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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-t-butylsulfanyl-3-chloromethylpyridine 1609289-23-7 C10H14ClNS
    2-t-butylsulfanyl-3-chloromethylpyridine
    —— 2-sec-butylsulfanyl-3-chloromethylpyridine 1609289-62-4 C10H14ClNS
    2-sec-butylsulfanyl-3-chloromethylpyridine
    —— 2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-[(Z)-2-chloro-3-phenylprop-2-enylidene]amino]acetamide —— C20H16Cl2N4OS3
    2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-[(Z)-2-chloro-3-phenylprop-2-enylidene]amino]acetamide
    —— 3-chloromethyl-2-(2,2,2-trifluoroethylsulfanyl)pyridine 1609289-27-1 C8H7ClF3NS
    3-chloromethyl-2-(2,2,2-trifluoroethylsulfanyl)pyridine
    —— N-[(Z)-(2-chlorophenyl)methylideneamino]-2-[[4-(4-chlorophenyl)-1,3-thiazol-2-yl]sulfanyl]acetamide —— C18H13Cl2N3OS2
    N-[(Z)-(2-chlorophenyl)methylideneamino]-2-[[4-(4-chlorophenyl)-1,3-thiazol-2-yl]sulfanyl]acetamide
    —— 2-[[4-(4-chlorophenyl)-1,3-thiazol-2-yl]sulfanyl]-N-[(Z)-(4-fluorophenyl)methylideneamino]acetamide —— C18H13ClFN3OS2
    2-[[4-(4-chlorophenyl)-1,3-thiazol-2-yl]sulfanyl]-N-[(Z)-(4-fluorophenyl)methylideneamino]acetamide
    —— 2-[[4-(4-chlorophenyl)-1,3-thiazol-2-yl]sulfanyl]-N-[(Z)-(4-methylphenyl)methylideneamino]acetamide —— C19H16ClN3OS2
    2-[[4-(4-chlorophenyl)-1,3-thiazol-2-yl]sulfanyl]-N-[(Z)-(4-methylphenyl)methylideneamino]acetamide
    —— 4-cyclopropyl-N-(4-((7-methoxy-1,5-naphthyridin-4-yl)sulfanyl)phenyl)-1-phthalazinamine —— C26H21N5OS
    4-cyclopropyl-N-(4-((7-methoxy-1,5-naphthyridin-4-yl)sulfanyl)phenyl)-1-phthalazinamine
    —— 4-(6,7-dihydrothieno[3,2-c]pyridin-5(4H)-yl)-N-(4-((7-(methyloxy)-1,5-naphthyridin-4-yl)thio)phenyl)-1-phthalazinamine —— C30H24N6OS2
    4-(6,7-dihydrothieno[3,2-c]pyridin-5(4H)-yl)-N-(4-((7-(methyloxy)-1,5-naphthyridin-4-yl)thio)phenyl)-1-phthalazinamine
    —— N-(4-((7-(methyloxy)-1,5-naphthyridin-4-yl)thio)phenyl)-4-(4-morpholinyl)-1-phthalazinamine —— C27H24N6O2S
    N-(4-((7-(methyloxy)-1,5-naphthyridin-4-yl)thio)phenyl)-4-(4-morpholinyl)-1-phthalazinamine
    —— N-methyl-N'-(4-((7-(methyloxy)-1,5-naphthyridin-4-yl)thio)phenyl)-N-propyl-1,4-phthalazinediamine —— C27H26N6OS
    N-methyl-N'-(4-((7-(methyloxy)-1,5-naphthyridin-4-yl)thio)phenyl)-N-propyl-1,4-phthalazinediamine
    —— C16H13ClN4OS4 —— C16H13ClN4OS4
    C16H13ClN4OS4
    —— 2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-(5-methylthiophen-2-yl)methylideneamino]acetamide —— C17H15ClN4OS4
    2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-(5-methylthiophen-2-yl)methylideneamino]acetamide
    —— 1-(Propanethioylamino)ethyl 2-methylprop-2-enoate —— C9H15NO2S
    1-(Propanethioylamino)ethyl 2-methylprop-2-enoate
    —— 4-chloro-2-(cyclopentylthio)-6,7-dihydro-5H-cyclopenta[b]pyridine —— C13H16ClNS
    4-chloro-2-(cyclopentylthio)-6,7-dihydro-5H-cyclopenta[b]pyridine
    —— (E)-hept-2-enethial —— C7H12S
    (E)-hept-2-enethial
    —— [[4-(2-Methylsulfonylethyl)cyclohexyl]amino] 2,2,2-trifluoroacetate —— C11H18F3NO4S
    [[4-(2-Methylsulfonylethyl)cyclohexyl]amino] 2,2,2-trifluoroacetate
    —— 2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]acetamide —— C17H16N4OS4
    2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]acetamide
    —— 1-Sulfinosulfanylpentane —— C5H12O2S2
    1-Sulfinosulfanylpentane
    —— 2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-thiophen-2-ylmethylideneamino]acetamide —— C16H14N4OS4
    2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-thiophen-2-ylmethylideneamino]acetamide
    —— 2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-(3-methylphenyl)methylideneamino]acetamide —— C19H17ClN4OS3
    2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-(3-methylphenyl)methylideneamino]acetamide
    —— 3-methylsulfonyl-3H-pyrazole —— C4H6N2O2S
    3-methylsulfonyl-3H-pyrazole
    —— 2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]acetamide —— C18H18N4OS4
    2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-(3-methylthiophen-2-yl)methylideneamino]acetamide
    —— N-[4-[[4-[1-(5-methyl-4-oxo-3-phenylpyrrolo[2,1-f][1,2,4]triazin-2-yl)ethylamino]-7H-pyrrolo[2,3-d]pyrimidin-5-yl]sulfanyl]phenyl]methanesulfonamide —— C28H26N8O3S2
    N-[4-[[4-[1-(5-methyl-4-oxo-3-phenylpyrrolo[2,1-f][1,2,4]triazin-2-yl)ethylamino]-7H-pyrrolo[2,3-d]pyrimidin-5-yl]sulfanyl]phenyl]methanesulfonamide
    —— (Z)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-(trifluoromethyl)-1,2,4-triazol-4-yl]-1-phenylmethanimine —— C17H12BrF3N4S
    (Z)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-(trifluoromethyl)-1,2,4-triazol-4-yl]-1-phenylmethanimine
    —— N-[(Z)-[3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl]methylideneamino]furan-2-carboxamide —— C19H11N5O6S2
    N-[(Z)-[3-nitro-4-[(6-nitro-1,3-benzothiazol-2-yl)sulfanyl]phenyl]methylideneamino]furan-2-carboxamide
    —— 2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-(2-bromophenyl)methylideneamino]acetamide —— C18H15BrN4OS3
    2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-(2-bromophenyl)methylideneamino]acetamide
    —— 1-sulfanylidene-2H-pyrazin-1-ium —— C4H5N2S+
    1-sulfanylidene-2H-pyrazin-1-ium
    —— 2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-(3-bromophenyl)methylideneamino]acetamide —— C18H15BrN4OS3
    2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-(3-bromophenyl)methylideneamino]acetamide
    —— 2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-(4-chlorophenyl)methylideneamino]acetamide —— C18H15ClN4OS3
    2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-(4-chlorophenyl)methylideneamino]acetamide
    —— N-[(Z)-(4-chlorophenyl)methylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C19H17ClN4OS3
    N-[(Z)-(4-chlorophenyl)methylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— (NZ)-N-[(5-methyl-2-methylsulfanylthiophen-3-yl)methylidene]hydroxylamine —— C7H9NOS2
    (NZ)-N-[(5-methyl-2-methylsulfanylthiophen-3-yl)methylidene]hydroxylamine
    —— C17H16ClN5OS3 —— C17H16ClN5OS3
    C17H16ClN5OS3
    —— 6-(cyclopropylmethylthio)pyridin-3-ol 1593701-59-7 C9H11NOS
    6-(cyclopropylmethylthio)pyridin-3-ol
    —— Trimethyl(1-methylsulfonylpropan-2-yl)silane —— C7H18O2SSi
    Trimethyl(1-methylsulfonylpropan-2-yl)silane
    —— C22H24ClN5OS3 —— C22H24ClN5OS3
    C22H24ClN5OS3
    —— 2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-pyridin-2-ylmethylideneamino]acetamide —— C17H14ClN5OS3
    2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-pyridin-2-ylmethylideneamino]acetamide
    —— 2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-(5-methylthiophen-2-yl)methylideneamino]acetamide —— C17H15ClN4OS4
    2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-(5-methylthiophen-2-yl)methylideneamino]acetamide
    —— 9-[4-(tert-butylamino)butyl]-8-[[6-(1H-pyrazol-5-yl)-1,3-benzodioxol-5-yl]sulfanyl]purin-6-amine —— C23H28N8O2S
    9-[4-(tert-butylamino)butyl]-8-[[6-(1H-pyrazol-5-yl)-1,3-benzodioxol-5-yl]sulfanyl]purin-6-amine
    —— 2-(5-amino-1,3,4-thiadiazol-2-yl)-N-[(Z)-[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]acetamide —— C15H12ClN5O2S2
    2-(5-amino-1,3,4-thiadiazol-2-yl)-N-[(Z)-[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]acetamide
    —— 9-[4-(cyclopropylamino)butyl]-8-[[6-(1H-pyrazol-5-yl)-1,3-benzodioxol-5-yl]sulfanyl]purin-6-amine —— C22H24N8O2S
    9-[4-(cyclopropylamino)butyl]-8-[[6-(1H-pyrazol-5-yl)-1,3-benzodioxol-5-yl]sulfanyl]purin-6-amine
    —— N-[(Z)-(3-chlorophenyl)methylideneamino]-2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C18H14Cl2N4OS3
    N-[(Z)-(3-chlorophenyl)methylideneamino]-2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[(Z)-[2-(ethylamino)-2-sulfanylideneethylidene]amino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C16H19N5OS4
    N-[(Z)-[2-(ethylamino)-2-sulfanylideneethylidene]amino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N-[3-[6-amino-8-[[6-(1H-pyrazol-5-yl)-1,3-benzodioxol-5-yl]sulfanyl]purin-9-yl]propyl]-2-methylpropane-2-sulfinamide —— C22H26N8O3S2
    N-[3-[6-amino-8-[[6-(1H-pyrazol-5-yl)-1,3-benzodioxol-5-yl]sulfanyl]purin-9-yl]propyl]-2-methylpropane-2-sulfinamide
    —— N-[3-[6-amino-8-[[6-(1H-pyrazol-5-yl)-1,3-benzodioxol-5-yl]sulfanyl]purin-9-yl]propyl]propane-2-sulfonamide —— C21H24N8O4S2
    N-[3-[6-amino-8-[[6-(1H-pyrazol-5-yl)-1,3-benzodioxol-5-yl]sulfanyl]purin-9-yl]propyl]propane-2-sulfonamide
    —— 2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-(5-methylfuran-2-yl)methylideneamino]acetamide —— C17H15ClN4O2S3
    2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-(5-methylfuran-2-yl)methylideneamino]acetamide
    —— 2-[[(2-Ethylsulfanylphenyl)-phosphanylmethylidene]amino]-4-(trifluoromethylsulfanyl)phenol —— C16H15F3NOPS2
    2-[[(2-Ethylsulfanylphenyl)-phosphanylmethylidene]amino]-4-(trifluoromethylsulfanyl)phenol
    —— 1-methyl-N-(3-methylsulfonylpropyl)azetidin-3-amine —— C8H18N2O2S
    1-methyl-N-(3-methylsulfonylpropyl)azetidin-3-amine
    —— N-[(Z)-(3-methylphenyl)methylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C20H20N4OS3
    N-[(Z)-(3-methylphenyl)methylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N'-[(1Z,2Z)-2-bromo-3-phenylprop-2-en-1-ylidene]-2-[(4,6-dimethylpyrimidin-2-yl)sulfanyl]acetohydrazide —— C17H17BrN4OS
    N'-[(1Z,2Z)-2-bromo-3-phenylprop-2-en-1-ylidene]-2-[(4,6-dimethylpyrimidin-2-yl)sulfanyl]acetohydrazide