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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-(3-methylphenyl)methylideneamino]acetamide —— C16H15ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-(3-methylphenyl)methylideneamino]acetamide
    —— (Z)-1-(5-quinolin-8-ylsulfanylfuran-2-yl)-N-(1,2,4-triazol-4-yl)methanimine —— C16H11N5OS
    (Z)-1-(5-quinolin-8-ylsulfanylfuran-2-yl)-N-(1,2,4-triazol-4-yl)methanimine
    —— 3-[(Z)-hydroxyiminomethyl]-9-methyl-2-(4-methylphenyl)sulfanylpyrido[1,2-a]pyrimidin-4-one —— C17H15N3O2S
    3-[(Z)-hydroxyiminomethyl]-9-methyl-2-(4-methylphenyl)sulfanylpyrido[1,2-a]pyrimidin-4-one
    —— 2-[[5-[(1S)-1-cyano-2-(4-methylphenyl)ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide —— C17H20N4OS3
    2-[[5-[(1S)-1-cyano-2-(4-methylphenyl)ethyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]-N-propylacetamide
    —— (2R)-2-[[4-(3-methoxypropyl)-5-oxo-1H-1,2,4-triazol-3-yl]sulfanyl]-3-(4-methylphenyl)propanenitrile —— C16H20N4O2S
    (2R)-2-[[4-(3-methoxypropyl)-5-oxo-1H-1,2,4-triazol-3-yl]sulfanyl]-3-(4-methylphenyl)propanenitrile
    —— (2Z)-5-ethoxy-2-[(furan-2-ylmethylamino)methylidene]-1-benzothiophen-3-one —— C16H15NO3S
    (2Z)-5-ethoxy-2-[(furan-2-ylmethylamino)methylidene]-1-benzothiophen-3-one
    —— (2R)-2-(3-methyl-2,4-dioxo-7-propan-2-yl-1-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-3-(4-methylphenyl)propanenitrile —— C23H27N5O2S
    (2R)-2-(3-methyl-2,4-dioxo-7-propan-2-yl-1-propylpyrimido[4,5-d]pyrimidin-5-yl)sulfanyl-3-(4-methylphenyl)propanenitrile
    —— 1-[(Z)-(4-methylsulfanylphenyl)methylideneamino]tetrazol-5-amine 5848-48-6 C9H10N6S
    1-[(Z)-(4-methylsulfanylphenyl)methylideneamino]tetrazol-5-amine
    —— (2S)-N-[(3-fluorophenyl)methyl]-N-methyl-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C14H16FN3OS2
    (2S)-N-[(3-fluorophenyl)methyl]-N-methyl-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— (Z)-1-(furan-2-yl)-N-(3-methylsulfanyl-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-yl)methanimine —— C9H8N6OS
    (Z)-1-(furan-2-yl)-N-(3-methylsulfanyl-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-yl)methanimine
    —— (2R)-4-butoxy-1-methylsulfonyl-N-propylbutan-2-amine —— C12H27NO3S
    (2R)-4-butoxy-1-methylsulfonyl-N-propylbutan-2-amine
    —— (Z)-N-(3-ethylsulfanyl-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-yl)-1-(furan-2-yl)methanimine —— C10H10N6OS
    (Z)-N-(3-ethylsulfanyl-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-yl)-1-(furan-2-yl)methanimine
    —— (2R)-1-cyclohexyl-3-methylsulfonylpropan-2-amine —— C10H21NO2S
    (2R)-1-cyclohexyl-3-methylsulfonylpropan-2-amine
    —— (2S)-1-cyclopentyl-3-methylsulfonylpropan-2-amine —— C9H19NO2S
    (2S)-1-cyclopentyl-3-methylsulfonylpropan-2-amine
    —— (2S)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide —— C15H18FN3OS3
    (2S)-2-[(5-ethylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide
    —— (2S)-1-cyclohexyl-3-methylsulfonylpropan-2-amine —— C10H21NO2S
    (2S)-1-cyclohexyl-3-methylsulfonylpropan-2-amine
    —— (2R)-1-cyclopentyl-3-methylsulfonylpropan-2-amine —— C9H19NO2S
    (2R)-1-cyclopentyl-3-methylsulfonylpropan-2-amine
    —— (2S)-4-butoxy-1-methylsulfonyl-N-propylbutan-2-amine —— C12H27NO3S
    (2S)-4-butoxy-1-methylsulfonyl-N-propylbutan-2-amine
    —— (1R)-1-(4-methylcyclohexyl)-3-methylsulfonylpropan-1-amine —— C11H23NO2S
    (1R)-1-(4-methylcyclohexyl)-3-methylsulfonylpropan-1-amine
    —— (1S)-1-(4-methylcyclohexyl)-3-methylsulfonylpropan-1-amine —— C11H23NO2S
    (1S)-1-(4-methylcyclohexyl)-3-methylsulfonylpropan-1-amine
    —— N-[(Z)-(3-chlorophenyl)methylideneamino]-2-phenylsulfanylacetamide —— C15H13ClN2OS
    N-[(Z)-(3-chlorophenyl)methylideneamino]-2-phenylsulfanylacetamide
    —— (2R)-2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-(4-methylphenyl)propanenitrile —— C18H22N4S2
    (2R)-2-[[5-(cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-3-(4-methylphenyl)propanenitrile
    —— 6-((1-Acetyl-2-hydroxy-1-propenyl)thio)-1,2,4-triazine-3,5(2H,4H)-dione —— C8H9N3O4S
    6-((1-Acetyl-2-hydroxy-1-propenyl)thio)-1,2,4-triazine-3,5(2H,4H)-dione
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(Z)-thiophen-2-ylmethylideneamino]acetamide —— C13H14N4OS2
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(Z)-thiophen-2-ylmethylideneamino]acetamide
    —— (2S)-3-(4-methylphenyl)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanenitrile —— C16H18N4S
    (2S)-3-(4-methylphenyl)-2-[(5-methyl-4-prop-2-enyl-1,2,4-triazol-3-yl)sulfanyl]propanenitrile
    —— (2S)-N-[(3-fluorophenyl)methyl]-N-methyl-2-pyridin-2-ylsulfanylpropanamide —— C16H17FN2OS
    (2S)-N-[(3-fluorophenyl)methyl]-N-methyl-2-pyridin-2-ylsulfanylpropanamide
    —— (NZ)-N-[[5-[(dimethylamino)methyl]-2-ethylsulfanylthiophen-3-yl]methylidene]hydroxylamine —— C10H16N2OS2
    (NZ)-N-[[5-[(dimethylamino)methyl]-2-ethylsulfanylthiophen-3-yl]methylidene]hydroxylamine
    —— N-butyl-2-(2-chlorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C16H22ClNO3S2
    N-butyl-2-(2-chlorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— (2S)-N-[[4-(dimethylamino)phenyl]methyl]-N-methyl-2-phenylsulfanylpropanamide —— C19H24N2OS
    (2S)-N-[[4-(dimethylamino)phenyl]methyl]-N-methyl-2-phenylsulfanylpropanamide
    —— N-[(Z)-benzylideneamino]-2-[2-(dimethylamino)-6-methylpyrimidin-4-yl]sulfanylacetamide —— C16H19N5OS
    N-[(Z)-benzylideneamino]-2-[2-(dimethylamino)-6-methylpyrimidin-4-yl]sulfanylacetamide
    —— 1-[1-[(2R)-1-methoxypropan-2-yl]-2,5-dimethylpyrrol-3-yl]-2-(1-methylimidazol-2-yl)sulfanylethanone —— C16H23N3O2S
    1-[1-[(2R)-1-methoxypropan-2-yl]-2,5-dimethylpyrrol-3-yl]-2-(1-methylimidazol-2-yl)sulfanylethanone
    —— (2S)-N-benzyl-2-(2-chlorophenyl)sulfanyl-N-ethylpropanamide —— C18H20ClNOS
    (2S)-N-benzyl-2-(2-chlorophenyl)sulfanyl-N-ethylpropanamide
    —— (2R)-2-phenylsulfanyl-N-(2,4,4-trimethylpentan-2-yl)propanamide —— C17H27NOS
    (2R)-2-phenylsulfanyl-N-(2,4,4-trimethylpentan-2-yl)propanamide
    —— 2-(2-chlorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-propylacetamide —— C15H20ClNO3S2
    2-(2-chlorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-propylacetamide
    —— 2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]ethanol —— C16H22N2O2S2
    2-[[5-[(5S)-5-tert-butyl-4,5,6,7-tetrahydro-1-benzothiophen-2-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]ethanol
    —— (2S)-2-(2-chlorophenyl)sulfanyl-1-[(2S,6R)-2,6-dimethylmorpholin-4-yl]propan-1-one —— C15H20ClNO2S
    (2S)-2-(2-chlorophenyl)sulfanyl-1-[(2S,6R)-2,6-dimethylmorpholin-4-yl]propan-1-one
    —— 2-(2-chlorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylacetamide —— C14H18ClNO3S2
    2-(2-chlorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylacetamide
    —— N-[(R)-phenyl(pyridin-4-yl)methyl]-2-pyridin-4-ylsulfanylacetamide —— C19H17N3OS
    N-[(R)-phenyl(pyridin-4-yl)methyl]-2-pyridin-4-ylsulfanylacetamide
    —— 2-amino-6-[2-oxo-2-[(2R)-2-thiophen-2-ylpyrrolidin-1-yl]ethyl]sulfanylpyridine-3,5-dicarbonitrile —— C17H15N5OS2
    2-amino-6-[2-oxo-2-[(2R)-2-thiophen-2-ylpyrrolidin-1-yl]ethyl]sulfanylpyridine-3,5-dicarbonitrile
    —— N-[(R)-phenyl(pyridin-4-yl)methyl]-2-phenylsulfanylacetamide —— C20H18N2OS
    N-[(R)-phenyl(pyridin-4-yl)methyl]-2-phenylsulfanylacetamide
    —— N-[(2S)-3-methylbutan-2-yl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide —— C13H17F3N2OS
    N-[(2S)-3-methylbutan-2-yl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide
    —— N-[3-(N-methylanilino)propyl]-3-phenylsulfanylpropanamide —— C19H24N2OS
    N-[3-(N-methylanilino)propyl]-3-phenylsulfanylpropanamide
    —— (2S)-N-cyclopropyl-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylpropanamide —— C12H13F3N2OS
    (2S)-N-cyclopropyl-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylpropanamide
    —— (NZ)-N-[[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]hydroxylamine —— C11H7BrClNO2S
    (NZ)-N-[[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]hydroxylamine
    —— N-[(Z)-1-thiophen-2-ylethylideneamino]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C10H11N5OS2
    N-[(Z)-1-thiophen-2-ylethylideneamino]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— (Z)-N-(3-ethylsulfanyl-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-yl)-1-thiophen-2-ylmethanimine —— C10H10N6S2
    (Z)-N-(3-ethylsulfanyl-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-yl)-1-thiophen-2-ylmethanimine
    —— (Z)-1-(4-methylsulfanylphenyl)-N-(1,2,4-triazol-4-yl)methanimine —— C10H10N4S
    (Z)-1-(4-methylsulfanylphenyl)-N-(1,2,4-triazol-4-yl)methanimine
    —— (NE)-N-[(1R,2R,5R)-2-[4-(difluoromethyl)-6-methylpyrimidin-2-yl]sulfanyl-6,8-dioxabicyclo[3.2.1]octan-4-ylidene]hydroxylamine —— C12H13F2N3O3S
    (NE)-N-[(1R,2R,5R)-2-[4-(difluoromethyl)-6-methylpyrimidin-2-yl]sulfanyl-6,8-dioxabicyclo[3.2.1]octan-4-ylidene]hydroxylamine
    —— 2-(2-methylphenyl)sulfanyl-N-[(Z)-(6-methylpyridin-2-yl)methylideneamino]acetamide —— C16H17N3OS
    2-(2-methylphenyl)sulfanyl-N-[(Z)-(6-methylpyridin-2-yl)methylideneamino]acetamide
    —— 2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-prop-2-enylacetamide —— C17H22BrNO3S2
    2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-prop-2-enylacetamide