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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2S)-3-(4,6-dimethylpyrimidin-2-yl)sulfanyl-2-methyl-2-(propylamino)propanenitrile —— C13H20N4S
    (2S)-3-(4,6-dimethylpyrimidin-2-yl)sulfanyl-2-methyl-2-(propylamino)propanenitrile
    —— (2R)-2-amino-3-(4,6-dimethylpyrimidin-2-yl)sulfanyl-2-methylpropanenitrile —— C10H14N4S
    (2R)-2-amino-3-(4,6-dimethylpyrimidin-2-yl)sulfanyl-2-methylpropanenitrile
    —— (1S,2S)-1-(4,6-dimethylpyrimidin-2-yl)sulfanyl-1-(furan-2-yl)propan-2-amine —— C13H17N3OS
    (1S,2S)-1-(4,6-dimethylpyrimidin-2-yl)sulfanyl-1-(furan-2-yl)propan-2-amine
    —— (2R)-2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-2-pyridin-4-ylethanamine —— C13H16N4S
    (2R)-2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-2-pyridin-4-ylethanamine
    —— (1R,3R)-1-(4,6-dimethylpyrimidin-2-yl)sulfanyl-3-methylcyclohexane-1-carboxylic acid —— C14H20N2O2S
    (1R,3R)-1-(4,6-dimethylpyrimidin-2-yl)sulfanyl-3-methylcyclohexane-1-carboxylic acid
    —— 3-[(1R)-1-(4,6-dimethylpyrimidin-2-yl)sulfanylethyl]aniline —— C14H17N3S
    3-[(1R)-1-(4,6-dimethylpyrimidin-2-yl)sulfanylethyl]aniline
    —— 4,6-dimethyl-2-[[(2R)-piperidin-2-yl]methylsulfanyl]pyrimidine —— C12H19N3S
    4,6-dimethyl-2-[[(2R)-piperidin-2-yl]methylsulfanyl]pyrimidine
    —— (1R,2S)-1-(4,6-dimethylpyrimidin-2-yl)sulfanyl-1-(5-methylthiophen-2-yl)propan-2-amine —— C14H19N3S2
    (1R,2S)-1-(4,6-dimethylpyrimidin-2-yl)sulfanyl-1-(5-methylthiophen-2-yl)propan-2-amine
    —— 4,6-dimethyl-2-[[(2S)-pyrrolidin-2-yl]methylsulfanyl]pyrimidine —— C11H17N3S
    4,6-dimethyl-2-[[(2S)-pyrrolidin-2-yl]methylsulfanyl]pyrimidine
    —— [(1R,2R,4R)-2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-4-methylcyclohexyl]methanamine —— C14H23N3S
    [(1R,2R,4R)-2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-4-methylcyclohexyl]methanamine
    —— (2R)-2-amino-3-(4,6-dimethylpyrimidin-2-yl)sulfanylpropanenitrile —— C9H12N4S
    (2R)-2-amino-3-(4,6-dimethylpyrimidin-2-yl)sulfanylpropanenitrile
    —— 3-benzylsulfanyl-6-[2-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]-2H-1,2,4-triazin-5-one —— C27H22N6O2S
    3-benzylsulfanyl-6-[2-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]-2H-1,2,4-triazin-5-one
    —— (1S,2R)-1-(4,6-dimethylpyrimidin-2-yl)sulfanyl-1-thiophen-3-ylbutan-2-amine —— C14H19N3S2
    (1S,2R)-1-(4,6-dimethylpyrimidin-2-yl)sulfanyl-1-thiophen-3-ylbutan-2-amine
    —— (2R)-5-(4,6-dimethylpyrimidin-2-yl)sulfanyl-2-(ethylamino)-2-methylpentanenitrile —— C14H22N4S
    (2R)-5-(4,6-dimethylpyrimidin-2-yl)sulfanyl-2-(ethylamino)-2-methylpentanenitrile
    —— 6-[2-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]-3-methylsulfanyl-2H-1,2,4-triazin-5-one —— C21H18N6O2S
    6-[2-[(3-methyl-5-oxo-1-phenylpyrazol-4-ylidene)methylamino]phenyl]-3-methylsulfanyl-2H-1,2,4-triazin-5-one
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-2-ethylbutanoic acid —— C12H18N2O2S
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-2-ethylbutanoic acid
    —— 2-[1-[[(2S)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanyl-1,3-benzoxazole —— C13H13N5O2S
    2-[1-[[(2S)-oxolan-2-yl]methyl]tetrazol-5-yl]sulfanyl-1,3-benzoxazole
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[2-[(2R,6R)-2,6-dimethylmorpholin-4-yl]ethyl]propanamide —— C17H25ClN2O2S
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[2-[(2R,6R)-2,6-dimethylmorpholin-4-yl]ethyl]propanamide
    —— 2-[(4-hydroxyanilino)methylidene]-1-benzothiophen-3-one —— C15H11NO2S
    2-[(4-hydroxyanilino)methylidene]-1-benzothiophen-3-one
    —— (2S,5S)-5-[(2-bromophenyl)sulfanylmethyl]oxolane-2-carboxylic acid —— C12H13BrO3S
    (2S,5S)-5-[(2-bromophenyl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2R,5S)-5-[(3-chloro-4-fluorophenyl)sulfanylmethyl]oxolane-2-carboxylic acid —— C12H12ClFO3S
    (2R,5S)-5-[(3-chloro-4-fluorophenyl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[(2S)-3-methyl-2-morpholin-4-ylbutyl]propanamide —— C18H27ClN2O2S
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[(2S)-3-methyl-2-morpholin-4-ylbutyl]propanamide
    —— (2R,5S)-5-(phenylsulfanylmethyl)oxolane-2-carboxylic acid —— C12H14O3S
    (2R,5S)-5-(phenylsulfanylmethyl)oxolane-2-carboxylic acid
    —— (2S,5S)-5-[(1-methylpyrazol-4-yl)sulfanylmethyl]oxolane-2-carboxylic acid —— C10H14N2O3S
    (2S,5S)-5-[(1-methylpyrazol-4-yl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2R,5R)-5-[(2,4-dimethylphenyl)sulfanylmethyl]oxolane-2-carboxylic acid —— C14H18O3S
    (2R,5R)-5-[(2,4-dimethylphenyl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2R,5R)-5-[(3-chloro-4-fluorophenyl)sulfanylmethyl]oxolane-2-carboxylic acid —— C12H12ClFO3S
    (2R,5R)-5-[(3-chloro-4-fluorophenyl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2R,5S)-5-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanylmethyl]oxolane-2-carboxylic acid —— C8H12N4O3S
    (2R,5S)-5-[(5-amino-1H-1,2,4-triazol-3-yl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2S,5R)-5-[(2-bromophenyl)sulfanylmethyl]oxolane-2-carboxylic acid —— C12H13BrO3S
    (2S,5R)-5-[(2-bromophenyl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2R,5S)-5-[(1-methylpyrazol-4-yl)sulfanylmethyl]oxolane-2-carboxylic acid —— C10H14N2O3S
    (2R,5S)-5-[(1-methylpyrazol-4-yl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2R)-2-(4-bromophenyl)sulfanyl-1-[(2R)-2-pyridin-4-ylpyrrolidin-1-yl]propan-1-one —— C18H19BrN2OS
    (2R)-2-(4-bromophenyl)sulfanyl-1-[(2R)-2-pyridin-4-ylpyrrolidin-1-yl]propan-1-one
    —— (2R,5S)-5-[(4-methylpyrimidin-2-yl)sulfanylmethyl]oxolane-2-carboxylic acid —— C11H14N2O3S
    (2R,5S)-5-[(4-methylpyrimidin-2-yl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2R,5S)-5-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanylmethyl]oxolane-2-carboxylic acid —— C9H12N2O4S
    (2R,5S)-5-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2S,5S)-5-[(4-methylpyrimidin-2-yl)sulfanylmethyl]oxolane-2-carboxylic acid —— C11H14N2O3S
    (2S,5S)-5-[(4-methylpyrimidin-2-yl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2S,5S)-5-(pyrimidin-2-ylsulfanylmethyl)oxolane-2-carboxylic acid —— C10H12N2O3S
    (2S,5S)-5-(pyrimidin-2-ylsulfanylmethyl)oxolane-2-carboxylic acid
    —— (2S,5R)-5-[(2,4-dimethylphenyl)sulfanylmethyl]oxolane-2-carboxylic acid —— C14H18O3S
    (2S,5R)-5-[(2,4-dimethylphenyl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2R,5R)-5-(pyridin-2-ylsulfanylmethyl)oxolane-2-carboxylic acid —— C11H13NO3S
    (2R,5R)-5-(pyridin-2-ylsulfanylmethyl)oxolane-2-carboxylic acid
    —— (2R)-2-(2-chlorophenyl)sulfanyl-N-[(2R)-3-methyl-2-morpholin-4-ylbutyl]propanamide —— C18H27ClN2O2S
    (2R)-2-(2-chlorophenyl)sulfanyl-N-[(2R)-3-methyl-2-morpholin-4-ylbutyl]propanamide
    —— (2R,5R)-5-[(2-amino-6-chlorophenyl)sulfanylmethyl]oxolane-2-carboxylic acid —— C12H14ClNO3S
    (2R,5R)-5-[(2-amino-6-chlorophenyl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2S,5R)-5-(phenylsulfanylmethyl)oxolane-2-carboxylic acid —— C12H14O3S
    (2S,5R)-5-(phenylsulfanylmethyl)oxolane-2-carboxylic acid
    —— (2S,5R)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]oxolane-2-carboxylic acid —— C9H13N3O3S
    (2S,5R)-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2S,5S)-5-[(2-amino-4-methylphenyl)sulfanylmethyl]oxolane-2-carboxylic acid —— C13H17NO3S
    (2S,5S)-5-[(2-amino-4-methylphenyl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2R,5S)-5-[(2-amino-6-chlorophenyl)sulfanylmethyl]oxolane-2-carboxylic acid —— C12H14ClNO3S
    (2R,5S)-5-[(2-amino-6-chlorophenyl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2R,5R)-5-[(2-bromophenyl)sulfanylmethyl]oxolane-2-carboxylic acid —— C12H13BrO3S
    (2R,5R)-5-[(2-bromophenyl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2R,5R)-5-[(2-amino-4-methylphenyl)sulfanylmethyl]oxolane-2-carboxylic acid —— C13H17NO3S
    (2R,5R)-5-[(2-amino-4-methylphenyl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2S,5S)-5-(pyridin-2-ylsulfanylmethyl)oxolane-2-carboxylic acid —— C11H13NO3S
    (2S,5S)-5-(pyridin-2-ylsulfanylmethyl)oxolane-2-carboxylic acid
    —— (2S,5S)-5-[(4-hydroxyphenyl)sulfanylmethyl]oxolane-2-carboxylic acid —— C12H14O4S
    (2S,5S)-5-[(4-hydroxyphenyl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2S,5S)-5-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]oxolane-2-carboxylic acid —— C9H13N3O3S
    (2S,5S)-5-[(5-methyl-1H-1,2,4-triazol-3-yl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2S,5S)-5-(phenylsulfanylmethyl)oxolane-2-carboxylic acid —— C12H14O3S
    (2S,5S)-5-(phenylsulfanylmethyl)oxolane-2-carboxylic acid
    —— (2R,5S)-5-[(6-oxo-1H-pyrimidin-2-yl)sulfanylmethyl]oxolane-2-carboxylic acid —— C10H12N2O4S
    (2R,5S)-5-[(6-oxo-1H-pyrimidin-2-yl)sulfanylmethyl]oxolane-2-carboxylic acid
    —— (2S,5S)-5-[(5-methylpyrimidin-2-yl)sulfanylmethyl]oxolane-2-carboxylic acid —— C11H14N2O3S
    (2S,5S)-5-[(5-methylpyrimidin-2-yl)sulfanylmethyl]oxolane-2-carboxylic acid