan-2-yl-2,3-dihydro-1-benzothiophen-3-amine —— C11H13F2NS
    (3R)-5,7-difluoro-N-propan-2-yl-2,3-dihydro-1-benzothiophen-3-amine
    —— (3R)-5-fluoro-N-methyl-2,3-dihydro-1-benzothiophen-3-amine —— C9H10FNS
    (3R)-5-fluoro-N-methyl-2,3-dihydro-1-benzothiophen-3-amine
    —— 2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-[(E)-3-(furan-2-yl)-2-methylprop-2-enylidene]amino]acetamide —— C19H17ClN4O2S3
    2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-[(E)-3-(furan-2-yl)-2-methylprop-2-enylidene]amino]acetamide
    —— (3S)-N-ethyl-4,7-difluoro-2,3-dihydro-1-benzothiophen-3-amine —— C10H11F2NS
    (3S)-N-ethyl-4,7-difluoro-2,3-dihydro-1-benzothiophen-3-amine
    —— (3S)-7-bromo-N-methyl-2,3-dihydro-1-benzothiophen-3-amine —— C9H10BrNS
    (3S)-7-bromo-N-methyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (3S)-N-ethyl-7-fluoro-2,3-dihydro-1-benzothiophen-3-amine —— C10H12FNS
    (3S)-N-ethyl-7-fluoro-2,3-dihydro-1-benzothiophen-3-amine
    —— (3R)-5,6-difluoro-2,3-dihydro-1-benzothiophen-3-amine —— C8H7F2NS
    (3R)-5,6-difluoro-2,3-dihydro-1-benzothiophen-3-amine
    —— (3R)-5,6-difluoro-N-propan-2-yl-2,3-dihydro-1-benzothiophen-3-amine —— C11H13F2NS
    (3R)-5,6-difluoro-N-propan-2-yl-2,3-dihydro-1-benzothiophen-3-amine
    —— (3R)-5,6-dimethyl-2,3-dihydro-1-benzothiophen-3-amine —— C10H13NS
    (3R)-5,6-dimethyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (3R)-N-ethyl-4,7-difluoro-2,3-dihydro-1-benzothiophen-3-amine —— C10H11F2NS
    (3R)-N-ethyl-4,7-difluoro-2,3-dihydro-1-benzothiophen-3-amine
    —— (3S)-5-fluoro-N-propyl-2,3-dihydro-1-benzothiophen-3-amine —— C11H14FNS
    (3S)-5-fluoro-N-propyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (3S)-5,6-difluoro-N-propan-2-yl-2,3-dihydro-1-benzothiophen-3-amine —— C11H13F2NS
    (3S)-5,6-difluoro-N-propan-2-yl-2,3-dihydro-1-benzothiophen-3-amine
    —— (3S)-5,7-difluoro-N-methyl-2,3-dihydro-1-benzothiophen-3-amine —— C9H9F2NS
    (3S)-5,7-difluoro-N-methyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (3S)-5,7-dimethyl-2,3-dihydro-1-benzothiophen-3-amine —— C10H13NS
    (3S)-5,7-dimethyl-2,3-dihydro-1-benzothiophen-3-amine
    —— N-[(1S)-1-(4-methylsulfanylphenyl)ethyl]-1H-pyrazol-4-amine —— C12H15N3S
    N-[(1S)-1-(4-methylsulfanylphenyl)ethyl]-1H-pyrazol-4-amine
    —— 2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-1-(furan-2-yl)ethylideneamino]acetamide —— C17H16N4O2S3
    2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-1-(furan-2-yl)ethylideneamino]acetamide
    —— (3R)-7-fluoro-N-propyl-2,3-dihydro-1-benzothiophen-3-amine —— C11H14FNS
    (3R)-7-fluoro-N-propyl-2,3-dihydro-1-benzothiophen-3-amine
    —— (3S)-7-fluoro-N-propyl-2,3-dihydro-1-benzothiophen-3-amine —— C11H14FNS
    (3S)-7-fluoro-N-propyl-2,3-dihydro-1-benzothiophen-3-amine