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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 5-(3,3-Dimethyl-5-methylthio-3,4-dihydropyrrol-2-ylidenemethyl)-1,4,4,5-tetramethylpyrrolidine-2-thione —— C16H26N2S2
    5-(3,3-Dimethyl-5-methylthio-3,4-dihydropyrrol-2-ylidenemethyl)-1,4,4,5-tetramethylpyrrolidine-2-thione
    —— (3S)-N-[4-[4-[[(3S)-1,1-dioxothiolan-3-yl]sulfonylamino]phenyl]sulfanylphenyl]-1,1-dioxothiolane-3-sulfonamide —— C20H24N2O8S5
    (3S)-N-[4-[4-[[(3S)-1,1-dioxothiolan-3-yl]sulfonylamino]phenyl]sulfanylphenyl]-1,1-dioxothiolane-3-sulfonamide
    —— (3R)-N-[4-[4-[[(3S)-1,1-dioxothiolan-3-yl]sulfonylamino]phenyl]sulfanylphenyl]-1,1-dioxothiolane-3-sulfonamide —— C20H24N2O8S5
    (3R)-N-[4-[4-[[(3S)-1,1-dioxothiolan-3-yl]sulfonylamino]phenyl]sulfanylphenyl]-1,1-dioxothiolane-3-sulfonamide
    —— Pyrrolidine-5-thione, 3,3-dimethyl-2-[5-(methylthio)-3,4-dihydro-2,3,3-trimethyl-2(2H)pyrrolyl]methylene- —— C15H24N2S2
    Pyrrolidine-5-thione, 3,3-dimethyl-2-[5-(methylthio)-3,4-dihydro-2,3,3-trimethyl-2(2H)pyrrolyl]methylene-
    —— (3R)-N-[4-[4-[[(3R)-1,1-dioxothiolan-3-yl]sulfonylamino]phenyl]sulfanylphenyl]-1,1-dioxothiolane-3-sulfonamide —— C20H24N2O8S5
    (3R)-N-[4-[4-[[(3R)-1,1-dioxothiolan-3-yl]sulfonylamino]phenyl]sulfanylphenyl]-1,1-dioxothiolane-3-sulfonamide
    —— ethyl (1Z)-N-(3-methylsulfanyl-1,2,4-thiadiazol-5-yl)methanehydrazonate —— C6H10N4OS2
    ethyl (1Z)-N-(3-methylsulfanyl-1,2,4-thiadiazol-5-yl)methanehydrazonate
    —— Cyclopenteno[4.3-b]tetrahydrofuran, 3-[(4-methyl-5-oxo-3-phenylthio)tetrahydrofuran-2-yloxymethylene]- —— C19H18O5S
    Cyclopenteno[4.3-b]tetrahydrofuran, 3-[(4-methyl-5-oxo-3-phenylthio)tetrahydrofuran-2-yloxymethylene]-
    —— Pyridine, 2-(3-chloro-4,4,4-trifluoro-2-phenyl-2-butenylthio)-5,5,5-trifluoromethyl- —— C16H10ClF6NS
    Pyridine, 2-(3-chloro-4,4,4-trifluoro-2-phenyl-2-butenylthio)-5,5,5-trifluoromethyl-
    —— (3Z)-3-[(4-methylanilino)methylidene]-1-benzothiophene-2-thione —— C16H13NS2
    (3Z)-3-[(4-methylanilino)methylidene]-1-benzothiophene-2-thione
    —— (3,3-Dimethyl-5-methylthio-3,4(2H)-dihydropyrrol-2-ylidene)acetonitrile —— C9H12N2S
    (3,3-Dimethyl-5-methylthio-3,4(2H)-dihydropyrrol-2-ylidene)acetonitrile
    —— (3E)-3-(anilinomethylidene)-1-benzothiophene-2-thione —— C15H11NS2
    (3E)-3-(anilinomethylidene)-1-benzothiophene-2-thione
    —— 2-Pyrrolidinone, 5-[[(3,4-dihydro-2H-pyrrol-5-yl)thio]methylene]-4,4-dimethyl- —— C11H16N2OS
    2-Pyrrolidinone, 5-[[(3,4-dihydro-2H-pyrrol-5-yl)thio]methylene]-4,4-dimethyl-
    —— (5Z)-3-(4-ethoxyphenyl)-5-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C23H19NO3S3
    (5Z)-3-(4-ethoxyphenyl)-5-[[5-(4-methylphenyl)sulfanylfuran-2-yl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (5Z)-5-[[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-3-(4-ethoxyphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one —— C22H16ClNO3S3
    (5Z)-5-[[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-3-(4-ethoxyphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one
    —— 2-(4-bromophenyl)sulfanyl-N-[(1R,2R,3R)-2,3-dimethylcyclohexyl]-5-morpholin-4-ylsulfonylbenzamide —— C25H31BrN2O4S2
    2-(4-bromophenyl)sulfanyl-N-[(1R,2R,3R)-2,3-dimethylcyclohexyl]-5-morpholin-4-ylsulfonylbenzamide
    —— 2-(4-bromophenyl)sulfanyl-N-[(1R,2R,3S)-2,3-dimethylcyclohexyl]-5-morpholin-4-ylsulfonylbenzamide —— C25H31BrN2O4S2
    2-(4-bromophenyl)sulfanyl-N-[(1R,2R,3S)-2,3-dimethylcyclohexyl]-5-morpholin-4-ylsulfonylbenzamide
    —— 2-(4-bromophenyl)sulfanyl-N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]-5-morpholin-4-ylsulfonylbenzamide —— C25H31BrN2O4S2
    2-(4-bromophenyl)sulfanyl-N-[(1S,2R,3S)-2,3-dimethylcyclohexyl]-5-morpholin-4-ylsulfonylbenzamide
    —— 2-Cyano-3-[5-methylthio-2-furanyl]-2-propenoic acid, methyl ester 76542-54-6 C10H9NO3S
    2-Cyano-3-[5-methylthio-2-furanyl]-2-propenoic acid, methyl ester
    —— 2-(4-bromophenyl)sulfanyl-N-[(1S,2R,3R)-2,3-dimethylcyclohexyl]-5-morpholin-4-ylsulfonylbenzamide —— C25H31BrN2O4S2
    2-(4-bromophenyl)sulfanyl-N-[(1S,2R,3R)-2,3-dimethylcyclohexyl]-5-morpholin-4-ylsulfonylbenzamide
    —— (5Z)-5-[(4-bromophenyl)-hydroxymethylidene]-4-thia-2-azatricyclo[7.3.0.03,7]dodeca-1,3(7),8-trien-6-one —— C17H12BrNO2S
    (5Z)-5-[(4-bromophenyl)-hydroxymethylidene]-4-thia-2-azatricyclo[7.3.0.03,7]dodeca-1,3(7),8-trien-6-one
    —— 2-(1-Propenylthio)thiophene —— C7H8S2
    2-(1-Propenylthio)thiophene
    —— (Z)-1-(3-nitro-4-quinolin-5-ylsulfanylphenyl)-N-(1,2,4-triazol-4-yl)methanimine —— C18H12N6O2S
    (Z)-1-(3-nitro-4-quinolin-5-ylsulfanylphenyl)-N-(1,2,4-triazol-4-yl)methanimine
    —— 1-(Ethylthio)-2-(methylthio)-buta-1,3-diene —— C7H12S2
    1-(Ethylthio)-2-(methylthio)-buta-1,3-diene
    —— N,N-dimethyl-2-[(2Z)-2-[[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylidene]hydrazinyl]-5-nitrobenzenesulfonamide —— C19H19N7O6S2
    N,N-dimethyl-2-[(2Z)-2-[[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylidene]hydrazinyl]-5-nitrobenzenesulfonamide
    —— 8-[(2,4-Dinitrophenyl)sulfanyl]-9H-purin-6-amine —— C11H7N7O4S
    8-[(2,4-Dinitrophenyl)sulfanyl]-9H-purin-6-amine
    —— N,N-Dimethyl-4-(methylsulfonyl)-1,3-cyclooctadien-1-amine —— C11H19NO2S
    N,N-Dimethyl-4-(methylsulfonyl)-1,3-cyclooctadien-1-amine
    —— Ethyl 2-[4-[[2-(1,3-benzothiazol-2-ylsulfanyl)-5-nitrophenyl]methylideneamino]phenyl]acetate —— C24H19N3O4S2
    Ethyl 2-[4-[[2-(1,3-benzothiazol-2-ylsulfanyl)-5-nitrophenyl]methylideneamino]phenyl]acetate
    —— N-(2,4-dimethoxyphenyl)-1-[2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-5-nitrophenyl]methanimine —— C18H17N5O4S
    N-(2,4-dimethoxyphenyl)-1-[2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-5-nitrophenyl]methanimine
    —— (Z)-1-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]-N-(1,2,4-triazol-4-yl)methanimine —— C12H10N8O2S
    (Z)-1-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]-N-(1,2,4-triazol-4-yl)methanimine
    —— 2-[4-[(2,4-Dimethoxyphenyl)iminomethyl]-2-nitrophenyl]sulfanyl-3-methylquinazolin-4-one —— C24H20N4O5S
    2-[4-[(2,4-Dimethoxyphenyl)iminomethyl]-2-nitrophenyl]sulfanyl-3-methylquinazolin-4-one
    —— Ethyl 2-[4-[[4-[(4-methyl-5-phenyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]phenyl]acetate —— C26H23N5O4S
    Ethyl 2-[4-[[4-[(4-methyl-5-phenyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]phenyl]acetate
    —— (Z)-1-[2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-5-nitrophenyl]-N-(1,2,4-triazol-4-yl)methanimine —— C12H10N8O2S
    (Z)-1-[2-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-5-nitrophenyl]-N-(1,2,4-triazol-4-yl)methanimine
    —— [(Z)-[4-(3-methyl-4-oxoquinazolin-2-yl)sulfanyl-3-nitrophenyl]methylideneamino]thiourea —— C17H14N6O3S2
    [(Z)-[4-(3-methyl-4-oxoquinazolin-2-yl)sulfanyl-3-nitrophenyl]methylideneamino]thiourea
    —— 3-methyl-2-[2-nitro-4-[(Z)-1,2,4-triazol-4-yliminomethyl]phenyl]sulfanylquinazolin-4-one —— C18H13N7O3S
    3-methyl-2-[2-nitro-4-[(Z)-1,2,4-triazol-4-yliminomethyl]phenyl]sulfanylquinazolin-4-one
    —— 1-[2-(1,3-benzothiazol-2-ylsulfanyl)-5-nitrophenyl]-N-(2,4-dimethoxyphenyl)methanimine —— C22H17N3O4S2
    1-[2-(1,3-benzothiazol-2-ylsulfanyl)-5-nitrophenyl]-N-(2,4-dimethoxyphenyl)methanimine
    —— (Z)-1-[4-[(4-methyl-5-phenyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]-N-(1,2,4-triazol-4-yl)methanimine —— C18H14N8O2S
    (Z)-1-[4-[(4-methyl-5-phenyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]-N-(1,2,4-triazol-4-yl)methanimine
    —— N-(2,4-dimethoxyphenyl)-1-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methanimine —— C18H17N5O4S
    N-(2,4-dimethoxyphenyl)-1-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methanimine
    —— N-(2,4-dimethoxyphenyl)-1-[4-[(4-methyl-5-phenyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methanimine —— C24H21N5O4S
    N-(2,4-dimethoxyphenyl)-1-[4-[(4-methyl-5-phenyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methanimine
    —— N-[(Z)-[4-(3-methyl-4-oxoquinazolin-2-yl)sulfanyl-3-nitrophenyl]methylideneamino]benzenecarbothioamide —— C23H17N5O3S2
    N-[(Z)-[4-(3-methyl-4-oxoquinazolin-2-yl)sulfanyl-3-nitrophenyl]methylideneamino]benzenecarbothioamide
    —— 3-methyl-2-[2-nitro-4-[(Z)-[(4-nitrophenyl)hydrazinylidene]methyl]phenyl]sulfanylquinazolin-4-one —— C22H16N6O5S
    3-methyl-2-[2-nitro-4-[(Z)-[(4-nitrophenyl)hydrazinylidene]methyl]phenyl]sulfanylquinazolin-4-one
    —— 2-[[5-[(4-chloroanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-pyridin-4-ylmethylideneamino]acetamide —— C20H20ClN7OS
    2-[[5-[(4-chloroanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-pyridin-4-ylmethylideneamino]acetamide
    —— (2S)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-(4-methylphenyl)ethylideneamino]propanamide —— C24H28N6OS
    (2S)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-(4-methylphenyl)ethylideneamino]propanamide
    —— (2R)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-(4-methylphenyl)ethylideneamino]propanamide —— C24H28N6OS
    (2R)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-(4-methylphenyl)ethylideneamino]propanamide
    —— 2-[[5-[(4-chloroanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(3-hydroxyphenyl)methylideneamino]acetamide —— C21H21ClN6O2S
    2-[[5-[(4-chloroanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(3-hydroxyphenyl)methylideneamino]acetamide
    —— 2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-(4-methylphenyl)ethylideneamino]acetamide —— C24H28N6OS
    2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-(4-methylphenyl)ethylideneamino]acetamide
    —— N-[(Z)-(4-bromophenyl)methylideneamino]-2-(2-methylphenyl)sulfanylacetamide —— C16H15BrN2OS
    N-[(Z)-(4-bromophenyl)methylideneamino]-2-(2-methylphenyl)sulfanylacetamide
    —— N-[(Z)-(4-chlorophenyl)methylideneamino]-2-(2-methylphenyl)sulfanylacetamide —— C16H15ClN2OS
    N-[(Z)-(4-chlorophenyl)methylideneamino]-2-(2-methylphenyl)sulfanylacetamide
    —— N-(4-methoxyphenyl)-1-[5-[[5-(naphthalen-1-ylmethyl)-4-phenyl-1,2,4-triazol-3-yl]sulfanyl]furan-2-yl]methanimine —— C31H24N4O2S
    N-(4-methoxyphenyl)-1-[5-[[5-(naphthalen-1-ylmethyl)-4-phenyl-1,2,4-triazol-3-yl]sulfanyl]furan-2-yl]methanimine
    —— N-(2-methylsulfanyl-1,3-benzothiazol-6-yl)-1-(3-nitro-4-pyridin-2-ylsulfanylphenyl)methanimine —— C20H14N4O2S3
    N-(2-methylsulfanyl-1,3-benzothiazol-6-yl)-1-(3-nitro-4-pyridin-2-ylsulfanylphenyl)methanimine
    —— 2,3-Disila-5-heptene, 2,2,3,3,4-pentamethyl-4-(phenylthio)- —— C16H28SSi2
    2,3-Disila-5-heptene, 2,2,3,3,4-pentamethyl-4-(phenylthio)-