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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— N-[[4-ethyl-5-(2-morpholin-4-ium-4-ylethylsulfanyl)-1,2,4-triazol-3-yl]methyl]-2,4-dimethylaniline —— C19H30N5OS+
    N-[[4-ethyl-5-(2-morpholin-4-ium-4-ylethylsulfanyl)-1,2,4-triazol-3-yl]methyl]-2,4-dimethylaniline
    —— Ethyl 2-[(4-cyano-1-piperidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl)sulfanyl]acetate —— C19H26N3O2S+
    Ethyl 2-[(4-cyano-1-piperidin-1-yl-5,6,7,8-tetrahydroisoquinolin-2-ium-3-yl)sulfanyl]acetate
    —— N-[[4-ethyl-5-(2-piperidin-1-ium-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]methyl]-4-fluoroaniline —— C18H27FN5S+
    N-[[4-ethyl-5-(2-piperidin-1-ium-1-ylethylsulfanyl)-1,2,4-triazol-3-yl]methyl]-4-fluoroaniline
    —— N-[[4-ethyl-5-(2-morpholin-4-ium-4-ylethylsulfanyl)-1,2,4-triazol-3-yl]methyl]-4-fluoroaniline —— C17H25FN5OS+
    N-[[4-ethyl-5-(2-morpholin-4-ium-4-ylethylsulfanyl)-1,2,4-triazol-3-yl]methyl]-4-fluoroaniline
    —— (2S)-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate —— C12H11N2O3S-
    (2S)-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate
    —— (2R)-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate —— C12H11N2O3S-
    (2R)-2-[[5-(3-methylphenyl)-1,3,4-oxadiazol-2-yl]sulfanyl]propanoate
    —— (2S)-2-(2-chlorophenyl)sulfanyl-N-methyl-N-[[1-(2,2,2-trifluoroethyl)imidazol-2-yl]methyl]propanamide —— C16H17ClF3N3OS
    (2S)-2-(2-chlorophenyl)sulfanyl-N-methyl-N-[[1-(2,2,2-trifluoroethyl)imidazol-2-yl]methyl]propanamide
    —— (2R)-2-[1-(2-methylpropyl)tetrazol-5-yl]sulfanylcyclohexan-1-one —— C11H18N4OS
    (2R)-2-[1-(2-methylpropyl)tetrazol-5-yl]sulfanylcyclohexan-1-one
    —— (2S)-2-[1-(2-methylpropyl)tetrazol-5-yl]sulfanylcyclohexan-1-one —— C11H18N4OS
    (2S)-2-[1-(2-methylpropyl)tetrazol-5-yl]sulfanylcyclohexan-1-one
    —— 4-[[5-[(2-Chlorophenyl)methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]methyl]morpholin-4-ium —— C15H20ClN4OS+
    4-[[5-[(2-Chlorophenyl)methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]methyl]morpholin-4-ium
    —— N-[(1R,2S)-2-methylcyclohexyl]-2-[[4-methyl-5-(morpholin-4-ium-4-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H30N5O2S+
    N-[(1R,2S)-2-methylcyclohexyl]-2-[[4-methyl-5-(morpholin-4-ium-4-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 4-[[5-[(2-Fluorophenyl)methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]methyl]morpholin-4-ium —— C15H20FN4OS+
    4-[[5-[(2-Fluorophenyl)methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]methyl]morpholin-4-ium
    —— 4-[[5-[(3-Fluorophenyl)methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]methyl]morpholin-4-ium —— C15H20FN4OS+
    4-[[5-[(3-Fluorophenyl)methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]methyl]morpholin-4-ium
    —— 4-[[5-[(4-Bromophenyl)methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]methyl]morpholin-4-ium —— C15H20BrN4OS+
    4-[[5-[(4-Bromophenyl)methylsulfanyl]-4-methyl-1,2,4-triazol-3-yl]methyl]morpholin-4-ium
    —— N-[(1S,2S)-2-methylcyclohexyl]-2-[[4-methyl-5-(morpholin-4-ium-4-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C17H30N5O2S+
    N-[(1S,2S)-2-methylcyclohexyl]-2-[[4-methyl-5-(morpholin-4-ium-4-ylmethyl)-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 3-[(5-Pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanoate —— C10H8N3O3S-
    3-[(5-Pyridin-4-yl-1,3,4-oxadiazol-2-yl)sulfanyl]propanoate
    —— 6-Methyl-2-methylsulfanyl-5-prop-2-enylpyrimidine-4-thiolate —— C9H11N2S2-
    6-Methyl-2-methylsulfanyl-5-prop-2-enylpyrimidine-4-thiolate
    —— 2-[(5-Ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetate —— C6H7N2O3S-
    2-[(5-Ethyl-1,3,4-oxadiazol-2-yl)sulfanyl]acetate
    —— (2R)-2-[(4,5-dimethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoate —— C10H13N2O3S-
    (2R)-2-[(4,5-dimethyl-6-oxo-1H-pyrimidin-2-yl)sulfanyl]butanoate
    —— 1-[4-[2-(4-Bromophenyl)sulfanylpyridine-3-carbonyl]-1,4-diazepan-1-yl]ethanone —— C19H20BrN3O2S
    1-[4-[2-(4-Bromophenyl)sulfanylpyridine-3-carbonyl]-1,4-diazepan-1-yl]ethanone
    —— 4-[(6S)-2-fluoro-8-methoxy-6H-benzo[b][4,1]benzoxathiepin-6-yl]-1-methylpiperidin-1-ium —— C20H23FNO2S+
    4-[(6S)-2-fluoro-8-methoxy-6H-benzo[b][4,1]benzoxathiepin-6-yl]-1-methylpiperidin-1-ium
    —— 1-[(1S)-1-[5-chloro-2-(2-chlorophenyl)sulfanylphenyl]ethyl]-4-methylpiperazine-1,4-diium —— C19H24Cl2N2S+2
    1-[(1S)-1-[5-chloro-2-(2-chlorophenyl)sulfanylphenyl]ethyl]-4-methylpiperazine-1,4-diium
    —— (2S)-1-(4-ethylpiperazin-1-yl)-2-(2-fluorophenyl)sulfanylpropan-1-one —— C15H21FN2OS
    (2S)-1-(4-ethylpiperazin-1-yl)-2-(2-fluorophenyl)sulfanylpropan-1-one
    —— 1-[(1R)-1-[5-chloro-2-(2-chlorophenyl)sulfanylphenyl]ethyl]-4-methylpiperazine-1,4-diium —— C19H24Cl2N2S+2
    1-[(1R)-1-[5-chloro-2-(2-chlorophenyl)sulfanylphenyl]ethyl]-4-methylpiperazine-1,4-diium
    —— (2R)-1-(4-ethylpiperazin-1-yl)-2-(2-fluorophenyl)sulfanylpropan-1-one —— C15H21FN2OS
    (2R)-1-(4-ethylpiperazin-1-yl)-2-(2-fluorophenyl)sulfanylpropan-1-one
    —— 2-Amino-4,6-dimethyl-5-[(5-phenylsulfanylfuran-2-yl)methylidene]cyclopenta[b]pyridin-1-ium-3,7-dicarbonitrile —— C23H17N4OS+
    2-Amino-4,6-dimethyl-5-[(5-phenylsulfanylfuran-2-yl)methylidene]cyclopenta[b]pyridin-1-ium-3,7-dicarbonitrile
    —— 1-[(1S)-1-[5-chloro-2-(2,5-dichlorophenyl)sulfanylphenyl]ethyl]-4-methylpiperazine-1,4-diium —— C19H23Cl3N2S+2
    1-[(1S)-1-[5-chloro-2-(2,5-dichlorophenyl)sulfanylphenyl]ethyl]-4-methylpiperazine-1,4-diium
    —— 4-oxo-2-[2-[(2S)-piperidin-2-yl]ethylsulfanyl]-6-propyl-1H-pyrimidine-5-carbonitrile —— C15H22N4OS
    4-oxo-2-[2-[(2S)-piperidin-2-yl]ethylsulfanyl]-6-propyl-1H-pyrimidine-5-carbonitrile
    —— 1-[(1R)-1-[5-chloro-2-(2,5-dichlorophenyl)sulfanylphenyl]ethyl]-4-methylpiperazine-1,4-diium —— C19H23Cl3N2S+2
    1-[(1R)-1-[5-chloro-2-(2,5-dichlorophenyl)sulfanylphenyl]ethyl]-4-methylpiperazine-1,4-diium
    —— (2S)-2-[[5-cyano-6-(furan-2-yl)-4-oxo-1H-pyrimidin-2-yl]sulfanyl]-3-methylbutanoic acid —— C14H13N3O4S
    (2S)-2-[[5-cyano-6-(furan-2-yl)-4-oxo-1H-pyrimidin-2-yl]sulfanyl]-3-methylbutanoic acid
    —— (2R)-2-[[5-cyano-6-(furan-2-yl)-4-oxo-1H-pyrimidin-2-yl]sulfanyl]-3-methylbutanoic acid —— C14H13N3O4S
    (2R)-2-[[5-cyano-6-(furan-2-yl)-4-oxo-1H-pyrimidin-2-yl]sulfanyl]-3-methylbutanoic acid
    —— (2R)-3-[(5-cyano-4-oxo-6-propyl-1H-pyrimidin-2-yl)sulfanyl]-2-methylpropanethioamide —— C12H16N4OS2
    (2R)-3-[(5-cyano-4-oxo-6-propyl-1H-pyrimidin-2-yl)sulfanyl]-2-methylpropanethioamide
    —— (2S)-3-[(5-cyano-4-oxo-6-propyl-1H-pyrimidin-2-yl)sulfanyl]-2-methylpropanethioamide —— C12H16N4OS2
    (2S)-3-[(5-cyano-4-oxo-6-propyl-1H-pyrimidin-2-yl)sulfanyl]-2-methylpropanethioamide
    —— 4-oxo-2-[2-[(2R)-piperidin-2-yl]ethylsulfanyl]-6-propyl-1H-pyrimidine-5-carbonitrile —— C15H22N4OS
    4-oxo-2-[2-[(2R)-piperidin-2-yl]ethylsulfanyl]-6-propyl-1H-pyrimidine-5-carbonitrile
    —— (2S)-2-[(5-cyano-4-oxo-6-propyl-1H-pyrimidin-2-yl)sulfanyl]-3-methylbutanoic acid —— C13H17N3O3S
    (2S)-2-[(5-cyano-4-oxo-6-propyl-1H-pyrimidin-2-yl)sulfanyl]-3-methylbutanoic acid
    —— 2-[4-[(1R)-1-(5-chloro-2-phenylsulfanylphenyl)ethyl]piperazine-1,4-diium-1-yl]ethanol —— C20H27ClN2OS+2
    2-[4-[(1R)-1-(5-chloro-2-phenylsulfanylphenyl)ethyl]piperazine-1,4-diium-1-yl]ethanol
    —— 4-[(6R)-8-chloro-2-fluoro-6H-benzo[b][4,1]benzoxathiepin-6-yl]-1-methylpiperidin-1-ium —— C19H20ClFNOS+
    4-[(6R)-8-chloro-2-fluoro-6H-benzo[b][4,1]benzoxathiepin-6-yl]-1-methylpiperidin-1-ium
    —— 5-[[5-cyano-4-(furan-2-yl)-6-oxo-1H-pyrimidin-2-yl]sulfanyl]pentanoic acid —— C14H13N3O4S
    5-[[5-cyano-4-(furan-2-yl)-6-oxo-1H-pyrimidin-2-yl]sulfanyl]pentanoic acid
    —— 1-Methyl-4-[2-[4-(trifluoromethyl)phenyl]sulfanylphenoxy]piperidin-1-ium —— C19H21F3NOS+
    1-Methyl-4-[2-[4-(trifluoromethyl)phenyl]sulfanylphenoxy]piperidin-1-ium
    —— Dimethyl-[2-[methyl-[(2-naphthalen-1-ylsulfanylphenyl)methyl]azaniumyl]ethyl]azanium —— C22H28N2S+2
    Dimethyl-[2-[methyl-[(2-naphthalen-1-ylsulfanylphenyl)methyl]azaniumyl]ethyl]azanium
    —— 6-(furan-2-yl)-4-oxo-2-[[(3S)-piperidin-3-yl]methylsulfanyl]-1H-pyrimidine-5-carbonitrile —— C15H16N4O2S
    6-(furan-2-yl)-4-oxo-2-[[(3S)-piperidin-3-yl]methylsulfanyl]-1H-pyrimidine-5-carbonitrile
    —— [2-[4-chloro-2-[(1S)-1-hydroxyethyl]phenyl]sulfanylphenyl]-(4-methylpiperazin-4-ium-1-yl)methanone —— C20H24ClN2O2S+
    [2-[4-chloro-2-[(1S)-1-hydroxyethyl]phenyl]sulfanylphenyl]-(4-methylpiperazin-4-ium-1-yl)methanone
    —— 1-[(1S)-4-(4-chlorophenyl)sulfanyl-2,3-dihydro-1H-inden-1-yl]-4-methylpiperazine-1,4-diium —— C20H25ClN2S+2
    1-[(1S)-4-(4-chlorophenyl)sulfanyl-2,3-dihydro-1H-inden-1-yl]-4-methylpiperazine-1,4-diium
    —— (2R)-1-(4-ethylpiperazin-1-yl)-2-(4-fluorophenyl)sulfanylpropan-1-one —— C15H21FN2OS
    (2R)-1-(4-ethylpiperazin-1-yl)-2-(4-fluorophenyl)sulfanylpropan-1-one
    —— 2-[(2S)-2-aminobutyl]sulfanyl-6-(furan-2-yl)-4-oxo-1H-pyrimidine-5-carbonitrile —— C13H14N4O2S
    2-[(2S)-2-aminobutyl]sulfanyl-6-(furan-2-yl)-4-oxo-1H-pyrimidine-5-carbonitrile
    —— 2-[(2R)-1-aminopropan-2-yl]sulfanyl-4-oxo-6-propyl-1H-pyrimidine-5-carbonitrile —— C11H16N4OS
    2-[(2R)-1-aminopropan-2-yl]sulfanyl-4-oxo-6-propyl-1H-pyrimidine-5-carbonitrile
    —— 2-Amino-6-[(4-fluorophenyl)methylsulfanyl]-4-thiophen-2-ylpyridin-1-ium-3,5-dicarbonitrile —— C18H12FN4S2+
    2-Amino-6-[(4-fluorophenyl)methylsulfanyl]-4-thiophen-2-ylpyridin-1-ium-3,5-dicarbonitrile
    —— 2-Amino-6-[(2-fluorophenyl)methylsulfanyl]-4-thiophen-2-ylpyridin-1-ium-3,5-dicarbonitrile —— C18H12FN4S2+
    2-Amino-6-[(2-fluorophenyl)methylsulfanyl]-4-thiophen-2-ylpyridin-1-ium-3,5-dicarbonitrile
    —— 2-[(2R)-2-aminobutyl]sulfanyl-4-oxo-6-propyl-1H-pyrimidine-5-carbonitrile —— C12H18N4OS
    2-[(2R)-2-aminobutyl]sulfanyl-4-oxo-6-propyl-1H-pyrimidine-5-carbonitrile
    —— 2-[(2R)-1-aminopropan-2-yl]sulfanyl-6-(furan-2-yl)-4-oxo-1H-pyrimidine-5-carbonitrile —— C12H12N4O2S
    2-[(2R)-1-aminopropan-2-yl]sulfanyl-6-(furan-2-yl)-4-oxo-1H-pyrimidine-5-carbonitrile