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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(1,3-benzothiazol-2-ylsulfanyl)-3-[(E)-hydroxyiminomethyl]-9-methylpyrido[1,2-a]pyrimidin-4-one —— C17H12N4O2S2
    2-(1,3-benzothiazol-2-ylsulfanyl)-3-[(E)-hydroxyiminomethyl]-9-methylpyrido[1,2-a]pyrimidin-4-one
    —— 3-[(2E)-2-[[5-[4-(difluoromethylsulfanyl)phenyl]furan-2-yl]methylidene]hydrazinyl]propanenitrile —— C15H13F2N3OS
    3-[(2E)-2-[[5-[4-(difluoromethylsulfanyl)phenyl]furan-2-yl]methylidene]hydrazinyl]propanenitrile
    —— 2-(1-Butylimidazol-2-yl)sulfanylethanol —— C9H16N2OS
    2-(1-Butylimidazol-2-yl)sulfanylethanol
    —— 2-(1-Butylimidazol-2-yl)sulfanylethanamine —— C9H17N3S
    2-(1-Butylimidazol-2-yl)sulfanylethanamine
    —— 2-[1-(2-Methylpropyl)imidazol-2-yl]sulfanylethanamine —— C9H17N3S
    2-[1-(2-Methylpropyl)imidazol-2-yl]sulfanylethanamine
    —— 2-(1-Propylimidazol-2-yl)sulfanylacetamide —— C8H13N3OS
    2-(1-Propylimidazol-2-yl)sulfanylacetamide
    —— 2-[1-(2-Methoxyethyl)imidazol-2-yl]sulfanylethanamine —— C8H15N3OS
    2-[1-(2-Methoxyethyl)imidazol-2-yl]sulfanylethanamine
    —— 2-[1-(2-Methoxyethyl)imidazol-2-yl]sulfanylacetonitrile —— C8H11N3OS
    2-[1-(2-Methoxyethyl)imidazol-2-yl]sulfanylacetonitrile
    —— 2-[1-[(2R)-butan-2-yl]imidazol-2-yl]sulfanylethanol —— C9H16N2OS
    2-[1-[(2R)-butan-2-yl]imidazol-2-yl]sulfanylethanol
    —— 3-(1-Prop-2-enylimidazol-2-yl)sulfanylpropanenitrile —— C9H11N3S
    3-(1-Prop-2-enylimidazol-2-yl)sulfanylpropanenitrile
    —— 2-[1-[(2S)-butan-2-yl]imidazol-2-yl]sulfanylacetonitrile —— C9H13N3S
    2-[1-[(2S)-butan-2-yl]imidazol-2-yl]sulfanylacetonitrile
    —— 5-[(1S)-1-[[5-cyclopropyl-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-ethyl-1,2,4-oxadiazole —— C16H19N5O2S
    5-[(1S)-1-[[5-cyclopropyl-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-ethyl-1,2,4-oxadiazole
    —— 5-[(1R)-1-[[4-cyclohexyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-ethyl-1,2,4-oxadiazole —— C18H23N5O2S
    5-[(1R)-1-[[4-cyclohexyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-ethyl-1,2,4-oxadiazole
    —— 5-[(1R)-1-[[5-cyclopropyl-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-ethyl-1,2,4-oxadiazole —— C16H19N5O2S
    5-[(1R)-1-[[5-cyclopropyl-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-3-ethyl-1,2,4-oxadiazole
    —— N-cyclohexyl-5-[(1R)-1-(3-ethyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C14H21N5OS2
    N-cyclohexyl-5-[(1R)-1-(3-ethyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— N-cyclohexyl-5-[(1S)-1-(3-ethyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine —— C14H21N5OS2
    N-cyclohexyl-5-[(1S)-1-(3-ethyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-1,3,4-thiadiazol-2-amine
    —— 3-nitro-4-(phenylsulfanyl)benzenecarbaldehyde O-(3,4-dichlorobenzyl)oxime —— C20H14Cl2N2O3S
    3-nitro-4-(phenylsulfanyl)benzenecarbaldehyde O-(3,4-dichlorobenzyl)oxime
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-2-(2-methylphenyl)sulfanyl-N-(thiophen-2-ylmethyl)acetamide —— C18H21NO3S3
    N-[(3R)-1,1-dioxothiolan-3-yl]-2-(2-methylphenyl)sulfanyl-N-(thiophen-2-ylmethyl)acetamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-2-(2-methylphenyl)sulfanyl-N-(thiophen-2-ylmethyl)acetamide —— C18H21NO3S3
    N-[(3S)-1,1-dioxothiolan-3-yl]-2-(2-methylphenyl)sulfanyl-N-(thiophen-2-ylmethyl)acetamide
    —— 5-[(1S)-1-(3-ethyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-3-methyl-7-propan-2-yl-1-propylpyrimido[4,5-d]pyrimidine-2,4-dione —— C19H26N6O3S
    5-[(1S)-1-(3-ethyl-1,2,4-oxadiazol-5-yl)ethyl]sulfanyl-3-methyl-7-propan-2-yl-1-propylpyrimido[4,5-d]pyrimidine-2,4-dione
    —— 2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-(5-methylfuran-2-yl)ethyl]acetamide —— C17H16ClN3O3S
    2-[[5-(4-chlorophenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]-N-[(1S)-1-(5-methylfuran-2-yl)ethyl]acetamide
    —— 3-(4-fluorophenyl)sulfanyl-N-[(1S)-1-(5-methylfuran-2-yl)ethyl]propanamide —— C16H18FNO2S
    3-(4-fluorophenyl)sulfanyl-N-[(1S)-1-(5-methylfuran-2-yl)ethyl]propanamide
    —— 3-[(E)-(methoxyimino)methyl]-2-[(4-methylphenyl)sulfanyl]-4H-pyrido[1,2-a]pyrimidin-4-one —— C17H15N3O2S
    3-[(E)-(methoxyimino)methyl]-2-[(4-methylphenyl)sulfanyl]-4H-pyrido[1,2-a]pyrimidin-4-one
    —— 3-(4-fluorophenyl)sulfanyl-N-[(1R)-1-(5-methylfuran-2-yl)ethyl]propanamide —— C16H18FNO2S
    3-(4-fluorophenyl)sulfanyl-N-[(1R)-1-(5-methylfuran-2-yl)ethyl]propanamide
    —— N-[(2R)-2-hydroxy-3-(3-methylphenoxy)propyl]-2-phenylsulfanylpyridine-3-carboxamide —— C22H22N2O3S
    N-[(2R)-2-hydroxy-3-(3-methylphenoxy)propyl]-2-phenylsulfanylpyridine-3-carboxamide
    —— (2R)-2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]butanoic acid —— C7H11N3O3S
    (2R)-2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]butanoic acid
    —— (2S)-2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]butanoic acid —— C7H11N3O3S
    (2S)-2-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]butanoic acid
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(E)-(2-methoxy-5-methylsulfanylthiophen-3-yl)methylideneamino]-5-methyltriazole-4-carboxamide —— C13H14N8O3S2
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(E)-(2-methoxy-5-methylsulfanylthiophen-3-yl)methylideneamino]-5-methyltriazole-4-carboxamide
    —— N'-[(E)-phenylmethylidene]-2-(pyrimidin-2-ylsulfanyl)acetohydrazide —— C13H12N4OS
    N'-[(E)-phenylmethylidene]-2-(pyrimidin-2-ylsulfanyl)acetohydrazide
    —— 2-(Pyrimidin-2-ylsulfanyl)-N'-[(E)-(2,3,4-trimethylphenyl)methylidene]acetohydrazide —— C16H18N4OS
    2-(Pyrimidin-2-ylsulfanyl)-N'-[(E)-(2,3,4-trimethylphenyl)methylidene]acetohydrazide
    —— N'-[(E)-[3-Bromo-4-(dimethylamino)phenyl]methylidene]-2-(pyrimidin-2-ylsulfanyl)acetohydrazide —— C15H16BrN5OS
    N'-[(E)-[3-Bromo-4-(dimethylamino)phenyl]methylidene]-2-(pyrimidin-2-ylsulfanyl)acetohydrazide
    —— 2-[(4,6-dimethylpyrimidin-2-yl)sulfanyl]-N'-[(E)-pyridin-3-ylmethylidene]acetohydrazide —— C14H15N5OS
    2-[(4,6-dimethylpyrimidin-2-yl)sulfanyl]-N'-[(E)-pyridin-3-ylmethylidene]acetohydrazide
    —— 5-bromo-2-hydroxy-N-[(E)-[2-(4-methylphenyl)sulfanylquinolin-3-yl]methylideneamino]benzamide —— C24H18BrN3O2S
    5-bromo-2-hydroxy-N-[(E)-[2-(4-methylphenyl)sulfanylquinolin-3-yl]methylideneamino]benzamide
    —— N-[(3-phenyl-1,2-oxazol-5-yl)methyl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide —— C18H14F3N3O2S
    N-[(3-phenyl-1,2-oxazol-5-yl)methyl]-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylacetamide
    —— 3-bromo-N'-{(E)-[5-(quinolin-8-ylsulfanyl)furan-2-yl]methylidene}benzohydrazide —— C21H14BrN3O2S
    3-bromo-N'-{(E)-[5-(quinolin-8-ylsulfanyl)furan-2-yl]methylidene}benzohydrazide
    —— N'-{[5-(8-quinolinylthio)-2-furyl]methylene}pentanohydrazide —— C19H19N3O2S
    N'-{[5-(8-quinolinylthio)-2-furyl]methylene}pentanohydrazide
    —— 2-(1-naphthyl)-N'-{[5-(8-quinolinylthio)-2-furyl]methylene}acetohydrazide —— C26H19N3O2S
    2-(1-naphthyl)-N'-{[5-(8-quinolinylthio)-2-furyl]methylene}acetohydrazide
    —— 3-(4-methylsulfanylphenyl)-5-pyrrol-2-ylidene-2H-1,2,4-oxadiazole —— C13H11N3OS
    3-(4-methylsulfanylphenyl)-5-pyrrol-2-ylidene-2H-1,2,4-oxadiazole
    —— (2S)-2-propylsulfonyl-N-[4-(1H-1,2,4-triazol-5-ylsulfanyl)phenyl]propanamide —— C14H18N4O3S2
    (2S)-2-propylsulfonyl-N-[4-(1H-1,2,4-triazol-5-ylsulfanyl)phenyl]propanamide
    —— (2R)-2-propylsulfonyl-N-[4-(1H-1,2,4-triazol-5-ylsulfanyl)phenyl]propanamide —— C14H18N4O3S2
    (2R)-2-propylsulfonyl-N-[4-(1H-1,2,4-triazol-5-ylsulfanyl)phenyl]propanamide
    —— (5Z)-5-[(4-methylsulfanylphenyl)methylidene]-3-[(E)-(4-methylsulfanylphenyl)methylideneamino]-2-sulfanylidene-1,3-thiazolidin-4-one —— C19H16N2OS4
    (5Z)-5-[(4-methylsulfanylphenyl)methylidene]-3-[(E)-(4-methylsulfanylphenyl)methylideneamino]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (E)-1-(2-benzylsulfanyl-5-ethylthiophen-3-yl)-N-[(E)-(2-benzylsulfanyl-5-ethylthiophen-3-yl)methylideneamino]methanimine —— C28H28N2S4
    (E)-1-(2-benzylsulfanyl-5-ethylthiophen-3-yl)-N-[(E)-(2-benzylsulfanyl-5-ethylthiophen-3-yl)methylideneamino]methanimine
    —— (NE)-N-[[2,5-bis(methylsulfanyl)thiophen-3-yl]methylidene]hydroxylamine —— C7H9NOS3
    (NE)-N-[[2,5-bis(methylsulfanyl)thiophen-3-yl]methylidene]hydroxylamine
    —— 2-[(4-methylsulfanylphenyl)methylamino]-4-(trifluoromethyl)-1H-pyrimidin-6-one —— C13H12F3N3OS
    2-[(4-methylsulfanylphenyl)methylamino]-4-(trifluoromethyl)-1H-pyrimidin-6-one
    —— Propyl 3-(4-aminophenyl)sulfanylquinoxaline-2-carboxylate —— C18H17N3O2S
    Propyl 3-(4-aminophenyl)sulfanylquinoxaline-2-carboxylate
    —— 1-({N'-[(E)-[4-(Methylsulfanyl)phenyl]methylidene]hydrazinecarbonyl}methyl)pyridin-1-ium —— C15H16N3OS+
    1-({N'-[(E)-[4-(Methylsulfanyl)phenyl]methylidene]hydrazinecarbonyl}methyl)pyridin-1-ium
    —— 2-[[2-(Furan-2-yl)-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl]sulfanyl]aniline —— C16H13N5OS
    2-[[2-(Furan-2-yl)-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl]sulfanyl]aniline
    —— 5-(1,8,10,12-Tetrazatricyclo[7.3.0.03,7]dodeca-2,7,9,11-tetraen-2-ylsulfanyl)-1,3,4-thiadiazol-2-amine —— C10H9N7S2
    5-(1,8,10,12-Tetrazatricyclo[7.3.0.03,7]dodeca-2,7,9,11-tetraen-2-ylsulfanyl)-1,3,4-thiadiazol-2-amine
    —— Propyl 3-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]quinoxaline-2-carboxylate —— C14H13N5O2S2
    Propyl 3-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]quinoxaline-2-carboxylate
    —— 2-(5,6,7,8-Tetrahydro-[1,2,4]triazolo[5,1-b]quinazolin-9-ylsulfanyl)aniline —— C15H15N5S
    2-(5,6,7,8-Tetrahydro-[1,2,4]triazolo[5,1-b]quinazolin-9-ylsulfanyl)aniline