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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-[[5-(pyridin-3-ylmethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid —— C11H12N4O2S2
    3-[[5-(pyridin-3-ylmethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid
    —— 5-(2-aminoethylsulfanyl)-N-methyl-N-(2-pyridin-4-ylethyl)-1,3,4-thiadiazol-2-amine —— C12H17N5S2
    5-(2-aminoethylsulfanyl)-N-methyl-N-(2-pyridin-4-ylethyl)-1,3,4-thiadiazol-2-amine
    —— 3-[[5-(pyridin-4-ylmethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid —— C11H12N4O2S2
    3-[[5-(pyridin-4-ylmethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid
    —— 2-[1-[2-(3-chlorophenyl)ethyl]imidazol-2-yl]sulfanylacetamide —— C13H14ClN3OS
    2-[1-[2-(3-chlorophenyl)ethyl]imidazol-2-yl]sulfanylacetamide
    —— 2-[[5-[benzyl(ethyl)amino]-1,3,4-thiadiazol-2-yl]sulfanyl]ethanol —— C13H17N3OS2
    2-[[5-[benzyl(ethyl)amino]-1,3,4-thiadiazol-2-yl]sulfanyl]ethanol
    —— 3-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid —— C12H13N3O2S2
    3-[[5-(benzylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid
    —— 2-[[5-[[(3S)-1,1-dioxothiolan-3-yl]amino]-1,3,4-thiadiazol-2-yl]sulfanyl]ethanol —— C8H13N3O3S3
    2-[[5-[[(3S)-1,1-dioxothiolan-3-yl]amino]-1,3,4-thiadiazol-2-yl]sulfanyl]ethanol
    —— 3-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid —— C12H13N3O2S2
    3-[[5-(4-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid
    —— 2-[[5-[methyl(2-pyridin-4-ylethyl)amino]-1,3,4-thiadiazol-2-yl]sulfanyl]ethanol —— C12H16N4OS2
    2-[[5-[methyl(2-pyridin-4-ylethyl)amino]-1,3,4-thiadiazol-2-yl]sulfanyl]ethanol
    —— 3-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid —— C12H13N3O2S2
    3-[[5-(3-methylanilino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid
    —— 5-(2-aminoethylsulfanyl)-N-[(3R)-1,1-dioxothiolan-3-yl]-1,3,4-thiadiazol-2-amine —— C8H14N4O2S3
    5-(2-aminoethylsulfanyl)-N-[(3R)-1,1-dioxothiolan-3-yl]-1,3,4-thiadiazol-2-amine
    —— 5-Methylsulfanyl-3-(piperidin-1-ium-1-ylmethyl)-1,3,4-thiadiazole-2-thione —— C9H16N3S3+
    5-Methylsulfanyl-3-(piperidin-1-ium-1-ylmethyl)-1,3,4-thiadiazole-2-thione
    —— 5-(2-aminoethylsulfanyl)-N-benzyl-N-ethyl-1,3,4-thiadiazol-2-amine —— C13H18N4S2
    5-(2-aminoethylsulfanyl)-N-benzyl-N-ethyl-1,3,4-thiadiazol-2-amine
    —— 4-[(1R)-1-(4-fluorophenyl)-2-nitroethyl]sulfanylaniline —— C14H13FN2O2S
    4-[(1R)-1-(4-fluorophenyl)-2-nitroethyl]sulfanylaniline
    —— 4-[(1S)-1-(4-fluorophenyl)-2-nitroethyl]sulfanylaniline —— C14H13FN2O2S
    4-[(1S)-1-(4-fluorophenyl)-2-nitroethyl]sulfanylaniline
    —— (3R)-3-(4-chlorophenyl)sulfanyl-1-(pyridin-3-ylmethyl)pyrrolidine-2,5-dione —— C16H13ClN2O2S
    (3R)-3-(4-chlorophenyl)sulfanyl-1-(pyridin-3-ylmethyl)pyrrolidine-2,5-dione
    —— (3S)-3-(4-chlorophenyl)sulfanyl-1-(pyridin-3-ylmethyl)pyrrolidine-2,5-dione —— C16H13ClN2O2S
    (3S)-3-(4-chlorophenyl)sulfanyl-1-(pyridin-3-ylmethyl)pyrrolidine-2,5-dione
    —— (3S)-3-(4-chlorophenyl)sulfanyl-1-(pyridin-4-ylmethyl)pyrrolidine-2,5-dione —— C16H13ClN2O2S
    (3S)-3-(4-chlorophenyl)sulfanyl-1-(pyridin-4-ylmethyl)pyrrolidine-2,5-dione
    —— (1S,2R)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-2-phenylcyclopropane-1-carboxamide —— C18H18N2OS
    (1S,2R)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-2-phenylcyclopropane-1-carboxamide
    —— 2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-tert-butylacetamide —— C13H16N5OS+
    2-(6-amino-3,5-dicyanopyridin-1-ium-2-yl)sulfanyl-N-tert-butylacetamide
    —— 3-[1-[2-(3-chlorophenyl)ethyl]imidazol-2-yl]sulfanylpropanenitrile —— C14H14ClN3S
    3-[1-[2-(3-chlorophenyl)ethyl]imidazol-2-yl]sulfanylpropanenitrile
    —— 4-Methyl-2-(2-morpholin-4-ium-4-ylethylsulfanyl)-6-(trifluoromethyl)pyridine-3-carbonitrile —— C14H17F3N3OS+
    4-Methyl-2-(2-morpholin-4-ium-4-ylethylsulfanyl)-6-(trifluoromethyl)pyridine-3-carbonitrile
    —— 3-[1-[2-(4-chlorophenyl)ethyl]imidazol-2-yl]sulfanylpropanenitrile —— C14H14ClN3S
    3-[1-[2-(4-chlorophenyl)ethyl]imidazol-2-yl]sulfanylpropanenitrile
    —— [2-[2-(Hydroxymethyl)phenyl]sulfanylphenyl]methylazanium —— C14H16NOS+
    [2-[2-(Hydroxymethyl)phenyl]sulfanylphenyl]methylazanium
    —— (2S)-5-ethoxy-2-(furan-2-ylmethyliminomethyl)-1-benzothiophen-3-one —— C16H15NO3S
    (2S)-5-ethoxy-2-(furan-2-ylmethyliminomethyl)-1-benzothiophen-3-one
    —— 2-[[5-[benzyl(ethyl)amino]-1,3,4-thiadiazol-2-yl]sulfanyl]acetonitrile —— C13H14N4S2
    2-[[5-[benzyl(ethyl)amino]-1,3,4-thiadiazol-2-yl]sulfanyl]acetonitrile
    —— 3-[[5-[3-(dimethylamino)propylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid —— C10H18N4O2S2
    3-[[5-[3-(dimethylamino)propylamino]-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid
    —— 2-[[5-[[(3R)-1,1-dioxothiolan-3-yl]amino]-1,3,4-thiadiazol-2-yl]sulfanyl]acetonitrile —— C8H10N4O2S3
    2-[[5-[[(3R)-1,1-dioxothiolan-3-yl]amino]-1,3,4-thiadiazol-2-yl]sulfanyl]acetonitrile
    —— 3-(8,8-dimethyl-4,10-dioxo-7,9-dihydro-6H-[1,2,4]triazino[4,3-b][4,1,2]benzothiadiazin-3-yl)propanoate —— C14H15N4O4S-
    3-(8,8-dimethyl-4,10-dioxo-7,9-dihydro-6H-[1,2,4]triazino[4,3-b][4,1,2]benzothiadiazin-3-yl)propanoate
    —— (3R,4R,5R)-5-acetyl-2-imino-4-thiophen-2-ylthiolane-3-carbonitrile —— C11H10N2OS2
    (3R,4R,5R)-5-acetyl-2-imino-4-thiophen-2-ylthiolane-3-carbonitrile
    —— [5-ethylsulfanyl-4-[(Z)-hydroxyiminomethyl]thiophen-2-yl]methyl-dimethylazanium —— C10H17N2OS2+
    [5-ethylsulfanyl-4-[(Z)-hydroxyiminomethyl]thiophen-2-yl]methyl-dimethylazanium
    —— 2-[1-(Carboxylatomethylsulfanyl)cyclopentyl]sulfanylacetate —— C9H12O4S2-2
    2-[1-(Carboxylatomethylsulfanyl)cyclopentyl]sulfanylacetate
    —— 2-[3-Cyano-6-methyl-4-(trifluoromethyl)pyridin-2-yl]sulfanylacetate —— C10H6F3N2O2S-
    2-[3-Cyano-6-methyl-4-(trifluoromethyl)pyridin-2-yl]sulfanylacetate
    —— 2-[6-amino-3,5-dicyano-4-(2-methylpropyl)pyridin-1-ium-2-yl]sulfanyl-N,N-diethylacetamide —— C17H24N5OS+
    2-[6-amino-3,5-dicyano-4-(2-methylpropyl)pyridin-1-ium-2-yl]sulfanyl-N,N-diethylacetamide
    —— 3-[[5-(Cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid —— C11H17N3O2S2
    3-[[5-(Cyclohexylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid
    —— 2-(4-Chlorophenyl)sulfanyl-1-(4-methylpiperazin-4-ium-1-yl)ethanone —— C13H18ClN2OS+
    2-(4-Chlorophenyl)sulfanyl-1-(4-methylpiperazin-4-ium-1-yl)ethanone
    —— 5-Pyridin-2-ylsulfanylfuran-2-carboxylate —— C10H6NO3S-
    5-Pyridin-2-ylsulfanylfuran-2-carboxylate
    —— 5-(2-aminoethylsulfanyl)-N-(2-chlorophenyl)-1,3,4-thiadiazol-2-amine —— C10H11ClN4S2
    5-(2-aminoethylsulfanyl)-N-(2-chlorophenyl)-1,3,4-thiadiazol-2-amine
    —— (4,6-Dimethyl-2-methylsulfanylpyridin-3-yl)methylazanium —— C9H15N2S+
    (4,6-Dimethyl-2-methylsulfanylpyridin-3-yl)methylazanium
    —— 5-(2-aminoethylsulfanyl)-N-(4-chlorophenyl)-1,3,4-thiadiazol-2-amine —— C10H11ClN4S2
    5-(2-aminoethylsulfanyl)-N-(4-chlorophenyl)-1,3,4-thiadiazol-2-amine
    —— 3-[[5-(4-methylpiperidin-1-yl)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid —— C11H17N3O2S2
    3-[[5-(4-methylpiperidin-1-yl)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid
    —— [2-(2-Chlorophenyl)sulfanylphenyl]methyl-dimethylazanium —— C15H17ClNS+
    [2-(2-Chlorophenyl)sulfanylphenyl]methyl-dimethylazanium
    —— 2-Amino-6-(2-phenylethylsulfanyl)pyridin-1-ium-3,5-dicarbonitrile —— C15H13N4S+
    2-Amino-6-(2-phenylethylsulfanyl)pyridin-1-ium-3,5-dicarbonitrile
    —— 1-Methyl-4-(2-phenylsulfanylphenoxy)piperidin-1-ium —— C18H22NOS+
    1-Methyl-4-(2-phenylsulfanylphenoxy)piperidin-1-ium
    —— [2-(4-Methoxyphenyl)sulfanylphenyl]methyl-methylazanium —— C15H18NOS+
    [2-(4-Methoxyphenyl)sulfanylphenyl]methyl-methylazanium
    —— Nitromethylsulfonylcyclohexane —— C7H13NO4S
    Nitromethylsulfonylcyclohexane
    —— 2-[[5-(2-morpholin-4-ylethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetonitrile —— C10H15N5OS2
    2-[[5-(2-morpholin-4-ylethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]acetonitrile
    —— 3-[[5-(furan-2-ylmethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid —— C10H11N3O3S2
    3-[[5-(furan-2-ylmethylamino)-1,3,4-thiadiazol-2-yl]sulfanyl]propanoic acid
    —— 4-((2S,3R,4S,5S)-3,4,5-Trihydroxy-tetrahydro-thiopyran-2-ylsulfanyl)-thiobenzimidic acid methyl ester; hydriodide —— C13H17NO3S3*HI
    4-((2S,3R,4S,5S)-3,4,5-Trihydroxy-tetrahydro-thiopyran-2-ylsulfanyl)-thiobenzimidic acid methyl ester; hydriodide
    —— methyl 4-[(2S,3R,4S,5S)-3,4,5-trihydroxythian-2-yl]sulfanylbenzenecarboximidothioate —— C13H17NO3S3
    methyl 4-[(2S,3R,4S,5S)-3,4,5-trihydroxythian-2-yl]sulfanylbenzenecarboximidothioate