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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 6-[2-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]-3-[(4-methylphenyl)methylsulfanyl]-2H-1,2,4-triazin-5-one —— C28H24N6O2S
    6-[2-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]-3-[(4-methylphenyl)methylsulfanyl]-2H-1,2,4-triazin-5-one
    —— 3-butylsulfanyl-6-[2-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]-2H-1,2,4-triazin-5-one —— C24H24N6O2S
    3-butylsulfanyl-6-[2-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]-2H-1,2,4-triazin-5-one
    —— S-methyl N-[[2-(methylsulfanylcarbonylhydrazinylidene)cyclohexylidene]amino]carbamothioate —— C10H16N4O2S2
    S-methyl N-[[2-(methylsulfanylcarbonylhydrazinylidene)cyclohexylidene]amino]carbamothioate
    —— 6-[5-bromo-2-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]-3-ethylsulfanyl-2H-1,2,4-triazin-5-one —— C22H19BrN6O2S
    6-[5-bromo-2-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]-3-ethylsulfanyl-2H-1,2,4-triazin-5-one
    —— 2-(3,4-dimethylphenyl)sulfanyl-N-[[(2S)-1,4-dioxan-2-yl]methyl]pyridine-3-carboxamide —— C19H22N2O3S
    2-(3,4-dimethylphenyl)sulfanyl-N-[[(2S)-1,4-dioxan-2-yl]methyl]pyridine-3-carboxamide
    —— 2-(3,4-dimethylphenyl)sulfanyl-N-[[(2R)-1,4-dioxan-2-yl]methyl]pyridine-3-carboxamide —— C19H22N2O3S
    2-(3,4-dimethylphenyl)sulfanyl-N-[[(2R)-1,4-dioxan-2-yl]methyl]pyridine-3-carboxamide
    —— 2-methyl-N-[[(1S,2S)-2-methyl-2-(4-methylsulfanylphenyl)cyclopropyl]methyl]propan-2-amine —— C16H25NS
    2-methyl-N-[[(1S,2S)-2-methyl-2-(4-methylsulfanylphenyl)cyclopropyl]methyl]propan-2-amine
    —— 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-methyl-N-[(1S)-1-(5-methylthiophen-2-yl)ethyl]propanamide —— C18H25N3OS2
    3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-methyl-N-[(1S)-1-(5-methylthiophen-2-yl)ethyl]propanamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-2-(1-ethylimidazol-2-yl)sulfanyl-N-(2-methylpropyl)acetamide —— C15H25N3O3S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-2-(1-ethylimidazol-2-yl)sulfanyl-N-(2-methylpropyl)acetamide
    —— 4-(4-chlorophenyl)sulfanyl-1-[(2R)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-yl)pyrrolidin-1-yl]butan-1-one —— C21H27ClN4OS
    4-(4-chlorophenyl)sulfanyl-1-[(2R)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-yl)pyrrolidin-1-yl]butan-1-one
    —— 2-[[5-[(3R,5R)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N,N-diethylacetamide —— C20H31N5O2S
    2-[[5-[(3R,5R)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N,N-diethylacetamide
    —— 2-[[5-[(3R,5S)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N,N-diethylacetamide —— C20H31N5O2S
    2-[[5-[(3R,5S)-3,5-dimethylpiperidin-1-yl]-4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N,N-diethylacetamide
    —— 2-(4-fluorophenyl)sulfanyl-1-[(2S)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-yl)pyrrolidin-1-yl]ethanone —— C19H23FN4OS
    2-(4-fluorophenyl)sulfanyl-1-[(2S)-2-(6,7,8,9-tetrahydro-5H-[1,2,4]triazolo[4,3-a]azepin-3-yl)pyrrolidin-1-yl]ethanone
    —— 3-[(3-methylphenyl)methylsulfanyl]-4-[[(2R)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazole —— C19H26N4OS
    3-[(3-methylphenyl)methylsulfanyl]-4-[[(2R)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazole
    —— 1-(5-methylthiophen-2-yl)-2-[[4-[[(2R)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]ethanone —— C18H24N4O2S2
    1-(5-methylthiophen-2-yl)-2-[[4-[[(2R)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]ethanone
    —— N,N-diethyl-2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H29N5O2S
    N,N-diethyl-2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 1-morpholin-4-yl-2-[[4-[[(2R)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]ethanone —— C17H27N5O3S
    1-morpholin-4-yl-2-[[4-[[(2R)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]ethanone
    —— 2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]-N,N-di(propan-2-yl)acetamide —— C19H33N5O2S
    2-[[4-[[(2S)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazol-3-yl]sulfanyl]-N,N-di(propan-2-yl)acetamide
    —— N-[(3-oxo-1-benzothiophen-2-ylidene)amino]benzenecarbothioamide —— C15H10N2OS2
    N-[(3-oxo-1-benzothiophen-2-ylidene)amino]benzenecarbothioamide
    —— 3-[(4-methylphenyl)methylsulfanyl]-4-[[(2R)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazole —— C19H26N4OS
    3-[(4-methylphenyl)methylsulfanyl]-4-[[(2R)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazole
    —— 4-Amino-3-[(2,5-dichlorophenyl)diazenyl]-5-oxo-6-[[4-[4-[2-(4-oxocyclohexa-2,5-dien-1-ylidene)hydrazinyl]phenyl]sulfanylphenyl]hydrazinylidene]naphthalene-2,7-disulfonic acid —— C34H23Cl2N7O8S3
    4-Amino-3-[(2,5-dichlorophenyl)diazenyl]-5-oxo-6-[[4-[4-[2-(4-oxocyclohexa-2,5-dien-1-ylidene)hydrazinyl]phenyl]sulfanylphenyl]hydrazinylidene]naphthalene-2,7-disulfonic acid
    —— 6-[[4-(4-nitrophenyl)sulfanylanilino]methylidene]cyclohexa-2,4-dien-1-one —— C19H14N2O3S
    6-[[4-(4-nitrophenyl)sulfanylanilino]methylidene]cyclohexa-2,4-dien-1-one
    —— (2R)-1-cyclopentyl-3-methylsulfanylpropan-2-amine —— C9H19NS
    (2R)-1-cyclopentyl-3-methylsulfanylpropan-2-amine
    —— 3-Amino-2-[2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetyl]but-2-enenitrile —— C21H17N5OS
    3-Amino-2-[2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetyl]but-2-enenitrile
    —— (2R)-1-cyclohexyl-3-methylsulfanylpropan-2-amine —— C10H21NS
    (2R)-1-cyclohexyl-3-methylsulfanylpropan-2-amine
    —— (2S)-3-methyl-1-methylsulfanylbutan-2-amine —— C6H15NS
    (2S)-3-methyl-1-methylsulfanylbutan-2-amine
    —— (2R)-1-methylsulfanylhex-4-yn-2-amine —— C7H13NS
    (2R)-1-methylsulfanylhex-4-yn-2-amine
    —— (2R)-1-methylsulfanylpent-4-en-2-amine —— C6H13NS
    (2R)-1-methylsulfanylpent-4-en-2-amine
    —— (1R)-1-cyclohexyl-2-methylsulfanylethanamine —— C9H19NS
    (1R)-1-cyclohexyl-2-methylsulfanylethanamine
    —— (2S)-1-cyclopentyl-3-methylsulfanylpropan-2-amine —— C9H19NS
    (2S)-1-cyclopentyl-3-methylsulfanylpropan-2-amine
    —— (1S)-1-cyclohexyl-2-methylsulfanylethanamine —— C9H19NS
    (1S)-1-cyclohexyl-2-methylsulfanylethanamine
    —— (2S)-4-methyl-1-methylsulfanylpentan-2-amine —— C7H17NS
    (2S)-4-methyl-1-methylsulfanylpentan-2-amine
    —— (2S)-1-methylsulfanylhex-4-yn-2-amine —— C7H13NS
    (2S)-1-methylsulfanylhex-4-yn-2-amine
    —— (2S)-1-methylsulfanylbutan-2-amine —— C5H13NS
    (2S)-1-methylsulfanylbutan-2-amine
    —— (2S)-1-methylsulfanylpentan-2-amine —— C6H15NS
    (2S)-1-methylsulfanylpentan-2-amine
    —— 2-(2-bromophenyl)-5-[[4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3,4-oxadiazole —— C16H12BrN5O2S
    2-(2-bromophenyl)-5-[[4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanylmethyl]-1,3,4-oxadiazole
    —— N-cyclohexyl-2-[[4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-propan-2-ylacetamide —— C18H26N4O2S
    N-cyclohexyl-2-[[4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-N-propan-2-ylacetamide
    —— (2R)-N-(furan-2-ylmethyl)-2-[[4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C15H16N4O3S
    (2R)-N-(furan-2-ylmethyl)-2-[[4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— [3-(2,4-difluorophenyl)sulfanyl-1H-pyrazin-2-ylidene]-nitrosomethanamine —— C11H8F2N4OS
    [3-(2,4-difluorophenyl)sulfanyl-1H-pyrazin-2-ylidene]-nitrosomethanamine
    —— [3-(2-chlorophenyl)sulfanyl-1H-pyrazin-2-ylidene]-nitrosomethanamine —— C11H9ClN4OS
    [3-(2-chlorophenyl)sulfanyl-1H-pyrazin-2-ylidene]-nitrosomethanamine
    —— 2-[[2-[amino(nitroso)methylidene]-1H-pyrazin-3-yl]sulfanyl]-6-methyl-1H-pyrimidin-4-one —— C10H10N6O2S
    2-[[2-[amino(nitroso)methylidene]-1H-pyrazin-3-yl]sulfanyl]-6-methyl-1H-pyrimidin-4-one
    —— (2S)-2-(3-cyanopyrazin-2-yl)sulfanylpropanoic acid —— C8H7N3O2S
    (2S)-2-(3-cyanopyrazin-2-yl)sulfanylpropanoic acid
    —— N-[2-[1-(3-oxo-1-benzothiophen-2-ylidene)ethylamino]ethyl]acetamide —— C14H16N2O2S
    N-[2-[1-(3-oxo-1-benzothiophen-2-ylidene)ethylamino]ethyl]acetamide
    —— 6-[[[2,6-bis(phenylsulfanyl)pyridin-3-yl]amino]methylidene]-4-bromo-2-methoxycyclohexa-2,4-dien-1-one —— C25H19BrN2O2S2
    6-[[[2,6-bis(phenylsulfanyl)pyridin-3-yl]amino]methylidene]-4-bromo-2-methoxycyclohexa-2,4-dien-1-one
    —— (2S)-2-[[4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-1-morpholin-4-ylpropan-1-one —— C14H18N4O3S
    (2S)-2-[[4-(furan-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-1-morpholin-4-ylpropan-1-one
    —— 2-[1-(4-chloroanilino)ethylidene]-1-benzothiophen-3-one —— C16H12ClNOS
    2-[1-(4-chloroanilino)ethylidene]-1-benzothiophen-3-one
    —— 4-fluoro-N-[2-(6-methyl-3-prop-2-enylsulfanyl-1,2,4-triazin-5-yl)ethenyl]aniline —— C15H15FN4S
    4-fluoro-N-[2-(6-methyl-3-prop-2-enylsulfanyl-1,2,4-triazin-5-yl)ethenyl]aniline
    —— (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-[(3S)-oxolan-3-yl]methanimine —— C14H15ClN4OS
    (Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-[(3S)-oxolan-3-yl]methanimine
    —— N-[[(2R)-1-methylpiperidin-2-yl]methyl]-2-phenylsulfanylethanamine —— C15H24N2S
    N-[[(2R)-1-methylpiperidin-2-yl]methyl]-2-phenylsulfanylethanamine
    —— N'-[(3-oxo-1-benzothiophen-2-ylidene)methyl]-2-(1-phenylethylideneamino)oxyacetohydrazide —— C19H17N3O3S
    N'-[(3-oxo-1-benzothiophen-2-ylidene)methyl]-2-(1-phenylethylideneamino)oxyacetohydrazide