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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(4-fluorophenyl)sulfanyl-N-[4-(1H-1,2,4-triazol-5-ylsulfanyl)phenyl]acetamide —— C16H13FN4OS2
    2-(4-fluorophenyl)sulfanyl-N-[4-(1H-1,2,4-triazol-5-ylsulfanyl)phenyl]acetamide
    —— 2-[(5-tert-butyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-(3-phenylpropyl)acetamide —— C17H23N3O2S
    2-[(5-tert-butyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-(3-phenylpropyl)acetamide
    —— (2R)-2-(1-benzyltetrazol-5-yl)sulfanyl-N-[(2S)-pentan-2-yl]propanamide —— C16H23N5OS
    (2R)-2-(1-benzyltetrazol-5-yl)sulfanyl-N-[(2S)-pentan-2-yl]propanamide
    —— (2R)-N,N-diethyl-2-[[5-[[(2S)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide —— C14H24N4O2S2
    (2R)-N,N-diethyl-2-[[5-[[(2S)-oxolan-2-yl]methylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]propanamide
    —— 2-[[5-ethyl-4-[(2S)-1-(methylamino)-1-oxopropan-2-yl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C10H16N4O3S
    2-[[5-ethyl-4-[(2S)-1-(methylamino)-1-oxopropan-2-yl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[4-[(2R)-1-(dimethylamino)-1-oxopropan-2-yl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C9H14N4O3S
    2-[[4-[(2R)-1-(dimethylamino)-1-oxopropan-2-yl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (2R)-2-[(5-tert-butyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide —— C17H22FN3O2S
    (2R)-2-[(5-tert-butyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide
    —— 2-[[5-[[(2S)-heptan-2-yl]amino]-1,3,4-thiadiazol-2-yl]sulfanyl]acetic acid —— C11H19N3O2S2
    2-[[5-[[(2S)-heptan-2-yl]amino]-1,3,4-thiadiazol-2-yl]sulfanyl]acetic acid
    —— 2-[(5-tert-butyl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-[(2S)-2-thiophen-2-ylpyrrolidin-1-yl]ethanone —— C16H21N3O2S2
    2-[(5-tert-butyl-1,3,4-oxadiazol-2-yl)sulfanyl]-1-[(2S)-2-thiophen-2-ylpyrrolidin-1-yl]ethanone
    —— (2R)-N-(2-methylbutan-2-yl)-2-[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylpropanamide —— C14H25N5O2S
    (2R)-N-(2-methylbutan-2-yl)-2-[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylpropanamide
    —— 2-[[4-[(2S)-heptan-2-yl]-5-methyl-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C12H21N3O2S
    2-[[4-[(2S)-heptan-2-yl]-5-methyl-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[4-[(2S)-heptan-2-yl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C11H19N3O2S
    2-[[4-[(2S)-heptan-2-yl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (2S)-N-(2-methylbutan-2-yl)-2-(1-propan-2-yltetrazol-5-yl)sulfanylpropanamide —— C12H23N5OS
    (2S)-N-(2-methylbutan-2-yl)-2-(1-propan-2-yltetrazol-5-yl)sulfanylpropanamide
    —— (2S)-2-[(5-tert-butyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide —— C17H22FN3O2S
    (2S)-2-[(5-tert-butyl-1,3,4-oxadiazol-2-yl)sulfanyl]-N-[(3-fluorophenyl)methyl]-N-methylpropanamide
    —— (2S)-N-(2-methylbutan-2-yl)-2-[1-[[(2S)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylpropanamide —— C14H25N5O2S
    (2S)-N-(2-methylbutan-2-yl)-2-[1-[[(2S)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylpropanamide
    —— (2R)-N,N-diethyl-2-[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylpropanamide —— C13H23N5O2S
    (2R)-N,N-diethyl-2-[1-[[(2R)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanylpropanamide
    —— 2-[[5-ethyl-4-[(2S,3R)-3-methylpentan-2-yl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C12H21N3O2S
    2-[[5-ethyl-4-[(2S,3R)-3-methylpentan-2-yl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[5-methyl-4-[(2R,3R)-3-methylpentan-2-yl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C11H19N3O2S
    2-[[5-methyl-4-[(2R,3R)-3-methylpentan-2-yl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (1R)-N-cyclopropyl-N-(2-methylpropyl)-1-(4-methylsulfanylphenyl)ethane-1,2-diamine —— C16H26N2S
    (1R)-N-cyclopropyl-N-(2-methylpropyl)-1-(4-methylsulfanylphenyl)ethane-1,2-diamine
    —— 2-[[5-ethyl-4-[(3S)-1-methylpyrrolidin-3-yl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C11H18N4O2S
    2-[[5-ethyl-4-[(3S)-1-methylpyrrolidin-3-yl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[4-[(2R)-1-pyrazol-1-ylpropan-2-yl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C10H13N5O2S
    2-[[4-[(2R)-1-pyrazol-1-ylpropan-2-yl]-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-1-imidazol-1-ylpropan-2-yl]acetamide —— C16H20N6O2S
    2-[[4-ethyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(2R)-1-imidazol-1-ylpropan-2-yl]acetamide
    —— 2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-1-imidazol-1-ylpropan-2-yl]acetamide —— C18H22N6OS
    2-[(4-benzyl-5-methyl-1,2,4-triazol-3-yl)sulfanyl]-N-[(2R)-1-imidazol-1-ylpropan-2-yl]acetamide
    —— (1R)-N-[(2S)-1-methoxypropan-2-yl]-N-methyl-1-(4-methylsulfanylphenyl)ethane-1,2-diamine —— C14H24N2OS
    (1R)-N-[(2S)-1-methoxypropan-2-yl]-N-methyl-1-(4-methylsulfanylphenyl)ethane-1,2-diamine
    —— 2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]acetamide —— C23H28N4O2S
    2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]acetamide
    —— N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide —— C18H26N4OS2
    N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]-2-[(4-ethyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]acetamide
    —— 2-(2,4-dimethylphenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C14H19NO3S2
    2-(2,4-dimethylphenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— N-benzyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C22H24N4O3S3
    N-benzyl-N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methylacetamide —— C15H19N3O3S2
    2-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-methylacetamide
    —— 2-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanyl-N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]acetamide —— C18H25N3OS
    2-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanyl-N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]acetamide
    —— 2-(4,6-diaminopyrimidin-2-yl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylacetamide —— C12H19N5O3S2
    2-(4,6-diaminopyrimidin-2-yl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]-N-ethylacetamide
    —— 2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C16H20N4O3S3
    2-[[5-(2,3-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C18H23N3O2S
    N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]-2-[(5-phenyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— 2-(4-bromophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C12H14BrNO3S2
    2-(4-bromophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— 2-(4,6-diaminopyrimidin-2-yl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C10H15N5O3S2
    2-(4,6-diaminopyrimidin-2-yl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— 2-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C20H22N4O4S2
    2-[[4-benzyl-5-(2-methylfuran-3-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-2-(4-fluorophenyl)sulfanylacetamide —— C12H14FNO3S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-2-(4-fluorophenyl)sulfanylacetamide
    —— 2-(2,5-dimethylphenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C14H19NO3S2
    2-(2,5-dimethylphenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C15H18N4O3S3
    N-[(3S)-1,1-dioxothiolan-3-yl]-2-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 2-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C14H17N3O3S2
    2-(3-cyano-4,6-dimethylpyridin-2-yl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— 2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C19H20N4O4S2
    2-[[4-benzyl-5-(furan-2-yl)-1,2,4-triazol-3-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— 2-(3,4-dimethylphenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C14H19NO3S2
    2-(3,4-dimethylphenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— 2-[(4-benzyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C19H20N4O3S3
    2-[(4-benzyl-5-thiophen-2-yl-1,2,4-triazol-3-yl)sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— N-[(2R)-2-hydroxy-3-methoxypropyl]-N-methyl-2-(4-methylphenyl)sulfanylacetamide —— C14H21NO3S
    N-[(2R)-2-hydroxy-3-methoxypropyl]-N-methyl-2-(4-methylphenyl)sulfanylacetamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-N-methyl-2-pyrimidin-2-ylsulfanylacetamide —— C11H15N3O3S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-N-methyl-2-pyrimidin-2-ylsulfanylacetamide
    —— N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]acetamide —— C17H27N3O2S
    N-[(1S,2S,3S)-2,3-dimethylcyclohexyl]-2-[(6-oxo-4-propyl-1H-pyrimidin-2-yl)sulfanyl]acetamide
    —— N-[(2S)-2-hydroxy-3-methoxypropyl]-N-methyl-2-(4-methylphenyl)sulfanylacetamide —— C14H21NO3S
    N-[(2S)-2-hydroxy-3-methoxypropyl]-N-methyl-2-(4-methylphenyl)sulfanylacetamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-2-phenylsulfanylacetamide —— C12H15NO3S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-2-phenylsulfanylacetamide
    —— 2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C16H20N4O3S3
    2-[[5-(3,4-dimethylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— N-[(3S)-1,1-dioxothiolan-3-yl]-2-pyrimidin-2-ylsulfanylacetamide —— C10H13N3O3S2
    N-[(3S)-1,1-dioxothiolan-3-yl]-2-pyrimidin-2-ylsulfanylacetamide