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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (3S)-3-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-3-phenylpropanenitrile —— C13H11N3OS
    (3S)-3-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-3-phenylpropanenitrile
    —— (3R)-N'-hydroxy-3-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-3-phenylpropanimidamide —— C13H15N3OS2
    (3R)-N'-hydroxy-3-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-3-phenylpropanimidamide
    —— (3R)-3-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-3-phenylpropanenitrile —— C13H11N3OS
    (3R)-3-[(6-oxo-1H-pyrimidin-2-yl)sulfanyl]-3-phenylpropanenitrile
    —— (3S)-N'-hydroxy-3-(1-methylpyrazol-4-yl)sulfanyl-3-phenylpropanimidamide —— C13H16N4OS
    (3S)-N'-hydroxy-3-(1-methylpyrazol-4-yl)sulfanyl-3-phenylpropanimidamide
    —— (3R)-3-[(6-methyl-4-oxo-1H-pyrimidin-2-yl)sulfanyl]-3-phenylpropanenitrile —— C14H13N3OS
    (3R)-3-[(6-methyl-4-oxo-1H-pyrimidin-2-yl)sulfanyl]-3-phenylpropanenitrile
    —— (3R)-3-(4-bromophenyl)sulfanyl-3-phenylpropan-1-amine —— C15H16BrNS
    (3R)-3-(4-bromophenyl)sulfanyl-3-phenylpropan-1-amine
    —— (3S)-3-(1-methyltetrazol-5-yl)sulfanyl-3-phenylpropan-1-amine —— C11H15N5S
    (3S)-3-(1-methyltetrazol-5-yl)sulfanyl-3-phenylpropan-1-amine
    —— (3S)-3-(3,4-dimethylphenyl)sulfanyl-3-phenylpropan-1-amine —— C17H21NS
    (3S)-3-(3,4-dimethylphenyl)sulfanyl-3-phenylpropan-1-amine
    —— 3-[(2-fluorophenyl)methylsulfanyl]-4-[[(2S)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazole —— C18H23FN4OS
    3-[(2-fluorophenyl)methylsulfanyl]-4-[[(2S)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazole
    —— 2-[(2-methylsulfanylanilino)methylidene]-1-benzothiophen-3-one —— C16H13NOS2
    2-[(2-methylsulfanylanilino)methylidene]-1-benzothiophen-3-one
    —— 1-[5-[(2-fluorophenyl)methylsulfanyl]-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]-4-methylpiperidine —— C20H27FN4OS
    1-[5-[(2-fluorophenyl)methylsulfanyl]-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]-4-methylpiperidine
    —— (1R)-N-methyl-1-[4-[(2-methylphenyl)methylsulfanyl]phenyl]ethanamine —— C17H21NS
    (1R)-N-methyl-1-[4-[(2-methylphenyl)methylsulfanyl]phenyl]ethanamine
    —— (3S,5R)-3-[[4-(furan-2-ylmethyl)-5-piperidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]-5-methyloxolan-2-one —— C17H22N4O3S
    (3S,5R)-3-[[4-(furan-2-ylmethyl)-5-piperidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]-5-methyloxolan-2-one
    —— [1-(5-ethylimino-4-nitrothiophen-2-ylidene)ethylamino]thiourea —— C9H13N5O2S2
    [1-(5-ethylimino-4-nitrothiophen-2-ylidene)ethylamino]thiourea
    —— 4-[5-[(2-fluorophenyl)methylsulfanyl]-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]morpholine —— C18H23FN4O2S
    4-[5-[(2-fluorophenyl)methylsulfanyl]-4-[[(2R)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]morpholine
    —— 4-[5-[(2-fluorophenyl)methylsulfanyl]-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]morpholine —— C18H23FN4O2S
    4-[5-[(2-fluorophenyl)methylsulfanyl]-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]morpholine
    —— 4-[5-(2-chloroprop-2-enylsulfanyl)-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]morpholine —— C14H21ClN4O2S
    4-[5-(2-chloroprop-2-enylsulfanyl)-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]morpholine
    —— (2R,3S)-N-ethyl-3-methylsulfonylbutan-2-amine —— C7H17NO2S
    (2R,3S)-N-ethyl-3-methylsulfonylbutan-2-amine
    —— (2R,3R)-2-methylsulfonylpentan-3-amine —— C6H15NO2S
    (2R,3R)-2-methylsulfonylpentan-3-amine
    —— (2S,3S)-N-methyl-3-methylsulfonylbutan-2-amine —— C6H15NO2S
    (2S,3S)-N-methyl-3-methylsulfonylbutan-2-amine
    —— (2R,3S)-N-methyl-3-methylsulfonylbutan-2-amine —— C6H15NO2S
    (2R,3S)-N-methyl-3-methylsulfonylbutan-2-amine
    —— (1S,2S)-N-methyl-2-methylsulfonylcyclopentan-1-amine —— C7H15NO2S
    (1S,2S)-N-methyl-2-methylsulfonylcyclopentan-1-amine
    —— (1R,2S)-N-methyl-2-methylsulfonylcyclooctan-1-amine —— C10H21NO2S
    (1R,2S)-N-methyl-2-methylsulfonylcyclooctan-1-amine
    —— (1S,2R)-N-methyl-2-methylsulfonylcyclooctan-1-amine —— C10H21NO2S
    (1S,2R)-N-methyl-2-methylsulfonylcyclooctan-1-amine
    —— (1S,2S)-2-methylsulfonyl-N-propylcycloheptan-1-amine —— C11H23NO2S
    (1S,2S)-2-methylsulfonyl-N-propylcycloheptan-1-amine
    —— (1S,2S)-2-methylsulfonyl-N-propylcyclopentan-1-amine —— C9H19NO2S
    (1S,2S)-2-methylsulfonyl-N-propylcyclopentan-1-amine
    —— (1R,2R)-2-methylsulfonylcyclooctan-1-amine —— C9H19NO2S
    (1R,2R)-2-methylsulfonylcyclooctan-1-amine
    —— (1R,2R)-N-ethyl-2-methylsulfonylcycloheptan-1-amine —— C10H21NO2S
    (1R,2R)-N-ethyl-2-methylsulfonylcycloheptan-1-amine
    —— (1R,2S)-2-methylsulfonylcyclooctan-1-amine —— C9H19NO2S
    (1R,2S)-2-methylsulfonylcyclooctan-1-amine
    —— (1R,2R)-N-methyl-2-methylsulfonylcyclopentan-1-amine —— C7H15NO2S
    (1R,2R)-N-methyl-2-methylsulfonylcyclopentan-1-amine
    —— (2S,3S)-3-methylsulfonylbutan-2-amine —— C5H13NO2S
    (2S,3S)-3-methylsulfonylbutan-2-amine
    —— (1S,2R)-N-ethyl-2-methylsulfonylcycloheptan-1-amine —— C10H21NO2S
    (1S,2R)-N-ethyl-2-methylsulfonylcycloheptan-1-amine
    —— (1R,2R)-2-methylsulfonylcycloheptan-1-amine —— C8H17NO2S
    (1R,2R)-2-methylsulfonylcycloheptan-1-amine
    —— (2S,3R)-N-methyl-3-methylsulfonylbutan-2-amine —— C6H15NO2S
    (2S,3R)-N-methyl-3-methylsulfonylbutan-2-amine
    —— (1R,2S)-N-ethyl-2-methylsulfonylcyclopentan-1-amine —— C8H17NO2S
    (1R,2S)-N-ethyl-2-methylsulfonylcyclopentan-1-amine
    —— Rel-(1R,2S)-N-methyl-2-(methylsulfonyl)cyclopentan-1-amine —— C7H15NO2S
    Rel-(1R,2S)-N-methyl-2-(methylsulfonyl)cyclopentan-1-amine
    —— (2S,3R)-N-methyl-2-methylsulfonylpentan-3-amine —— C7H17NO2S
    (2S,3R)-N-methyl-2-methylsulfonylpentan-3-amine
    —— (1R,2R)-N-methyl-2-methylsulfonylcyclododecan-1-amine —— C14H29NO2S
    (1R,2R)-N-methyl-2-methylsulfonylcyclododecan-1-amine
    —— (1R,2R)-N-ethyl-2-methylsulfonylcyclopentan-1-amine —— C8H17NO2S
    (1R,2R)-N-ethyl-2-methylsulfonylcyclopentan-1-amine
    —— (2R,3S)-N-methyl-2-methylsulfonylpentan-3-amine —— C7H17NO2S
    (2R,3S)-N-methyl-2-methylsulfonylpentan-3-amine
    —— (1S,2S)-N-ethyl-2-methylsulfonylcyclooctan-1-amine —— C11H23NO2S
    (1S,2S)-N-ethyl-2-methylsulfonylcyclooctan-1-amine
    —— 2-(4,6-dimethoxy-1H-pyrimidin-2-ylidene)-1-benzothiophen-3-one —— C14H12N2O3S
    2-(4,6-dimethoxy-1H-pyrimidin-2-ylidene)-1-benzothiophen-3-one
    —— 6-[5-bromo-2-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]-3-prop-2-enylsulfanyl-2H-1,2,4-triazin-5-one —— C23H19BrN6O2S
    6-[5-bromo-2-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]-3-prop-2-enylsulfanyl-2H-1,2,4-triazin-5-one
    —— 4-methyl-N-[2-(6-methyl-3-propylsulfanyl-1,2,4-triazin-5-yl)ethenyl]aniline —— C16H20N4S
    4-methyl-N-[2-(6-methyl-3-propylsulfanyl-1,2,4-triazin-5-yl)ethenyl]aniline
    —— (1S,2R)-2-(2-methylsulfonylethylamino)cyclopentane-1-carbonitrile —— C9H16N2O2S
    (1S,2R)-2-(2-methylsulfonylethylamino)cyclopentane-1-carbonitrile
    —— 2-[(4-bromoanilino)-phenylmethylidene]-1-benzothiophen-3-one —— C21H14BrNOS
    2-[(4-bromoanilino)-phenylmethylidene]-1-benzothiophen-3-one
    —— (1R,2S)-2-(4-methylsulfanylanilino)cyclohexane-1-carbonitrile —— C14H18N2S
    (1R,2S)-2-(4-methylsulfanylanilino)cyclohexane-1-carbonitrile
    —— 2-[(4-methylanilino)methylidene]-1-benzothiophen-3-one —— C16H13NOS
    2-[(4-methylanilino)methylidene]-1-benzothiophen-3-one
    —— 4-[5-(2-methylpropylsulfanyl)-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]morpholine —— C15H26N4O2S
    4-[5-(2-methylpropylsulfanyl)-4-[[(2S)-oxolan-2-yl]methyl]-1,2,4-triazol-3-yl]morpholine
    —— (1R,2S)-2-[2-(difluoromethylsulfanyl)anilino]cyclohexane-1-carbonitrile —— C14H16F2N2S
    (1R,2S)-2-[2-(difluoromethylsulfanyl)anilino]cyclohexane-1-carbonitrile