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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-(2-(diethylamino)ethyl)-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C15H24N4O2S
    N-(2-(diethylamino)ethyl)-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— 8-(tert-butyl)-N,N-dicyclohexyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C24H37N3O2S
    8-(tert-butyl)-N,N-dicyclohexyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— 7-Methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C9H11N3O2S
    7-Methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— 8-(tert-butyl)-N-isobutyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C16H25N3O2S
    8-(tert-butyl)-N-isobutyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— 8-(tert-butyl)-6-oxo-N-(3,3,5-trimethylcyclohexyl)-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C21H33N3O2S
    8-(tert-butyl)-6-oxo-N-(3,3,5-trimethylcyclohexyl)-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— N,7-dimethyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C10H13N3O2S
    N,7-dimethyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— N-(4-chlorophenethyl)-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C17H18ClN3O2S
    N-(4-chlorophenethyl)-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— N-(2-hydroxyethyl)-N-isopropyl-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C14H21N3O3S
    N-(2-hydroxyethyl)-N-isopropyl-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— N-benzyl-7-methyl-6-oxo-N-(pyridin-2-yl)-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C21H20N4O2S
    N-benzyl-7-methyl-6-oxo-N-(pyridin-2-yl)-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— N-benzyl-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C16H17N3O2S
    N-benzyl-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— N-(2-hydroxypropyl)-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C12H17N3O3S
    N-(2-hydroxypropyl)-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— N-cyclododecyl-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C21H33N3O2S
    N-cyclododecyl-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— N-benzyl-8-(tert-butyl)-N-(2-hydroxyethyl)-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C21H27N3O3S
    N-benzyl-8-(tert-butyl)-N-(2-hydroxyethyl)-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— N-(3-methoxypropyl)-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C13H19N3O3S
    N-(3-methoxypropyl)-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— 8-(tert-butyl)-N,N-diisobutyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C20H33N3O2S
    8-(tert-butyl)-N,N-diisobutyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— 7-methyl-6-oxo-N-((tetrahydrofuran-2-yl)methyl)-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C14H19N3O3S
    7-methyl-6-oxo-N-((tetrahydrofuran-2-yl)methyl)-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— 3-(3-hydroxyazetidine-1-carbonyl)-7-methyl-3,4-dihydropyrimido[2,1-b][1,3]thiazin-6(2H)-one —— C12H15N3O3S
    3-(3-hydroxyazetidine-1-carbonyl)-7-methyl-3,4-dihydropyrimido[2,1-b][1,3]thiazin-6(2H)-one
    —— N-benzyl-N-(2-hydroxyethyl)-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C18H21N3O3S
    N-benzyl-N-(2-hydroxyethyl)-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— 8-(tert-butyl)-3-(4-ethylpiperazine-1-carbonyl)-3,4-dihydropyrimido[2,1-b][1,3]thiazin-6(2H)-one —— C18H28N4O2S
    8-(tert-butyl)-3-(4-ethylpiperazine-1-carbonyl)-3,4-dihydropyrimido[2,1-b][1,3]thiazin-6(2H)-one
    —— 8-(tert-butyl)-N-cyclohexyl-N-ethyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C20H31N3O2S
    8-(tert-butyl)-N-cyclohexyl-N-ethyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— N-(2,2-diethoxyethyl)-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C15H23N3O4S
    N-(2,2-diethoxyethyl)-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— N-benzyl-N-butyl-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C20H25N3O2S
    N-benzyl-N-butyl-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— N-(2,4-difluorobenzyl)-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C16H15F2N3O2S
    N-(2,4-difluorobenzyl)-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— N-cyclohexyl-N,7-dimethyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C16H23N3O2S
    N-cyclohexyl-N,7-dimethyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— N-methoxy-N,7-dimethyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C11H15N3O3S
    N-methoxy-N,7-dimethyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— N,N-dicyclohexyl-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C21H31N3O2S
    N,N-dicyclohexyl-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— 3-(2,6-dimethylmorpholine-4-carbonyl)-7-methyl-3,4-dihydropyrimido[2,1-b][1,3]thiazin-6(2H)-one —— C15H21N3O3S
    3-(2,6-dimethylmorpholine-4-carbonyl)-7-methyl-3,4-dihydropyrimido[2,1-b][1,3]thiazin-6(2H)-one
    —— 7-methyl-6-oxo-N-(pyridin-3-ylmethyl)-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C15H16N4O2S
    7-methyl-6-oxo-N-(pyridin-3-ylmethyl)-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— N,N-bis(2-hydroxyethyl)-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide —— C13H19N3O4S
    N,N-bis(2-hydroxyethyl)-7-methyl-6-oxo-2,3,4,6-tetrahydropyrimido[2,1-b][1,3]thiazine-3-carboxamide
    —— 2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(Z)-(4-bromophenyl)methylideneamino]acetamide —— C17H16Br2N2OS
    2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(Z)-(4-bromophenyl)methylideneamino]acetamide
    —— 3-(2-(3-(morpholinomethyl)-1,4-thiazepan-4-yl)-2-oxoethyl)-2,3,7,8-tetrahydrocyclopenta[d]thiazolo[3,2-a]pyrimidin-5(6H)-one —— C21H30N4O3S2
    3-(2-(3-(morpholinomethyl)-1,4-thiazepan-4-yl)-2-oxoethyl)-2,3,7,8-tetrahydrocyclopenta[d]thiazolo[3,2-a]pyrimidin-5(6H)-one
    —— 3-(Phenylthio)-1-(3-(piperidin-1-ylmethyl)-1,4-thiazepan-4-yl)propan-1-one —— C20H30N2OS2
    3-(Phenylthio)-1-(3-(piperidin-1-ylmethyl)-1,4-thiazepan-4-yl)propan-1-one
    —— 2-((4-Fluorophenyl)thio)-1-(3-(pyrrolidin-1-ylmethyl)-1,4-thiazepan-4-yl)ethanone —— C18H25FN2OS2
    2-((4-Fluorophenyl)thio)-1-(3-(pyrrolidin-1-ylmethyl)-1,4-thiazepan-4-yl)ethanone
    —— 2-((1-methyl-1H-tetrazol-5-yl)thio)-1-(3-(morpholinomethyl)-1,4-thiazepan-4-yl)ethanone —— C14H24N6O2S2
    2-((1-methyl-1H-tetrazol-5-yl)thio)-1-(3-(morpholinomethyl)-1,4-thiazepan-4-yl)ethanone
    —— 2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(Z)-(3,4-difluorophenyl)methylideneamino]acetamide —— C17H15BrF2N2OS
    2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(Z)-(3,4-difluorophenyl)methylideneamino]acetamide
    —— 2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(Z)-(3-bromophenyl)methylideneamino]acetamide —— C17H16Br2N2OS
    2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(Z)-(3-bromophenyl)methylideneamino]acetamide
    —— 1-(2-Benzyl-4-cyclopropylpiperazin-1-yl)-2-((4-fluorophenyl)thio)ethanone —— C22H25FN2OS
    1-(2-Benzyl-4-cyclopropylpiperazin-1-yl)-2-((4-fluorophenyl)thio)ethanone
    —— N-(1,4-diazabicyclo[2.2.2]octan-2-ylmethyl)-3-(phenylthio)propanamide —— C16H23N3OS
    N-(1,4-diazabicyclo[2.2.2]octan-2-ylmethyl)-3-(phenylthio)propanamide
    —— 1-(2-benzyl-4-cyclopropylpiperazin-1-yl)-2-((1-methyl-1H-tetrazol-5-yl)thio)ethanone —— C18H24N6OS
    1-(2-benzyl-4-cyclopropylpiperazin-1-yl)-2-((1-methyl-1H-tetrazol-5-yl)thio)ethanone
    —— 3-(2-(2-benzyl-4-cyclopropylpiperazin-1-yl)-2-oxoethyl)-2,3,7,8-tetrahydrocyclopenta[d]thiazolo[3,2-a]pyrimidin-5(6H)-one —— C25H30N4O2S
    3-(2-(2-benzyl-4-cyclopropylpiperazin-1-yl)-2-oxoethyl)-2,3,7,8-tetrahydrocyclopenta[d]thiazolo[3,2-a]pyrimidin-5(6H)-one
    —— N-(1,4-diazabicyclo[2.2.2]octan-2-ylmethyl)-2-((1-methyl-1H-tetrazol-5-yl)thio)acetamide —— C11H19N7OS
    N-(1,4-diazabicyclo[2.2.2]octan-2-ylmethyl)-2-((1-methyl-1H-tetrazol-5-yl)thio)acetamide
    —— 2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(Z)-(5-methylfuran-2-yl)methylideneamino]acetamide —— C16H17BrN2O2S
    2-(4-bromo-2,5-dimethylphenyl)sulfanyl-N-[(Z)-(5-methylfuran-2-yl)methylideneamino]acetamide
    —— (Z)-N-(4-methylpiperazin-4-ium-1-yl)-1-(4-methylsulfanylphenyl)methanimine —— C13H20N3S+
    (Z)-N-(4-methylpiperazin-4-ium-1-yl)-1-(4-methylsulfanylphenyl)methanimine
    —— (Z)-N-(4-methylpiperazin-1-yl)-1-(4-methylsulfanylphenyl)methanimine —— C13H19N3S
    (Z)-N-(4-methylpiperazin-1-yl)-1-(4-methylsulfanylphenyl)methanimine
    —— 1-(2-(3-Methyl-1,2,4-oxadiazol-5-yl)pyrrolidin-1-yl)-3-(phenylthio)propan-1-one —— C16H19N3O2S
    1-(2-(3-Methyl-1,2,4-oxadiazol-5-yl)pyrrolidin-1-yl)-3-(phenylthio)propan-1-one
    —— (Z)-4-(3-bromophenyl)-N-ethyl-3-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1,3-thiazol-2-imine —— C19H18BrN3S2
    (Z)-4-(3-bromophenyl)-N-ethyl-3-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1,3-thiazol-2-imine
    —— 2-(4-Fluorophenyl)sulfanyl-1-[4-[2-(2-propan-2-ylimidazol-1-yl)ethyl]piperazin-1-yl]ethanone —— C20H27FN4OS
    2-(4-Fluorophenyl)sulfanyl-1-[4-[2-(2-propan-2-ylimidazol-1-yl)ethyl]piperazin-1-yl]ethanone
    —— 3-Phenylsulfanyl-1-[4-[2-(2-propan-2-ylimidazol-1-yl)ethyl]piperazin-1-yl]propan-1-one —— C21H30N4OS
    3-Phenylsulfanyl-1-[4-[2-(2-propan-2-ylimidazol-1-yl)ethyl]piperazin-1-yl]propan-1-one
    —— 3-[(Z)-(3-nitrophenyl)methylideneamino]-6-(2-nitrophenyl)sulfanyl-5-phenylthieno[2,3-d]pyrimidin-4-one —— C25H15N5O5S2
    3-[(Z)-(3-nitrophenyl)methylideneamino]-6-(2-nitrophenyl)sulfanyl-5-phenylthieno[2,3-d]pyrimidin-4-one
    —— 6-(2-nitrophenyl)sulfanyl-5-phenyl-3-[(Z)-(3,4,5-trimethoxyphenyl)methylideneamino]thieno[2,3-d]pyrimidin-4-one —— C28H22N4O6S2
    6-(2-nitrophenyl)sulfanyl-5-phenyl-3-[(Z)-(3,4,5-trimethoxyphenyl)methylideneamino]thieno[2,3-d]pyrimidin-4-one