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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-[(3-bromobenzyl)thio]-5-(difluoromethyl)-4H-1,2,4-triazol-4-amine —— C10H9BrF2N4S
    3-[(3-bromobenzyl)thio]-5-(difluoromethyl)-4H-1,2,4-triazol-4-amine
    —— 3-(difluoromethyl)-5-[(2-nitrophenyl)thio]-4H-1,2,4-triazole —— C9H6F2N4O2S
    3-(difluoromethyl)-5-[(2-nitrophenyl)thio]-4H-1,2,4-triazole
    —— 3-[(2-chlorobenzyl)thio]-5-(difluoromethyl)-4H-1,2,4-triazol-4-amine —— C10H9ClF2N4S
    3-[(2-chlorobenzyl)thio]-5-(difluoromethyl)-4H-1,2,4-triazol-4-amine
    —— 2-[[(7Z)-3-cyano-4-(furan-2-yl)-7-(furan-2-ylmethylidene)-5,6-dihydrocyclopenta[b]pyridin-2-yl]sulfanyl]-N-(oxolan-2-ylmethyl)acetamide —— C25H23N3O4S
    2-[[(7Z)-3-cyano-4-(furan-2-yl)-7-(furan-2-ylmethylidene)-5,6-dihydrocyclopenta[b]pyridin-2-yl]sulfanyl]-N-(oxolan-2-ylmethyl)acetamide
    —— 3-(Difluoromethyl)-5-((4-methylbenzyl)thio)-4H-1,2,4-triazole —— C11H11F2N3S
    3-(Difluoromethyl)-5-((4-methylbenzyl)thio)-4H-1,2,4-triazole
    —— 3-(difluoromethyl)-5-[(2-fluorobenzyl)thio]-4H-1,2,4-triazole —— C10H8F3N3S
    3-(difluoromethyl)-5-[(2-fluorobenzyl)thio]-4H-1,2,4-triazole
    —— 3-(Difluoromethyl)-5-((2-nitro-4-(trifluoromethyl)phenyl)thio)-4H-1,2,4-triazole —— C10H5F5N4O2S
    3-(Difluoromethyl)-5-((2-nitro-4-(trifluoromethyl)phenyl)thio)-4H-1,2,4-triazole
    —— 3-(difluoromethyl)-5-[(3-fluorobenzyl)thio]-4H-1,2,4-triazol-4-amine —— C10H9F3N4S
    3-(difluoromethyl)-5-[(3-fluorobenzyl)thio]-4H-1,2,4-triazol-4-amine
    —— (5E)-3-(2-methylphenyl)-2-(2-methylphenyl)imino-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one —— C25H22N2OS2
    (5E)-3-(2-methylphenyl)-2-(2-methylphenyl)imino-5-[(4-methylsulfanylphenyl)methylidene]-1,3-thiazolidin-4-one
    —— 3-(difluoromethyl)-5-[(4-methyl-2-nitrophenyl)thio]-4H-1,2,4-triazol-4-amine —— C10H9F2N5O2S
    3-(difluoromethyl)-5-[(4-methyl-2-nitrophenyl)thio]-4H-1,2,4-triazol-4-amine
    —— N-(4-fluorophenyl)-2-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]acetamide —— C25H18FN3O5S2
    N-(4-fluorophenyl)-2-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]acetamide
    —— 1-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-3-phenylurea —— C20H15ClN4O3S
    1-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-3-phenylurea
    —— (E)-4-chloro-1-ethoxy-1-ethylsulfanylbut-1-ene —— C8H15ClOS
    (E)-4-chloro-1-ethoxy-1-ethylsulfanylbut-1-ene
    —— 3-[(2-methylbenzyl)thio]-5-(trifluoromethyl)-4H-1,2,4-triazole —— C11H10F3N3S
    3-[(2-methylbenzyl)thio]-5-(trifluoromethyl)-4H-1,2,4-triazole
    —— 3-{[(5-ethyl-4H-1,2,4-triazol-3-yl)thio]methyl}pyridine —— C10H12N4S
    3-{[(5-ethyl-4H-1,2,4-triazol-3-yl)thio]methyl}pyridine
    —— 3-ethyl-5-[(pyridin-3-ylmethyl)thio]-4H-1,2,4-triazol-4-amine —— C10H13N5S
    3-ethyl-5-[(pyridin-3-ylmethyl)thio]-4H-1,2,4-triazol-4-amine
    —— 3-[(2-fluorobenzyl)thio]-5-(trifluoromethyl)-4H-1,2,4-triazole —— C10H7F4N3S
    3-[(2-fluorobenzyl)thio]-5-(trifluoromethyl)-4H-1,2,4-triazole
    —— 3-[(4-bromobenzyl)thio]-5-(trifluoromethyl)-4H-1,2,4-triazole —— C10H7BrF3N3S
    3-[(4-bromobenzyl)thio]-5-(trifluoromethyl)-4H-1,2,4-triazole
    —— 3-[(4-fluorobenzyl)thio]-5-(trifluoromethyl)-4H-1,2,4-triazole —— C10H7F4N3S
    3-[(4-fluorobenzyl)thio]-5-(trifluoromethyl)-4H-1,2,4-triazole
    —— 3-ethyl-5-[(3-fluorobenzyl)thio]-4H-1,2,4-triazol-4-amine —— C11H13FN4S
    3-ethyl-5-[(3-fluorobenzyl)thio]-4H-1,2,4-triazol-4-amine
    —— (5Z)-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-3-(2-oxo-2-pyrrolidin-1-ylethyl)-1,3-thiazolidine-2,4-dione —— C22H18ClN3O5S2
    (5Z)-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-3-(2-oxo-2-pyrrolidin-1-ylethyl)-1,3-thiazolidine-2,4-dione
    —— (Z)-1-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]-N-(1,2,4-triazol-4-yl)methanimine —— C15H10ClN5O2S
    (Z)-1-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]-N-(1,2,4-triazol-4-yl)methanimine
    —— 3-(4-chlorobenzyl)-5-[(4-chlorobenzyl)thio]-4H-1,2,4-triazole —— C16H13Cl2N3S
    3-(4-chlorobenzyl)-5-[(4-chlorobenzyl)thio]-4H-1,2,4-triazole
    —— 3-[(2-chlorobenzyl)thio]-5-(4-methylbenzyl)-4H-1,2,4-triazol-4-amine —— C17H17ClN4S
    3-[(2-chlorobenzyl)thio]-5-(4-methylbenzyl)-4H-1,2,4-triazol-4-amine
    —— N-(1,3-benzodioxol-5-yl)-2-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]acetamide —— C26H19N3O7S2
    N-(1,3-benzodioxol-5-yl)-2-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]acetamide
    —— (E)-3-[5-[(4-chlorophenyl)sulfanylmethyl]-2,4-dimethylphenyl]-2-cyanoprop-2-enethioamide —— C19H17ClN2S2
    (E)-3-[5-[(4-chlorophenyl)sulfanylmethyl]-2,4-dimethylphenyl]-2-cyanoprop-2-enethioamide
    —— (E)-3-[3-[(4-chlorophenyl)sulfanylmethyl]-2,5-dimethylphenyl]-2-cyanoprop-2-enethioamide —— C19H17ClN2S2
    (E)-3-[3-[(4-chlorophenyl)sulfanylmethyl]-2,5-dimethylphenyl]-2-cyanoprop-2-enethioamide
    —— 3-(4-chlorobenzyl)-5-[(2-fluorobenzyl)thio]-4H-1,2,4-triazol-4-amine —— C16H14ClFN4S
    3-(4-chlorobenzyl)-5-[(2-fluorobenzyl)thio]-4H-1,2,4-triazol-4-amine
    —— 3-{[(4-Chlorophenyl)thio]methyl}-6-hydrazino[1,2,4]triazolo[3,4-b][1,3,4]thiadiazole —— C10H9ClN6S2
    3-{[(4-Chlorophenyl)thio]methyl}-6-hydrazino[1,2,4]triazolo[3,4-b][1,3,4]thiadiazole
    —— N-(3-chlorophenyl)-2-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]acetamide —— C25H18ClN3O5S2
    N-(3-chlorophenyl)-2-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]acetamide
    —— 3-(4-chlorobenzyl)-5-[(2-chlorobenzyl)thio]-4H-1,2,4-triazol-4-amine —— C16H14Cl2N4S
    3-(4-chlorobenzyl)-5-[(2-chlorobenzyl)thio]-4H-1,2,4-triazol-4-amine
    —— N-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]-4,6-dimorpholin-4-yl-1,3,5-triazin-2-amine —— C25H28N8O4S
    N-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]-4,6-dimorpholin-4-yl-1,3,5-triazin-2-amine
    —— 3-(4-methylbenzyl)-5-[(2-methylbenzyl)thio]-4H-1,2,4-triazol-4-amine —— C18H20N4S
    3-(4-methylbenzyl)-5-[(2-methylbenzyl)thio]-4H-1,2,4-triazol-4-amine
    —— 3-[(4-chlorobenzyl)thio]-5-(4-methylbenzyl)-4H-1,2,4-triazole —— C17H16ClN3S
    3-[(4-chlorobenzyl)thio]-5-(4-methylbenzyl)-4H-1,2,4-triazole
    —— (5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-3-(2-oxo-2-pyrrolidin-1-ylethyl)-1,3-thiazolidine-2,4-dione —— C23H21N3O5S2
    (5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-3-(2-oxo-2-pyrrolidin-1-ylethyl)-1,3-thiazolidine-2,4-dione
    —— 3-benzyl-5-[(2-chlorobenzyl)sulfanyl]-4H-1,2,4-triazol-4-amine —— C16H15ClN4S
    3-benzyl-5-[(2-chlorobenzyl)sulfanyl]-4H-1,2,4-triazol-4-amine
    —— 3-benzyl-5-[(2-fluorobenzyl)thio]-4H-1,2,4-triazol-4-amine —— C16H15FN4S
    3-benzyl-5-[(2-fluorobenzyl)thio]-4H-1,2,4-triazol-4-amine
    —— 3-(benzylthio)-5-(4-methylbenzyl)-4H-1,2,4-triazole —— C17H17N3S
    3-(benzylthio)-5-(4-methylbenzyl)-4H-1,2,4-triazole
    —— N-methyl-N-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]-4,6-di(piperidin-1-yl)-1,3,5-triazin-2-amine —— C28H34N8O2S
    N-methyl-N-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]-4,6-di(piperidin-1-yl)-1,3,5-triazin-2-amine
    —— 3-[(4-chlorobenzyl)thio]-5-(4-methylbenzyl)-4H-1,2,4-triazol-4-amine —— C17H17ClN4S
    3-[(4-chlorobenzyl)thio]-5-(4-methylbenzyl)-4H-1,2,4-triazol-4-amine
    —— N-[(Z)-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]-2-(3-methylphenoxy)acetamide —— C23H18N4O4S2
    N-[(Z)-[4-(1,3-benzothiazol-2-ylsulfanyl)-3-nitrophenyl]methylideneamino]-2-(3-methylphenoxy)acetamide
    —— 3-(4-chlorobenzyl)-5-[(4-chlorobenzyl)thio]-4H-1,2,4-triazol-4-amine —— C16H14Cl2N4S
    3-(4-chlorobenzyl)-5-[(4-chlorobenzyl)thio]-4H-1,2,4-triazol-4-amine
    —— 3-(2-methylbenzyl)-5-[(2-methylbenzyl)thio]-4H-1,2,4-triazol-4-amine —— C18H20N4S
    3-(2-methylbenzyl)-5-[(2-methylbenzyl)thio]-4H-1,2,4-triazol-4-amine
    —— 3-[(2-chlorobenzyl)thio]-5-(2-methylbenzyl)-4H-1,2,4-triazole —— C17H16ClN3S
    3-[(2-chlorobenzyl)thio]-5-(2-methylbenzyl)-4H-1,2,4-triazole
    —— 3-[(4-chlorobenzyl)thio]-5-(2-methylbenzyl)-4H-1,2,4-triazole —— C17H16ClN3S
    3-[(4-chlorobenzyl)thio]-5-(2-methylbenzyl)-4H-1,2,4-triazole
    —— 2-[[4-[(Z)-benzylideneamino]-5-methyl-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C12H12N4O2S
    2-[[4-[(Z)-benzylideneamino]-5-methyl-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— propan-2-yl (E)-2-cyano-3-(2-ethylsulfanyl-5-methylfuran-3-yl)prop-2-enoate —— C14H17NO3S
    propan-2-yl (E)-2-cyano-3-(2-ethylsulfanyl-5-methylfuran-3-yl)prop-2-enoate
    —— N-[(E)-amino-[(6E)-6-[amino(nitroso)methylidene]-2-phenylsulfanylcyclohexa-2,4-dien-1-ylidene]methyl]hydroxylamine —— C14H14N4O2S
    N-[(E)-amino-[(6E)-6-[amino(nitroso)methylidene]-2-phenylsulfanylcyclohexa-2,4-dien-1-ylidene]methyl]hydroxylamine
    —— N-(4-chlorophenyl)-2-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]acetamide —— C25H18ClN3O5S2
    N-(4-chlorophenyl)-2-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]acetamide
    —— (5Z)-3-(2-chloro-4-fluorobenzyl)-5-({5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene)-1,3-thiazolidine-2,4-dione —— C22H15ClFNO3S2
    (5Z)-3-(2-chloro-4-fluorobenzyl)-5-({5-[(4-methylphenyl)sulfanyl]furan-2-yl}methylidene)-1,3-thiazolidine-2,4-dione