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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-3-amino-2-[2-[[4-(4-chlorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]but-3-enenitrile —— C14H11ClN4OS3
    (2S)-3-amino-2-[2-[[4-(4-chlorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]but-3-enenitrile
    —— (Z)-N-(3,5-dimethyl-1,2,4-triazol-4-yl)-1-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methanimine —— C14H14N8O2S
    (Z)-N-(3,5-dimethyl-1,2,4-triazol-4-yl)-1-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methanimine
    —— (Z)-1-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]-N-morpholin-4-ylmethanimine —— C14H16N6O3S
    (Z)-1-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]-N-morpholin-4-ylmethanimine
    —— (Z)-4-(3,4-dimethylphenyl)-N-ethyl-3-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1,3-thiazol-2-imine —— C21H23N3S2
    (Z)-4-(3,4-dimethylphenyl)-N-ethyl-3-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1,3-thiazol-2-imine
    —— 3-[(4-bromophenyl)methyl]-4-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C17H15BrN4S2
    3-[(4-bromophenyl)methyl]-4-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 2-((4-fluorophenyl)thio)-N-(1-(thiazol-2-yl)piperidin-4-yl)acetamide —— C16H18FN3OS2
    2-((4-fluorophenyl)thio)-N-(1-(thiazol-2-yl)piperidin-4-yl)acetamide
    —— 2-[[4-[(Z)-(4-chlorophenyl)methylideneamino]-5-methyl-1,2,4-triazol-3-yl]sulfanyl]-1-morpholin-4-ylethanone —— C16H18ClN5O2S
    2-[[4-[(Z)-(4-chlorophenyl)methylideneamino]-5-methyl-1,2,4-triazol-3-yl]sulfanyl]-1-morpholin-4-ylethanone
    —— (E)-3-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-4-hydroxypent-3-en-2-one —— C14H15N3O2S2
    (E)-3-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]-4-hydroxypent-3-en-2-one
    —— 3-[4-(difluoromethoxy)phenyl]-4-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]-1H-1,2,4-triazole-5-thione —— C19H14F2N8O3S2
    3-[4-(difluoromethoxy)phenyl]-4-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 2-(pyrimidin-2-ylthio)-N-(2-(thiophen-3-yl)benzyl)acetamide —— C17H15N3OS2
    2-(pyrimidin-2-ylthio)-N-(2-(thiophen-3-yl)benzyl)acetamide
    —— 2-(pyridin-4-ylthio)-N-(2-(thiophen-3-yl)benzyl)acetamide —— C18H16N2OS2
    2-(pyridin-4-ylthio)-N-(2-(thiophen-3-yl)benzyl)acetamide
    —— N-benzyl-2-[[4-[(Z)-(4-chlorophenyl)methylideneamino]-5-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-methylacetamide —— C20H20ClN5OS
    N-benzyl-2-[[4-[(Z)-(4-chlorophenyl)methylideneamino]-5-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-methylacetamide
    —— 2-(4-Fluorophenyl)sulfanyl-1-[3-(furan-2-ylmethylsulfonyl)azetidin-1-yl]ethanone —— C16H16FNO4S2
    2-(4-Fluorophenyl)sulfanyl-1-[3-(furan-2-ylmethylsulfonyl)azetidin-1-yl]ethanone
    —— ethyl N-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]carbamate —— C14H13N5O4S
    ethyl N-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]carbamate
    —— 3-(isobutylsulfonyl)-N-propylazetidine-1-carboxamide —— C11H22N2O3S
    3-(isobutylsulfonyl)-N-propylazetidine-1-carboxamide
    —— 1-(3-(Isobutylsulfonyl)azetidin-1-yl)-3-methoxypropan-1-one —— C11H21NO4S
    1-(3-(Isobutylsulfonyl)azetidin-1-yl)-3-methoxypropan-1-one
    —— 2-Cyclohexyl-1-(3-(cyclohexylsulfonyl)azetidin-1-yl)ethanone —— C17H29NO3S
    2-Cyclohexyl-1-(3-(cyclohexylsulfonyl)azetidin-1-yl)ethanone
    —— 1-(3-(Isobutylsulfonyl)azetidin-1-yl)-3-(4-(methylthio)phenyl)propan-1-one —— C17H25NO3S2
    1-(3-(Isobutylsulfonyl)azetidin-1-yl)-3-(4-(methylthio)phenyl)propan-1-one
    —— 1-(3-(Isobutylsulfonyl)azetidin-1-yl)-3-methylbut-2-en-1-one —— C12H21NO3S
    1-(3-(Isobutylsulfonyl)azetidin-1-yl)-3-methylbut-2-en-1-one
    —— 1-[3-(Furan-2-ylmethylsulfonyl)azetidin-1-yl]-3-phenylsulfanylpropan-1-one —— C17H19NO4S2
    1-[3-(Furan-2-ylmethylsulfonyl)azetidin-1-yl]-3-phenylsulfanylpropan-1-one
    —— 1-(3-(Isobutylsulfonyl)azetidin-1-yl)-2-methylpropan-1-one —— C11H21NO3S
    1-(3-(Isobutylsulfonyl)azetidin-1-yl)-2-methylpropan-1-one
    —— Cyclohexyl(3-(cyclohexylsulfonyl)azetidin-1-yl)methanone —— C16H27NO3S
    Cyclohexyl(3-(cyclohexylsulfonyl)azetidin-1-yl)methanone
    —— 1-(3-(Cyclohexylsulfonyl)azetidin-1-yl)-2-(pyrimidin-2-ylthio)ethanone —— C15H21N3O3S2
    1-(3-(Cyclohexylsulfonyl)azetidin-1-yl)-2-(pyrimidin-2-ylthio)ethanone
    —— 1-(3-(Isobutylsulfonyl)azetidin-1-yl)-3-methylbutan-1-one —— C12H23NO3S
    1-(3-(Isobutylsulfonyl)azetidin-1-yl)-3-methylbutan-1-one
    —— 1-(3-(Cyclohexylsulfonyl)azetidin-1-yl)-3-(4-(methylthio)phenyl)propan-1-one —— C19H27NO3S2
    1-(3-(Cyclohexylsulfonyl)azetidin-1-yl)-3-(4-(methylthio)phenyl)propan-1-one
    —— 1-(3-(Isobutylsulfonyl)azetidin-1-yl)-2-(pyridin-4-ylthio)ethanone —— C14H20N2O3S2
    1-(3-(Isobutylsulfonyl)azetidin-1-yl)-2-(pyridin-4-ylthio)ethanone
    —— 1-(3-(Isobutylsulfonyl)azetidin-1-yl)-3,3-dimethylbutan-1-one —— C13H25NO3S
    1-(3-(Isobutylsulfonyl)azetidin-1-yl)-3,3-dimethylbutan-1-one
    —— tert-butyl N-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]carbamate —— C15H18N6O4S
    tert-butyl N-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]carbamate
    —— 1-(2-methoxyphenyl)-3-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]thiourea —— C19H16N6O3S2
    1-(2-methoxyphenyl)-3-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]thiourea
    —— 1-benzyl-3-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]thiourea —— C19H16N6O2S2
    1-benzyl-3-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]thiourea
    —— N-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]thiophene-2-carboxamide —— C15H12N6O3S2
    N-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]thiophene-2-carboxamide
    —— (3R)-N-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]-2,3-dihydro-1,4-benzodioxine-3-carboxamide —— C19H16N6O5S
    (3R)-N-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]-2,3-dihydro-1,4-benzodioxine-3-carboxamide
    —— N-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzodioxole-5-carboxamide —— C19H13N5O5S
    N-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]-1,3-benzodioxole-5-carboxamide
    —— N-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]cyclopropanecarboxamide —— C15H13N5O3S
    N-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]cyclopropanecarboxamide
    —— 1-(3-(Cyclohexylsulfonyl)azetidin-1-yl)-2-cyclopentylethanone —— C16H27NO3S
    1-(3-(Cyclohexylsulfonyl)azetidin-1-yl)-2-cyclopentylethanone
    —— 1-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]-3-[[(2R)-oxolan-2-yl]methyl]thiourea —— C17H18N6O3S2
    1-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]-3-[[(2R)-oxolan-2-yl]methyl]thiourea
    —— 1-(3-(Cyclohexylsulfonyl)azetidin-1-yl)-2-ethylbutan-1-one —— C15H27NO3S
    1-(3-(Cyclohexylsulfonyl)azetidin-1-yl)-2-ethylbutan-1-one
    —— 1-(3-(Cyclohexylsulfonyl)azetidin-1-yl)butan-1-one —— C13H23NO3S
    1-(3-(Cyclohexylsulfonyl)azetidin-1-yl)butan-1-one
    —— 1-(3-(Isobutylsulfonyl)azetidin-1-yl)propan-1-one —— C10H19NO3S
    1-(3-(Isobutylsulfonyl)azetidin-1-yl)propan-1-one
    —— 2-Ethyl-1-(3-(isobutylsulfonyl)azetidin-1-yl)butan-1-one —— C13H25NO3S
    2-Ethyl-1-(3-(isobutylsulfonyl)azetidin-1-yl)butan-1-one
    —— (1R,4R)-1,7,7-trimethyl-N-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]bicyclo[2.2.1]hept-2-en-2-amine —— C20H24N6O2S
    (1R,4R)-1,7,7-trimethyl-N-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]bicyclo[2.2.1]hept-2-en-2-amine
    —— (Z)-N-morpholin-4-yl-1-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methanimine —— C15H15N5O3S
    (Z)-N-morpholin-4-yl-1-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methanimine
    —— 1-(3-(Cyclohexylsulfonyl)azetidin-1-yl)-2,2,2-trifluoroethanone —— C11H16F3NO3S
    1-(3-(Cyclohexylsulfonyl)azetidin-1-yl)-2,2,2-trifluoroethanone
    —— 3-butyl-1-methyl-1-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]thiourea —— C16H21N7O2S2
    3-butyl-1-methyl-1-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]thiourea
    —— 3-(3-(Cyclohexylsulfonyl)azetidin-1-yl)-3-oxopropanenitrile —— C12H18N2O3S
    3-(3-(Cyclohexylsulfonyl)azetidin-1-yl)-3-oxopropanenitrile
    —— 4,4,4-Trifluoro-1-(3-(isobutylsulfonyl)azetidin-1-yl)butan-1-one —— C11H18F3NO3S
    4,4,4-Trifluoro-1-(3-(isobutylsulfonyl)azetidin-1-yl)butan-1-one
    —— (Z)-4-hydroxy-3-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]pent-3-en-2-one —— C14H15N3O2S2
    (Z)-4-hydroxy-3-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]pent-3-en-2-one
    —— (Z)-3-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-4-hydroxypent-3-en-2-one —— C15H17N3O2S2
    (Z)-3-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-4-hydroxypent-3-en-2-one
    —— 1-(3,4-dimethoxyphenyl)-3-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]thiourea —— C19H19N7O4S2
    1-(3,4-dimethoxyphenyl)-3-[(Z)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]thiourea
    —— 1-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]-3-[[(2S)-oxolan-2-yl]methyl]thiourea —— C17H18N6O3S2
    1-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]-3-[[(2S)-oxolan-2-yl]methyl]thiourea