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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (4E)-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-1-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]-5-thiophen-2-ylpyrrolidine-2,3-dione —— C27H23N3O3S3
    (4E)-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-1-[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]-5-thiophen-2-ylpyrrolidine-2,3-dione
    —— 2-[[(2S)-pyrrolidin-2-yl]methylsulfanyl]aniline —— C11H16N2S
    2-[[(2S)-pyrrolidin-2-yl]methylsulfanyl]aniline
    —— ethane;1-(6-methyl-2-methylsulfanylpyrimidin-4-yl)-3-N-phenyl-1,2,4-triazole-3,5-diamine —— C16H21N7S
    ethane;1-(6-methyl-2-methylsulfanylpyrimidin-4-yl)-3-N-phenyl-1,2,4-triazole-3,5-diamine
    —— 3-[3-(4-Acetyloxan-4-yl)phenyl]sulfanylpropanoic acid —— C16H20O4S
    3-[3-(4-Acetyloxan-4-yl)phenyl]sulfanylpropanoic acid
    —— 4-[[3-(cyclopropylmethyl)-2-methyl-6-oxo-5-propan-2-yl-1H-pyridin-4-yl]sulfanyl]-6-methyl-2-methylidenehepta-3,5-dienenitrile —— C22H28N2OS
    4-[[3-(cyclopropylmethyl)-2-methyl-6-oxo-5-propan-2-yl-1H-pyridin-4-yl]sulfanyl]-6-methyl-2-methylidenehepta-3,5-dienenitrile
    —— 1-Butyl-3,5-bis(nonadecylsulfanyl)benzene —— C48H90S2
    1-Butyl-3,5-bis(nonadecylsulfanyl)benzene
    —— 3-[2-(3,5-difluorophenyl)ethyl]-8-(2,5-dimethoxyphenyl)sulfanyl-7H-purin-3-ium-6-amine —— C21H20F2N5O2S+
    3-[2-(3,5-difluorophenyl)ethyl]-8-(2,5-dimethoxyphenyl)sulfanyl-7H-purin-3-ium-6-amine
    —— <1-13C>Thioanisol —— C7H8S
    <1-13C>Thioanisol
    —— [(Z)-[6-(4-methylphenyl)sulfanylpyridin-3-yl]methylideneamino] 2-chlorobenzoate —— C20H15ClN2O2S
    [(Z)-[6-(4-methylphenyl)sulfanylpyridin-3-yl]methylideneamino] 2-chlorobenzoate
    —— 2-Chloro-2-(1-chloroethylsulfanyl)ethanethiol —— C4H8Cl2S2
    2-Chloro-2-(1-chloroethylsulfanyl)ethanethiol
    —— N-[(Z)-[5-(4-methylphenyl)sulfanylfuran-2-yl]methylideneamino]-3-(trifluoromethyl)benzamide —— C20H15F3N2O2S
    N-[(Z)-[5-(4-methylphenyl)sulfanylfuran-2-yl]methylideneamino]-3-(trifluoromethyl)benzamide
    —— 1-[[2-(4-Methylsulfanylphenyl)cyclohexen-1-yl]methyl]piperazine —— C18H26N2S
    1-[[2-(4-Methylsulfanylphenyl)cyclohexen-1-yl]methyl]piperazine
    —— (4E)-1-(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-5-(furan-2-yl)pyrrolidine-2,3-dione —— C26H21N3O4S2
    (4E)-1-(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-5-(furan-2-yl)pyrrolidine-2,3-dione
    —— 3-ethyl-7-phenylsulfanyl-6-propan-2-yl-5H-pyrazolo[5,1-c][1,2,4]triazole;methyl 3,6-dimethyl-5H-pyrazolo[5,1-c][1,2,4]triazole-7-carboxylate —— C23H28N8O2S
    3-ethyl-7-phenylsulfanyl-6-propan-2-yl-5H-pyrazolo[5,1-c][1,2,4]triazole;methyl 3,6-dimethyl-5H-pyrazolo[5,1-c][1,2,4]triazole-7-carboxylate
    —— (4E)-1-(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-5-pyridin-4-ylpyrrolidine-2,3-dione —— C27H22N4O3S2
    (4E)-1-(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-5-pyridin-4-ylpyrrolidine-2,3-dione
    —— 2-(Disulfanyl)-3-methylpentanethioamide —— C6H13NS3
    2-(Disulfanyl)-3-methylpentanethioamide
    —— (E)-3-(5-chloro-1,3-dimethylpyrazol-4-yl)-1-[2-[2-([1,2,4]triazolo[3,4-c][1,2,4]benzotriazin-1-ylsulfanyl)acetyl]pyrazolidin-1-yl]prop-2-en-1-one —— C21H20ClN9O2S
    (E)-3-(5-chloro-1,3-dimethylpyrazol-4-yl)-1-[2-[2-([1,2,4]triazolo[3,4-c][1,2,4]benzotriazin-1-ylsulfanyl)acetyl]pyrazolidin-1-yl]prop-2-en-1-one
    —— 1,2,3-Tris(octadecylsulfanyl)benzene —— C60H114S3
    1,2,3-Tris(octadecylsulfanyl)benzene
    —— 2,5-dimethyl-3,4-didehydro-2H-thiopyran —— C7H8S
    2,5-dimethyl-3,4-didehydro-2H-thiopyran
    —— ethane;propane;10H-thiochromeno[2,3-b]pyrazine —— C16H22N2S
    ethane;propane;10H-thiochromeno[2,3-b]pyrazine
    —— 1-(15-Methyl-13-bicyclo[8.7.0]heptadecanyl)ethanethiol —— C20H38S
    1-(15-Methyl-13-bicyclo[8.7.0]heptadecanyl)ethanethiol
    —— 1-[4-[[2-[(2-Methylphenyl)methylsulfanyl]pyridin-3-yl]methyl]piperazin-1-yl]ethanimine —— C20H26N4S
    1-[4-[[2-[(2-Methylphenyl)methylsulfanyl]pyridin-3-yl]methyl]piperazin-1-yl]ethanimine
    —— 3-Methylsulfanyl-1-sulfanylpyrrole-2,5-diol —— C5H7NO2S2
    3-Methylsulfanyl-1-sulfanylpyrrole-2,5-diol
    —— N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-4,6-di(piperidin-1-yl)-1,3,5-triazin-2-amine —— C26H29ClN8O2S
    N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-4,6-di(piperidin-1-yl)-1,3,5-triazin-2-amine
    —— N-[(Z)-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]-N-phenylaniline —— C23H16BrClN2OS
    N-[(Z)-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]-N-phenylaniline
    —— [2-(Cyanomethylcarbamoyl)cyclohexylidene]-[4-[2-oxo-2-(2-thiophen-2-ylethylamino)ethyl]sulfanylphenyl]methanesulfinic acid —— C24H27N3O4S3
    [2-(Cyanomethylcarbamoyl)cyclohexylidene]-[4-[2-oxo-2-(2-thiophen-2-ylethylamino)ethyl]sulfanylphenyl]methanesulfinic acid
    —— 2-(3,3-Difluoro-1-methylpiperidin-4-yl)-2-(6-imidazo[1,2-a]pyrimidin-3-ylsulfanyl-1,3-benzothiazol-2-yl)acetamide —— C21H20F2N6OS2
    2-(3,3-Difluoro-1-methylpiperidin-4-yl)-2-(6-imidazo[1,2-a]pyrimidin-3-ylsulfanyl-1,3-benzothiazol-2-yl)acetamide
    —— (4E)-1-(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-5-thiophen-2-ylpyrrolidine-2,3-dione —— C26H21N3O3S3
    (4E)-1-(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)-4-[(2,5-dimethylphenyl)-hydroxymethylidene]-5-thiophen-2-ylpyrrolidine-2,3-dione
    —— N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-1,3-benzothiazol-2-amine —— C20H13ClN4O2S2
    N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-1,3-benzothiazol-2-amine
    —— (2Z,5Z)-3-[(2,6-dichlorophenyl)methyl]-2-(3,3-dimethyl-2-oxobutylidene)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-1,3-thiazolidin-4-one —— C30H26Cl2N2O4S2
    (2Z,5Z)-3-[(2,6-dichlorophenyl)methyl]-2-(3,3-dimethyl-2-oxobutylidene)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-1,3-thiazolidin-4-one
    —— 2-[(2,3-difluorophenyl)methylsulfanyl]-4-(2-hydroxypropan-2-ylamino)-1H-pyrimidin-6-one —— C14H15F2N3O2S
    2-[(2,3-difluorophenyl)methylsulfanyl]-4-(2-hydroxypropan-2-ylamino)-1H-pyrimidin-6-one
    —— 7-Ethylsulfanyl-2-methylhept-2-ene —— C10H20S
    7-Ethylsulfanyl-2-methylhept-2-ene
    —— N-[(Z)-[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]-4-cyano-2-fluorobenzamide —— C19H11ClFN3O2S
    N-[(Z)-[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]-4-cyano-2-fluorobenzamide
    —— methyl 2-[5-bromo-4-(4-chlorophenyl)sulfanyl-7,8-difluoro-2,3-dihydro-1H-pyrrolo[1,2-a]indol-3-yl]acetate —— C20H15BrClF2NO2S
    methyl 2-[5-bromo-4-(4-chlorophenyl)sulfanyl-7,8-difluoro-2,3-dihydro-1H-pyrrolo[1,2-a]indol-3-yl]acetate
    —— Ethane;3-methyl-4-(2-methylphenyl)sulfanylbutan-2-one —— C14H22OS
    Ethane;3-methyl-4-(2-methylphenyl)sulfanylbutan-2-one
    —— (E)-3-amino-2-[2-[[4-(4-chlorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]but-2-enenitrile —— C14H11ClN4OS3
    (E)-3-amino-2-[2-[[4-(4-chlorophenyl)-5-sulfanylidene-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]but-2-enenitrile
    —— (Z)-1-[5-(4-chlorophenyl)sulfanyl-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]-N-[(2,6-dichlorophenyl)methoxy]methanimine —— C19H13Cl3F3N3OS
    (Z)-1-[5-(4-chlorophenyl)sulfanyl-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]-N-[(2,6-dichlorophenyl)methoxy]methanimine
    —— N-[(E)-1-(4-tert-butylphenyl)ethylideneamino]-4-(4-phenylsulfanylphenyl)-1,3-thiazol-2-amine —— C27H27N3S2
    N-[(E)-1-(4-tert-butylphenyl)ethylideneamino]-4-(4-phenylsulfanylphenyl)-1,3-thiazol-2-amine
    —— (Dithiocarboxytrisulfanyl)methanedithioic acid —— C2H2S7
    (Dithiocarboxytrisulfanyl)methanedithioic acid
    —— 2,5-Dithiabicyclo[4.4.0]deca-1(10),6,8-trien-3-yne —— C8H4S2
    2,5-Dithiabicyclo[4.4.0]deca-1(10),6,8-trien-3-yne
    —— ethyl (2Z)-2-[[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-7-methyl-3-oxo-5-phenyl-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C27H21ClN2O4S2
    ethyl (2Z)-2-[[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-7-methyl-3-oxo-5-phenyl-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— 1,3-Bis-heptylmercapto-benzol 21128-59-6 C20H34S2
    1,3-Bis-heptylmercapto-benzol
    —— 1-[5-(Cyclohexa-1,3-dien-1-ylmethyl)-1,4-dioxin-2-yl]-4-[3-[5-(trifluoromethyl)pyridin-2-yl]sulfanylpropyl]piperazine —— C24H28F3N3O2S
    1-[5-(Cyclohexa-1,3-dien-1-ylmethyl)-1,4-dioxin-2-yl]-4-[3-[5-(trifluoromethyl)pyridin-2-yl]sulfanylpropyl]piperazine
    —— 1,2-Dichloro-1-ethylsulfonylethene —— C4H6Cl2O2S
    1,2-Dichloro-1-ethylsulfonylethene
    —— 3,3-Dimethylpent-1-enyl-diethyl-[1-(1-ethylcyclopropyl)-2,2-dimethylpropyl]-lambda4-sulfane —— C21H42S
    3,3-Dimethylpent-1-enyl-diethyl-[1-(1-ethylcyclopropyl)-2,2-dimethylpropyl]-lambda4-sulfane
    —— 8-(2,5-dimethoxyphenyl)sulfanyl-3-(2-thiophen-2-ylethyl)-7H-purin-3-ium-6-amine —— C19H20N5O2S2+
    8-(2,5-dimethoxyphenyl)sulfanyl-3-(2-thiophen-2-ylethyl)-7H-purin-3-ium-6-amine
    —— 3-[2-(5-Anilino-1,3,4-thiadiazol-2-yl)thiophen-3-yl]sulfanylpropanoic acid —— C15H13N3O2S3
    3-[2-(5-Anilino-1,3,4-thiadiazol-2-yl)thiophen-3-yl]sulfanylpropanoic acid
    —— 3,3-Dimethylpent-1-enyl-diethyl-[1-(1-ethylcyclopropyl)-2,2-dimethylpropyl]-lambda4-sulfane —— C21H41S-
    3,3-Dimethylpent-1-enyl-diethyl-[1-(1-ethylcyclopropyl)-2,2-dimethylpropyl]-lambda4-sulfane
    —— (E)-3-amino-2-[2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]acetyl]but-2-enenitrile —— C8H9N5OS2
    (E)-3-amino-2-[2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]acetyl]but-2-enenitrile
    —— Ethane;4-(2-methylsulfanylpyrimidin-4-yl)-1,3-thiazol-2-amine —— C10H14N4S2
    Ethane;4-(2-methylsulfanylpyrimidin-4-yl)-1,3-thiazol-2-amine