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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[(Z)-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylideneamino]octanamide —— C19H25N5O3S
    N-[(Z)-[4-(1-methylimidazol-2-yl)sulfanyl-3-nitrophenyl]methylideneamino]octanamide
    —— (5Z)-2-phenyl-3-(5-phenylsulfanyl-1H-indol-2-yl)-5-[(3,4,5-trimethoxyphenyl)methylidene]imidazol-4-one —— C33H27N3O4S
    (5Z)-2-phenyl-3-(5-phenylsulfanyl-1H-indol-2-yl)-5-[(3,4,5-trimethoxyphenyl)methylidene]imidazol-4-one
    —— methyl (2E)-2-[[4-(dimethylamino)phenyl]methylidene]-1,3-benzodithiole-5-carboxylate —— C18H17NO2S2
    methyl (2E)-2-[[4-(dimethylamino)phenyl]methylidene]-1,3-benzodithiole-5-carboxylate
    —— 1-[(2R)-butan-2-yl]-3-(2-methylsulfonylethyl)urea —— C8H18N2O3S
    1-[(2R)-butan-2-yl]-3-(2-methylsulfonylethyl)urea
    —— (5Z)-5-[(4-hydroxy-3-methoxyphenyl)methylidene]-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)imidazol-4-one —— C30H22N4O3S
    (5Z)-5-[(4-hydroxy-3-methoxyphenyl)methylidene]-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)imidazol-4-one
    —— (5Z)-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)-5-[(2-sulfanylphenyl)methylidene]imidazol-4-one —— C29H20N4OS2
    (5Z)-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)-5-[(2-sulfanylphenyl)methylidene]imidazol-4-one
    —— (5Z)-5-[(3-nitrophenyl)methylidene]-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)imidazol-4-one —— C29H19N5O3S
    (5Z)-5-[(3-nitrophenyl)methylidene]-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)imidazol-4-one
    —— (5Z)-5-[(4-chlorophenyl)methylidene]-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)imidazol-4-one —— C29H19ClN4OS
    (5Z)-5-[(4-chlorophenyl)methylidene]-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)imidazol-4-one
    —— (5Z)-5-[2-(furan-2-yl)ethylidene]-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)imidazol-4-one —— C28H20N4O2S
    (5Z)-5-[2-(furan-2-yl)ethylidene]-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)imidazol-4-one
    —— (5Z)-5-[[4-(dimethylamino)phenyl]methylidene]-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)imidazol-4-one —— C31H25N5OS
    (5Z)-5-[[4-(dimethylamino)phenyl]methylidene]-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)imidazol-4-one
    —— 1-[(2S)-butan-2-yl]-3-(2-methylsulfonylethyl)urea —— C8H18N2O3S
    1-[(2S)-butan-2-yl]-3-(2-methylsulfonylethyl)urea
    —— (5Z)-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)-5-[(3,4,5-trimethoxyphenyl)methylidene]imidazol-4-one —— C32H26N4O4S
    (5Z)-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)-5-[(3,4,5-trimethoxyphenyl)methylidene]imidazol-4-one
    —— (5Z)-5-[(E)-2-oxo-4-phenylbut-3-enylidene]-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)imidazol-4-one —— C32H22N4O2S
    (5Z)-5-[(E)-2-oxo-4-phenylbut-3-enylidene]-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)imidazol-4-one
    —— (5Z)-5-[(4-methylsulfanylphenyl)methylidene]-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)imidazol-4-one —— C30H22N4OS2
    (5Z)-5-[(4-methylsulfanylphenyl)methylidene]-2-phenyl-3-(6-phenylsulfanyl-1H-benzimidazol-2-yl)imidazol-4-one
    —— 4-[(Z)-(5-ethylsulfanylimidazo[5,1-e]tetrazol-7-ylidene)methyl]-N,N-dimethylaniline —— C14H16N6S
    4-[(Z)-(5-ethylsulfanylimidazo[5,1-e]tetrazol-7-ylidene)methyl]-N,N-dimethylaniline
    —— (2E)-6,7-dichloro-2-(6,7-dichloro-3-oxo-1-benzothiophen-2-ylidene)-1-benzothiophen-3-one —— C16H4Cl4O2S2
    (2E)-6,7-dichloro-2-(6,7-dichloro-3-oxo-1-benzothiophen-2-ylidene)-1-benzothiophen-3-one
    —— [(Z)-(3-methylsulfanyl-6,7-dihydro-5H-2-benzothiophen-4-ylidene)amino]urea —— C10H13N3OS2
    [(Z)-(3-methylsulfanyl-6,7-dihydro-5H-2-benzothiophen-4-ylidene)amino]urea
    —— 1,2,5,6-tetrathiocin —— C4H4S4
    1,2,5,6-tetrathiocin
    —— Methyl {5'-(phenylimino)-spiro[adamantane-2,2'-[1,3]oxathiolane]-4'-ylidene}acetate —— C21H23NO3S
    Methyl {5'-(phenylimino)-spiro[adamantane-2,2'-[1,3]oxathiolane]-4'-ylidene}acetate
    —— (7Z)-5-ethylsulfanyl-7-(2-furylmethylene)imidazo[5,1-e]tetrazole —— C10H9N5OS
    (7Z)-5-ethylsulfanyl-7-(2-furylmethylene)imidazo[5,1-e]tetrazole
    —— (1E)-1-(3-methylsulfanylpropylsulfanyl)cyclododecene —— C16H30S2
    (1E)-1-(3-methylsulfanylpropylsulfanyl)cyclododecene
    —— [(Z)-2,3-dichloroprop-2-enyl] thiocyanate —— C4H3Cl2NS
    [(Z)-2,3-dichloroprop-2-enyl] thiocyanate
    —— 2-[[5-[(3R)-oxan-3-yl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C9H13N3O3S
    2-[[5-[(3R)-oxan-3-yl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 2-[[5-[(3R)-oxan-3-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetic acid —— C9H12N2O4S
    2-[[5-[(3R)-oxan-3-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetic acid
    —— 2-[[5-[(3S)-oxan-3-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetic acid —— C9H12N2O4S
    2-[[5-[(3S)-oxan-3-yl]-1,3,4-oxadiazol-2-yl]sulfanyl]acetic acid
    —— 2-[[5-[(3S)-oxan-3-yl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C9H13N3O3S
    2-[[5-[(3S)-oxan-3-yl]-1H-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— (3S,3aR,10Z)-3-phenylsulfanyl-2,3,3a,5,6,7,8,9-octahydro-1H-cyclopenta[9]annulen-4-one —— C18H22OS
    (3S,3aR,10Z)-3-phenylsulfanyl-2,3,3a,5,6,7,8,9-octahydro-1H-cyclopenta[9]annulen-4-one
    —— 13-amino-4-methyl-10-oxo-14-thia-2,3,7,8,11,12-hexazatricyclo[7.5.0.02,6]tetradeca-1(9),3,5,7,12-pentaene-5-carbonitrile —— C9H6N8OS
    13-amino-4-methyl-10-oxo-14-thia-2,3,7,8,11,12-hexazatricyclo[7.5.0.02,6]tetradeca-1(9),3,5,7,12-pentaene-5-carbonitrile
    —— (2S)-1-(2-amino-4,6-dihydropyrrolo[3,4-d][1,3]thiazol-5-yl)-2-phenylsulfanylpropan-1-one —— C14H15N3OS2
    (2S)-1-(2-amino-4,6-dihydropyrrolo[3,4-d][1,3]thiazol-5-yl)-2-phenylsulfanylpropan-1-one
    —— (2R)-1-(2-amino-4,6-dihydropyrrolo[3,4-d][1,3]thiazol-5-yl)-2-phenylsulfanylpropan-1-one —— C14H15N3OS2
    (2R)-1-(2-amino-4,6-dihydropyrrolo[3,4-d][1,3]thiazol-5-yl)-2-phenylsulfanylpropan-1-one
    —— 3-Acetyl-5-methylmercapto-1,3,4-thiadiazolidone-2-azine —— C10H12N6O2S4
    3-Acetyl-5-methylmercapto-1,3,4-thiadiazolidone-2-azine
    —— 3-Acetyl-5-benzylmercapto-1,3,4-thiadiazolidone-2-azine —— C22H20N6O2S4
    3-Acetyl-5-benzylmercapto-1,3,4-thiadiazolidone-2-azine
    —— (4-Bromophenylsulfanyl)pyruvate —— C9H6BrO3S-
    (4-Bromophenylsulfanyl)pyruvate
    —— 6,6-Dimethyl-1-[3-(phenylsulfanylmethyl)phenyl]-1,3,5-triazine-2,4-diamine;chloride —— C18H21ClN5S-
    6,6-Dimethyl-1-[3-(phenylsulfanylmethyl)phenyl]-1,3,5-triazine-2,4-diamine;chloride
    —— (Z)-N-[3-[(3-bromophenyl)methylsulfanyl]-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-yl]-1-(4-fluorophenyl)methanimine —— C17H12BrFN6S
    (Z)-N-[3-[(3-bromophenyl)methylsulfanyl]-[1,2,4]triazolo[4,3-b][1,2,4]triazol-7-yl]-1-(4-fluorophenyl)methanimine
    —— (2E)-2-methoxyimino-2-[5-[[3-(4-methylsulfanylphenyl)-1,4-dihydropyrazol-5-ylidene]amino]thiophen-3-yl]acetic acid —— C17H16N4O3S2
    (2E)-2-methoxyimino-2-[5-[[3-(4-methylsulfanylphenyl)-1,4-dihydropyrazol-5-ylidene]amino]thiophen-3-yl]acetic acid
    —— N-[(Z)-(4-bromophenyl)methylideneamino]-2-(6-methyl-2-methylsulfanylpyrimidin-4-yl)oxyacetamide —— C15H15BrN4O2S
    N-[(Z)-(4-bromophenyl)methylideneamino]-2-(6-methyl-2-methylsulfanylpyrimidin-4-yl)oxyacetamide
    —— 4-cyano-2-fluoro-N-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]benzamide —— C19H12FN3O2S
    4-cyano-2-fluoro-N-[(Z)-(5-phenylsulfanylfuran-2-yl)methylideneamino]benzamide
    —— N-[(Z)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]furan-2-carboxamide —— C17H12N4O3S
    N-[(Z)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]furan-2-carboxamide
    —— N-[(Z)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-2-methoxyacetamide —— C15H14N4O3S
    N-[(Z)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-2-methoxyacetamide
    —— N-[(Z)-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-2-cyanoacetamide —— C15H10N4O2S2
    N-[(Z)-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-2-cyanoacetamide
    —— (5E)-4-amino-5-(furan-2-ylmethylidene)-2-iminothiophene-3-carbonitrile —— C10H7N3OS
    (5E)-4-amino-5-(furan-2-ylmethylidene)-2-iminothiophene-3-carbonitrile
    —— (2E)-3-(dimethylamino)-1-[4-(phenylsulfanyl)phenyl]prop-2-en-1-one —— C17H17NOS
    (2E)-3-(dimethylamino)-1-[4-(phenylsulfanyl)phenyl]prop-2-en-1-one
    —— 3-nitro-N-[(Z)-(5-pyridin-2-ylsulfanylfuran-2-yl)methylideneamino]benzamide —— C17H12N4O4S
    3-nitro-N-[(Z)-(5-pyridin-2-ylsulfanylfuran-2-yl)methylideneamino]benzamide
    —— N-[(Z)-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-2-(2-methylphenoxy)acetamide —— C21H17N3O3S2
    N-[(Z)-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-2-(2-methylphenoxy)acetamide
    —— N-[(Z)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-3-fluorobenzamide —— C19H13FN4O2S
    N-[(Z)-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-3-fluorobenzamide
    —— N-[(Z)-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-2-methoxyacetamide —— C15H13N3O3S2
    N-[(Z)-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylideneamino]-2-methoxyacetamide
    —— (5E)-3-methyl-2-(3-methylsulfanylphenyl)imino-5-(pyridin-3-ylmethylidene)-1,3-thiazolidin-4-one —— C17H15N3OS2
    (5E)-3-methyl-2-(3-methylsulfanylphenyl)imino-5-(pyridin-3-ylmethylidene)-1,3-thiazolidin-4-one
    —— 2-[5-({5-[(4-chlorophenyl)sulfanyl]-2-furyl}methylene)-2,4-dioxo-1,3-thiazolidin-3-yl]-N-(4-methylphenyl)acetamide —— C23H17ClN2O4S2
    2-[5-({5-[(4-chlorophenyl)sulfanyl]-2-furyl}methylene)-2,4-dioxo-1,3-thiazolidin-3-yl]-N-(4-methylphenyl)acetamide
    —— (6E)-4-chloro-6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]-2-nitrocyclohexa-2,4-dien-1-one —— C18H15ClN4O3S
    (6E)-4-chloro-6-[[2-[(3,5-dimethyl-1H-pyrazol-4-yl)sulfanyl]anilino]methylidene]-2-nitrocyclohexa-2,4-dien-1-one