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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-2-(4-methylphenyl)sulfanyl-N-[(3S)-pyrrolidin-3-yl]propanamide —— C14H20N2OS
    (2S)-2-(4-methylphenyl)sulfanyl-N-[(3S)-pyrrolidin-3-yl]propanamide
    —— 3-(4-methylphenyl)sulfanyl-N-[(3S)-pyrrolidin-3-yl]propanamide —— C14H20N2OS
    3-(4-methylphenyl)sulfanyl-N-[(3S)-pyrrolidin-3-yl]propanamide
    —— (2R)-2-phenylsulfanyl-N-[(3R)-pyrrolidin-3-yl]propanamide —— C13H18N2OS
    (2R)-2-phenylsulfanyl-N-[(3R)-pyrrolidin-3-yl]propanamide
    —— 3-(4,6-Diaminopyrimidin-2-yl)sulfanylpropylazanium —— C7H14N5S+
    3-(4,6-Diaminopyrimidin-2-yl)sulfanylpropylazanium
    —— (2-Amino-2-sulfanylideneethyl)-dimethylazanium —— C4H11N2S+
    (2-Amino-2-sulfanylideneethyl)-dimethylazanium
    —— 3-(1-methyltetrazol-5-yl)sulfanyl-N-[(1R)-3-methyl-1-thiophen-2-ylbutyl]propanamide —— C14H21N5OS2
    3-(1-methyltetrazol-5-yl)sulfanyl-N-[(1R)-3-methyl-1-thiophen-2-ylbutyl]propanamide
    —— N-[(3R)-1,1-dioxothiolan-3-yl]-2-(5-methylpyridin-2-yl)sulfanylacetamide —— C12H16N2O3S2
    N-[(3R)-1,1-dioxothiolan-3-yl]-2-(5-methylpyridin-2-yl)sulfanylacetamide
    —— 1-[(2S)-2-ethylhexyl]-3-(2-methylsulfonylethyl)urea —— C12H26N2O3S
    1-[(2S)-2-ethylhexyl]-3-(2-methylsulfonylethyl)urea
    —— 5-Benzylsulfanyl-4-(imidazo[2,1-b][1,3]thiazol-6-ylmethyl)-1,2,4-triazol-3-amine —— C15H14N6S2
    5-Benzylsulfanyl-4-(imidazo[2,1-b][1,3]thiazol-6-ylmethyl)-1,2,4-triazol-3-amine
    —— 1-[(2S)-heptan-2-yl]-3-(2-methylsulfonylethyl)urea —— C11H24N2O3S
    1-[(2S)-heptan-2-yl]-3-(2-methylsulfonylethyl)urea
    —— (2S)-N-[(1S)-3-methyl-1-thiophen-2-ylbutyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C15H22N4OS2
    (2S)-N-[(1S)-3-methyl-1-thiophen-2-ylbutyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2S)-N-[(1R)-3-methyl-1-thiophen-2-ylbutyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C15H22N4OS2
    (2S)-N-[(1R)-3-methyl-1-thiophen-2-ylbutyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2R)-N-[(1R)-3-methyl-1-thiophen-2-ylbutyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide —— C15H22N4OS2
    (2R)-N-[(1R)-3-methyl-1-thiophen-2-ylbutyl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propanamide
    —— (2R)-N,N,3-trimethyl-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]butanamide —— C16H21N3O2S
    (2R)-N,N,3-trimethyl-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]butanamide
    —— (2S)-N,N,3-trimethyl-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]butanamide —— C16H21N3O2S
    (2S)-N,N,3-trimethyl-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]butanamide
    —— (2S)-3-methyl-2-(1-propan-2-yltetrazol-5-yl)sulfanyl-N-(pyridin-3-ylmethyl)butanamide —— C15H22N6OS
    (2S)-3-methyl-2-(1-propan-2-yltetrazol-5-yl)sulfanyl-N-(pyridin-3-ylmethyl)butanamide
    —— (2R)-3-methyl-2-(1-propan-2-yltetrazol-5-yl)sulfanyl-N-(pyridin-3-ylmethyl)butanamide —— C15H22N6OS
    (2R)-3-methyl-2-(1-propan-2-yltetrazol-5-yl)sulfanyl-N-(pyridin-3-ylmethyl)butanamide
    —— (2S)-1-[(2R)-2-(1-methylpyrrol-2-yl)azepan-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one —— C17H25N5OS
    (2S)-1-[(2R)-2-(1-methylpyrrol-2-yl)azepan-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one
    —— (2R)-1-[(2S)-2-(1-methylpyrrol-2-yl)azepan-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one —— C17H25N5OS
    (2R)-1-[(2S)-2-(1-methylpyrrol-2-yl)azepan-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one
    —— ethyl (2R)-2-[[4-(2-amino-2-oxoethyl)-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanoate —— C13H16N4O3S2
    ethyl (2R)-2-[[4-(2-amino-2-oxoethyl)-5-thiophen-2-yl-1,2,4-triazol-3-yl]sulfanyl]propanoate
    —— (2R)-1-[(2R)-2-(1-methylpyrrol-2-yl)azepan-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one —— C17H25N5OS
    (2R)-1-[(2R)-2-(1-methylpyrrol-2-yl)azepan-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one
    —— (2S)-1-[(2S)-2-(1-methylpyrrol-2-yl)azepan-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one —— C17H25N5OS
    (2S)-1-[(2S)-2-(1-methylpyrrol-2-yl)azepan-1-yl]-2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]propan-1-one
    —— (2R)-2-(3-chloropyridin-2-yl)sulfanyl-3-methyl-N-(pyridin-3-ylmethyl)butanamide —— C16H18ClN3OS
    (2R)-2-(3-chloropyridin-2-yl)sulfanyl-3-methyl-N-(pyridin-3-ylmethyl)butanamide
    —— (2S)-N-[(E)-[1-(4-fluorophenyl)-3-phenylsulfanylpropylidene]amino]oxolane-2-carboxamide —— C20H21FN2O2S
    (2S)-N-[(E)-[1-(4-fluorophenyl)-3-phenylsulfanylpropylidene]amino]oxolane-2-carboxamide
    —— (2R)-3-methyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-N-(pyridin-3-ylmethyl)butanamide —— C15H19N3OS2
    (2R)-3-methyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-N-(pyridin-3-ylmethyl)butanamide
    —— (2S)-3-methyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-N-(pyridin-3-ylmethyl)butanamide —— C15H19N3OS2
    (2S)-3-methyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]-N-(pyridin-3-ylmethyl)butanamide
    —— (2S)-2-[[5-(2,2,2-trifluoroethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C7H9F3N4OS2
    (2S)-2-[[5-(2,2,2-trifluoroethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— ethyl (8S,8aS)-5,7,7-tricyano-6-imino-8-(4-methylsulfanylphenyl)-3,5,8,8a-tetrahydro-1H-isoquinoline-2-carboxylate —— C22H21N5O2S
    ethyl (8S,8aS)-5,7,7-tricyano-6-imino-8-(4-methylsulfanylphenyl)-3,5,8,8a-tetrahydro-1H-isoquinoline-2-carboxylate
    —— 3-methylsulfanyl-4-[[(2R)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazole —— C12H20N4OS
    3-methylsulfanyl-4-[[(2R)-oxolan-2-yl]methyl]-5-pyrrolidin-1-yl-1,2,4-triazole
    —— (2R)-2-[[5-(2,2,2-trifluoroethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C7H9F3N4OS2
    (2R)-2-[[5-(2,2,2-trifluoroethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— ethyl (8R,8aS)-5,7,7-tricyano-6-imino-8-(4-methylsulfanylphenyl)-3,5,8,8a-tetrahydro-1H-isoquinoline-2-carboxylate —— C22H21N5O2S
    ethyl (8R,8aS)-5,7,7-tricyano-6-imino-8-(4-methylsulfanylphenyl)-3,5,8,8a-tetrahydro-1H-isoquinoline-2-carboxylate
    —— ethyl (8R,8aR)-5,7,7-tricyano-6-imino-8-(4-methylsulfanylphenyl)-3,5,8,8a-tetrahydro-1H-isoquinoline-2-carboxylate —— C22H21N5O2S
    ethyl (8R,8aR)-5,7,7-tricyano-6-imino-8-(4-methylsulfanylphenyl)-3,5,8,8a-tetrahydro-1H-isoquinoline-2-carboxylate
    —— 2-Phenylsulfanylethylazanium —— C8H12NS+
    2-Phenylsulfanylethylazanium
    —— (2S)-2-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanyl-3-methylbutanamide —— C13H17N3OS
    (2S)-2-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanyl-3-methylbutanamide
    —— 4-[(R)-(4,6-dimethoxypyrimidin-2-yl)-phenylmethyl]sulfanylaniline —— C19H19N3O2S
    4-[(R)-(4,6-dimethoxypyrimidin-2-yl)-phenylmethyl]sulfanylaniline
    —— 1-[(2R)-2-ethylmorpholin-4-yl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C14H18N4O2S2
    1-[(2R)-2-ethylmorpholin-4-yl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— 4-[(S)-(4,6-dimethoxypyrimidin-2-yl)-phenylmethyl]sulfanylaniline —— C19H19N3O2S
    4-[(S)-(4,6-dimethoxypyrimidin-2-yl)-phenylmethyl]sulfanylaniline
    —— 1-[(2S)-2-ethylmorpholin-4-yl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethanone —— C14H18N4O2S2
    1-[(2S)-2-ethylmorpholin-4-yl]-2-[(5-thiophen-2-yl-1H-1,2,4-triazol-3-yl)sulfanyl]ethanone
    —— (2S)-N-[(1R,2S)-2-methylcyclohexyl]-2-methylsulfonylpropanamide —— C11H21NO3S
    (2S)-N-[(1R,2S)-2-methylcyclohexyl]-2-methylsulfonylpropanamide
    —— [2-(azepan-1-yl)-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate —— C17H23NO3S
    [2-(azepan-1-yl)-2-oxoethyl] (2S)-2-phenylsulfanylpropanoate
    —— 2-(3,4-dimethylphenyl)-5-(2-ethoxyethylsulfanyl)-1,3,4-oxadiazole —— C14H18N2O2S
    2-(3,4-dimethylphenyl)-5-(2-ethoxyethylsulfanyl)-1,3,4-oxadiazole
    —— (2R)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-3-methylbutanamide —— C15H20N4OS2
    (2R)-2-[[4-cyclopropyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]-3-methylbutanamide
    —— (3R,5S)-3-[(4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-5-methyloxolan-2-one —— C9H13N3O2S
    (3R,5S)-3-[(4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-5-methyloxolan-2-one
    —— (1R)-1-(4-butyl-5-ethylsulfanyl-1,2,4-triazol-3-yl)-N,N-dimethylpropan-1-amine —— C13H26N4S
    (1R)-1-(4-butyl-5-ethylsulfanyl-1,2,4-triazol-3-yl)-N,N-dimethylpropan-1-amine
    —— (1R)-1-[4-butyl-5-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine —— C20H27ClN6OS
    (1R)-1-[4-butyl-5-[[5-(2-chlorophenyl)-1,3,4-oxadiazol-2-yl]methylsulfanyl]-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine
    —— (3S,5S)-3-[(4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-5-methyloxolan-2-one —— C9H13N3O2S
    (3S,5S)-3-[(4-ethyl-1,2,4-triazol-3-yl)sulfanyl]-5-methyloxolan-2-one
    —— 3-(4-fluorophenyl)sulfanyl-N-[(2R)-1-methoxypropan-2-yl]propanamide —— C13H18FNO2S
    3-(4-fluorophenyl)sulfanyl-N-[(2R)-1-methoxypropan-2-yl]propanamide
    —— 2-[[4-butyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]acetonitrile —— C13H23N5S
    2-[[4-butyl-5-[(1R)-1-(dimethylamino)propyl]-1,2,4-triazol-3-yl]sulfanyl]acetonitrile
    —— 3-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-4-(furan-2-ylmethyl)-1,2,4-triazole —— C15H14FN3OS
    3-[(1R)-1-(4-fluorophenyl)ethyl]sulfanyl-4-(furan-2-ylmethyl)-1,2,4-triazole
    —— (1R)-1-[5-[(4-bromo-2-fluorophenyl)methylsulfanyl]-4-butyl-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine —— C18H26BrFN4S
    (1R)-1-[5-[(4-bromo-2-fluorophenyl)methylsulfanyl]-4-butyl-1,2,4-triazol-3-yl]-N,N-dimethylpropan-1-amine