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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (1R,2R,4R)-4-methyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]cyclohexane-1-carbonitrile —— C13H20N4OS
    (1R,2R,4R)-4-methyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]cyclohexane-1-carbonitrile
    —— 3-[(1R)-2-amino-1-pyridin-3-ylethyl]sulfanyl-4-propan-2-yl-1H-1,2,4-triazol-5-one —— C12H17N5OS
    3-[(1R)-2-amino-1-pyridin-3-ylethyl]sulfanyl-4-propan-2-yl-1H-1,2,4-triazol-5-one
    —— (2R)-2-(cyclopropylamino)-3-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]propanenitrile —— C10H15N5OS
    (2R)-2-(cyclopropylamino)-3-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]propanenitrile
    —— 3-[(1R)-2-amino-1-(5-methylthiophen-2-yl)ethyl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one —— C12H18N4OS2
    3-[(1R)-2-amino-1-(5-methylthiophen-2-yl)ethyl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one
    —— 3-[(1R,2R)-2-amino-1-(5-bromothiophen-2-yl)propyl]sulfanyl-4-ethyl-1H-1,2,4-triazol-5-one —— C11H15BrN4OS2
    3-[(1R,2R)-2-amino-1-(5-bromothiophen-2-yl)propyl]sulfanyl-4-ethyl-1H-1,2,4-triazol-5-one
    —— 3-[(2S)-2-hydroxy-2-phenylethyl]sulfanyl-4-propan-2-yl-1H-1,2,4-triazol-5-one —— C13H17N3O2S
    3-[(2S)-2-hydroxy-2-phenylethyl]sulfanyl-4-propan-2-yl-1H-1,2,4-triazol-5-one
    —— 3-[(1S,2S)-2-amino-1-thiophen-2-ylbutyl]sulfanyl-4-ethyl-1H-1,2,4-triazol-5-one —— C12H18N4OS2
    3-[(1S,2S)-2-amino-1-thiophen-2-ylbutyl]sulfanyl-4-ethyl-1H-1,2,4-triazol-5-one
    —— 1-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]cyclopentane-1-carboxylic acid —— C11H17N3O3S
    1-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]cyclopentane-1-carboxylic acid
    —— 3-[(2R)-3-amino-1,1,1-trifluoropropan-2-yl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one —— C8H13F3N4OS
    3-[(2R)-3-amino-1,1,1-trifluoropropan-2-yl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one
    —— (3S)-3-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N'-hydroxypentanimidamide —— C9H17N5O2S
    (3S)-3-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N'-hydroxypentanimidamide
    —— 3-[(2S)-2-hydroxy-3-(propylamino)propyl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one —— C11H22N4O2S
    3-[(2S)-2-hydroxy-3-(propylamino)propyl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one
    —— 3-[(1S)-2-amino-1-(4-bromothiophen-2-yl)ethyl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one —— C11H15BrN4OS2
    3-[(1S)-2-amino-1-(4-bromothiophen-2-yl)ethyl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one
    —— 3-[(2R,3S)-3-amino-1,1,1-trifluorobutan-2-yl]sulfanyl-4-propan-2-yl-1H-1,2,4-triazol-5-one —— C9H15F3N4OS
    3-[(2R,3S)-3-amino-1,1,1-trifluorobutan-2-yl]sulfanyl-4-propan-2-yl-1H-1,2,4-triazol-5-one
    —— 3-[2-[(2S)-piperidin-2-yl]ethylsulfanyl]-4-propyl-1H-1,2,4-triazol-5-one —— C12H22N4OS
    3-[2-[(2S)-piperidin-2-yl]ethylsulfanyl]-4-propyl-1H-1,2,4-triazol-5-one
    —— (1R,2R)-2-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]cyclopentane-1-carbonitrile —— C10H14N4OS
    (1R,2R)-2-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]cyclopentane-1-carbonitrile
    —— (1R,3R)-1-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-3-methylcyclohexane-1-carboxylic acid —— C12H19N3O3S
    (1R,3R)-1-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-3-methylcyclohexane-1-carboxylic acid
    —— (2R)-N'-hydroxy-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]butanimidamide —— C9H17N5O2S
    (2R)-N'-hydroxy-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]butanimidamide
    —— 3-[(3S,4R)-4-amino-2,2-dimethylhexan-3-yl]sulfanyl-4-ethyl-1H-1,2,4-triazol-5-one —— C12H24N4OS
    3-[(3S,4R)-4-amino-2,2-dimethylhexan-3-yl]sulfanyl-4-ethyl-1H-1,2,4-triazol-5-one
    —— 3-[(2R,3S)-3-amino-1,1,1-trifluorobutan-2-yl]sulfanyl-4-ethyl-1H-1,2,4-triazol-5-one —— C8H13F3N4OS
    3-[(2R,3S)-3-amino-1,1,1-trifluorobutan-2-yl]sulfanyl-4-ethyl-1H-1,2,4-triazol-5-one
    —— 4-ethyl-3-[(3R)-piperidin-3-yl]sulfanyl-1H-1,2,4-triazol-5-one —— C9H16N4OS
    4-ethyl-3-[(3R)-piperidin-3-yl]sulfanyl-1H-1,2,4-triazol-5-one
    —— 3-[(2S)-2-hydroxy-3-(propylamino)propyl]sulfanyl-4-propan-2-yl-1H-1,2,4-triazol-5-one —— C11H22N4O2S
    3-[(2S)-2-hydroxy-3-(propylamino)propyl]sulfanyl-4-propan-2-yl-1H-1,2,4-triazol-5-one
    —— (1R,2S)-2-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]cyclohexane-1-carbonitrile —— C11H16N4OS
    (1R,2S)-2-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]cyclohexane-1-carbonitrile
    —— 3-[(1S)-2-amino-1-(3-methylthiophen-2-yl)ethyl]sulfanyl-4-propan-2-yl-1H-1,2,4-triazol-5-one —— C12H18N4OS2
    3-[(1S)-2-amino-1-(3-methylthiophen-2-yl)ethyl]sulfanyl-4-propan-2-yl-1H-1,2,4-triazol-5-one
    —— 2-(1-oxidopyridin-1-ium-2-yl)sulfanyl-1-[(4R)-4-propylazepan-1-yl]ethanone —— C16H24N2O2S
    2-(1-oxidopyridin-1-ium-2-yl)sulfanyl-1-[(4R)-4-propylazepan-1-yl]ethanone
    —— 3-[(1R)-2-amino-1-(5-chlorothiophen-2-yl)ethyl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one —— C11H15ClN4OS2
    3-[(1R)-2-amino-1-(5-chlorothiophen-2-yl)ethyl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one
    —— 3-[(1S)-2-amino-1-(5-methylthiophen-2-yl)ethyl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one —— C12H18N4OS2
    3-[(1S)-2-amino-1-(5-methylthiophen-2-yl)ethyl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one
    —— (1R,2S,4R)-4-methyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]cyclohexane-1-carbonitrile —— C13H20N4OS
    (1R,2S,4R)-4-methyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]cyclohexane-1-carbonitrile
    —— (2R)-2-(methylamino)-3-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]propanenitrile —— C7H11N5OS
    (2R)-2-(methylamino)-3-[(4-methyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]propanenitrile
    —— 4-ethyl-3-[[(2R)-pyrrolidin-2-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one —— C9H16N4OS
    4-ethyl-3-[[(2R)-pyrrolidin-2-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one
    —— 3-[(2R)-2-hydroxy-2-phenylethyl]sulfanyl-4-propan-2-yl-1H-1,2,4-triazol-5-one —— C13H17N3O2S
    3-[(2R)-2-hydroxy-2-phenylethyl]sulfanyl-4-propan-2-yl-1H-1,2,4-triazol-5-one
    —— (3S)-3-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]pentanenitrile —— C10H16N4OS
    (3S)-3-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]pentanenitrile
    —— (2R)-4-methoxy-2-methyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]butanoic acid —— C11H19N3O4S
    (2R)-4-methoxy-2-methyl-2-[(5-oxo-4-propyl-1H-1,2,4-triazol-3-yl)sulfanyl]butanoic acid
    —— 3-[(1S)-2-amino-1-(5-methylfuran-2-yl)ethyl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one —— C12H18N4O2S
    3-[(1S)-2-amino-1-(5-methylfuran-2-yl)ethyl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one
    —— 3-[(1R,2S)-2-amino-1-(furan-2-yl)propyl]sulfanyl-4-propan-2-yl-1H-1,2,4-triazol-5-one —— C12H18N4O2S
    3-[(1R,2S)-2-amino-1-(furan-2-yl)propyl]sulfanyl-4-propan-2-yl-1H-1,2,4-triazol-5-one
    —— 3-[(1R)-2-amino-1-(5-methylfuran-2-yl)ethyl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one —— C12H18N4O2S
    3-[(1R)-2-amino-1-(5-methylfuran-2-yl)ethyl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one
    —— 3-[(2S)-3-amino-1,1,1-trifluoropropan-2-yl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one —— C8H13F3N4OS
    3-[(2S)-3-amino-1,1,1-trifluoropropan-2-yl]sulfanyl-4-propyl-1H-1,2,4-triazol-5-one
    —— 4-ethyl-3-[[(3S)-piperidin-3-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one —— C10H18N4OS
    4-ethyl-3-[[(3S)-piperidin-3-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one
    —— 4-ethyl-3-[[(3S)-pyrrolidin-3-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one —— C9H16N4OS
    4-ethyl-3-[[(3S)-pyrrolidin-3-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one
    —— 3-[(1S)-2-amino-1-pyridin-3-ylethyl]sulfanyl-4-propan-2-yl-1H-1,2,4-triazol-5-one —— C12H17N5OS
    3-[(1S)-2-amino-1-pyridin-3-ylethyl]sulfanyl-4-propan-2-yl-1H-1,2,4-triazol-5-one
    —— 3-[(1S,2R)-2-amino-1-(furan-2-yl)propyl]sulfanyl-4-propan-2-yl-1H-1,2,4-triazol-5-one —— C12H18N4O2S
    3-[(1S,2R)-2-amino-1-(furan-2-yl)propyl]sulfanyl-4-propan-2-yl-1H-1,2,4-triazol-5-one
    —— (1R,2R,4R)-4-methyl-2-[(5-oxo-4-propan-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]cyclohexane-1-carbonitrile —— C13H20N4OS
    (1R,2R,4R)-4-methyl-2-[(5-oxo-4-propan-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]cyclohexane-1-carbonitrile
    —— 4-cyclopropyl-3-[(2S)-2-hydroxy-3-(propylamino)propyl]sulfanyl-1H-1,2,4-triazol-5-one —— C11H20N4O2S
    4-cyclopropyl-3-[(2S)-2-hydroxy-3-(propylamino)propyl]sulfanyl-1H-1,2,4-triazol-5-one
    —— 3-[(1S,2R)-2-amino-1-(5-bromothiophen-2-yl)propyl]sulfanyl-4-ethyl-1H-1,2,4-triazol-5-one —— C11H15BrN4OS2
    3-[(1S,2R)-2-amino-1-(5-bromothiophen-2-yl)propyl]sulfanyl-4-ethyl-1H-1,2,4-triazol-5-one
    —— 4-ethyl-3-[(2S)-2-hydroxy-3-(propan-2-ylamino)propyl]sulfanyl-1H-1,2,4-triazol-5-one —— C10H20N4O2S
    4-ethyl-3-[(2S)-2-hydroxy-3-(propan-2-ylamino)propyl]sulfanyl-1H-1,2,4-triazol-5-one
    —— (2S)-N'-hydroxy-2-methyl-3-[(5-oxo-4-propan-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanimidamide —— C9H17N5O2S
    (2S)-N'-hydroxy-2-methyl-3-[(5-oxo-4-propan-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanimidamide
    —— (2S)-2-methyl-3-[(5-oxo-4-propan-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanenitrile —— C9H14N4OS
    (2S)-2-methyl-3-[(5-oxo-4-propan-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]propanenitrile
    —— (1R,2S)-2-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]cyclopentane-1-carbonitrile —— C10H14N4OS
    (1R,2S)-2-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]cyclopentane-1-carbonitrile
    —— (2S)-2-[(5-oxo-4-propan-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]butanenitrile —— C9H14N4OS
    (2S)-2-[(5-oxo-4-propan-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]butanenitrile
    —— 4-ethyl-3-[[(2R)-piperidin-2-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one —— C10H18N4OS
    4-ethyl-3-[[(2R)-piperidin-2-yl]methylsulfanyl]-1H-1,2,4-triazol-5-one
    —— 6-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N'-hydroxypyridine-3-carboximidamide —— C10H12N6O2S
    6-[(4-ethyl-5-oxo-1H-1,2,4-triazol-3-yl)sulfanyl]-N'-hydroxypyridine-3-carboximidamide