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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1-[4-[(3-methyl-1,2-oxazol-5-yl)methyl]piperazin-1-yl]-4-phenylsulfanylbutan-1-one —— C19H25N3O2S
    1-[4-[(3-methyl-1,2-oxazol-5-yl)methyl]piperazin-1-yl]-4-phenylsulfanylbutan-1-one
    —— N-[(S)-cyclopentyl-(4-fluorophenyl)methyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide —— C16H19FN4OS
    N-[(S)-cyclopentyl-(4-fluorophenyl)methyl]-2-(1H-1,2,4-triazol-5-ylsulfanyl)acetamide
    —— 2-(1-hydrazinylethylidene)-1-benzothiophen-3-one —— C10H10N2OS
    2-(1-hydrazinylethylidene)-1-benzothiophen-3-one
    —— ethyl 2-acetylimino-7-(hydroxyamino)-6-phenylsulfanyl-5,6-dihydro-4H-1-benzothiophene-3-carboxylate —— C19H20N2O4S2
    ethyl 2-acetylimino-7-(hydroxyamino)-6-phenylsulfanyl-5,6-dihydro-4H-1-benzothiophene-3-carboxylate
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-[(2S)-2-(3-methyl-1,2-oxazol-5-yl)pyrrolidin-1-yl]ethanone —— C12H15N5O2S2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-1-[(2S)-2-(3-methyl-1,2-oxazol-5-yl)pyrrolidin-1-yl]ethanone
    —— 5-Methyl-4-[[4-[4-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]sulfanylanilino]methylidene]-2-phenylpyrazol-3-one —— C34H28N6O2S
    5-Methyl-4-[[4-[4-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]sulfanylanilino]methylidene]-2-phenylpyrazol-3-one
    —— 2-(4-fluorophenyl)sulfanyl-N-methyl-N-[(1S)-1-thiophen-2-ylethyl]acetamide —— C15H16FNOS2
    2-(4-fluorophenyl)sulfanyl-N-methyl-N-[(1S)-1-thiophen-2-ylethyl]acetamide
    —— N-methyl-2-(2-methylphenyl)sulfanyl-N-[(1S)-1-thiophen-2-ylethyl]acetamide —— C16H19NOS2
    N-methyl-2-(2-methylphenyl)sulfanyl-N-[(1S)-1-thiophen-2-ylethyl]acetamide
    —— 2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-methyl-N-[(1R)-1-thiophen-2-ylethyl]acetamide —— C17H20N4OS3
    2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-methyl-N-[(1R)-1-thiophen-2-ylethyl]acetamide
    —— N-[2-[(3R,5R)-3,5-dimethylpiperidin-1-yl]-2-methylpropyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H33N5OS
    N-[2-[(3R,5R)-3,5-dimethylpiperidin-1-yl]-2-methylpropyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— [(2-oxo-1-benzothiophen-3-ylidene)amino]thiourea 29775-76-6 C9H7N3OS2
    [(2-oxo-1-benzothiophen-3-ylidene)amino]thiourea
    —— 2-(3-tert-butyl-5-oxo-1-phenylpyrazol-4-ylidene)-2-[4-(trifluoromethylsulfanyl)anilino]acetonitrile —— C22H19F3N4OS
    2-(3-tert-butyl-5-oxo-1-phenylpyrazol-4-ylidene)-2-[4-(trifluoromethylsulfanyl)anilino]acetonitrile
    —— N-[(2R)-4-(4-bromophenyl)butan-2-yl]-2-pyridin-4-ylsulfanylacetamide —— C17H19BrN2OS
    N-[(2R)-4-(4-bromophenyl)butan-2-yl]-2-pyridin-4-ylsulfanylacetamide
    —— 3-(4-chlorophenyl)-5-[(5-methyl-1,2,4-oxadiazol-3-yl)methylsulfanyl]-1,3,4-thiadiazole-2-thione —— C12H9ClN4OS3
    3-(4-chlorophenyl)-5-[(5-methyl-1,2,4-oxadiazol-3-yl)methylsulfanyl]-1,3,4-thiadiazole-2-thione
    —— 3-cyclopropyl-5-[(1R)-1-[[4-methyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-1,2,4-oxadiazole —— C15H17N5OS2
    3-cyclopropyl-5-[(1R)-1-[[4-methyl-5-(thiophen-2-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-1,2,4-oxadiazole
    —— N-[(4R)-1-tert-butyl-4,5,6,7-tetrahydroindazol-4-yl]-2-(2-fluorophenyl)sulfanylacetamide —— C19H24FN3OS
    N-[(4R)-1-tert-butyl-4,5,6,7-tetrahydroindazol-4-yl]-2-(2-fluorophenyl)sulfanylacetamide
    —— N-[2-(N-methylanilino)ethyl]-2-phenylsulfanylacetamide —— C17H20N2OS
    N-[2-(N-methylanilino)ethyl]-2-phenylsulfanylacetamide
    —— (2R)-3-methoxy-2-methyl-2-[(6-methyl-4-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoic acid —— C10H14N2O4S
    (2R)-3-methoxy-2-methyl-2-[(6-methyl-4-oxo-1H-pyrimidin-2-yl)sulfanyl]propanoic acid
    —— (2S)-2-(2,4-dimethylphenyl)sulfanyl-3-methoxy-2-methylpropanoic acid —— C13H18O3S
    (2S)-2-(2,4-dimethylphenyl)sulfanyl-3-methoxy-2-methylpropanoic acid
    —— (2S)-2-(4-amino-2-fluorophenyl)sulfanyl-3-methoxy-2-methylpropanoic acid —— C11H14FNO3S
    (2S)-2-(4-amino-2-fluorophenyl)sulfanyl-3-methoxy-2-methylpropanoic acid
    —— 2-[2-[[(2S)-1-methoxypropan-2-yl]amino]phenyl]sulfanylacetamide —— C12H18N2O2S
    2-[2-[[(2S)-1-methoxypropan-2-yl]amino]phenyl]sulfanylacetamide
    —— 4-hydroxy-3-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]pent-3-en-2-one —— C14H15N3O2S2
    4-hydroxy-3-[[5-(2-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]pent-3-en-2-one
    —— 4-cyclopentylsulfanyl-N-[(2R)-1-methoxypropan-2-yl]aniline —— C15H23NOS
    4-cyclopentylsulfanyl-N-[(2R)-1-methoxypropan-2-yl]aniline
    —— N-[(2R)-1-methoxypropan-2-yl]-4-(1H-1,2,4-triazol-5-ylsulfanyl)aniline —— C12H16N4OS
    N-[(2R)-1-methoxypropan-2-yl]-4-(1H-1,2,4-triazol-5-ylsulfanyl)aniline
    —— N-[(2R)-1-methoxypropan-2-yl]-2-methylsulfanylaniline —— C11H17NOS
    N-[(2R)-1-methoxypropan-2-yl]-2-methylsulfanylaniline
    —— N-[(2S)-1-methoxypropan-2-yl]-4-methylsulfanylaniline —— C11H17NOS
    N-[(2S)-1-methoxypropan-2-yl]-4-methylsulfanylaniline
    —— 2-[2-[[(2R)-1-methoxypropan-2-yl]amino]phenyl]sulfanylacetamide —— C12H18N2O2S
    2-[2-[[(2R)-1-methoxypropan-2-yl]amino]phenyl]sulfanylacetamide
    —— (2S)-2-(2-chlorophenyl)sulfanyl-N-(1-pyrimidin-2-ylpiperidin-4-yl)propanamide —— C18H21ClN4OS
    (2S)-2-(2-chlorophenyl)sulfanyl-N-(1-pyrimidin-2-ylpiperidin-4-yl)propanamide
    —— N-cyclopentyl-N-[2-(dimethylamino)ethyl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C19H29N5O2S
    N-cyclopentyl-N-[2-(dimethylamino)ethyl]-2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[(1R,3R)-1-(hydroxymethyl)-3-methylcyclohexyl]-2-thiophen-2-ylsulfanylacetamide —— C14H21NO2S2
    N-[(1R,3R)-1-(hydroxymethyl)-3-methylcyclohexyl]-2-thiophen-2-ylsulfanylacetamide
    —— 3-(4-bromophenyl)sulfanyl-N-[(1S)-1-(1,5-dimethylpyrazol-4-yl)ethyl]propanamide —— C16H20BrN3OS
    3-(4-bromophenyl)sulfanyl-N-[(1S)-1-(1,5-dimethylpyrazol-4-yl)ethyl]propanamide
    —— N-ethyl-N-[(3-fluorophenyl)methyl]-2-[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylacetamide —— C17H22FN5O2S
    N-ethyl-N-[(3-fluorophenyl)methyl]-2-[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylacetamide
    —— [2-oxo-2-(3-phenylsulfanylpropylamino)ethyl] 2-[(3R)-1,1-dioxo-2,3-dihydrothiophen-3-yl]acetate —— C17H21NO5S2
    [2-oxo-2-(3-phenylsulfanylpropylamino)ethyl] 2-[(3R)-1,1-dioxo-2,3-dihydrothiophen-3-yl]acetate
    —— [2-oxo-2-(3-phenylsulfanylpropylamino)ethyl] 2-[(3S)-1,1-dioxo-2,3-dihydrothiophen-3-yl]acetate —— C17H21NO5S2
    [2-oxo-2-(3-phenylsulfanylpropylamino)ethyl] 2-[(3S)-1,1-dioxo-2,3-dihydrothiophen-3-yl]acetate
    —— 2-ethylsulfonyl-N-[(1R,3R)-3-(trifluoromethyl)cyclohexyl]acetamide —— C11H18F3NO3S
    2-ethylsulfonyl-N-[(1R,3R)-3-(trifluoromethyl)cyclohexyl]acetamide
    —— N-[(3-phenyl-1,2-oxazol-5-yl)methyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C17H19N5O2S
    N-[(3-phenyl-1,2-oxazol-5-yl)methyl]-2-[(4-propan-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-[(3-phenyl-1,2-oxazol-5-yl)methyl]propanamide —— C20H22N4O2S
    3-(4,6-dimethyl-2-methylsulfanylpyrimidin-5-yl)-N-[(3-phenyl-1,2-oxazol-5-yl)methyl]propanamide
    —— N-(2-cyanopropan-2-yl)-N-methyl-2-[[5-[[(2R)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C14H21N5O2S2
    N-(2-cyanopropan-2-yl)-N-methyl-2-[[5-[[(2R)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 3-(4-bromophenyl)sulfanyl-N-[[(3S)-1,1-dioxothiolan-3-yl]methyl]propanamide —— C14H18BrNO3S2
    3-(4-bromophenyl)sulfanyl-N-[[(3S)-1,1-dioxothiolan-3-yl]methyl]propanamide
    —— (2S)-2-(2-ethylsulfonylethyl)-3-methyl-N-(2-methylpropyl)butan-1-amine —— C13H29NO2S
    (2S)-2-(2-ethylsulfonylethyl)-3-methyl-N-(2-methylpropyl)butan-1-amine
    —— N'-(4-benzyl-3-benzylsulfanyl-1,2,4-thiadiazol-4-ium-5-yl)-N-phenylbenzenecarboximidamide —— C29H25N4S2+
    N'-(4-benzyl-3-benzylsulfanyl-1,2,4-thiadiazol-4-ium-5-yl)-N-phenylbenzenecarboximidamide
    —— 2-chloro-N'-hydroxy-6-(1,3,4-thiadiazol-2-ylsulfanyl)benzenecarboximidamide —— C9H7ClN4OS2
    2-chloro-N'-hydroxy-6-(1,3,4-thiadiazol-2-ylsulfanyl)benzenecarboximidamide
    —— 2-chloro-N'-hydroxy-6-(4-methylpyrimidin-2-yl)sulfanylbenzenecarboximidamide —— C12H11ClN4OS
    2-chloro-N'-hydroxy-6-(4-methylpyrimidin-2-yl)sulfanylbenzenecarboximidamide
    —— 2-(5-bromopyridin-2-yl)sulfanyl-N-[(3R)-2-methyl-4-oxopentan-3-yl]acetamide —— C13H17BrN2O2S
    2-(5-bromopyridin-2-yl)sulfanyl-N-[(3R)-2-methyl-4-oxopentan-3-yl]acetamide
    —— 1-[(3S)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-(1,3-thiazol-2-ylsulfanyl)ethanone —— C16H13N3OS4
    1-[(3S)-3,5-dithiophen-2-yl-3,4-dihydropyrazol-2-yl]-2-(1,3-thiazol-2-ylsulfanyl)ethanone
    —— N-[(1R,2S)-2-methylcyclohexyl]-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C15H24N4OS2
    N-[(1R,2S)-2-methylcyclohexyl]-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— (2S)-N-benzyl-N-methyl-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide —— C17H22N4OS2
    (2S)-N-benzyl-N-methyl-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]propanamide
    —— N-[(3R)-2-methyl-4-oxopentan-3-yl]-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C14H22N4O2S2
    N-[(3R)-2-methyl-4-oxopentan-3-yl]-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— N-[(1S)-3-methyl-1-phenylbutyl]-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide —— C19H26N4OS2
    N-[(1S)-3-methyl-1-phenylbutyl]-2-[(5-pyrrolidin-1-yl-1,3,4-thiadiazol-2-yl)sulfanyl]acetamide
    —— 2-(5-bromopyridin-2-yl)sulfanyl-N-[(5-ethylthiophen-2-yl)methyl]acetamide —— C14H15BrN2OS2
    2-(5-bromopyridin-2-yl)sulfanyl-N-[(5-ethylthiophen-2-yl)methyl]acetamide