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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— [4-[3-[Heptyl(pentylcarbamoyl)amino]phenyl]sulfanylphenyl] butanoate —— C29H42N2O3S
    [4-[3-[Heptyl(pentylcarbamoyl)amino]phenyl]sulfanylphenyl] butanoate
    —— 3-[(1E)-1-{2-[({5-[(2-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-4-ium-2-yl}sulfanyl)acetyl]hydrazinylidene}ethyl]phenolate —— C19H17ClN4O2S3
    3-[(1E)-1-{2-[({5-[(2-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-4-ium-2-yl}sulfanyl)acetyl]hydrazinylidene}ethyl]phenolate
    —— 3,5-dibromo-N-[(Z)-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]-4-hydroxybenzamide —— C18H10Br3ClN2O3S
    3,5-dibromo-N-[(Z)-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]-4-hydroxybenzamide
    —— 3-chloro-4-[(5-chloro-1,3-benzothiazol-2-yl)sulfanyl]-N-(2,4-dimethylphenoxy)aniline;sulfur monoxide —— C21H16Cl2N2O2S3
    3-chloro-4-[(5-chloro-1,3-benzothiazol-2-yl)sulfanyl]-N-(2,4-dimethylphenoxy)aniline;sulfur monoxide
    —— 3-[(Z)-N-[[2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-4-ium-2-yl]sulfanyl]acetyl]amino]-C-methylcarbonimidoyl]phenolate —— C19H17ClN4O2S3
    3-[(Z)-N-[[2-[[5-[(2-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-4-ium-2-yl]sulfanyl]acetyl]amino]-C-methylcarbonimidoyl]phenolate
    —— Ethane;1-(3-ethylsulfanyl-6-methylpyridin-2-yl)ethanone —— C12H19NOS
    Ethane;1-(3-ethylsulfanyl-6-methylpyridin-2-yl)ethanone
    —— Trihydroxy-[2-sulfanylidenepropyl-bis(2-sulfanylpropyl)-lambda4-sulfanyl]phosphanium —— C9H22O3PS4+
    Trihydroxy-[2-sulfanylidenepropyl-bis(2-sulfanylpropyl)-lambda4-sulfanyl]phosphanium
    —— 3-Methyl-7-methylsulfanylhept-2-ene —— C9H18S
    3-Methyl-7-methylsulfanylhept-2-ene
    —— 3-Methyl-4-methylsulfanylbutan-1-ol —— C6H14OS
    3-Methyl-4-methylsulfanylbutan-1-ol
    —— 2-Ethylsulfanylcyclohex-3-en-1-amine —— C8H15NS
    2-Ethylsulfanylcyclohex-3-en-1-amine
    —— 2-cyano-N-[(Z)-(5-pyridin-2-ylsulfanylfuran-2-yl)methylideneamino]acetamide —— C13H10N4O2S
    2-cyano-N-[(Z)-(5-pyridin-2-ylsulfanylfuran-2-yl)methylideneamino]acetamide
    —— 3-Hexyl-2-methyltridecane-2-thiol —— C20H42S
    3-Hexyl-2-methyltridecane-2-thiol
    —— 2-Phenylsulfanylethyl 2-methylidenebutanoate —— C13H16O2S
    2-Phenylsulfanylethyl 2-methylidenebutanoate
    —— (5E)-2-(2-chlorophenyl)imino-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-1,3-thiazolidin-4-one —— C22H13Cl2N3O3S2
    (5E)-2-(2-chlorophenyl)imino-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-1,3-thiazolidin-4-one
    —— Tri(cycloheptyloxy)-(trithiol-4-yl)phosphanium —— C23H40O3PS3+
    Tri(cycloheptyloxy)-(trithiol-4-yl)phosphanium
    —— Bis(methylsulfanyl)methane;methanamine;phenylsulfanylbenzene —— C29H38N2S4
    Bis(methylsulfanyl)methane;methanamine;phenylsulfanylbenzene
    —— 6-[2-(Cyclopropylmethyl-carbamoyl)phenylsulfanyl]-3-E-[2-(pyridin-2-yl)ethenyl]-1H-indazole —— C25H22N4OS
    6-[2-(Cyclopropylmethyl-carbamoyl)phenylsulfanyl]-3-E-[2-(pyridin-2-yl)ethenyl]-1H-indazole
    —— [4-bromo-5-(3-methoxyphenyl)sulfanylthiophen-2-yl]methyl N-tert-butyl-N-methylcarbamate —— C18H22BrNO3S2
    [4-bromo-5-(3-methoxyphenyl)sulfanylthiophen-2-yl]methyl N-tert-butyl-N-methylcarbamate
    —— 2-N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-4-N-phenyl-6-pyrrolidin-1-yl-1,3,5-triazine-2,4-diamine —— C26H23ClN8O2S
    2-N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-4-N-phenyl-6-pyrrolidin-1-yl-1,3,5-triazine-2,4-diamine
    —— 6-(2,5-dihydroxy-3-methylsulfanylpyrrol-1-yl)-N-methylhexanamide —— C12H20N2O3S
    6-(2,5-dihydroxy-3-methylsulfanylpyrrol-1-yl)-N-methylhexanamide
    —— (E)-1,1,1,4,4,4-hexafluorobut-2-ene-2,3-dithiol —— C4H2F6S2
    (E)-1,1,1,4,4,4-hexafluorobut-2-ene-2,3-dithiol
    —— 2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-(2-methylphenyl)methylideneamino]acetamide —— C19H17ClN4OS3
    2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-(2-methylphenyl)methylideneamino]acetamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(2-chlorophenyl)ethylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C20H17ClN8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(2-chlorophenyl)ethylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— ethyl {4-[4-(3-cyclohexyl-1-heptylureido)phenylsulphanyl]phenyl}acetate 735314-83-7 C30H42N2O3S
    ethyl {4-[4-(3-cyclohexyl-1-heptylureido)phenylsulphanyl]phenyl}acetate
    —— [5-Phenylsulfanyl-4-propan-2-yl-1-(pyridin-4-ylmethyl)imidazol-2-yl]methyldiazene —— C19H21N5S
    [5-Phenylsulfanyl-4-propan-2-yl-1-(pyridin-4-ylmethyl)imidazol-2-yl]methyldiazene
    —— (NZ)-N-[[6-(4-chlorophenyl)sulfanylpyridin-3-yl]methylidene]hydroxylamine —— C12H9ClN2OS
    (NZ)-N-[[6-(4-chlorophenyl)sulfanylpyridin-3-yl]methylidene]hydroxylamine
    —— 2-(2,3,4,5,6-Pentafluorophenyl)sulfanyloxirane —— C8H3F5OS
    2-(2,3,4,5,6-Pentafluorophenyl)sulfanyloxirane
    —— 2-{[5-(Benzylsulfanyl)-1,3,4-thiadiazol-2-YL]sulfanyl}-N'-[(E)-1-(4-chlorophenyl)ethylidene]acetohydrazide —— C19H17ClN4OS3
    2-{[5-(Benzylsulfanyl)-1,3,4-thiadiazol-2-YL]sulfanyl}-N'-[(E)-1-(4-chlorophenyl)ethylidene]acetohydrazide
    —— 4-(1H-imidazol-5-ylsulfanyl)aniline —— C9H9N3S
    4-(1H-imidazol-5-ylsulfanyl)aniline
    —— 5-[2-(Dimethylamino)vinyl]-3-{[(2-methyl-1,3-thiazol-4-yl)methyl]sulfanyl}-4-isothiazolecarbonitrile —— C13H14N4S3
    5-[2-(Dimethylamino)vinyl]-3-{[(2-methyl-1,3-thiazol-4-yl)methyl]sulfanyl}-4-isothiazolecarbonitrile
    —— 2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1Z)-1-(2-chlorophenyl)ethylidene]acetohydrazide —— C19H16Cl2N4OS3
    2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1Z)-1-(2-chlorophenyl)ethylidene]acetohydrazide
    —— 3,4-Diethyl-3-methyl-4-methylsulfonylhexane —— C12H26O2S
    3,4-Diethyl-3-methyl-4-methylsulfonylhexane
    —— 3-(2,5-dihydroxy-3-methylsulfanylpyrrol-1-yl)-N-methylpropanamide —— C9H14N2O3S
    3-(2,5-dihydroxy-3-methylsulfanylpyrrol-1-yl)-N-methylpropanamide
    —— 3-Amino-2-(3-amino-2-hydroxybutan-2-yl)sulfinylbutan-2-ol —— C8H20N2O3S
    3-Amino-2-(3-amino-2-hydroxybutan-2-yl)sulfinylbutan-2-ol
    —— ethynyl N-methyl-N-propanimidoyl-N'-propan-2-ylcarbamimidothioate —— C10H17N3S
    ethynyl N-methyl-N-propanimidoyl-N'-propan-2-ylcarbamimidothioate
    —— 3,5,6-trichloro-N-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]pyridin-2-amine —— C15H10Cl3N7O2S
    3,5,6-trichloro-N-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]pyridin-2-amine
    —— 2-ethenylsulfonyl-N-[2-[(2-ethenylsulfonylacetyl)amino]-5-ethylsulfonyl-4-oxopentyl]acetamide —— C15H24N2O9S3
    2-ethenylsulfonyl-N-[2-[(2-ethenylsulfonylacetyl)amino]-5-ethylsulfonyl-4-oxopentyl]acetamide
    —— N-[(E)-[2-(4,6-dimethoxypyrimidin-2-yl)sulfanylphenyl]methylideneamino]-2-fluoroaniline —— C19H17FN4O2S
    N-[(E)-[2-(4,6-dimethoxypyrimidin-2-yl)sulfanylphenyl]methylideneamino]-2-fluoroaniline
    —— 3-(3-ethylsulfanyl-2,5-dihydroxypyrrol-1-yl)-N-[2-(2,5,6-trimethylheptan-2-yloxy)ethyl]propanamide —— C21H38N2O4S
    3-(3-ethylsulfanyl-2,5-dihydroxypyrrol-1-yl)-N-[2-(2,5,6-trimethylheptan-2-yloxy)ethyl]propanamide
    —— (Z)-1-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]-N-(1,2,4-triazol-4-yl)methanimine —— C14H10N6OS
    (Z)-1-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]-N-(1,2,4-triazol-4-yl)methanimine
    —— 2-[5-bromo-4-(4-chlorophenyl)sulfanyl-8-fluoro-2,3-dihydro-1H-pyrrolo[1,2-a]indol-3-yl]propanoic acid —— C20H16BrClFNO2S
    2-[5-bromo-4-(4-chlorophenyl)sulfanyl-8-fluoro-2,3-dihydro-1H-pyrrolo[1,2-a]indol-3-yl]propanoic acid
    —— N-cyclobutyl-N-(3-fluoro-4-phenylsulfanylphenyl)imidazo[1,5-a]pyrazin-4-ium-4-amine —— C22H20FN4S+
    N-cyclobutyl-N-(3-fluoro-4-phenylsulfanylphenyl)imidazo[1,5-a]pyrazin-4-ium-4-amine
    —— (2Z)-2-(methylaminomethylidene)-1-benzothiophen-3-one —— C10H9NOS
    (2Z)-2-(methylaminomethylidene)-1-benzothiophen-3-one
    —— 2-(2-Fluoropropylsulfinyl)ethanimine —— C5H10FNOS
    2-(2-Fluoropropylsulfinyl)ethanimine
    —— N-ethyl-1-ethylsulfanylethanamine —— C6H15NS
    N-ethyl-1-ethylsulfanylethanamine
    —— 5-(1H-benzimidazol-2-ylsulfanyl)thiophene-2-carbaldehyde;ethane —— C14H14N2OS2
    5-(1H-benzimidazol-2-ylsulfanyl)thiophene-2-carbaldehyde;ethane
    —— 4-N-[2-(dimethylamino)ethyl]-2-N-[5-(5-methylfuran-2-yl)-1H-pyrazol-3-yl]-6-phenylsulfanyl-1,3,5-triazine-2,4-diamine —— C21H24N8OS
    4-N-[2-(dimethylamino)ethyl]-2-N-[5-(5-methylfuran-2-yl)-1H-pyrazol-3-yl]-6-phenylsulfanyl-1,3,5-triazine-2,4-diamine
    —— N-(cyclopropylmethoxy)-2-[[3-(2-pyridin-2-ylethenyl)-1H-indazol-6-yl]sulfanyl]benzamide —— C25H22N4O2S
    N-(cyclopropylmethoxy)-2-[[3-(2-pyridin-2-ylethenyl)-1H-indazol-6-yl]sulfanyl]benzamide
    —— 3-[1-[3-(2-fluoroethylsulfanyl)pyridin-4-yl]ethylideneamino]-N-methyl-5-(trifluoromethyl)pyridin-2-amine —— C16H16F4N4S
    3-[1-[3-(2-fluoroethylsulfanyl)pyridin-4-yl]ethylideneamino]-N-methyl-5-(trifluoromethyl)pyridin-2-amine
    —— 1-[4-(2-Hydroxypropylsulfanyl)phenyl]sulfanylpropan-2-ol —— C12H18O2S2
    1-[4-(2-Hydroxypropylsulfanyl)phenyl]sulfanylpropan-2-ol