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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-1-[1-[(2S)-1-methoxypropan-2-yl]-2,5-dimethylpyrrol-3-yl]ethanone —— C27H28N4O2S
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-1-[1-[(2S)-1-methoxypropan-2-yl]-2,5-dimethylpyrrol-3-yl]ethanone
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-1-[1-[(2R)-1-methoxypropan-2-yl]-2,5-dimethylpyrrol-3-yl]ethanone —— C27H28N4O2S
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-1-[1-[(2R)-1-methoxypropan-2-yl]-2,5-dimethylpyrrol-3-yl]ethanone
    —— 1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethanone —— C25H22N4O2S
    1-(4-acetyl-3,5-dimethyl-1H-pyrrol-2-yl)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethanone
    —— 2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(2,2,2-trifluoroethyl)acetamide —— C19H15F3N4OS
    2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]-N-(2,2,2-trifluoroethyl)acetamide
    —— 1-(5-Chlorothiophen-2-yl)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethanone —— C21H14ClN3OS2
    1-(5-Chlorothiophen-2-yl)-2-[(5,6-diphenyl-1,2,4-triazin-3-yl)sulfanyl]ethanone
    —— 2-{[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-(3-methoxypropyl)acetamide —— C23H26N4O2S
    2-{[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-(3-methoxypropyl)acetamide
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide —— C24H26N4O2S
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[[(2S)-oxolan-2-yl]methyl]acetamide
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[(2R)-butan-2-yl]acetamide —— C23H26N4OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[(2R)-butan-2-yl]acetamide
    —— 2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[(2S)-2-cyano-3-methylbutan-2-yl]acetamide —— C25H27N5OS
    2-[[5,6-bis(4-methylphenyl)-1,2,4-triazin-3-yl]sulfanyl]-N-[(2S)-2-cyano-3-methylbutan-2-yl]acetamide
    —— 2-{[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-cyclopentylacetamide —— C24H26N4OS
    2-{[5,6-Bis(4-methylphenyl)-1,2,4-triazin-3-YL]sulfanyl}-N-cyclopentylacetamide
    —— 5,6-Di(furan-2-yl)-3-(propylsulfanyl)-1,2,4-triazine —— C14H13N3O2S
    5,6-Di(furan-2-yl)-3-(propylsulfanyl)-1,2,4-triazine
    —— 4,7-Bis(benzylsulfanyl)[1,3]thiazolo[4,5-d]pyridazine —— C19H15N3S3
    4,7-Bis(benzylsulfanyl)[1,3]thiazolo[4,5-d]pyridazine
    —— 2-[6-(Carboxylatomethylsulfanyl)pyridazin-3-yl]sulfanylacetate —— C8H6N2O4S2-2
    2-[6-(Carboxylatomethylsulfanyl)pyridazin-3-yl]sulfanylacetate
    —— 5,6-Di(furan-2-yl)-3-(hexylsulfanyl)-1,2,4-triazine —— C17H19N3O2S
    5,6-Di(furan-2-yl)-3-(hexylsulfanyl)-1,2,4-triazine
    —— 3-(1,3-benzothiazol-2-ylsulfanyl)-5-N,6-N-bis(2-methylphenyl)-1,2,4-triazine-5,6-diamine —— C24H20N6S2
    3-(1,3-benzothiazol-2-ylsulfanyl)-5-N,6-N-bis(2-methylphenyl)-1,2,4-triazine-5,6-diamine
    —— 3-Hexylsulfanyl-5,6-diphenyl-1,2,4-triazine —— C21H23N3S
    3-Hexylsulfanyl-5,6-diphenyl-1,2,4-triazine
    —— 3-(5-methyl-1H-pyrazol-3-yl)-4-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C14H14N6S2
    3-(5-methyl-1H-pyrazol-3-yl)-4-[(Z)-(4-methylsulfanylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 6-methyl-N-(4-methylphenyl)-3-methylsulfanyl-1,2,4-triazin-5-amine —— C12H14N4S
    6-methyl-N-(4-methylphenyl)-3-methylsulfanyl-1,2,4-triazin-5-amine
    —— Ethyl 5-[(5-phenyl-1,2,4-triazin-3-yl)sulfanyl]-1,2,3-thiadiazole-4-carboxylate —— C14H11N5O2S2
    Ethyl 5-[(5-phenyl-1,2,4-triazin-3-yl)sulfanyl]-1,2,3-thiadiazole-4-carboxylate
    —— 3-[(3-Nitro-2-pyridinyl)sulfanyl]-5,6-diphenyl-1,2,4-triazine —— C20H13N5O2S
    3-[(3-Nitro-2-pyridinyl)sulfanyl]-5,6-diphenyl-1,2,4-triazine
    —— (2R)-2-[6-(4-chlorophenyl)sulfanylpyridazin-3-yl]-2-phenylacetonitrile —— C18H12ClN3S
    (2R)-2-[6-(4-chlorophenyl)sulfanylpyridazin-3-yl]-2-phenylacetonitrile
    —— (2R)-2-(4-chlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetamide —— C18H14ClN3OS
    (2R)-2-(4-chlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetamide
    —— (E)-2-{3-[(4-chlorobenzyl)sulfanyl]-6-methyl-1,2,4-triazin-5-yl}-N,N-dimethyl-1-ethenamine —— C15H17ClN4S
    (E)-2-{3-[(4-chlorobenzyl)sulfanyl]-6-methyl-1,2,4-triazin-5-yl}-N,N-dimethyl-1-ethenamine
    —— Methyl 2-({6-methyl-3-[3-(trifluoromethyl)phenyl]-1,2,4-triazin-5-yl}sulfanyl)benzenecarboxylate —— C19H14F3N3O2S
    Methyl 2-({6-methyl-3-[3-(trifluoromethyl)phenyl]-1,2,4-triazin-5-yl}sulfanyl)benzenecarboxylate
    —— 2-Chlorophenyl 6-methyl-3-phenyl-1,2,4-triazin-5-yl sulfide —— C16H12ClN3S
    2-Chlorophenyl 6-methyl-3-phenyl-1,2,4-triazin-5-yl sulfide
    —— (2S)-2-phenyl-2-(6-phenylsulfanylpyridazin-3-yl)acetonitrile —— C18H13N3S
    (2S)-2-phenyl-2-(6-phenylsulfanylpyridazin-3-yl)acetonitrile
    —— N-(2-(3-((4-Chlorobenzyl)sulfanyl)-6-methyl-1,2,4-triazin-5-yl)vinyl)-4-fluoroaniline —— C19H16ClFN4S
    N-(2-(3-((4-Chlorobenzyl)sulfanyl)-6-methyl-1,2,4-triazin-5-yl)vinyl)-4-fluoroaniline
    —— 5-(4-Chlorophenyl)sulfanyl-3-(furan-2-yl)-6-phenyl-1,2,4-triazine —— C19H12ClN3OS
    5-(4-Chlorophenyl)sulfanyl-3-(furan-2-yl)-6-phenyl-1,2,4-triazine
    —— (2R)-2-(4-chlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetonitrile —— C18H12ClN3S
    (2R)-2-(4-chlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetonitrile
    —— (2R)-2-(2,4-dichlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetamide —— C18H13Cl2N3OS
    (2R)-2-(2,4-dichlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetamide
    —— (2S)-2-[6-(4-chlorophenyl)sulfanylpyridazin-3-yl]-2-phenylacetonitrile —— C18H12ClN3S
    (2S)-2-[6-(4-chlorophenyl)sulfanylpyridazin-3-yl]-2-phenylacetonitrile
    —— N-(2-{3-[(4-chlorobenzyl)sulfanyl]-6-methyl-1,2,4-triazin-5-yl}vinyl)-4-methylaniline —— C20H19ClN4S
    N-(2-{3-[(4-chlorobenzyl)sulfanyl]-6-methyl-1,2,4-triazin-5-yl}vinyl)-4-methylaniline
    —— (2S)-2-(4-chlorophenyl)-2-[6-(4-chlorophenyl)sulfanylpyridazin-3-yl]acetonitrile —— C18H11Cl2N3S
    (2S)-2-(4-chlorophenyl)-2-[6-(4-chlorophenyl)sulfanylpyridazin-3-yl]acetonitrile
    —— 4-Fluorophenyl 6-methyl-3-(4-methylphenyl)-1,2,4-triazin-5-yl sulfide —— C17H14FN3S
    4-Fluorophenyl 6-methyl-3-(4-methylphenyl)-1,2,4-triazin-5-yl sulfide
    —— (2R)-2-(2,6-dichlorophenyl)-2-[6-(2,4-difluorophenyl)sulfanylpyridazin-3-yl]acetamide —— C18H11Cl2F2N3OS
    (2R)-2-(2,6-dichlorophenyl)-2-[6-(2,4-difluorophenyl)sulfanylpyridazin-3-yl]acetamide
    —— (2S)-2-(2,4-dichlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetamide —— C18H13Cl2N3OS
    (2S)-2-(2,4-dichlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetamide
    —— Ethyl 5-[(4-methoxyphenyl)sulfanyl]-3-phenyl-1,2,4-triazine-6-carboxylate —— C19H17N3O3S
    Ethyl 5-[(4-methoxyphenyl)sulfanyl]-3-phenyl-1,2,4-triazine-6-carboxylate
    —— Ethyl 5-{[2-(methoxycarbonyl)phenyl]sulfanyl}-3-[3-(trifluoromethyl)phenyl]-1,2,4-triazine-6-carboxylate —— C21H16F3N3O4S
    Ethyl 5-{[2-(methoxycarbonyl)phenyl]sulfanyl}-3-[3-(trifluoromethyl)phenyl]-1,2,4-triazine-6-carboxylate
    —— N-(2-(3-(Benzylsulfanyl)-6-methyl-1,2,4-triazin-5-yl)vinyl)-4-methylaniline —— C20H20N4S
    N-(2-(3-(Benzylsulfanyl)-6-methyl-1,2,4-triazin-5-yl)vinyl)-4-methylaniline
    —— Ethyl 5-[(2,5-dimethylphenyl)sulfanyl]-3-phenyl-1,2,4-triazine-6-carboxylate —— C20H19N3O2S
    Ethyl 5-[(2,5-dimethylphenyl)sulfanyl]-3-phenyl-1,2,4-triazine-6-carboxylate
    —— Ethyl 2-{[3-phenyl-6-(trifluoromethyl)-1,2,4-triazin-5-yl]sulfanyl}acetate —— C14H12F3N3O2S
    Ethyl 2-{[3-phenyl-6-(trifluoromethyl)-1,2,4-triazin-5-yl]sulfanyl}acetate
    —— (2S)-2-(4-chlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetonitrile —— C18H12ClN3S
    (2S)-2-(4-chlorophenyl)-2-(6-phenylsulfanylpyridazin-3-yl)acetonitrile
    —— (2R)-2-(4-chlorophenyl)-2-[6-(4-chlorophenyl)sulfanylpyridazin-3-yl]acetamide —— C18H13Cl2N3OS
    (2R)-2-(4-chlorophenyl)-2-[6-(4-chlorophenyl)sulfanylpyridazin-3-yl]acetamide
    —— Ethyl 5-[(2,6-dichlorophenyl)sulfanyl]-3-phenyl-1,2,4-triazine-6-carboxylate —— C18H13Cl2N3O2S
    Ethyl 5-[(2,6-dichlorophenyl)sulfanyl]-3-phenyl-1,2,4-triazine-6-carboxylate
    —— Ethyl 5-{[2-(methoxycarbonyl)phenyl]sulfanyl}-3-phenyl-1,2,4-triazine-6-carboxylate —— C20H17N3O4S
    Ethyl 5-{[2-(methoxycarbonyl)phenyl]sulfanyl}-3-phenyl-1,2,4-triazine-6-carboxylate
    —— 4-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]-3-nitrobenzonitrile —— C22H13N5O2S
    4-[(5,6-Diphenyl-1,2,4-triazin-3-yl)sulfanyl]-3-nitrobenzonitrile
    —— Ethyl 3-phenyl-5-{[3-(trifluoromethyl)phenyl]sulfanyl}-1,2,4-triazine-6-carboxylate —— C19H14F3N3O2S
    Ethyl 3-phenyl-5-{[3-(trifluoromethyl)phenyl]sulfanyl}-1,2,4-triazine-6-carboxylate
    —— Ethyl 5-[(2-chlorophenyl)sulfanyl]-3-phenyl-1,2,4-triazine-6-carboxylate —— C18H14ClN3O2S
    Ethyl 5-[(2-chlorophenyl)sulfanyl]-3-phenyl-1,2,4-triazine-6-carboxylate
    —— 2-[[5,6-bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]-N-cyclopentylacetamide —— C18H18N4O3S
    2-[[5,6-bis(furan-2-yl)-1,2,4-triazin-3-yl]sulfanyl]-N-cyclopentylacetamide
    —— N-(2-(3-(Benzylsulfanyl)-6-methyl-1,2,4-triazin-5-yl)vinyl)-4-chloroaniline —— C19H17ClN4S
    N-(2-(3-(Benzylsulfanyl)-6-methyl-1,2,4-triazin-5-yl)vinyl)-4-chloroaniline