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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N'-{(E)-[4-(methylsulfanyl)phenyl]methylidene}-2-(pyrimidin-2-ylsulfanyl)acetohydrazide —— C14H14N4OS2
    N'-{(E)-[4-(methylsulfanyl)phenyl]methylidene}-2-(pyrimidin-2-ylsulfanyl)acetohydrazide
    —— 5-[(E)-2-(dimethylamino)ethenyl]-3-(methylsulfanyl)-1,2-thiazole-4-carbonitrile —— C9H11N3S2
    5-[(E)-2-(dimethylamino)ethenyl]-3-(methylsulfanyl)-1,2-thiazole-4-carbonitrile
    —— (3R)-3-[ethyl-[2-(2-fluorophenyl)sulfanylethyl]amino]butanoic acid —— C14H20FNO2S
    (3R)-3-[ethyl-[2-(2-fluorophenyl)sulfanylethyl]amino]butanoic acid
    —— (2R)-2-isothiocyanatobutane —— C5H9NS
    (2R)-2-isothiocyanatobutane
    —— (3S)-3-[ethyl-[2-(2-fluorophenyl)sulfanylethyl]amino]butanoic acid —— C14H20FNO2S
    (3S)-3-[ethyl-[2-(2-fluorophenyl)sulfanylethyl]amino]butanoic acid
    —— (Z)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(2-chlorophenyl)methanimine —— C16H13ClN4S
    (Z)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(2-chlorophenyl)methanimine
    —— (Z)-1-(4-chlorophenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C17H15ClN4S
    (Z)-1-(4-chlorophenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— (Z)-1-(4-ethylphenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C19H20N4S
    (Z)-1-(4-ethylphenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— (Z)-1-(4-methylphenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C18H18N4S
    (Z)-1-(4-methylphenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— (Z)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-pyridin-2-ylmethanimine —— C16H15N5S
    (Z)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-pyridin-2-ylmethanimine
    —— (Z)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-pyridin-4-ylmethanimine —— C16H15N5S
    (Z)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]-1-pyridin-4-ylmethanimine
    —— (Z)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(4-fluorophenyl)methanimine —— C16H13FN4S
    (Z)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(4-fluorophenyl)methanimine
    —— (Z)-1-(2-chlorophenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C17H15ClN4S
    (Z)-1-(2-chlorophenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— (Z)-1-(4-fluorophenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C17H15FN4S
    (Z)-1-(4-fluorophenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— (Z)-1-(3-chlorophenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine —— C17H15ClN4S
    (Z)-1-(3-chlorophenyl)-N-[3-[(4-methylphenyl)methylsulfanyl]-1,2,4-triazol-4-yl]methanimine
    —— (Z)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(3-chlorophenyl)methanimine —— C16H13ClN4S
    (Z)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(3-chlorophenyl)methanimine
    —— (Z)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(4-methylphenyl)methanimine —— C17H16N4S
    (Z)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(4-methylphenyl)methanimine
    —— (3R)-3-[ethyl-(2-thiophen-2-ylsulfanylacetyl)amino]butanoic acid —— C12H17NO3S2
    (3R)-3-[ethyl-(2-thiophen-2-ylsulfanylacetyl)amino]butanoic acid
    —— (3S)-3-[ethyl-(2-thiophen-2-ylsulfanylacetyl)amino]butanoic acid —— C12H17NO3S2
    (3S)-3-[ethyl-(2-thiophen-2-ylsulfanylacetyl)amino]butanoic acid
    —— 2-[(3R,5R)-5-methyl-2-oxooxolan-3-yl]sulfanyl-6-thiophen-2-yl-4-(trifluoromethyl)pyridine-3-carbonitrile —— C16H11F3N2O2S2
    2-[(3R,5R)-5-methyl-2-oxooxolan-3-yl]sulfanyl-6-thiophen-2-yl-4-(trifluoromethyl)pyridine-3-carbonitrile
    —— (Z)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(2-fluorophenyl)methanimine —— C16H13FN4S
    (Z)-N-(3-benzylsulfanyl-1,2,4-triazol-4-yl)-1-(2-fluorophenyl)methanimine
    —— (2R)-2-(3,4-difluorophenyl)sulfanyl-1-(4-ethylpiperazin-1-yl)propan-1-one —— C15H20F2N2OS
    (2R)-2-(3,4-difluorophenyl)sulfanyl-1-(4-ethylpiperazin-1-yl)propan-1-one
    —— N-cyclopentyl-2-(3,4-difluorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C17H21F2NO3S2
    N-cyclopentyl-2-(3,4-difluorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— (2S)-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]cyclohexan-1-one —— C14H22N4O2S
    (2S)-2-[(4-ethyl-5-morpholin-4-yl-1,2,4-triazol-3-yl)sulfanyl]cyclohexan-1-one
    —— N-butyl-2-(3,4-difluorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide —— C16H21F2NO3S2
    N-butyl-2-(3,4-difluorophenyl)sulfanyl-N-[(3S)-1,1-dioxothiolan-3-yl]acetamide
    —— 2-[4-oxo-1-[[(3S)-oxolan-3-yl]methyl]pyrimidin-2-yl]sulfanylacetic acid —— C11H14N2O4S
    2-[4-oxo-1-[[(3S)-oxolan-3-yl]methyl]pyrimidin-2-yl]sulfanylacetic acid
    —— 2-[4-oxo-1-[[(3R)-oxolan-3-yl]methyl]pyrimidin-2-yl]sulfanylacetic acid —— C11H14N2O4S
    2-[4-oxo-1-[[(3R)-oxolan-3-yl]methyl]pyrimidin-2-yl]sulfanylacetic acid
    —— 2-[[4-[[(3S)-oxolan-3-yl]methyl]-5-propyl-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C12H19N3O3S
    2-[[4-[[(3S)-oxolan-3-yl]methyl]-5-propyl-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (2S)-N,N-dimethyl-2-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide —— C16H21N3O2S
    (2S)-N,N-dimethyl-2-[[5-[(2R)-2-phenylpropyl]-1,3,4-oxadiazol-2-yl]sulfanyl]propanamide
    —— 2-[[4-[[(3R)-oxolan-3-yl]methyl]-5-propyl-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C12H19N3O3S
    2-[[4-[[(3R)-oxolan-3-yl]methyl]-5-propyl-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (2S)-N,N-dimethyl-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylpropanamide —— C11H13F3N2OS
    (2S)-N,N-dimethyl-2-[5-(trifluoromethyl)pyridin-2-yl]sulfanylpropanamide
    —— (2R)-N,N-dimethyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide —— C9H14N2OS2
    (2R)-N,N-dimethyl-2-[(4-methyl-1,3-thiazol-2-yl)sulfanyl]propanamide
    —— 2-[(1R)-1-pyridin-2-ylsulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole —— C13H11N3OS2
    2-[(1R)-1-pyridin-2-ylsulfanylethyl]-5-thiophen-2-yl-1,3,4-oxadiazole
    —— 2-[(1R)-1-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-5-(4-methylphenyl)-1,3,4-oxadiazole —— C16H19N5O2S
    2-[(1R)-1-[[4-(2-methoxyethyl)-1,2,4-triazol-3-yl]sulfanyl]ethyl]-5-(4-methylphenyl)-1,3,4-oxadiazole
    —— N-[(Z)-benzylideneamino]-2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]acetamide —— C12H11N5O3S
    N-[(Z)-benzylideneamino]-2-[(3,5-dioxo-2H-1,2,4-triazin-6-yl)sulfanyl]acetamide
    —— N-[(Z)-(3-methylfuran-2-yl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide —— C13H13N3O2S
    N-[(Z)-(3-methylfuran-2-yl)methylideneamino]-2-pyridin-2-ylsulfanylacetamide
    —— (Z)-3-(4-chlorophenyl)sulfanyl-4-(dimethylamino)but-3-en-2-one —— C12H14ClNOS
    (Z)-3-(4-chlorophenyl)sulfanyl-4-(dimethylamino)but-3-en-2-one
    —— 4,6-dimethyl-1-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-2-oxopyridine-3-carbonitrile —— C16H15N3OS
    4,6-dimethyl-1-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-2-oxopyridine-3-carbonitrile
    —— methyl (5Z)-2-methyl-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-1H-pyrrole-3-carboxylate —— C15H15NO3S
    methyl (5Z)-2-methyl-5-[(4-methylsulfanylphenyl)methylidene]-4-oxo-1H-pyrrole-3-carboxylate
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-(4-fluorophenyl)methylideneamino]acetamide —— C11H10FN5OS2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-(4-fluorophenyl)methylideneamino]acetamide
    —— 2-[(1S)-cyclopent-2-en-1-yl]-N-[3-[4-(2-methylpropyl)-5-methylsulfanyl-1,2,4-triazol-3-yl]propyl]acetamide —— C17H28N4OS
    2-[(1S)-cyclopent-2-en-1-yl]-N-[3-[4-(2-methylpropyl)-5-methylsulfanyl-1,2,4-triazol-3-yl]propyl]acetamide
    —— (1R)-N-(2-phenylsulfanylethyl)cyclohex-3-ene-1-carboxamide —— C15H19NOS
    (1R)-N-(2-phenylsulfanylethyl)cyclohex-3-ene-1-carboxamide
    —— (1R,2R)-2-methyl-N-(2-phenylsulfanylethyl)cyclopropane-1-carboxamide —— C13H17NOS
    (1R,2R)-2-methyl-N-(2-phenylsulfanylethyl)cyclopropane-1-carboxamide
    —— 2-[(1S)-cyclopent-2-en-1-yl]-N-(2-phenylsulfanylethyl)acetamide —— C15H19NOS
    2-[(1S)-cyclopent-2-en-1-yl]-N-(2-phenylsulfanylethyl)acetamide
    —— (2S)-N-[3-[4-(2-methylpropyl)-5-methylsulfanyl-1,2,4-triazol-3-yl]propyl]oxolane-2-carboxamide —— C15H26N4O2S
    (2S)-N-[3-[4-(2-methylpropyl)-5-methylsulfanyl-1,2,4-triazol-3-yl]propyl]oxolane-2-carboxamide
    —— 3-(2-fluorophenyl)-N-(2-phenylsulfanylethyl)propanamide —— C17H18FNOS
    3-(2-fluorophenyl)-N-(2-phenylsulfanylethyl)propanamide
    —— 2-[(3-methylphenyl)methylsulfanyl]-N-(2-phenylsulfanylethyl)acetamide —— C18H21NOS2
    2-[(3-methylphenyl)methylsulfanyl]-N-(2-phenylsulfanylethyl)acetamide
    —— 3-(4-fluorophenyl)-N-(2-phenylsulfanylethyl)propanamide —— C17H18FNOS
    3-(4-fluorophenyl)-N-(2-phenylsulfanylethyl)propanamide
    —— (1R)-N-[3-[4-(2-methylpropyl)-5-methylsulfanyl-1,2,4-triazol-3-yl]propyl]cyclohex-3-ene-1-carboxamide —— C17H28N4OS
    (1R)-N-[3-[4-(2-methylpropyl)-5-methylsulfanyl-1,2,4-triazol-3-yl]propyl]cyclohex-3-ene-1-carboxamide
    —— 6-tert-butyl-4-[(Z)-(4-chlorophenyl)methylideneamino]-3-methylsulfanyl-1,2,4-triazin-5-one —— C15H17ClN4OS
    6-tert-butyl-4-[(Z)-(4-chlorophenyl)methylideneamino]-3-methylsulfanyl-1,2,4-triazin-5-one