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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (8S,10S)-8,10-dimethyl-3,5-dioxa-4lambda4-thia-2,6-diazatricyclo[5.3.1.04,11]undeca-1,4(11),6-triene —— C8H10N2O2S
    (8S,10S)-8,10-dimethyl-3,5-dioxa-4lambda4-thia-2,6-diazatricyclo[5.3.1.04,11]undeca-1,4(11),6-triene
    —— (5R)-1-benzyl-5-(3-butylsulfanyl-1H-1,2,4-triazol-5-yl)pyrrolidin-2-one —— C17H22N4OS
    (5R)-1-benzyl-5-(3-butylsulfanyl-1H-1,2,4-triazol-5-yl)pyrrolidin-2-one
    —— (5R)-5-methyl-1,2,4,7-dithiadiazocane-3,8-dithione —— C5H8N2S4
    (5R)-5-methyl-1,2,4,7-dithiadiazocane-3,8-dithione
    —— (5S)-1-benzyl-5-(5-methylsulfanyl-1,3,4-oxadiazol-2-yl)pyrrolidin-2-one —— C14H15N3O2S
    (5S)-1-benzyl-5-(5-methylsulfanyl-1,3,4-oxadiazol-2-yl)pyrrolidin-2-one
    —— (2R)-2-(4-chlorophenyl)sulfanyl-1-methyl-3,4-dihydro-2H-pyridine-5-carbonitrile —— C13H13ClN2S
    (2R)-2-(4-chlorophenyl)sulfanyl-1-methyl-3,4-dihydro-2H-pyridine-5-carbonitrile
    —— 2-[[5-[(2S)-1-benzyl-5-oxopyrrolidin-2-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetic acid —— C16H18N4O3S
    2-[[5-[(2S)-1-benzyl-5-oxopyrrolidin-2-yl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetic acid
    —— 10-methoxybenzo[b][1]benzothiocin-12-one —— C16H12O2S
    10-methoxybenzo[b][1]benzothiocin-12-one
    —— 1-[2-[(1R,3R,4R)-3,4-dimethoxycyclohexyl]sulfanylpyridin-1-ium-1-yl]propan-2-one —— C16H24NO3S+
    1-[2-[(1R,3R,4R)-3,4-dimethoxycyclohexyl]sulfanylpyridin-1-ium-1-yl]propan-2-one
    —— 2-[(R)-tert-butylsulfinyl]ethanol —— C6H14O2S
    2-[(R)-tert-butylsulfinyl]ethanol
    —— 1-[2-[(1R,3R,4S)-3,4-dimethoxycyclohexyl]sulfanylpyridin-1-ium-1-yl]propan-2-one —— C16H24NO3S+
    1-[2-[(1R,3R,4S)-3,4-dimethoxycyclohexyl]sulfanylpyridin-1-ium-1-yl]propan-2-one
    —— (3S)-3-(1H-1,2,4-triazol-5-ylsulfanyl)thiolane 1,1-dioxide —— C6H9N3O2S2
    (3S)-3-(1H-1,2,4-triazol-5-ylsulfanyl)thiolane 1,1-dioxide
    —— (2S)-2-[3-[(5-aminopyridin-2-yl)amino]pyridin-2-yl]sulfanylpropanoic acid —— C13H14N4O2S
    (2S)-2-[3-[(5-aminopyridin-2-yl)amino]pyridin-2-yl]sulfanylpropanoic acid
    —— N-[(1R)-1-(4-chlorophenyl)ethyl]-2-pyridin-2-ylsulfanylacetamide —— C15H15ClN2OS
    N-[(1R)-1-(4-chlorophenyl)ethyl]-2-pyridin-2-ylsulfanylacetamide
    —— 2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-1-(3-chlorophenyl)ethyl]acetamide —— C12H13ClN4OS2
    2-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(1R)-1-(3-chlorophenyl)ethyl]acetamide
    —— 4,5-bis[[(R)-methylsulfinyl]methyl]imidazol-2-imine —— C7H11N3O2S2
    4,5-bis[[(R)-methylsulfinyl]methyl]imidazol-2-imine
    —— (1R,8S)-N,N-dimethyl-9,9-dioxo-9lambda6-thiabicyclo[6.2.0]decan-1-amine —— C11H21NO2S
    (1R,8S)-N,N-dimethyl-9,9-dioxo-9lambda6-thiabicyclo[6.2.0]decan-1-amine
    —— (E)-[(3E)-3-hydrazinylidene-1-[(S)-methylsulfinyl]-4-[(R)-methylsulfinyl]butan-2-ylidene]hydrazine —— C6H14N4O2S2
    (E)-[(3E)-3-hydrazinylidene-1-[(S)-methylsulfinyl]-4-[(R)-methylsulfinyl]butan-2-ylidene]hydrazine
    —— (2R)-2-(4-chlorophenyl)sulfanyl-N-[(Z)-(2,3,4-trimethylphenyl)methylideneamino]propanamide —— C19H21ClN2OS
    (2R)-2-(4-chlorophenyl)sulfanyl-N-[(Z)-(2,3,4-trimethylphenyl)methylideneamino]propanamide
    —— (2R,3R,4R,5R)-2-(1H-imidazol-2-ylsulfanyl)oxane-3,4,5-triol —— C8H12N2O4S
    (2R,3R,4R,5R)-2-(1H-imidazol-2-ylsulfanyl)oxane-3,4,5-triol
    —— 3-[(6S)-6H-benzo[c][1,5]benzoxathiepin-6-yl]-N,N-dimethylpropan-1-amine —— C18H21NOS
    3-[(6S)-6H-benzo[c][1,5]benzoxathiepin-6-yl]-N,N-dimethylpropan-1-amine
    —— Acethydrazide, 2-[4-cyano-5-methylthio-3-(2-thienyl)-1-pyrazolyl]-N2-(2,2-dimethylpropylidene)- —— C16H19N5OS2
    Acethydrazide, 2-[4-cyano-5-methylthio-3-(2-thienyl)-1-pyrazolyl]-N2-(2,2-dimethylpropylidene)-
    —— (3S)-3-ethoxy-5-phenyl-2,3-dihydro-1,4-benzothiazepine —— C17H17NOS
    (3S)-3-ethoxy-5-phenyl-2,3-dihydro-1,4-benzothiazepine
    —— ethyl (Z)-2-cyano-3-[(3-methylsulfanyl-1H-1,2,4-triazol-5-yl)amino]prop-2-enoate —— C9H11N5O2S
    ethyl (Z)-2-cyano-3-[(3-methylsulfanyl-1H-1,2,4-triazol-5-yl)amino]prop-2-enoate
    —— [(4R)-2,2-dimethyl-1,3-dithiolan-4-yl]methanol —— C6H12OS2
    [(4R)-2,2-dimethyl-1,3-dithiolan-4-yl]methanol
    —— 2-[(2R,5Z)-5-(cyanomethylidene)-3,3,6,6-tetramethyl-2-pyrimidin-2-ylsulfanyl-1,4-dioxan-2-yl]acetonitrile —— C16H18N4O2S
    2-[(2R,5Z)-5-(cyanomethylidene)-3,3,6,6-tetramethyl-2-pyrimidin-2-ylsulfanyl-1,4-dioxan-2-yl]acetonitrile
    —— 2-[(2S,5Z)-5-(cyanomethylidene)-3,3,6,6-tetramethyl-2-pyrimidin-2-ylsulfanyl-1,4-dioxan-2-yl]acetonitrile —— C16H18N4O2S
    2-[(2S,5Z)-5-(cyanomethylidene)-3,3,6,6-tetramethyl-2-pyrimidin-2-ylsulfanyl-1,4-dioxan-2-yl]acetonitrile
    —— N-[(1R)-1-(4-chlorophenyl)ethyl]-2-(1-methylimidazol-2-yl)sulfanylacetamide —— C14H16ClN3OS
    N-[(1R)-1-(4-chlorophenyl)ethyl]-2-(1-methylimidazol-2-yl)sulfanylacetamide
    —— ethyl (2Z)-2-[[5-(dimethylamino)furan-2-yl]methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C24H25N3O4S2
    ethyl (2Z)-2-[[5-(dimethylamino)furan-2-yl]methylidene]-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— [(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]urea —— C15H14N4O3S
    [(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]urea
    —— N-[(Z)-(4-bromophenyl)methylideneamino]-2-[[5-[(4-chloroanilino)methyl]-4-ethyl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H20BrClN6OS
    N-[(Z)-(4-bromophenyl)methylideneamino]-2-[[5-[(4-chloroanilino)methyl]-4-ethyl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 1-[(S)-[(Z)-2-[(S)-butylsulfinyl]ethenyl]sulfinyl]butane —— C10H20O2S2
    1-[(S)-[(Z)-2-[(S)-butylsulfinyl]ethenyl]sulfinyl]butane
    —— 6-methyl-3-[(2Z)-2-[(4-methylsulfanylphenyl)methylidene]hydrazinyl]-4H-1,2,4-triazin-5-one —— C12H13N5OS
    6-methyl-3-[(2Z)-2-[(4-methylsulfanylphenyl)methylidene]hydrazinyl]-4H-1,2,4-triazin-5-one
    —— (2S,3S,4S,5S)-2,3,4,5-tetrahydroxy-6-[(2S,3S,4S,5S)-2,3,4,5-tetrahydroxy-6-oxohexoxy]carbothioyloxyhexanal —— C13H22O12S
    (2S,3S,4S,5S)-2,3,4,5-tetrahydroxy-6-[(2S,3S,4S,5S)-2,3,4,5-tetrahydroxy-6-oxohexoxy]carbothioyloxyhexanal
    —— 5-[(2R)-butan-2-yl]-4-hydroxy-2-(2-methylpropylsulfanyl)-1H-pyrimidin-6-one —— C12H20N2O2S
    5-[(2R)-butan-2-yl]-4-hydroxy-2-(2-methylpropylsulfanyl)-1H-pyrimidin-6-one
    —— 2-(4-chlorophenyl)sulfanyl-N-[(Z)-(4-ethylphenyl)methylideneamino]acetamide —— C17H17ClN2OS
    2-(4-chlorophenyl)sulfanyl-N-[(Z)-(4-ethylphenyl)methylideneamino]acetamide
    —— (4R)-6-amino-4-(4-methylsulfanylphenyl)-3-propyl-2,4-dihydropyrano[2,3-c]pyrazole-5-carbonitrile —— C17H18N4OS
    (4R)-6-amino-4-(4-methylsulfanylphenyl)-3-propyl-2,4-dihydropyrano[2,3-c]pyrazole-5-carbonitrile
    —— (5E)-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-3-(2,4-dimethylphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one —— C24H17ClN2O3S3
    (5E)-5-[[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylidene]-3-(2,4-dimethylphenyl)-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (1R)-2,2,2-trichloro-1-[(1R)-2,2,2-trichloro-1-hydroxyethyl]sulfanylethanol —— C4H4Cl6O2S
    (1R)-2,2,2-trichloro-1-[(1R)-2,2,2-trichloro-1-hydroxyethyl]sulfanylethanol
    —— N-[2-[(5Z)-5-[(2-fluorophenyl)methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]ethyl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide —— C20H15FN4O4S3
    N-[2-[(5Z)-5-[(2-fluorophenyl)methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]ethyl]-2-[(5-thiophen-2-yl-1,3,4-oxadiazol-2-yl)sulfanyl]acetamide
    —— 2-(3,5-dimethyl-4-nitropyrazol-1-yl)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C15H17N5O3S
    2-(3,5-dimethyl-4-nitropyrazol-1-yl)-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]pyridine-3-carboxamide —— C19H13ClN4O3S
    N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]pyridine-3-carboxamide
    —— (E)-N-[(3-benzylsulfanyl-5-ethyl-1,2,4-triazol-4-yl)carbamothioyl]-3-[5-(3-chloro-4-methylphenyl)furan-2-yl]prop-2-enamide —— C26H24ClN5O2S2
    (E)-N-[(3-benzylsulfanyl-5-ethyl-1,2,4-triazol-4-yl)carbamothioyl]-3-[5-(3-chloro-4-methylphenyl)furan-2-yl]prop-2-enamide
    —— (4S)-4-(2-methylpropyl)-2-[1-[(4-methylsulfanylphenyl)methyl]pyrrol-2-yl]-4,5-dihydro-1,3-oxazole —— C19H24N2OS
    (4S)-4-(2-methylpropyl)-2-[1-[(4-methylsulfanylphenyl)methyl]pyrrol-2-yl]-4,5-dihydro-1,3-oxazole
    —— (4R)-2-[1-[(4-methylsulfanylphenyl)methyl]pyrrol-2-yl]-4-phenyl-4,5-dihydro-1,3-oxazole —— C21H20N2OS
    (4R)-2-[1-[(4-methylsulfanylphenyl)methyl]pyrrol-2-yl]-4-phenyl-4,5-dihydro-1,3-oxazole
    —— [(2R,3R)-2-[(1R)-1-methoxyethyl]-1,1-dioxothietan-3-yl]-trimethylazanium —— C9H20NO3S+
    [(2R,3R)-2-[(1R)-1-methoxyethyl]-1,1-dioxothietan-3-yl]-trimethylazanium
    —— (4R)-4-[(2-methylphenyl)methylsulfanylmethyl]-2-[1-[(4-methylsulfanylphenyl)methyl]pyrrol-2-yl]-4,5-dihydro-1,3-oxazole —— C24H26N2OS2
    (4R)-4-[(2-methylphenyl)methylsulfanylmethyl]-2-[1-[(4-methylsulfanylphenyl)methyl]pyrrol-2-yl]-4,5-dihydro-1,3-oxazole
    —— 2-[[5-[(3-chloroanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-(4-methylphenyl)ethylideneamino]propanamide —— C22H25ClN6OS
    2-[[5-[(3-chloroanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-(4-methylphenyl)ethylideneamino]propanamide
    —— (5Z)-5-({4-[(4-bromophenyl)sulfanyl]-3-nitrophenyl}methylidene)-2-sulfanylidene-1,3-thiazolidin-4-one —— C16H9BrN2O3S3
    (5Z)-5-({4-[(4-bromophenyl)sulfanyl]-3-nitrophenyl}methylidene)-2-sulfanylidene-1,3-thiazolidin-4-one
    —— methyl (2S)-2-[7-(4-fluorophenyl)-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylbutanoate —— C19H19FN4O4S
    methyl (2S)-2-[7-(4-fluorophenyl)-1,3-dimethyl-2,4-dioxopyrimido[4,5-d]pyrimidin-5-yl]sulfanylbutanoate
    —— methyl (2S,3R)-3-(2-aminophenyl)sulfanyl-2-hydroxy-3-phenylpropanoate —— C16H17NO3S
    methyl (2S,3R)-3-(2-aminophenyl)sulfanyl-2-hydroxy-3-phenylpropanoate