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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— Propyl 3-(2-aminophenyl)sulfanylquinoxaline-2-carboxylate —— C18H17N3O2S
    Propyl 3-(2-aminophenyl)sulfanylquinoxaline-2-carboxylate
    —— 5-[[2-(Furan-2-yl)-5,6-dimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl]sulfanyl]-1,3,4-thiadiazol-2-amine —— C13H11N7OS2
    5-[[2-(Furan-2-yl)-5,6-dimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl]sulfanyl]-1,3,4-thiadiazol-2-amine
    —— 5-[[2-(Furan-2-yl)-5,6,7,8-tetrahydro-[1,2,4]triazolo[5,1-b]quinazolin-9-yl]sulfanyl]-1,3,4-thiadiazol-2-amine —— C15H13N7OS2
    5-[[2-(Furan-2-yl)-5,6,7,8-tetrahydro-[1,2,4]triazolo[5,1-b]quinazolin-9-yl]sulfanyl]-1,3,4-thiadiazol-2-amine
    —— Methyl 3-(2-methylphenyl)sulfanylquinoxaline-2-carboxylate —— C17H14N2O2S
    Methyl 3-(2-methylphenyl)sulfanylquinoxaline-2-carboxylate
    —— 5-[(5,6-Dimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl)sulfanyl]-1,3,4-thiadiazol-2-amine —— C9H9N7S2
    5-[(5,6-Dimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl)sulfanyl]-1,3,4-thiadiazol-2-amine
    —— Ethyl 3-(2-aminophenyl)sulfanylquinoxaline-2-carboxylate —— C17H15N3O2S
    Ethyl 3-(2-aminophenyl)sulfanylquinoxaline-2-carboxylate
    —— 2-[(2,5,6-Trimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl)sulfanyl]aniline —— C14H15N5S
    2-[(2,5,6-Trimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl)sulfanyl]aniline
    —— 4-[[6-Ethyl-2-(furan-2-yl)-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl]sulfanyl]aniline —— C18H17N5OS
    4-[[6-Ethyl-2-(furan-2-yl)-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl]sulfanyl]aniline
    —— 5-[(2,5,6-Trimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl)sulfanyl]-1,3,4-thiadiazol-2-amine —— C10H11N7S2
    5-[(2,5,6-Trimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl)sulfanyl]-1,3,4-thiadiazol-2-amine
    —— 2-[[2-(Furan-2-yl)-5,6-dimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl]sulfanyl]aniline —— C17H15N5OS
    2-[[2-(Furan-2-yl)-5,6-dimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl]sulfanyl]aniline
    —— 5-[(5-Methyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl)sulfanyl]-1,3,4-thiadiazol-2-amine —— C8H7N7S2
    5-[(5-Methyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl)sulfanyl]-1,3,4-thiadiazol-2-amine
    —— 4-[[2-(Furan-2-yl)-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl]sulfanyl]aniline —— C16H13N5OS
    4-[[2-(Furan-2-yl)-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl]sulfanyl]aniline
    —— Ethyl 3-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]quinoxaline-2-carboxylate —— C13H11N5O2S2
    Ethyl 3-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]quinoxaline-2-carboxylate
    —— 3-(2-Aminophenyl)sulfanylquinoxaline-2-carboxylic acid —— C15H11N3O2S
    3-(2-Aminophenyl)sulfanylquinoxaline-2-carboxylic acid
    —— 2-[[2-(Furan-2-yl)-5,6,7,8-tetrahydro-[1,2,4]triazolo[5,1-b]quinazolin-9-yl]sulfanyl]aniline —— C19H17N5OS
    2-[[2-(Furan-2-yl)-5,6,7,8-tetrahydro-[1,2,4]triazolo[5,1-b]quinazolin-9-yl]sulfanyl]aniline
    —— 2-[(6-Ethyl-2,5-dimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl)sulfanyl]aniline —— C15H17N5S
    2-[(6-Ethyl-2,5-dimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl)sulfanyl]aniline
    —— 5-[[11-(Furan-2-yl)-1,8,10,12-tetrazatricyclo[7.3.0.03,7]dodeca-2,7,9,11-tetraen-2-yl]sulfanyl]-1,3,4-thiadiazol-2-amine —— C14H11N7OS2
    5-[[11-(Furan-2-yl)-1,8,10,12-tetrazatricyclo[7.3.0.03,7]dodeca-2,7,9,11-tetraen-2-yl]sulfanyl]-1,3,4-thiadiazol-2-amine
    —— 5-[[2-(Furan-2-yl)-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl]sulfanyl]-1,3,4-thiadiazol-2-amine —— C12H9N7OS2
    5-[[2-(Furan-2-yl)-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl]sulfanyl]-1,3,4-thiadiazol-2-amine
    —— 5-[[6-Ethyl-2-(furan-2-yl)-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl]sulfanyl]-1,3,4-thiadiazol-2-amine —— C14H13N7OS2
    5-[[6-Ethyl-2-(furan-2-yl)-5-methyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl]sulfanyl]-1,3,4-thiadiazol-2-amine
    —— 5-[(6-Ethyl-2,5-dimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl)sulfanyl]-1,3,4-thiadiazol-2-amine —— C11H13N7S2
    5-[(6-Ethyl-2,5-dimethyl-[1,2,4]triazolo[1,5-a]pyrimidin-7-yl)sulfanyl]-1,3,4-thiadiazol-2-amine
    —— 2-(1,8,10,12-Tetrazatricyclo[7.3.0.03,7]dodeca-2,7,9,11-tetraen-2-ylsulfanyl)aniline —— C14H13N5S
    2-(1,8,10,12-Tetrazatricyclo[7.3.0.03,7]dodeca-2,7,9,11-tetraen-2-ylsulfanyl)aniline
    —— 2-[[11-(Furan-2-yl)-1,8,10,12-tetrazatricyclo[7.3.0.03,7]dodeca-2,7,9,11-tetraen-2-yl]sulfanyl]aniline —— C18H15N5OS
    2-[[11-(Furan-2-yl)-1,8,10,12-tetrazatricyclo[7.3.0.03,7]dodeca-2,7,9,11-tetraen-2-yl]sulfanyl]aniline
    —— 3-[(5-Amino-1,3,4-thiadiazol-2-yl)sulfanyl]quinoxaline-2-carboxylic acid —— C11H7N5O2S2
    3-[(5-Amino-1,3,4-thiadiazol-2-yl)sulfanyl]quinoxaline-2-carboxylic acid
    —— N-[(E)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]-4-(thiophen-2-ylsulfonylamino)benzamide —— C21H17N7O5S3
    N-[(E)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]-4-(thiophen-2-ylsulfonylamino)benzamide
    —— 3-(3-methoxyphenyl)-4-[(E)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]-1H-1,2,4-triazole-5-thione —— C19H16N8O3S2
    3-(3-methoxyphenyl)-4-[(E)-[4-[(4-methyl-1,2,4-triazol-3-yl)sulfanyl]-3-nitrophenyl]methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 2-[(E)-(4-methylsulfanylphenyl)methylideneamino]oxy-N-(2,2,2-trifluoroethyl)acetamide —— C12H13F3N2O2S
    2-[(E)-(4-methylsulfanylphenyl)methylideneamino]oxy-N-(2,2,2-trifluoroethyl)acetamide
    —— 3-(naphthalen-1-ylmethyl)-4-[(E)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione —— C24H17N7O2S2
    3-(naphthalen-1-ylmethyl)-4-[(E)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]-1H-1,2,4-triazole-5-thione
    —— 3-(4-methylphenyl)sulfanyl-N-[(E)-pyridin-3-ylmethylideneamino]propanamide —— C16H17N3OS
    3-(4-methylphenyl)sulfanyl-N-[(E)-pyridin-3-ylmethylideneamino]propanamide
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(4-ethylphenyl)methanimine —— C19H19BrN4S
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(4-ethylphenyl)methanimine
    —— (E,Z)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-2-methyl-3-phenylprop-2-en-1-imine —— C20H19BrN4S
    (E,Z)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-2-methyl-3-phenylprop-2-en-1-imine
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propan-2-yl-1,2,4-triazol-4-yl]-1-(3-methylthiophen-2-yl)methanimine —— C18H19BrN4S2
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propan-2-yl-1,2,4-triazol-4-yl]-1-(3-methylthiophen-2-yl)methanimine
    —— (E)-1-(5-bromofuran-2-yl)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]methanimine —— C15H12Br2N4OS
    (E)-1-(5-bromofuran-2-yl)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]methanimine
    —— (E)-1-(2-bromophenyl)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]methanimine —— C17H14Br2N4S
    (E)-1-(2-bromophenyl)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]methanimine
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(2-chloro-6-fluorophenyl)methanimine —— C17H13BrClFN4S
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(2-chloro-6-fluorophenyl)methanimine
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(2-methylphenyl)methanimine —— C18H17BrN4S
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(2-methylphenyl)methanimine
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(2,3,6-trichlorophenyl)methanimine —— C17H12BrCl3N4S
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(2,3,6-trichlorophenyl)methanimine
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(4-fluorophenyl)methanimine —— C17H14BrFN4S
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(4-fluorophenyl)methanimine
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(4-methylsulfanylphenyl)methanimine —— C18H17BrN4S2
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(4-methylsulfanylphenyl)methanimine
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(2-fluorophenyl)methanimine —— C17H14BrFN4S
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(2-fluorophenyl)methanimine
    —— 4-[(E)-[3-[(4-bromophenyl)methylsulfanyl]-5-propan-2-yl-1,2,4-triazol-4-yl]iminomethyl]-N,N-diethylaniline —— C23H28BrN5S
    4-[(E)-[3-[(4-bromophenyl)methylsulfanyl]-5-propan-2-yl-1,2,4-triazol-4-yl]iminomethyl]-N,N-diethylaniline
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(3-chlorophenyl)methanimine —— C17H14BrClN4S
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(3-chlorophenyl)methanimine
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propan-2-yl-1,2,4-triazol-4-yl]-1-(4-ethylphenyl)methanimine —— C21H23BrN4S
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propan-2-yl-1,2,4-triazol-4-yl]-1-(4-ethylphenyl)methanimine
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-pyridin-2-ylmethanimine —— C16H14BrN5S
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-pyridin-2-ylmethanimine
    —— 4-[(E)-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]iminomethyl]-N,N-diethylaniline —— C21H24BrN5S
    4-[(E)-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]iminomethyl]-N,N-diethylaniline
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(3-methylphenyl)methanimine —— C18H17BrN4S
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(3-methylphenyl)methanimine
    —— (E)-1-(3-bromophenyl)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]methanimine —— C17H14Br2N4S
    (E)-1-(3-bromophenyl)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]methanimine
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propan-2-yl-1,2,4-triazol-4-yl]-1-thiophen-2-ylmethanimine —— C17H17BrN4S2
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-propan-2-yl-1,2,4-triazol-4-yl]-1-thiophen-2-ylmethanimine
    —— (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(4-methylphenyl)methanimine —— C18H17BrN4S
    (E)-N-[3-[(4-bromophenyl)methylsulfanyl]-5-methyl-1,2,4-triazol-4-yl]-1-(4-methylphenyl)methanimine
    —— 4-[(E)-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]iminomethyl]-N,N-diethylaniline —— C20H22ClN5S
    4-[(E)-[3-[(4-chlorophenyl)methylsulfanyl]-1,2,4-triazol-4-yl]iminomethyl]-N,N-diethylaniline
    —— (E,Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]-2-methyl-3-phenylprop-2-en-1-imine —— C22H23ClN4S
    (E,Z)-N-[3-[(4-chlorophenyl)methylsulfanyl]-5-propyl-1,2,4-triazol-4-yl]-2-methyl-3-phenylprop-2-en-1-imine