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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-benzyl-2-[[5,6-bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]propanamide —— C21H18N4O3S
    N-benzyl-2-[[5,6-bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]propanamide
    —— 5-(4-chloro-phenylsulfanyl)-3-(3-trifluoromethyl-phenyl)-[1,2,4]triazine-6-carboxylic acid ethyl ester —— C19H13ClF3N3O2S
    5-(4-chloro-phenylsulfanyl)-3-(3-trifluoromethyl-phenyl)-[1,2,4]triazine-6-carboxylic acid ethyl ester
    —— 3-((4-Chlorobenzyl)sulfanyl)-5-(2-(((4-fluorobenzyl)oxy)amino)vinyl)-6-methyl-1,2,4-triazine —— C20H18ClFN4OS
    3-((4-Chlorobenzyl)sulfanyl)-5-(2-(((4-fluorobenzyl)oxy)amino)vinyl)-6-methyl-1,2,4-triazine
    —— Ethyl 5-[(2,4-dichlorophenyl)sulfanyl]-3-[3-(trifluoromethyl)phenyl]-1,2,4-triazine-6-carboxylate —— C19H12Cl2F3N3O2S
    Ethyl 5-[(2,4-dichlorophenyl)sulfanyl]-3-[3-(trifluoromethyl)phenyl]-1,2,4-triazine-6-carboxylate
    —— Methyl 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]acetate —— C20H19N3O2S
    Methyl 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]acetate
    —— 5-[(4-Bromophenyl)sulfanyl]-6-methyl-3-[3-(trifluoromethyl)phenyl]-1,2,4-triazine —— C17H11BrF3N3S
    5-[(4-Bromophenyl)sulfanyl]-6-methyl-3-[3-(trifluoromethyl)phenyl]-1,2,4-triazine
    —— 4-Methylphenyl 3-phenyl-6-(trifluoromethyl)-1,2,4-triazin-5-yl sulfide —— C17H12F3N3S
    4-Methylphenyl 3-phenyl-6-(trifluoromethyl)-1,2,4-triazin-5-yl sulfide
    —— 2-(2,4-Dichlorophenyl)-2-[6-(phenylsulfanyl)-3-pyridazinyl]acetamide 209410-93-5 C18H13Cl2N3OS
    2-(2,4-Dichlorophenyl)-2-[6-(phenylsulfanyl)-3-pyridazinyl]acetamide
    —— 1-Benzyl-4-[(4-methylphenyl)sulfanyl]phthalazine —— C22H18N2S
    1-Benzyl-4-[(4-methylphenyl)sulfanyl]phthalazine
    —— Ethyl 5-[(2-chlorophenyl)sulfanyl]-3-(4-methylphenyl)-1,2,4-triazine-6-carboxylate —— C19H16ClN3O2S
    Ethyl 5-[(2-chlorophenyl)sulfanyl]-3-(4-methylphenyl)-1,2,4-triazine-6-carboxylate
    —— 3-(Benzylsulfanyl)-5-(2-(methoxyamino)vinyl)-6-methyl-1,2,4-triazine —— C14H16N4OS
    3-(Benzylsulfanyl)-5-(2-(methoxyamino)vinyl)-6-methyl-1,2,4-triazine
    —— 2-[6-(4-Chlorophenyl)sulfanylpyridazin-3-yl]-2-(2,4-dichlorophenyl)acetonitrile —— C18H10Cl3N3S
    2-[6-(4-Chlorophenyl)sulfanylpyridazin-3-yl]-2-(2,4-dichlorophenyl)acetonitrile
    —— 3,6-Diphenyl-1,2,4-triazin-5-yl 4-fluorophenyl sulfide —— C21H14FN3S
    3,6-Diphenyl-1,2,4-triazin-5-yl 4-fluorophenyl sulfide
    —— N-(1,1-dioxothiolan-3-yl)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-methylacetamide —— C22H22N4O3S2
    N-(1,1-dioxothiolan-3-yl)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-methylacetamide
    —— Ethyl 3-(4-methylphenyl)-5-{[3-(trifluoromethyl)phenyl]sulfanyl}-1,2,4-triazine-6-carboxylate —— C20H16F3N3O2S
    Ethyl 3-(4-methylphenyl)-5-{[3-(trifluoromethyl)phenyl]sulfanyl}-1,2,4-triazine-6-carboxylate
    —— 3,6-Diphenyl-1,2,4-triazin-5-yl 4-methylphenyl sulfide —— C22H17N3S
    3,6-Diphenyl-1,2,4-triazin-5-yl 4-methylphenyl sulfide
    —— 3-(Benzylsulfanyl)-5-(2-(((4-chlorobenzyl)oxy)amino)vinyl)-6-methyl-1,2,4-triazine —— C20H19ClN4OS
    3-(Benzylsulfanyl)-5-(2-(((4-chlorobenzyl)oxy)amino)vinyl)-6-methyl-1,2,4-triazine
    —— Copper;[methylamino(sulfoniumylidene)methyl]-[[2-[methylamino(sulfoniumylidene)methyl]azanidylimino-1-(4-methylsulfanylphenyl)ethylidene]amino]azanide —— C13H18CuN6S3
    Copper;[methylamino(sulfoniumylidene)methyl]-[[2-[methylamino(sulfoniumylidene)methyl]azanidylimino-1-(4-methylsulfanylphenyl)ethylidene]amino]azanide
    —— 4-Chloro-N-(2-(6-methyl-3-(propylsulfanyl)-1,2,4-triazin-5-yl)vinyl)aniline —— C15H17ClN4S
    4-Chloro-N-(2-(6-methyl-3-(propylsulfanyl)-1,2,4-triazin-5-yl)vinyl)aniline
    —— N-[(3-chlorophenyl)methyl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide —— C24H19ClN4OS
    N-[(3-chlorophenyl)methyl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide
    —— ethyl N-[2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetyl]carbamate —— C20H18N4O3S
    ethyl N-[2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetyl]carbamate
    —— 3-(2-Methylpropylsulfanyl)-5,6-diphenyl-1,2,4-triazine —— C19H19N3S
    3-(2-Methylpropylsulfanyl)-5,6-diphenyl-1,2,4-triazine
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-(2,3-dimethylcyclohexyl)acetamide —— C27H32N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-(2,3-dimethylcyclohexyl)acetamide
    —— 2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-(2,5-dimethyl-1-prop-2-enylpyrrol-3-yl)ethanone —— C28H28N4OS
    2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-(2,5-dimethyl-1-prop-2-enylpyrrol-3-yl)ethanone
    —— 3-[(4-Methylbenzyl)sulfanyl][1,2,4]triazino[5,6-d][3,1]benzoxazepine —— C18H14N4OS
    3-[(4-Methylbenzyl)sulfanyl][1,2,4]triazino[5,6-d][3,1]benzoxazepine
    —— 5-[(2,6-Dichlorophenyl)sulfanyl]-6-methyl-3-(4-methylphenyl)-1,2,4-triazine —— C17H13Cl2N3S
    5-[(2,6-Dichlorophenyl)sulfanyl]-6-methyl-3-(4-methylphenyl)-1,2,4-triazine
    —— Ethyl 5-[(3-chlorophenyl)sulfanyl]-3-[3-(trifluoromethyl)phenyl]-1,2,4-triazine-6-carboxylate —— C19H13ClF3N3O2S
    Ethyl 5-[(3-chlorophenyl)sulfanyl]-3-[3-(trifluoromethyl)phenyl]-1,2,4-triazine-6-carboxylate
    —— 2-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]-1-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]ethanone —— C28H24N4O2S
    2-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]-1-[1-(furan-2-ylmethyl)-2,5-dimethylpyrrol-3-yl]ethanone
    —— 4-[(4-Benzyl-1-phthalazinyl)sulfanyl]phenyl methyl ether —— C22H18N2OS
    4-[(4-Benzyl-1-phthalazinyl)sulfanyl]phenyl methyl ether
    —— 2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-[2,5-dimethyl-1-(oxolan-2-ylmethyl)pyrrol-3-yl]ethanone —— C30H32N4O2S
    2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-[2,5-dimethyl-1-(oxolan-2-ylmethyl)pyrrol-3-yl]ethanone
    —— N-tert-butyl-2-[(5,6-diethyl-1,2,4-triazin-3-yl)sulfanyl]acetamide —— C13H22N4OS
    N-tert-butyl-2-[(5,6-diethyl-1,2,4-triazin-3-yl)sulfanyl]acetamide
    —— Ethyl 5-[(2-chlorophenyl)sulfanyl]-3-[3-(trifluoromethyl)phenyl]-1,2,4-triazine-6-carboxylate —— C19H13ClF3N3O2S
    Ethyl 5-[(2-chlorophenyl)sulfanyl]-3-[3-(trifluoromethyl)phenyl]-1,2,4-triazine-6-carboxylate
    —— 5-(4-Bromophenyl)sulfanyl-3-(4-methylphenyl)-6-phenyl-1,2,4-triazine —— C22H16BrN3S
    5-(4-Bromophenyl)sulfanyl-3-(4-methylphenyl)-6-phenyl-1,2,4-triazine
    —— 1-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]propan-2-one —— C20H19N3OS
    1-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]propan-2-one
    —— Methyl-[1-(6-quinolin-8-ylsulfanylpyridazin-3-yl)imidazol-2-yl]phosphinate —— C17H13N5O2PS-
    Methyl-[1-(6-quinolin-8-ylsulfanylpyridazin-3-yl)imidazol-2-yl]phosphinate
    —— 1-(1-Adamantyl)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethanone —— C27H27N3OS
    1-(1-Adamantyl)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethanone
    —— Methyl-[1-(6-quinolin-8-ylsulfanylpyridazin-3-yl)imidazol-2-yl]phosphinic acid —— C17H14N5O2PS
    Methyl-[1-(6-quinolin-8-ylsulfanylpyridazin-3-yl)imidazol-2-yl]phosphinic acid
    —— N-cyclopentyl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]propanamide —— C23H24N4OS
    N-cyclopentyl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]propanamide
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[2-(4-chlorophenyl)ethyl]acetamide —— C27H25ClN4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[2-(4-chlorophenyl)ethyl]acetamide
    —— N-cyclohexyl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-methylacetamide —— C24H26N4OS
    N-cyclohexyl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-methylacetamide
    —— 3-[(2-Chloro-6-fluorophenyl)methylsulfanyl]-5,6-bis(4-methylphenyl)-1,2,4-triazine —— C24H19ClFN3S
    3-[(2-Chloro-6-fluorophenyl)methylsulfanyl]-5,6-bis(4-methylphenyl)-1,2,4-triazine
    —— Ethyl 3-(4-methylphenyl)-5-(phenylsulfanyl)-1,2,4-triazine-6-carboxylate —— C19H17N3O2S
    Ethyl 3-(4-methylphenyl)-5-(phenylsulfanyl)-1,2,4-triazine-6-carboxylate
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-1-(1H-pyrrol-2-yl)ethanone —— C21H16N4OS
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-1-(1H-pyrrol-2-yl)ethanone
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-cyclooctylacetamide —— C27H32N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-cyclooctylacetamide
    —— ethyl 5-[2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]propanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate —— C27H26N4O3S
    ethyl 5-[2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]propanoyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate
    —— N-butan-2-yl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide —— C21H22N4OS
    N-butan-2-yl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide
    —— Ethyl 3-[3-(trifluoromethyl)phenyl]-5-{[3-(trifluoromethyl)phenyl]sulfanyl}-1,2,4-triazine-6-carboxylate —— C20H13F6N3O2S
    Ethyl 3-[3-(trifluoromethyl)phenyl]-5-{[3-(trifluoromethyl)phenyl]sulfanyl}-1,2,4-triazine-6-carboxylate
    —— N-benzyl-2-(1H-1,2,3-triazol-5-ylsulfanyl)acetamide —— C11H12N4OS
    N-benzyl-2-(1H-1,2,3-triazol-5-ylsulfanyl)acetamide
    —— 8,11,11-Trimethyl-5-(2-piperidin-1-ylethylsulfanyl)-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene —— C18H28N4S
    8,11,11-Trimethyl-5-(2-piperidin-1-ylethylsulfanyl)-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene
    —— 5-Benzylsulfanyl-8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene —— C18H21N3S
    5-Benzylsulfanyl-8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene