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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (3S)-3-methyl-5-oxo-5-(2-phenylsulfanylethylamino)pentanoic acid —— C14H19NO3S
    (3S)-3-methyl-5-oxo-5-(2-phenylsulfanylethylamino)pentanoic acid
    —— 3-(4-chlorophenyl)sulfanyl-N-[(Z)-pyridin-2-ylmethylideneamino]propanamide —— C15H14ClN3OS
    3-(4-chlorophenyl)sulfanyl-N-[(Z)-pyridin-2-ylmethylideneamino]propanamide
    —— (2S)-N-[(Z)-benzylideneamino]-2-(4-chlorophenyl)sulfanylpropanamide —— C16H15ClN2OS
    (2S)-N-[(Z)-benzylideneamino]-2-(4-chlorophenyl)sulfanylpropanamide
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-[(Z)-pyridin-3-ylmethylideneamino]propanamide —— C15H14ClN3OS
    (2R)-2-(4-chlorophenyl)sulfanyl-N-[(Z)-pyridin-3-ylmethylideneamino]propanamide
    —— (Z)-1-[4-(4-chlorophenyl)sulfanylphenyl]-N-(1,2,4-triazol-4-yl)methanimine —— C15H11ClN4S
    (Z)-1-[4-(4-chlorophenyl)sulfanylphenyl]-N-(1,2,4-triazol-4-yl)methanimine
    —— (2R)-N-[(Z)-benzylideneamino]-2-phenylsulfanylpropanamide —— C16H16N2OS
    (2R)-N-[(Z)-benzylideneamino]-2-phenylsulfanylpropanamide
    —— (2S)-2-(4-chlorophenyl)sulfanyl-N-[(Z)-pyridin-3-ylmethylideneamino]propanamide —— C15H14ClN3OS
    (2S)-2-(4-chlorophenyl)sulfanyl-N-[(Z)-pyridin-3-ylmethylideneamino]propanamide
    —— (2R)-N-[(Z)-benzylideneamino]-2-(4-chlorophenyl)sulfanylpropanamide —— C16H15ClN2OS
    (2R)-N-[(Z)-benzylideneamino]-2-(4-chlorophenyl)sulfanylpropanamide
    —— [(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]urea —— C12H11N3O2S
    [(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]urea
    —— ethyl (1S,2Z)-2-[(2-pyrimidin-2-ylsulfanylacetyl)hydrazinylidene]cyclopentane-1-carboxylate —— C14H18N4O3S
    ethyl (1S,2Z)-2-[(2-pyrimidin-2-ylsulfanylacetyl)hydrazinylidene]cyclopentane-1-carboxylate
    —— ethyl (1R,2Z)-2-[(2-pyrimidin-2-ylsulfanylacetyl)hydrazinylidene]cyclopentane-1-carboxylate —— C14H18N4O3S
    ethyl (1R,2Z)-2-[(2-pyrimidin-2-ylsulfanylacetyl)hydrazinylidene]cyclopentane-1-carboxylate
    —— N-[(Z)-pyridin-2-ylmethylideneamino]-2-pyrimidin-2-ylsulfanylacetamide —— C12H11N5OS
    N-[(Z)-pyridin-2-ylmethylideneamino]-2-pyrimidin-2-ylsulfanylacetamide
    —— (2E)-2-{[5-(phenylsulfanyl)furan-2-yl]methylidene}hydrazinecarboxamide —— C12H11N3O2S
    (2E)-2-{[5-(phenylsulfanyl)furan-2-yl]methylidene}hydrazinecarboxamide
    —— (5Z)-3-ethyl-5-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methylidene]imidazolidine-2,4-dione —— C17H16N2O3S
    (5Z)-3-ethyl-5-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methylidene]imidazolidine-2,4-dione
    —— (NZ)-N-[(4-bromo-5-phenylsulfanylfuran-2-yl)methylidene]hydroxylamine —— C11H8BrNO2S
    (NZ)-N-[(4-bromo-5-phenylsulfanylfuran-2-yl)methylidene]hydroxylamine
    —— (2Z)-2-[[(5-chloropyridin-2-yl)amino]methylidene]-1-benzothiophen-3-one —— C14H9ClN2OS
    (2Z)-2-[[(5-chloropyridin-2-yl)amino]methylidene]-1-benzothiophen-3-one
    —— [(Z)-[5-[4-(difluoromethylsulfanyl)phenyl]furan-2-yl]methylideneamino]thiourea —— C13H11F2N3OS2
    [(Z)-[5-[4-(difluoromethylsulfanyl)phenyl]furan-2-yl]methylideneamino]thiourea
    —— 2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-thiophen-2-ylmethylideneamino]acetamide —— C10H10N4OS3
    2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-thiophen-2-ylmethylideneamino]acetamide
    —— (2Z)-2-[(4-hydroxyanilino)methylidene]-1-benzothiophen-3-one —— C15H11NO2S
    (2Z)-2-[(4-hydroxyanilino)methylidene]-1-benzothiophen-3-one
    —— N-[(E)-(5-methylfuran-2-yl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide 343365-20-8 C13H13N3O2S
    N-[(E)-(5-methylfuran-2-yl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide
    —— N-[(E)-(1-ethyl-3,5-dimethylpyrazol-4-yl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide 349659-45-6 C15H19N5OS
    N-[(E)-(1-ethyl-3,5-dimethylpyrazol-4-yl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide
    —— N-[(Z)-(3-chlorophenyl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide —— C14H12ClN3OS
    N-[(Z)-(3-chlorophenyl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide
    —— N'-[(1E)-1-(4-chlorophenyl)ethylidene]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetohydrazide —— C13H13ClN4OS2
    N'-[(1E)-1-(4-chlorophenyl)ethylidene]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetohydrazide
    —— N-[(Z)-(3-hydroxyphenyl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide —— C14H13N3O2S
    N-[(Z)-(3-hydroxyphenyl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide
    —— N-[(Z)-1-phenylethylideneamino]-2-pyridin-2-ylsulfanylacetamide —— C15H15N3OS
    N-[(Z)-1-phenylethylideneamino]-2-pyridin-2-ylsulfanylacetamide
    —— 6-[(2Z)-2-[1-(4-chlorophenyl)sulfanylpropan-2-ylidene]hydrazinyl]-1H-pyrimidin-2-one —— C13H13ClN4OS
    6-[(2Z)-2-[1-(4-chlorophenyl)sulfanylpropan-2-ylidene]hydrazinyl]-1H-pyrimidin-2-one
    —— [4-(2,5-difluorophenyl)sulfanyl-1H-pyridin-2-ylidene]-nitrosomethanamine —— C12H9F2N3OS
    [4-(2,5-difluorophenyl)sulfanyl-1H-pyridin-2-ylidene]-nitrosomethanamine
    —— [4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-1H-pyridin-2-ylidene]-nitrosomethanamine —— C10H10N4OS2
    [4-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-1H-pyridin-2-ylidene]-nitrosomethanamine
    —— [4-(1-methylimidazol-2-yl)sulfanyl-1H-pyridin-2-ylidene]-nitrosomethanamine —— C10H11N5OS
    [4-(1-methylimidazol-2-yl)sulfanyl-1H-pyridin-2-ylidene]-nitrosomethanamine
    —— [4-(3-bromophenyl)sulfanyl-1H-pyridin-2-ylidene]-nitrosomethanamine —— C12H10BrN3OS
    [4-(3-bromophenyl)sulfanyl-1H-pyridin-2-ylidene]-nitrosomethanamine
    —— N-[(Z)-pyridin-2-ylmethylideneamino]-2-pyridin-2-ylsulfanylacetamide —— C13H12N4OS
    N-[(Z)-pyridin-2-ylmethylideneamino]-2-pyridin-2-ylsulfanylacetamide
    —— [4-(3,4-difluorophenyl)sulfanyl-1H-pyridin-2-ylidene]-nitrosomethanamine —— C12H9F2N3OS
    [4-(3,4-difluorophenyl)sulfanyl-1H-pyridin-2-ylidene]-nitrosomethanamine
    —— [4-(4,6-dimethylpyrimidin-2-yl)sulfanyl-1H-pyridin-2-ylidene]-nitrosomethanamine —— C12H13N5OS
    [4-(4,6-dimethylpyrimidin-2-yl)sulfanyl-1H-pyridin-2-ylidene]-nitrosomethanamine
    —— nitroso-(4-phenylsulfanyl-1H-pyridin-2-ylidene)methanamine —— C12H11N3OS
    nitroso-(4-phenylsulfanyl-1H-pyridin-2-ylidene)methanamine
    —— (2S)-2-(2-cyanopyridin-4-yl)sulfanylpropanoic acid —— C9H8N2O2S
    (2S)-2-(2-cyanopyridin-4-yl)sulfanylpropanoic acid
    —— (2R)-2-(2-cyanopyridin-4-yl)sulfanylpropanoic acid —— C9H8N2O2S
    (2R)-2-(2-cyanopyridin-4-yl)sulfanylpropanoic acid
    —— N-[(Z)-furan-2-ylmethylideneamino]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C10H10N4O2S2
    N-[(Z)-furan-2-ylmethylideneamino]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— [(Z)-[5-[4-(difluoromethylsulfanyl)phenyl]furan-2-yl]methylideneamino]urea —— C13H11F2N3O2S
    [(Z)-[5-[4-(difluoromethylsulfanyl)phenyl]furan-2-yl]methylideneamino]urea
    —— tert-butyl N-[(1S)-1-[5-[2-(dimethylamino)-2-oxoethyl]sulfanyl-1,3,4-oxadiazol-2-yl]ethyl]carbamate —— C13H22N4O4S
    tert-butyl N-[(1S)-1-[5-[2-(dimethylamino)-2-oxoethyl]sulfanyl-1,3,4-oxadiazol-2-yl]ethyl]carbamate
    —— (2R)-2-(4-ethyl-3-oxopyrazin-2-yl)sulfanylpropanoic acid —— C9H12N2O3S
    (2R)-2-(4-ethyl-3-oxopyrazin-2-yl)sulfanylpropanoic acid
    —— (2R)-2-[4-(2-methylpropyl)-3-oxopyrazin-2-yl]sulfanylpropanoic acid —— C11H16N2O3S
    (2R)-2-[4-(2-methylpropyl)-3-oxopyrazin-2-yl]sulfanylpropanoic acid
    —— (2R)-2-(4-cyclopropyl-3-oxopyrazin-2-yl)sulfanylpropanoic acid —— C10H12N2O3S
    (2R)-2-(4-cyclopropyl-3-oxopyrazin-2-yl)sulfanylpropanoic acid
    —— (2S)-2-[4-(2-methylpropyl)-3-oxopyrazin-2-yl]sulfanylpropanoic acid —— C11H16N2O3S
    (2S)-2-[4-(2-methylpropyl)-3-oxopyrazin-2-yl]sulfanylpropanoic acid
    —— (2S)-2-(3-oxo-4-propan-2-ylpyrazin-2-yl)sulfanylpropanoic acid —— C10H14N2O3S
    (2S)-2-(3-oxo-4-propan-2-ylpyrazin-2-yl)sulfanylpropanoic acid
    —— 2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(Z)-pyridin-2-ylmethylideneamino]acetamide —— C11H12N6OS
    2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(Z)-pyridin-2-ylmethylideneamino]acetamide
    —— (2S)-2-(4-cyclopropyl-3-oxopyrazin-2-yl)sulfanylpropanoic acid —— C10H12N2O3S
    (2S)-2-(4-cyclopropyl-3-oxopyrazin-2-yl)sulfanylpropanoic acid
    —— (2S)-2-(4-ethyl-3-oxopyrazin-2-yl)sulfanylpropanoic acid —— C9H12N2O3S
    (2S)-2-(4-ethyl-3-oxopyrazin-2-yl)sulfanylpropanoic acid
    —— (2R)-2-(3-oxo-4-propan-2-ylpyrazin-2-yl)sulfanylpropanoic acid —— C10H14N2O3S
    (2R)-2-(3-oxo-4-propan-2-ylpyrazin-2-yl)sulfanylpropanoic acid
    —— (2S)-2-(4-methyl-3-oxopyrazin-2-yl)sulfanylpropanoic acid —— C8H10N2O3S
    (2S)-2-(4-methyl-3-oxopyrazin-2-yl)sulfanylpropanoic acid
    —— N-[(Z)-(4-methylphenyl)methylideneamino]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C13H14N4OS2
    N-[(Z)-(4-methylphenyl)methylideneamino]-2-[(5-methyl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide