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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]-2-(2-methylpyridin-4-yl)-5H-oxadiazole —— C16H16N6O2S
    5-[[5-(furan-2-yl)-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl]-2-(2-methylpyridin-4-yl)-5H-oxadiazole
    —— (1S)-N,N-diethyl-1-isothiocyanatopropan-1-amine —— C8H16N2S
    (1S)-N,N-diethyl-1-isothiocyanatopropan-1-amine
    —— (6Z)-5-imino-2-(4-methylphenyl)-6-({5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene)-5,6-dihydro-7H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one —— C24H18N4O2S2
    (6Z)-5-imino-2-(4-methylphenyl)-6-({5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene)-5,6-dihydro-7H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one
    —— [(Z)-[5-(4-chlorophenyl)sulfanyl-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]methylideneamino] 2-methylpropanoate —— C16H15ClF3N3O2S
    [(Z)-[5-(4-chlorophenyl)sulfanyl-1-methyl-3-(trifluoromethyl)pyrazol-4-yl]methylideneamino] 2-methylpropanoate
    —— (5Z)-5-[(4-methylphenyl)methylidene]-3-(3-methylsulfanylphenyl)-1,3-thiazolidine-2,4-dione —— C18H15NO2S2
    (5Z)-5-[(4-methylphenyl)methylidene]-3-(3-methylsulfanylphenyl)-1,3-thiazolidine-2,4-dione
    —— But-1-ene;5-(3-chlorophenyl)sulfanyl-1,2,4-trimethylpyrrole-3-carboxamide —— C18H23ClN2OS
    But-1-ene;5-(3-chlorophenyl)sulfanyl-1,2,4-trimethylpyrrole-3-carboxamide
    —— (6Z)-2-ethyl-5-imino-6-({5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene)-5,6-dihydro-7H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one —— C19H16N4O2S2
    (6Z)-2-ethyl-5-imino-6-({5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene)-5,6-dihydro-7H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7-one
    —— 6-methoxy-2-(4-methoxyphenyl)-3-[(4-methylphenyl)sulfanyl]-1H-1-benzothiophen-1-one —— C23H20O3S2
    6-methoxy-2-(4-methoxyphenyl)-3-[(4-methylphenyl)sulfanyl]-1H-1-benzothiophen-1-one
    —— (5Z)-5-[[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-1-(3-ethoxyphenyl)-2-sulfanylidene-1,3-diazinane-4,6-dione —— C23H16BrClN2O4S2
    (5Z)-5-[[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-1-(3-ethoxyphenyl)-2-sulfanylidene-1,3-diazinane-4,6-dione
    —— Ethyl 4-[4-[4-[ethylamino(formyl)amino]phenyl]sulfanylphenyl]sulfonyl-3-phenylbutanoate —— C27H30N2O5S2
    Ethyl 4-[4-[4-[ethylamino(formyl)amino]phenyl]sulfanylphenyl]sulfonyl-3-phenylbutanoate
    —— 2-({4-[2-(2-Thienyl)vinyl]-2-pyrimidinyl}sulfanyl)acetonitrile —— C12H9N3S2
    2-({4-[2-(2-Thienyl)vinyl]-2-pyrimidinyl}sulfanyl)acetonitrile
    —— 5-ethyl-N-(2-fluoro-4-methylsulfanylphenyl)-3-methoxy-4-[[2-methyl-3-(3-propan-2-yl-1,2,4-oxadiazol-5-yl)-6-bicyclo[3.2.2]nonanyl]oxy]pyridin-2-amine —— C30H39FN4O3S
    5-ethyl-N-(2-fluoro-4-methylsulfanylphenyl)-3-methoxy-4-[[2-methyl-3-(3-propan-2-yl-1,2,4-oxadiazol-5-yl)-6-bicyclo[3.2.2]nonanyl]oxy]pyridin-2-amine
    —— N-[(Z)-[5-(4-methylphenyl)sulfanylfuran-2-yl]methylideneamino]-4-nitroaniline —— C18H15N3O3S
    N-[(Z)-[5-(4-methylphenyl)sulfanylfuran-2-yl]methylideneamino]-4-nitroaniline
    —— [3-[6-(3-Chloropropoxy)-7-methoxyquinazolin-4-yl]sulfanylphenyl]urea —— C19H19ClN4O3S
    [3-[6-(3-Chloropropoxy)-7-methoxyquinazolin-4-yl]sulfanylphenyl]urea
    —— (2E)-3-{5-[(4-chlorophenyl)sulfanyl]furan-2-yl}-2-cyano-N-(3-methoxyphenyl)prop-2-enamide —— C21H15ClN2O3S
    (2E)-3-{5-[(4-chlorophenyl)sulfanyl]furan-2-yl}-2-cyano-N-(3-methoxyphenyl)prop-2-enamide
    —— [4-[3-[Butyl(heptylcarbamoyl)amino]phenyl]sulfanylphenyl] butanoate —— C28H40N2O3S
    [4-[3-[Butyl(heptylcarbamoyl)amino]phenyl]sulfanylphenyl] butanoate
    —— (Z)-2-tert-butylsulfonyl-3-[(2Z)-2-(2,2-dimethylpropylidene)hydrazinyl]prop-2-enenitrile —— C12H21N3O2S
    (Z)-2-tert-butylsulfonyl-3-[(2Z)-2-(2,2-dimethylpropylidene)hydrazinyl]prop-2-enenitrile
    —— methyl (2E)-2-({5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene)hydrazinecarboxylate —— C14H14N2O3S
    methyl (2E)-2-({5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene)hydrazinecarboxylate
    —— N-[1-(3,5-dimethylphenyl)-3-(4-fluorophenylthio)-2-propenylidene]-4-methylaniline 1140915-20-3 C24H22FNS
    N-[1-(3,5-dimethylphenyl)-3-(4-fluorophenylthio)-2-propenylidene]-4-methylaniline
    —— 1-Cyclohexylsulfanylbutan-1-amine —— C10H21NS
    1-Cyclohexylsulfanylbutan-1-amine
    —— [Dimethyl(2-oxohexyl)-lambda4-sulfanyl]-(trifluoromethylsulfonyl)oxidanium —— C9H18F3O4S2+
    [Dimethyl(2-oxohexyl)-lambda4-sulfanyl]-(trifluoromethylsulfonyl)oxidanium
    —— 3-benzyl-5,5-dimethyl-4-[(Z)-[4-(methylsulfanyl)benzylidene](oxido)-lambda~5~-azanyl]-1,3-thiazolidine-2-thione —— C20H22N2OS3
    3-benzyl-5,5-dimethyl-4-[(Z)-[4-(methylsulfanyl)benzylidene](oxido)-lambda~5~-azanyl]-1,3-thiazolidine-2-thione
    —— 1-But-2-enylsulfanyl-11-isothiocyanatoundec-5-ene —— C16H27NS2
    1-But-2-enylsulfanyl-11-isothiocyanatoundec-5-ene
    —— N-[1-phenyl-3-(4-chlorophenylthio)-2-propenylidene]aniline 1140912-83-9 C21H16ClNS
    N-[1-phenyl-3-(4-chlorophenylthio)-2-propenylidene]aniline
    —— 3-Ethyl-2,4-dimethylhexane-1-thiol —— C10H22S
    3-Ethyl-2,4-dimethylhexane-1-thiol
    —— (3aR,7aS)-1-[(2R)-4-(amino-tert-butyl-oxo-lambda6-sulfanylidene)butan-2-yl]-7a-methyl-3a,5,6,7-tetrahydro-3H-inden-4-one —— C18H31NO2S
    (3aR,7aS)-1-[(2R)-4-(amino-tert-butyl-oxo-lambda6-sulfanylidene)butan-2-yl]-7a-methyl-3a,5,6,7-tetrahydro-3H-inden-4-one
    —— 3-(Methoxymethylsulfonyl)-3-methylhexane —— C9H20O3S
    3-(Methoxymethylsulfonyl)-3-methylhexane
    —— 4-Propan-2-ylsulfonylbutane-1-sulfinic acid —— C7H16O4S2
    4-Propan-2-ylsulfonylbutane-1-sulfinic acid
    —— 2-[[5-(3a,4-dihydro-1-benzothiophen-2-yl)-6-chloro-5,6-dihydro-1H-benzimidazol-2-yl]sulfanyl]ethane-1,1-diol —— C17H17ClN2O2S2
    2-[[5-(3a,4-dihydro-1-benzothiophen-2-yl)-6-chloro-5,6-dihydro-1H-benzimidazol-2-yl]sulfanyl]ethane-1,1-diol
    —— [5-[4-(1,4-Dioxan-2-yl)phenyl]sulfanyl-4-fluoro-2-nitrophenyl]methanol —— C17H16FNO5S
    [5-[4-(1,4-Dioxan-2-yl)phenyl]sulfanyl-4-fluoro-2-nitrophenyl]methanol
    —— N-[(Z)-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]-3-(dimethylamino)benzamide —— C20H17BrClN3O2S
    N-[(Z)-[4-bromo-5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]-3-(dimethylamino)benzamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2,4-difluorophenyl)methylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide —— C19H14F2N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2,4-difluorophenyl)methylideneamino]-5-(phenylsulfanylmethyl)triazole-4-carboxamide
    —— (Z)-N-[(4-methylphenyl)methoxy]-1-[6-(4-methylphenyl)sulfanylpyridin-3-yl]methanimine —— C21H20N2OS
    (Z)-N-[(4-methylphenyl)methoxy]-1-[6-(4-methylphenyl)sulfanylpyridin-3-yl]methanimine
    —— (Z)-N-[(2,4-dichlorophenyl)methoxy]-1-[6-(4-methylphenyl)sulfanylpyridin-3-yl]methanimine —— C20H16Cl2N2OS
    (Z)-N-[(2,4-dichlorophenyl)methoxy]-1-[6-(4-methylphenyl)sulfanylpyridin-3-yl]methanimine
    —— 4-Methyl-2-(2-phenylethylsulfanyl)pyrimidine —— C13H14N2S
    4-Methyl-2-(2-phenylethylsulfanyl)pyrimidine
    —— N-[(Z)-[4-bromo-5-(4-methylphenyl)sulfanylfuran-2-yl]methylideneamino]aniline —— C18H15BrN2OS
    N-[(Z)-[4-bromo-5-(4-methylphenyl)sulfanylfuran-2-yl]methylideneamino]aniline
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(N-methylanilino)methyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]triazole-4-carboxamide —— C21H21N9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(N-methylanilino)methyl]-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]triazole-4-carboxamide
    —— 2-[(3Z,5E,7S)-7-methyldodeca-3,5-dienyl]sulfanylacetaldehyde;(4Z,6E,8S)-8-methyltrideca-4,6-diene —— C29H52OS
    2-[(3Z,5E,7S)-7-methyldodeca-3,5-dienyl]sulfanylacetaldehyde;(4Z,6E,8S)-8-methyltrideca-4,6-diene
    —— 2-Hydroxycyclohexadecane-1-thione —— C16H30OS
    2-Hydroxycyclohexadecane-1-thione
    —— 2-Chloro-4-[[3-(4-methoxyphenyl)sulfanylimidazo[1,2-a]pyrimidin-6-yl]methyl]benzamide —— C21H17ClN4O2S
    2-Chloro-4-[[3-(4-methoxyphenyl)sulfanylimidazo[1,2-a]pyrimidin-6-yl]methyl]benzamide
    —— S-(methylcarbamoyl) ethanethioate —— C4H7NO2S
    S-(methylcarbamoyl) ethanethioate
    —— 5-hydroxy-3,6-dihydro-2H-[1,3]thiazolo[3,2-c]pyrimidin-4-ium-7-one —— C6H7N2O2S+
    5-hydroxy-3,6-dihydro-2H-[1,3]thiazolo[3,2-c]pyrimidin-4-ium-7-one
    —— 2-[4-(Methoxyamino)cyclohex-3-en-1-yl]-3-methyl-2-(3,3,3-trifluoropropylsulfonyl)pent-4-ynenitrile —— C16H21F3N2O3S
    2-[4-(Methoxyamino)cyclohex-3-en-1-yl]-3-methyl-2-(3,3,3-trifluoropropylsulfonyl)pent-4-ynenitrile
    —— N-[2-[[(E)-(3-oxo-1-benzothiophen-2-ylidene)methyl]amino]ethyl]acetamide —— C13H14N2O2S
    N-[2-[[(E)-(3-oxo-1-benzothiophen-2-ylidene)methyl]amino]ethyl]acetamide
    —— (4-Aminophenyl) 2-cyano-2-[3-[hydroxy(pyridin-4-yl)methyl]phenyl]ethanimidothioate —— C21H18N4OS
    (4-Aminophenyl) 2-cyano-2-[3-[hydroxy(pyridin-4-yl)methyl]phenyl]ethanimidothioate
    —— 1-But-3-en-2-ylsulfonyl-2-hydroxyethanone —— C6H10O4S
    1-But-3-en-2-ylsulfonyl-2-hydroxyethanone
    —— 9-Ethyl-8-methylidene-1,4-dithiaspiro[4.5]decan-7-ol —— C11H18OS2
    9-Ethyl-8-methylidene-1,4-dithiaspiro[4.5]decan-7-ol
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-{(E)-[4-(dimethylamino)phenyl]methylidene}-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide —— C21H21N9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N'-{(E)-[4-(dimethylamino)phenyl]methylidene}-5-[(phenylsulfanyl)methyl]-1H-1,2,3-triazole-4-carbohydrazide
    —— 1-Butyl-3-(2-phenylethylsulfanyl)benzene —— C18H22S
    1-Butyl-3-(2-phenylethylsulfanyl)benzene
    —— 1-(Fluoromethyl)-4-[4-(fluoromethyl)phenyl]sulfanylbenzene —— C14H12F2S
    1-(Fluoromethyl)-4-[4-(fluoromethyl)phenyl]sulfanylbenzene