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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-methyl-4-(phenylthio)-2-(2-propenyl)-2,5-dihydrothiophene 1,1-dioxide —— C14H16O2S2
    3-methyl-4-(phenylthio)-2-(2-propenyl)-2,5-dihydrothiophene 1,1-dioxide
    —— ethyl 5-[2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate —— C26H24N4O3S
    ethyl 5-[2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetyl]-2,4-dimethyl-1H-pyrrole-3-carboxylate
    —— 3-(2,4-dinitro-phenylsulfanyl)-5-methyl-5<i>H</i>-[1,2,4]triazino[5,6-<i>b</i>]indole 4030-03-9 C16H10N6O4S
    3-(2,4-dinitro-phenylsulfanyl)-5-methyl-5<i>H</i>-[1,2,4]triazino[5,6-<i>b</i>]indole
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[3-(2-oxopyrrolidin-1-yl)propyl]acetamide —— C26H29N5O2S
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[3-(2-oxopyrrolidin-1-yl)propyl]acetamide
    —— 3-methyl-1-(5H-[1,2,4]triazino[5,6-b]indol-3-ylsulfanyl)pyrido[1,2-a]benzimidazole-4-carbonitrile —— C22H13N7S
    3-methyl-1-(5H-[1,2,4]triazino[5,6-b]indol-3-ylsulfanyl)pyrido[1,2-a]benzimidazole-4-carbonitrile
    —— 6-chloro-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]pyridazin-3-amine —— C12H11ClN4S
    6-chloro-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]pyridazin-3-amine
    —— 2-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]cyclohexan-1-one —— C21H19N3OS
    2-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]cyclohexan-1-one
    —— Ethyl 5-[(3-chlorophenyl)sulfanyl]-3-(4-methylphenyl)-1,2,4-triazine-6-carboxylate —— C19H16ClN3O2S
    Ethyl 5-[(3-chlorophenyl)sulfanyl]-3-(4-methylphenyl)-1,2,4-triazine-6-carboxylate
    —— 2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-[1-(2-methoxyethyl)-2,5-dimethylpyrrol-3-yl]ethanone —— C28H30N4O2S
    2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-[1-(2-methoxyethyl)-2,5-dimethylpyrrol-3-yl]ethanone
    —— Ethyl 2-[6-[5-(trifluoromethyl)pyridin-2-yl]sulfanylpyridazin-3-yl]oxypropanoate —— C15H14F3N3O3S
    Ethyl 2-[6-[5-(trifluoromethyl)pyridin-2-yl]sulfanylpyridazin-3-yl]oxypropanoate
    —— 1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]ethanone —— C27H26N4O2S
    1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]ethanone
    —— 2-{[5,6-Bis(4-fluorophenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-butylbutanamide —— C23H24F2N4OS
    2-{[5,6-Bis(4-fluorophenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-butylbutanamide
    —— 10-Bromo-3-(propylsulfanyl)[1,2,4]triazino[5,6-d][3,1]benzoxazepine —— C13H11BrN4OS
    10-Bromo-3-(propylsulfanyl)[1,2,4]triazino[5,6-d][3,1]benzoxazepine
    —— Ethyl 5-[(4-chlorophenyl)sulfanyl]-3-(4-methylphenyl)-1,2,4-triazine-6-carboxylate —— C19H16ClN3O2S
    Ethyl 5-[(4-chlorophenyl)sulfanyl]-3-(4-methylphenyl)-1,2,4-triazine-6-carboxylate
    —— 4-Chlorophenyl 3-phenyl-6-(trifluoromethyl)-1,2,4-triazin-5-yl sulfide —— C16H9ClF3N3S
    4-Chlorophenyl 3-phenyl-6-(trifluoromethyl)-1,2,4-triazin-5-yl sulfide
    —— 2-Methyl-3-methylsulfanyl-1,2,4-triazin-2-ium —— C5H8N3S+
    2-Methyl-3-methylsulfanyl-1,2,4-triazin-2-ium
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[2-(4-fluorophenyl)ethyl]acetamide —— C25H21FN4OS
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-[2-(4-fluorophenyl)ethyl]acetamide
    —— 3-(Hexylsulfanyl)[1,2,4]triazino[5,6-d][3,1]benzoxazepine —— C16H18N4OS
    3-(Hexylsulfanyl)[1,2,4]triazino[5,6-d][3,1]benzoxazepine
    —— 2-{[5,6-Bis(4-fluorophenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-[(2-chlorophenyl)methyl]acetamide —— C24H17ClF2N4OS
    2-{[5,6-Bis(4-fluorophenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-[(2-chlorophenyl)methyl]acetamide
    —— 2-{[5,6-Bis(4-chlorophenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-cyclopentylacetamide —— C22H20Cl2N4OS
    2-{[5,6-Bis(4-chlorophenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-cyclopentylacetamide
    —— 2-{[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-[2-(cyclohex-1-EN-1-YL)ethyl]acetamide —— C27H30N4OS
    2-{[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-[2-(cyclohex-1-EN-1-YL)ethyl]acetamide
    —— N-(1-adamantyl)-2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]acetamide —— C29H32N4OS
    N-(1-adamantyl)-2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]acetamide
    —— [(6-Methoxypyridazin-3-yl)thio]acetic acid —— C7H8N2O3S
    [(6-Methoxypyridazin-3-yl)thio]acetic acid
    —— 2-{[5,6-Bis(4-chlorophenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-butylbutanamide —— C23H24Cl2N4OS
    2-{[5,6-Bis(4-chlorophenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-butylbutanamide
    —— 8,11,11-Trimethyl-5-[(4-methylphenyl)methylsulfanyl]-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene —— C19H23N3S
    8,11,11-Trimethyl-5-[(4-methylphenyl)methylsulfanyl]-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene
    —— 2-[[5,6-bis(3-fluorophenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-butylbutanamide —— C23H24F2N4OS
    2-[[5,6-bis(3-fluorophenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-butylbutanamide
    —— 2-{[5,6-Bis(4-chlorophenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-[2-(cyclohex-1-EN-1-YL)ethyl]acetamide —— C25H24Cl2N4OS
    2-{[5,6-Bis(4-chlorophenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-[2-(cyclohex-1-EN-1-YL)ethyl]acetamide
    —— 2-{[5,6-Bis(4-fluorophenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-[2-(cyclohex-1-EN-1-YL)ethyl]acetamide —— C25H24F2N4OS
    2-{[5,6-Bis(4-fluorophenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-[2-(cyclohex-1-EN-1-YL)ethyl]acetamide
    —— 2-{[5,6-Bis(3-fluorophenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-cyclopentylbutanamide —— C24H24F2N4OS
    2-{[5,6-Bis(3-fluorophenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-cyclopentylbutanamide
    —— (NE)-N-[2,2-dimethyl-1-(5-methylsulfanyltetrazol-2-yl)propylidene]hydroxylamine —— C7H13N5OS
    (NE)-N-[2,2-dimethyl-1-(5-methylsulfanyltetrazol-2-yl)propylidene]hydroxylamine
    —— 5-methyl-3-(4-nitro-phenylsulfanyl)-5<i>H</i>-[1,2,4]triazino[5,6-<i>b</i>]indole 4064-52-2 C16H11N5O2S
    5-methyl-3-(4-nitro-phenylsulfanyl)-5<i>H</i>-[1,2,4]triazino[5,6-<i>b</i>]indole
    —— N-Benzyl-2-{[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-YL]sulfanyl}acetamide —— C26H24N4OS
    N-Benzyl-2-{[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-YL]sulfanyl}acetamide
    —— N-cyclooctyl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide —— C25H28N4OS
    N-cyclooctyl-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide
    —— 5-[(4-Fluorophenyl)methylsulfanyl]-8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene —— C18H20FN3S
    5-[(4-Fluorophenyl)methylsulfanyl]-8,11,11-trimethyl-3,4,6-triazatricyclo[6.2.1.02,7]undeca-2(7),3,5-triene
    —— 2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-(1,2,5-trimethylpyrrol-3-yl)ethanone —— C26H26N4OS
    2-[[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-1-(1,2,5-trimethylpyrrol-3-yl)ethanone
    —— N-[(E)-2-[[3-[(2-chlorophenyl)methylsulfanyl]-1H-1,2,4-triazol-5-yl]amino]-2-nitroso-1-phenylethenyl]hydroxylamine —— C17H15ClN6O2S
    N-[(E)-2-[[3-[(2-chlorophenyl)methylsulfanyl]-1H-1,2,4-triazol-5-yl]amino]-2-nitroso-1-phenylethenyl]hydroxylamine
    —— 2-{[5-(Thiophen-2-yl)-1,2,4-triazin-3-yl]sulfanyl}acetic acid —— C9H7N3O2S2
    2-{[5-(Thiophen-2-yl)-1,2,4-triazin-3-yl]sulfanyl}acetic acid
    —— N-[(E)-2-[(3-benzylsulfanyl-1H-1,2,4-triazol-5-yl)amino]-2-nitroso-1-phenylethenyl]hydroxylamine —— C17H16N6O2S
    N-[(E)-2-[(3-benzylsulfanyl-1H-1,2,4-triazol-5-yl)amino]-2-nitroso-1-phenylethenyl]hydroxylamine
    —— N-[(E)-2-[[3-[(4-chlorophenyl)methylsulfanyl]-1H-1,2,4-triazol-5-yl]amino]-2-nitroso-1-phenylethenyl]hydroxylamine —— C17H15ClN6O2S
    N-[(E)-2-[[3-[(4-chlorophenyl)methylsulfanyl]-1H-1,2,4-triazol-5-yl]amino]-2-nitroso-1-phenylethenyl]hydroxylamine
    —— 3-(2-Oxolanylmethylthio)-5,6-diphenyl-1,2,4-triazine 851789-48-5 C20H19N3OS
    3-(2-Oxolanylmethylthio)-5,6-diphenyl-1,2,4-triazine
    —— N-benzyl-2-(5H-[1,2,4]triazino[6,5-b][1,4]benzothiazin-3-ylsulfanyl)acetamide —— C18H15N5OS2
    N-benzyl-2-(5H-[1,2,4]triazino[6,5-b][1,4]benzothiazin-3-ylsulfanyl)acetamide
    —— 5-[[5-(methylcarbamoyl)-2H-triazol-4-yl]sulfanyl]-N-propan-2-ylthiadiazole-4-carboxamide —— C10H13N7O2S2
    5-[[5-(methylcarbamoyl)-2H-triazol-4-yl]sulfanyl]-N-propan-2-ylthiadiazole-4-carboxamide
    —— N-(1,1-dioxothiolan-3-yl)-2-(5H-[1,2,4]triazino[6,5-b][1,4]benzothiazin-3-ylsulfanyl)acetamide —— C15H15N5O3S3
    N-(1,1-dioxothiolan-3-yl)-2-(5H-[1,2,4]triazino[6,5-b][1,4]benzothiazin-3-ylsulfanyl)acetamide
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(oxolan-2-ylmethyl)propanamide 851208-27-0 C23H24N4O2S
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(oxolan-2-ylmethyl)propanamide
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(3-methylbutan-2-yl)acetamide —— C22H24N4OS
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(3-methylbutan-2-yl)acetamide
    —— N-[2-(2,4-dioxo-1,3-thiazolidin-3-yl)ethyl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide —— C22H19N5O3S2
    N-[2-(2,4-dioxo-1,3-thiazolidin-3-yl)ethyl]-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide
    —— N-(1-cyano-1-cyclopropylethyl)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide —— C23H21N5OS
    N-(1-cyano-1-cyclopropylethyl)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]acetamide
    —— 6,7-dimethoxy-2-(5H-[1,2,4]triazino[6,5-b][1,4]benzothiazin-3-ylsulfanylmethyl)-3H-quinazolin-4-one —— C20H16N6O3S2
    6,7-dimethoxy-2-(5H-[1,2,4]triazino[6,5-b][1,4]benzothiazin-3-ylsulfanylmethyl)-3H-quinazolin-4-one
    —— [6-(3,5-dimethyl-1H-pyrazol-1-yl)pyridazin-3-ylsulfanyl]acetic acid —— C11H12N4O2S
    [6-(3,5-dimethyl-1H-pyrazol-1-yl)pyridazin-3-ylsulfanyl]acetic acid
    —— 2-(5H-[1,2,4]triazino[6,5-b][1,4]benzothiazin-3-ylsulfanyl)-N-(2,3,4-trifluorophenyl)acetamide —— C17H10F3N5OS2
    2-(5H-[1,2,4]triazino[6,5-b][1,4]benzothiazin-3-ylsulfanyl)-N-(2,3,4-trifluorophenyl)acetamide