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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 1,2,3,4,10,11-hexahydrodibenzothiophen —— C12H14S
    1,2,3,4,10,11-hexahydrodibenzothiophen
    —— cis-1,2,3,4,4a,9a-Hexahydrodibenzothiophene —— C12H14S
    cis-1,2,3,4,4a,9a-Hexahydrodibenzothiophene
    —— Butanal, 2,3-bis-(methylthio) —— C6H12OS2
    Butanal, 2,3-bis-(methylthio)
    —— 1-Pyrrolidinecarbodithioic acid, 2,3,6-trichloro-5-(trifluoromethyl)-4-pyridinyl ester —— C11H8Cl3F3N2S2
    1-Pyrrolidinecarbodithioic acid, 2,3,6-trichloro-5-(trifluoromethyl)-4-pyridinyl ester
    —— 4-Morpholinecarbodithioic acid, 2,3,6-trichloro-5-(trifluoromethyl)-4-pyridinyl ester —— C11H8Cl3F3N2OS2
    4-Morpholinecarbodithioic acid, 2,3,6-trichloro-5-(trifluoromethyl)-4-pyridinyl ester
    —— 2,3,5,6-Tetrachloropyridin-4-yl 3,5-dimethylmorpholine-4-carbodithioate —— C12H12Cl4N2OS2
    2,3,5,6-Tetrachloropyridin-4-yl 3,5-dimethylmorpholine-4-carbodithioate
    —— 2,5-Dichloro-4,6-bis-p-tolylsulfanyl-3-trifluoromethyl-pyridine —— C20H14Cl2F3NS2
    2,5-Dichloro-4,6-bis-p-tolylsulfanyl-3-trifluoromethyl-pyridine
    —— 2,3,5-Trichloro-4-cyano-6-pentafluoroethylthiopyridine —— C8Cl3F5N2S
    2,3,5-Trichloro-4-cyano-6-pentafluoroethylthiopyridine
    —— 1-Piperidinecarbodithioic acid, 2,3,5,6-tetrachloro-4-pyridinyl ester —— C11H10Cl4N2S2
    1-Piperidinecarbodithioic acid, 2,3,5,6-tetrachloro-4-pyridinyl ester
    —— Pyrimidine, 4,6-bis(pentafluoroethyl)-2-[(pentafluoroethyl)thio]- —— C10HF15N2S
    Pyrimidine, 4,6-bis(pentafluoroethyl)-2-[(pentafluoroethyl)thio]-
    —— 4-Morpholinecarbodithioic acid, 2,3,5,6-tetrachloro-4-pyridinyl ester —— C10H8Cl4N2OS2
    4-Morpholinecarbodithioic acid, 2,3,5,6-tetrachloro-4-pyridinyl ester
    —— 2,5-Dichloro-3-ethoxycarbonyl-4,6-di(4-methylphenylthio)pyridine —— C22H19Cl2NO2S2
    2,5-Dichloro-3-ethoxycarbonyl-4,6-di(4-methylphenylthio)pyridine
    —— 1-Piperidinecarbodithioic acid, 2,3,6-trichloro-5-(trifluoromethyl)-4-pyridinyl ester —— C12H10Cl3F3N2S2
    1-Piperidinecarbodithioic acid, 2,3,6-trichloro-5-(trifluoromethyl)-4-pyridinyl ester
    —— 3-Allylsulfanyl-1-thiophen-2-yl-5,6,7,8-tetrahydro-isoquinoline-4-carbonitrile —— C17H16N2S2
    3-Allylsulfanyl-1-thiophen-2-yl-5,6,7,8-tetrahydro-isoquinoline-4-carbonitrile
    —— 3-nitro-5-[4-(trifluoromethyl)phenyl]thioaniline —— C13H9F3N2O2S
    3-nitro-5-[4-(trifluoromethyl)phenyl]thioaniline
    —— 2,2-Diallyl-3-methyl-4-phenylsulfanyl-2,5-dihydro-thiophene 1,1-dioxide —— C17H20O2S2
    2,2-Diallyl-3-methyl-4-phenylsulfanyl-2,5-dihydro-thiophene 1,1-dioxide
    —— Isoxazole, 5-bromomethyl-3-(5-methylsulfanylthiophen-2-yl)-4,5-dihydro- —— C9H10BrNOS2
    Isoxazole, 5-bromomethyl-3-(5-methylsulfanylthiophen-2-yl)-4,5-dihydro-
    —— 5-Pentafluoroethyl-2-pentafluoroethylthiopyrimidine —— C8H2F10N2S
    5-Pentafluoroethyl-2-pentafluoroethylthiopyrimidine
    —— Ethylamine, N,N-dinonyl-2-phenylthio —— C26H47NS
    Ethylamine, N,N-dinonyl-2-phenylthio
    —— 2,2,3,3,4,4,5,5-Octafluoro-pentanethioic acid, (2-hydroxy-ethyl)-amide —— C7H7F8NOS
    2,2,3,3,4,4,5,5-Octafluoro-pentanethioic acid, (2-hydroxy-ethyl)-amide
    —— Ethylamine, N,N-dioctyl-2-phenylthio —— C24H43NS
    Ethylamine, N,N-dioctyl-2-phenylthio
    —— Bis(4-cyano-1-methyl-1H-pyrazol-5-yl)sulfide —— C10H8N6S
    Bis(4-cyano-1-methyl-1H-pyrazol-5-yl)sulfide
    —— Isoxazole, 5-chloromethyl-3-(5-methylsulfanylthiophen-2-yl)-4,5-dihydro- —— C9H10ClNOS2
    Isoxazole, 5-chloromethyl-3-(5-methylsulfanylthiophen-2-yl)-4,5-dihydro-
    —— Thiophene, 3-bromo-2-[(chloromethyl)thio]- —— C5H4BrClS2
    Thiophene, 3-bromo-2-[(chloromethyl)thio]-
    —— 3-Hydrazino-2,5-dichloro-4-cyano-6-pentafluoroethylthiopyridine —— C8H3Cl2F5N4S
    3-Hydrazino-2,5-dichloro-4-cyano-6-pentafluoroethylthiopyridine
    —— (1R)-N-methyl-1-(4-methylsulfanylphenyl)-N-(oxan-4-yl)ethane-1,2-diamine —— C15H24N2OS
    (1R)-N-methyl-1-(4-methylsulfanylphenyl)-N-(oxan-4-yl)ethane-1,2-diamine
    —— Ethylamine, N,N-diheptyl-2-phenylthio —— C22H39NS
    Ethylamine, N,N-diheptyl-2-phenylthio
    —— S-(2,5-dichloro-4-cyano-6-ethyl-3-pyridyl) ethylxanthate —— C11H10Cl2N2OS3
    S-(2,5-dichloro-4-cyano-6-ethyl-3-pyridyl) ethylxanthate
    —— 1,4-Di(2,3,5,6-tetrafluorophenylthio)butane —— C16H10F8S2
    1,4-Di(2,3,5,6-tetrafluorophenylthio)butane
    —— 1,2-Bis(ethylthio)octane —— C12H26S2
    1,2-Bis(ethylthio)octane
    —— 3,4-Bis(ethylthio)hexane —— C10H22S2
    3,4-Bis(ethylthio)hexane
    —— 5-(5-Methyl-4H-[1,2,4]triazol-3-ylsulfanylmethyl)-4H-[1,2,4]triazole-3-thiol —— C6H8N6S2
    5-(5-Methyl-4H-[1,2,4]triazol-3-ylsulfanylmethyl)-4H-[1,2,4]triazole-3-thiol
    —— Carbamodithioic acid, diethyl-, 2,3,5,6-tetrafluoro-4-pyridinyl ester —— C10H10F4N2S2
    Carbamodithioic acid, diethyl-, 2,3,5,6-tetrafluoro-4-pyridinyl ester
    —— 4-[2-(2-Bromophenylthio)ethyl]pyridine —— C13H12BrNS
    4-[2-(2-Bromophenylthio)ethyl]pyridine
    —— 3-Phenylsulfanyl-tetrahydro-thiopyran —— C11H14S2
    3-Phenylsulfanyl-tetrahydro-thiopyran
    —— Morpholine-4-carbodithioic acid 2,3,6-trichloro-5-cyano-pyridin-4-yl ester —— C11H8Cl3N3OS2
    Morpholine-4-carbodithioic acid 2,3,6-trichloro-5-cyano-pyridin-4-yl ester
    —— 5-Trifluoromethyl-2-trifluoromethylthiopyrimidine —— C6H2F6N2S
    5-Trifluoromethyl-2-trifluoromethylthiopyrimidine
    —— 2,3,6-Trichloro-5-trifluoromethylsulfanyl-isonicotinonitrile —— C7Cl3F3N2S
    2,3,6-Trichloro-5-trifluoromethylsulfanyl-isonicotinonitrile
    —— 2,3,5,6-Tetrachloropyridin-4-yl 4-methylpiperazine-1-carbodithioate —— C11H11Cl4N3S2
    2,3,5,6-Tetrachloropyridin-4-yl 4-methylpiperazine-1-carbodithioate
    —— (2R)-2-phenyl-2,3,4,6-tetrahydro-1,6-benzothiazocin-5-one —— C16H15NOS
    (2R)-2-phenyl-2,3,4,6-tetrahydro-1,6-benzothiazocin-5-one
    —— 2-Ethylthio-2,4,4-trimethylpentane —— C10H22S
    2-Ethylthio-2,4,4-trimethylpentane
    —— 2,3-Bis(ethylthio)hexane —— C10H22S2
    2,3-Bis(ethylthio)hexane
    —— 2,3-Bis(ethylthio)-3-methylpentane —— C8H18S2
    2,3-Bis(ethylthio)-3-methylpentane
    —— 1-Ethylthio-5,5-dimethyl-2-hexene —— C10H20S
    1-Ethylthio-5,5-dimethyl-2-hexene
    —— Thioacetic acid, S-(4H-1,4,6,7-tetraazacyclohepta[jk]fluoren-5-yl) ester —— C15H10N4OS
    Thioacetic acid, S-(4H-1,4,6,7-tetraazacyclohepta[jk]fluoren-5-yl) ester
    —— (2S)-2-phenyl-2,3,4,6-tetrahydro-1,6-benzothiazocin-5-one —— C16H15NOS
    (2S)-2-phenyl-2,3,4,6-tetrahydro-1,6-benzothiazocin-5-one
    —— 3-Ethylthio-3-methylpentane —— C8H18S
    3-Ethylthio-3-methylpentane
    —— 2-Ethylthio-2,3-dimethylbutane —— C8H18S
    2-Ethylthio-2,3-dimethylbutane
    —— 2-Methylthio-2,3-dimethylbutane —— C7H16S
    2-Methylthio-2,3-dimethylbutane
    —— 3-[(4-Chlorophenyl)thio]-4-methyl-2,5-dihydrothiophene 1,1-dioxide —— C11H11ClO2S2
    3-[(4-Chlorophenyl)thio]-4-methyl-2,5-dihydrothiophene 1,1-dioxide