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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (E)-N-[[4-(dimethylamino)phenyl]methyl]-3-phenylsulfanylprop-2-enamide —— C18H20N2OS
    (E)-N-[[4-(dimethylamino)phenyl]methyl]-3-phenylsulfanylprop-2-enamide
    —— 4-(4-Sulfanylidenecyclohex-2-en-1-yl)butan-2-one —— C10H14OS
    4-(4-Sulfanylidenecyclohex-2-en-1-yl)butan-2-one
    —— (E)-6-(4-chlorophenylthio)imidazo[2,1-b]thiazole-5-carbaldehyde O-2,6-dichlorobenzyl oxime —— C19H12Cl3N3OS2
    (E)-6-(4-chlorophenylthio)imidazo[2,1-b]thiazole-5-carbaldehyde O-2,6-dichlorobenzyl oxime
    —— [2-[4-[2-[Benzyl-[(2-methylpropan-2-yl)oxycarbonyl]amino]ethyl]phenyl]sulfanylphenyl] butanoate —— C30H35NO4S
    [2-[4-[2-[Benzyl-[(2-methylpropan-2-yl)oxycarbonyl]amino]ethyl]phenyl]sulfanylphenyl] butanoate
    —— N-[1-(2,4-dimethylphenyl)-3-(4-fluorophenylthio)-2-propenylidene]-4-methylaniline 1140915-02-1 C24H22FNS
    N-[1-(2,4-dimethylphenyl)-3-(4-fluorophenylthio)-2-propenylidene]-4-methylaniline
    —— ethane;(1R)-1-ethyl-6-phenylsulfanyl-1,2,3,4-tetrahydronaphthalene —— C22H32S
    ethane;(1R)-1-ethyl-6-phenylsulfanyl-1,2,3,4-tetrahydronaphthalene
    —— [(Z)-N-[(2-methylpropan-2-yl)oxycarbonyl]-C-methylsulfanylcarbonimidoyl]carbamic acid —— C8H14N2O4S
    [(Z)-N-[(2-methylpropan-2-yl)oxycarbonyl]-C-methylsulfanylcarbonimidoyl]carbamic acid
    —— (2Z)-5-amino-2-[4-(methylsulfanyl)benzylidene]-7-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-7H-[1,3]thiazolo[3,2-a]pyridine-6,8-dicarbonitrile —— C24H18N4OS3
    (2Z)-5-amino-2-[4-(methylsulfanyl)benzylidene]-7-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-7H-[1,3]thiazolo[3,2-a]pyridine-6,8-dicarbonitrile
    —— [1-Amino-3-(3-azaniumylidenebutyldisulfanyl)propylidene]-[2-(methylamino)ethyl]azanium;dichloride —— C10H24Cl2N4S2
    [1-Amino-3-(3-azaniumylidenebutyldisulfanyl)propylidene]-[2-(methylamino)ethyl]azanium;dichloride
    —— [3-[3-[Hexylcarbamoyl(3-phenylpropyl)amino]phenyl]sulfanylphenyl] butanoate —— C32H40N2O3S
    [3-[3-[Hexylcarbamoyl(3-phenylpropyl)amino]phenyl]sulfanylphenyl] butanoate
    —— N-methyl-2-methylsulfanyl-N-(3-piperidin-4-ylpropyl)aniline —— C16H26N2S
    N-methyl-2-methylsulfanyl-N-(3-piperidin-4-ylpropyl)aniline
    —— 3-{[3-Chloro-5-(trifluoromethyl)-2-pyridinyl]sulfanyl}-5-{2-[3-(trifluoromethyl)anilino]vinyl}-4-isothiazolecarbonitrile —— C19H9ClF6N4S2
    3-{[3-Chloro-5-(trifluoromethyl)-2-pyridinyl]sulfanyl}-5-{2-[3-(trifluoromethyl)anilino]vinyl}-4-isothiazolecarbonitrile
    —— 4-[2-[6-amino-8-[(6-bromo-2,3-dihydro-1H-inden-5-yl)sulfanyl]-7H-purin-3-ium-3-yl]ethyl]piperidine-1-carbaldehyde —— C22H26BrN6OS+
    4-[2-[6-amino-8-[(6-bromo-2,3-dihydro-1H-inden-5-yl)sulfanyl]-7H-purin-3-ium-3-yl]ethyl]piperidine-1-carbaldehyde
    —— 5-(2-{[(2-Chloro-6-fluorobenzyl)oxy]imino}ethyl)-3-{[3-chloro-5-(trifluoromethyl)-2-pyridinyl]sulfanyl}-4-isothiazolecarbonitrile —— C19H10Cl2F4N4OS2
    5-(2-{[(2-Chloro-6-fluorobenzyl)oxy]imino}ethyl)-3-{[3-chloro-5-(trifluoromethyl)-2-pyridinyl]sulfanyl}-4-isothiazolecarbonitrile
    —— (E)-1-[2-[(2-chloropyridin-3-yl)oxymethyl]morpholin-4-yl]-3-phenylsulfanylprop-2-en-1-one —— C19H19ClN2O3S
    (E)-1-[2-[(2-chloropyridin-3-yl)oxymethyl]morpholin-4-yl]-3-phenylsulfanylprop-2-en-1-one
    —— 2-Chloro-5-hydroxy-4-(2-methoxyphenyl)sulfanylbenzaldehyde —— C14H11ClO3S
    2-Chloro-5-hydroxy-4-(2-methoxyphenyl)sulfanylbenzaldehyde
    —— (5Z)-6-oxo-5-[[4-[4-[(2Z)-2-(2-oxo-6-sulfonaphthalen-1-ylidene)hydrazinyl]phenyl]sulfanylphenyl]hydrazinylidene]naphthalene-2-sulfonic acid —— C32H22N4O8S3
    (5Z)-6-oxo-5-[[4-[4-[(2Z)-2-(2-oxo-6-sulfonaphthalen-1-ylidene)hydrazinyl]phenyl]sulfanylphenyl]hydrazinylidene]naphthalene-2-sulfonic acid
    —— 6-[2-(Azidomethyl)phenyl]sulfanyl-3-(2-methoxyphenyl)-[1,2,4]triazolo[4,3-a]pyridine —— C20H16N6OS
    6-[2-(Azidomethyl)phenyl]sulfanyl-3-(2-methoxyphenyl)-[1,2,4]triazolo[4,3-a]pyridine
    —— Bis(2-methyl-1,3-dithian-2-yl)-phenylmethanol;butane —— C21H34OS4
    Bis(2-methyl-1,3-dithian-2-yl)-phenylmethanol;butane
    —— 1-[(Z)-[5-(4-methylphenyl)sulfanylfuran-2-yl]methylideneamino]-3-phenylthiourea —— C19H17N3OS2
    1-[(Z)-[5-(4-methylphenyl)sulfanylfuran-2-yl]methylideneamino]-3-phenylthiourea
    —— 3-chloro-N-[(Z)-[5-(4-methylphenyl)sulfanylfuran-2-yl]methylideneamino]benzamide —— C19H15ClN2O2S
    3-chloro-N-[(Z)-[5-(4-methylphenyl)sulfanylfuran-2-yl]methylideneamino]benzamide
    —— 3-Methyl-2-methylidene-5-[(4-methylsulfanylphenyl)methylidene]imidazolidin-4-one —— C13H14N2OS
    3-Methyl-2-methylidene-5-[(4-methylsulfanylphenyl)methylidene]imidazolidin-4-one
    —— prop-2-enyl (2Z)-2-[[5-(3-chlorophenyl)furan-2-yl]methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C29H23ClN2O4S2
    prop-2-enyl (2Z)-2-[[5-(3-chlorophenyl)furan-2-yl]methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— 2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(1Z)-1-(2-chlorophenyl)ethylidene]acetohydrazide —— C19H17ClN4OS3
    2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(1Z)-1-(2-chlorophenyl)ethylidene]acetohydrazide
    —— 8-Ethylsulfanyl-1-methylsulfanyldecane —— C13H28S2
    8-Ethylsulfanyl-1-methylsulfanyldecane
    —— N'-[(3,5-dichloropyridin-4-yl)methyl]-2-(3-methylsulfanylphenyl)iminoacetohydrazide —— C15H14Cl2N4OS
    N'-[(3,5-dichloropyridin-4-yl)methyl]-2-(3-methylsulfanylphenyl)iminoacetohydrazide
    —— 2-(2-{[3-Chloro-5-(trifluoromethyl)-2-pyridinyl]sulfanyl}acetyl)-3-(dimethylamino)acrylonitrile —— C13H11ClF3N3OS
    2-(2-{[3-Chloro-5-(trifluoromethyl)-2-pyridinyl]sulfanyl}acetyl)-3-(dimethylamino)acrylonitrile
    —— (E)-2-(phenylthio)nicotinaldehyde O-3-fluorobenzyl oxime —— C19H15FN2OS
    (E)-2-(phenylthio)nicotinaldehyde O-3-fluorobenzyl oxime
    —— (E)-2-(2-chlorophenylthio)nicotinaldehyde O-2,4-dichlorobenzyl oxime —— C19H13Cl3N2OS
    (E)-2-(2-chlorophenylthio)nicotinaldehyde O-2,4-dichlorobenzyl oxime
    —— (E)-2-(phenylthio)nicotinaldehyde O-4-methylbenzyl oxime —— C20H18N2OS
    (E)-2-(phenylthio)nicotinaldehyde O-4-methylbenzyl oxime
    —— (E)-2-(2,4-dichlorophenylthio)nicotinaldehyde O-2,4-dichlorobenzyl oxime —— C19H12Cl4N2OS
    (E)-2-(2,4-dichlorophenylthio)nicotinaldehyde O-2,4-dichlorobenzyl oxime
    —— 2-{2-[(4-Chlorophenyl)sulfanyl]acetyl}-3-(dimethylamino)acrylonitrile —— C13H13ClN2OS
    2-{2-[(4-Chlorophenyl)sulfanyl]acetyl}-3-(dimethylamino)acrylonitrile
    —— 2,3-Dihydro-[1,4]oxathiino[2,3-b]pyridine —— C7H7NOS
    2,3-Dihydro-[1,4]oxathiino[2,3-b]pyridine
    —— (2E)-3-{4-bromo-5-[(4-chlorophenyl)sulfanyl]furan-2-yl}-2-cyano-N-[2-(1H-indol-3-yl)ethyl]prop-2-enamide —— C24H17BrClN3O2S
    (2E)-3-{4-bromo-5-[(4-chlorophenyl)sulfanyl]furan-2-yl}-2-cyano-N-[2-(1H-indol-3-yl)ethyl]prop-2-enamide
    —— 4-(2,6-Difluorophenyl)sulfanyl-2-(4-fluoro-2-methylphenyl)-7-methylpyrrolo[2,3-d]pyrimidine —— C20H14F3N3S
    4-(2,6-Difluorophenyl)sulfanyl-2-(4-fluoro-2-methylphenyl)-7-methylpyrrolo[2,3-d]pyrimidine
    —— (2Z,2'Z)-Dimethyl 2,2'-(ethane-1,2-diylidene)bis(hydrazinecarbodithioate) —— C6H10N4S4
    (2Z,2'Z)-Dimethyl 2,2'-(ethane-1,2-diylidene)bis(hydrazinecarbodithioate)
    —— 1-(4-Methylcyclohexyl)ethanethione —— C9H16S
    1-(4-Methylcyclohexyl)ethanethione
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2-chlorophenyl)methylideneamino]-5-[(4-chlorophenyl)sulfanylmethyl]triazole-4-carboxamide —— C19H14Cl2N8O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(2-chlorophenyl)methylideneamino]-5-[(4-chlorophenyl)sulfanylmethyl]triazole-4-carboxamide
    —— Methyl 2-[5-[2-cyano-2-(2,3,4,5-tetrahydropyridin-6-yl)acetyl]pyridin-2-yl]sulfanylacetate —— C16H17N3O3S
    Methyl 2-[5-[2-cyano-2-(2,3,4,5-tetrahydropyridin-6-yl)acetyl]pyridin-2-yl]sulfanylacetate
    —— 5-[[2-(4-Bromophenyl)sulfanyl-1-methylindol-3-yl]methylidene]-1-(4-chlorophenyl)-2-sulfanylidene-1,3-diazinane-4,6-dione —— C26H17BrClN3O2S2
    5-[[2-(4-Bromophenyl)sulfanyl-1-methylindol-3-yl]methylidene]-1-(4-chlorophenyl)-2-sulfanylidene-1,3-diazinane-4,6-dione
    —— (5Z)-3-(2-bromobenzyl)-5-{[5-(phenylsulfanyl)furan-2-yl]methylidene}-1,3-thiazolidine-2,4-dione —— C21H14BrNO3S2
    (5Z)-3-(2-bromobenzyl)-5-{[5-(phenylsulfanyl)furan-2-yl]methylidene}-1,3-thiazolidine-2,4-dione
    —— [(Z)-1-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]ethylideneamino]urea —— C15H13ClN4O3S
    [(Z)-1-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]ethylideneamino]urea
    —— amino-[[2-[2-(carbamimidoylsulfanylmethyl)-4-fluorophenyl]sulfanylthiophen-3-yl]methyl]carbamothioic S-acid —— C14H15FN4OS4
    amino-[[2-[2-(carbamimidoylsulfanylmethyl)-4-fluorophenyl]sulfanylthiophen-3-yl]methyl]carbamothioic S-acid
    —— 3-[5-[(2-Tert-butylsulfanylphenyl)methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]propanoic acid —— C17H19NO3S3
    3-[5-[(2-Tert-butylsulfanylphenyl)methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]propanoic acid
    —— N-ethyl-N'-methyl-2-methylsulfanyloxypropane-1,3-diamine —— C7H18N2OS
    N-ethyl-N'-methyl-2-methylsulfanyloxypropane-1,3-diamine
    —— 2-[(3,5-dichloro-1-hydroxypyridin-1-ium-4-yl)methylsulfanyl]-4-(trifluoromethyl)-1H-pyrimidin-6-one —— C11H7Cl2F3N3O2S+
    2-[(3,5-dichloro-1-hydroxypyridin-1-ium-4-yl)methylsulfanyl]-4-(trifluoromethyl)-1H-pyrimidin-6-one
    —— 3,5,5-trimethyl-4-[(Z)-[4-(methylsulfanyl)benzylidene](oxido)-lambda~5~-azanyl]-1,3-thiazolidine-2-thione —— C14H18N2OS3
    3,5,5-trimethyl-4-[(Z)-[4-(methylsulfanyl)benzylidene](oxido)-lambda~5~-azanyl]-1,3-thiazolidine-2-thione
    —— [propanoyl(2-sulfanylethyl)amino]sulfanyl (2S)-5-chloro-5-hydroxy-2-methylpentanoate —— C11H20ClNO4S2
    [propanoyl(2-sulfanylethyl)amino]sulfanyl (2S)-5-chloro-5-hydroxy-2-methylpentanoate
    —— 2-((3-Chloro-5-(trifluoromethyl)-2-pyridinyl)sulfanyl)-4-styrylpyrimidine —— C18H11ClF3N3S
    2-((3-Chloro-5-(trifluoromethyl)-2-pyridinyl)sulfanyl)-4-styrylpyrimidine
    —— 3-((3-Chloro-5-(trifluoromethyl)-2-pyridinyl)sulfanyl)-5-(2-(4-(trifluoromethoxy)phenylamino)vinyl)-4-isothiazolecarbonitrile —— C19H9ClF6N4OS2
    3-((3-Chloro-5-(trifluoromethyl)-2-pyridinyl)sulfanyl)-5-(2-(4-(trifluoromethoxy)phenylamino)vinyl)-4-isothiazolecarbonitrile