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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— (2R)-2-(4-methylsulfanylphenyl)-2-(1,4-oxazepan-4-yl)ethanamine —— C14H22N2OS
    (2R)-2-(4-methylsulfanylphenyl)-2-(1,4-oxazepan-4-yl)ethanamine
    —— 2-[[5-[(4-chloroanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-pyridin-2-ylmethylideneamino]acetamide —— C20H20ClN7OS
    2-[[5-[(4-chloroanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-pyridin-2-ylmethylideneamino]acetamide
    —— N-[(Z)-benzylideneamino]-2-[[5-[(1S)-1-(4-bromoanilino)ethyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H21BrN6OS
    N-[(Z)-benzylideneamino]-2-[[5-[(1S)-1-(4-bromoanilino)ethyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— N-[(Z)-benzylideneamino]-2-[[5-[(1R)-1-(4-bromoanilino)ethyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H21BrN6OS
    N-[(Z)-benzylideneamino]-2-[[5-[(1R)-1-(4-bromoanilino)ethyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— (2S)-2-[[5-[(3-chloroanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-(4-methylphenyl)ethylideneamino]propanamide —— C22H25ClN6OS
    (2S)-2-[[5-[(3-chloroanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-1-(4-methylphenyl)ethylideneamino]propanamide
    —— N-[(Z)-(1,3-dimethylpyrazol-4-yl)methylideneamino]-2-[[4-methyl-5-[(2-methylanilino)methyl]-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C19H24N8OS
    N-[(Z)-(1,3-dimethylpyrazol-4-yl)methylideneamino]-2-[[4-methyl-5-[(2-methylanilino)methyl]-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 2-[[5-[(4-bromoanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-pyridin-3-ylmethylideneamino]acetamide —— C18H18BrN7OS
    2-[[5-[(4-bromoanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-pyridin-3-ylmethylideneamino]acetamide
    —— 2-[[5-[(4-bromoanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(4-methylphenyl)methylideneamino]acetamide —— C20H21BrN6OS
    2-[[5-[(4-bromoanilino)methyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(4-methylphenyl)methylideneamino]acetamide
    —— 2-[[5-[(1S)-1-(4-bromoanilino)ethyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-1-(4-fluorophenyl)ethylideneamino]acetamide —— C21H22BrFN6OS
    2-[[5-[(1S)-1-(4-bromoanilino)ethyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-1-(4-fluorophenyl)ethylideneamino]acetamide
    —— (2S)-2-[(4-ethyl-1,3-thiazol-2-yl)sulfanyl]propanoic acid —— C8H11NO2S2
    (2S)-2-[(4-ethyl-1,3-thiazol-2-yl)sulfanyl]propanoic acid
    —— (2R)-2-[(4-ethyl-1,3-thiazol-2-yl)sulfanyl]propanoic acid —— C8H11NO2S2
    (2R)-2-[(4-ethyl-1,3-thiazol-2-yl)sulfanyl]propanoic acid
    —— 2-[[5-[(1R)-1-(4-bromoanilino)ethyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-1-(4-fluorophenyl)ethylideneamino]acetamide —— C21H22BrFN6OS
    2-[[5-[(1R)-1-(4-bromoanilino)ethyl]-4-methyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-1-(4-fluorophenyl)ethylideneamino]acetamide
    —— N-[(1R,2R)-2-carbamothioylcyclopentyl]acetamide —— C8H14N2OS
    N-[(1R,2R)-2-carbamothioylcyclopentyl]acetamide
    —— N-[(1S,2R)-2-carbamothioylcyclopentyl]cyclohexanecarboxamide —— C13H22N2OS
    N-[(1S,2R)-2-carbamothioylcyclopentyl]cyclohexanecarboxamide
    —— N-[(1R,2R)-2-carbamothioylcyclopentyl]cyclohexanecarboxamide —— C13H22N2OS
    N-[(1R,2R)-2-carbamothioylcyclopentyl]cyclohexanecarboxamide
    —— (2R)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-1-phenylethylideneamino]propanamide —— C23H26N6OS
    (2R)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-1-phenylethylideneamino]propanamide
    —— (2S)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(3-hydroxyphenyl)methylideneamino]propanamide —— C22H24N6O2S
    (2S)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(3-hydroxyphenyl)methylideneamino]propanamide
    —— (2S)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-1-phenylethylideneamino]propanamide —— C23H26N6OS
    (2S)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(E)-1-phenylethylideneamino]propanamide
    —— 2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(3-hydroxyphenyl)methylideneamino]acetamide —— C21H22N6O2S
    2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(3-hydroxyphenyl)methylideneamino]acetamide
    —— N-[(1S,2S)-2-carbamothioylcyclopentyl]cyclohexanecarboxamide —— C13H22N2OS
    N-[(1S,2S)-2-carbamothioylcyclopentyl]cyclohexanecarboxamide
    —— N-[(1R,2S)-2-carbamothioylcyclopentyl]cyclohexanecarboxamide —— C13H22N2OS
    N-[(1R,2S)-2-carbamothioylcyclopentyl]cyclohexanecarboxamide
    —— N-[(1S,2S)-2-carbamothioylcyclopentyl]acetamide —— C8H14N2OS
    N-[(1S,2S)-2-carbamothioylcyclopentyl]acetamide
    —— N-[(1R,2R)-2-carbamothioylcyclopentyl]-2-cyclopentylacetamide —— C13H22N2OS
    N-[(1R,2R)-2-carbamothioylcyclopentyl]-2-cyclopentylacetamide
    —— N-[(1R,2S)-2-carbamothioylcyclopentyl]-2-cyclopentylacetamide —— C13H22N2OS
    N-[(1R,2S)-2-carbamothioylcyclopentyl]-2-cyclopentylacetamide
    —— N-[(1S,2S)-2-carbamothioylcyclopentyl]-2-cyclopentylacetamide —— C13H22N2OS
    N-[(1S,2S)-2-carbamothioylcyclopentyl]-2-cyclopentylacetamide
    —— N-[(1S,2S)-2-carbamothioylcyclopentyl]cycloheptanecarboxamide —— C14H24N2OS
    N-[(1S,2S)-2-carbamothioylcyclopentyl]cycloheptanecarboxamide
    —— N-[(1S,2R)-2-carbamothioylcyclopentyl]cycloheptanecarboxamide —— C14H24N2OS
    N-[(1S,2R)-2-carbamothioylcyclopentyl]cycloheptanecarboxamide
    —— (2R)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(4-chlorophenyl)methylideneamino]propanamide —— C22H23ClN6OS
    (2R)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(4-chlorophenyl)methylideneamino]propanamide
    —— (2R)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(3-hydroxyphenyl)methylideneamino]propanamide —— C22H24N6O2S
    (2R)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(3-hydroxyphenyl)methylideneamino]propanamide
    —— N-[(1R,2S)-2-carbamothioylcyclopentyl]acetamide —— C8H14N2OS
    N-[(1R,2S)-2-carbamothioylcyclopentyl]acetamide
    —— (2S)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(4-chlorophenyl)methylideneamino]propanamide —— C22H23ClN6OS
    (2S)-2-[[5-(anilinomethyl)-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]-N-[(Z)-(4-chlorophenyl)methylideneamino]propanamide
    —— N-[(1R,2S)-2-carbamothioylcyclopentyl]cycloheptanecarboxamide —— C14H24N2OS
    N-[(1R,2S)-2-carbamothioylcyclopentyl]cycloheptanecarboxamide
    —— N-[(1R,2R)-2-carbamothioylcyclopentyl]cycloheptanecarboxamide —— C14H24N2OS
    N-[(1R,2R)-2-carbamothioylcyclopentyl]cycloheptanecarboxamide
    —— (2S)-N-[(Z)-(2-fluorophenyl)methylideneamino]-2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C23H25FN6OS
    (2S)-N-[(Z)-(2-fluorophenyl)methylideneamino]-2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— N-[(1S,2R)-2-carbamothioylcyclopentyl]-2-cyclopentylacetamide —— C13H22N2OS
    N-[(1S,2R)-2-carbamothioylcyclopentyl]-2-cyclopentylacetamide
    —— N-[(1S,2R)-2-carbamothioylcyclopentyl]acetamide —— C8H14N2OS
    N-[(1S,2R)-2-carbamothioylcyclopentyl]acetamide
    —— (3E)-4,6-diphenyl-3-(5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazol-6-ylidene)pyridin-2-one —— C20H13N5OS
    (3E)-4,6-diphenyl-3-(5H-[1,2,4]triazolo[3,4-b][1,3,4]thiadiazol-6-ylidene)pyridin-2-one
    —— (4Z)-4-[[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-5-methyl-2-phenylpyrazol-3-one —— C21H15ClN2O2S
    (4Z)-4-[[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylidene]-5-methyl-2-phenylpyrazol-3-one
    —— 2-chloro-4-cyclohexylsulfanyl-N'-hydroxybenzenecarboximidamide —— C13H17ClN2OS
    2-chloro-4-cyclohexylsulfanyl-N'-hydroxybenzenecarboximidamide
    —— 2-chloro-N'-hydroxy-4-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]benzenecarboximidamide —— C10H9ClN4O2S
    2-chloro-N'-hydroxy-4-[(5-methyl-1,3,4-oxadiazol-2-yl)sulfanyl]benzenecarboximidamide
    —— 2-chloro-N'-hydroxy-4-(3-methylphenyl)sulfanylbenzenecarboximidamide —— C14H13ClN2OS
    2-chloro-N'-hydroxy-4-(3-methylphenyl)sulfanylbenzenecarboximidamide
    —— 2-chloro-N'-hydroxy-4-(1,3,4-thiadiazol-2-ylsulfanyl)benzenecarboximidamide —— C9H7ClN4OS2
    2-chloro-N'-hydroxy-4-(1,3,4-thiadiazol-2-ylsulfanyl)benzenecarboximidamide
    —— 2-chloro-N'-hydroxy-4-(5-methylpyrimidin-2-yl)sulfanylbenzenecarboximidamide —— C12H11ClN4OS
    2-chloro-N'-hydroxy-4-(5-methylpyrimidin-2-yl)sulfanylbenzenecarboximidamide
    —— 2-chloro-4-(4-chlorophenyl)sulfanyl-N'-hydroxybenzenecarboximidamide —— C13H10Cl2N2OS
    2-chloro-4-(4-chlorophenyl)sulfanyl-N'-hydroxybenzenecarboximidamide
    —— (2Z)-6-ethoxy-2-[(2-hydroxyphenyl)methylidene]-1-benzothiophen-3-one —— C17H14O3S
    (2Z)-6-ethoxy-2-[(2-hydroxyphenyl)methylidene]-1-benzothiophen-3-one
    —— 3,3-dimethyl-N-[(1R)-1-(4-methylsulfanylphenyl)ethyl]butan-1-amine —— C15H25NS
    3,3-dimethyl-N-[(1R)-1-(4-methylsulfanylphenyl)ethyl]butan-1-amine
    —— 3,3-dimethyl-N-[(1S)-1-(4-methylsulfanylphenyl)ethyl]butan-1-amine —— C15H25NS
    3,3-dimethyl-N-[(1S)-1-(4-methylsulfanylphenyl)ethyl]butan-1-amine
    —— [(Z)-[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]thiourea —— C12H10ClN3OS2
    [(Z)-[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]thiourea
    —— (2E)-2-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)hydrazinecarbothioamide —— C12H10ClN3OS2
    (2E)-2-({5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)hydrazinecarbothioamide
    —— (3R)-3-methyl-5-oxo-5-(2-phenylsulfanylethylamino)pentanoic acid —— C14H19NO3S
    (3R)-3-methyl-5-oxo-5-(2-phenylsulfanylethylamino)pentanoic acid