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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2,4-Dimethyl-6-phenylsulfanylaniline —— C14H15NS
    2,4-Dimethyl-6-phenylsulfanylaniline
    —— (7E)-4-thiophen-2-yl-7-(thiophen-2-ylmethylidene)-2-(3,5,5-trimethylheptylsulfanyl)-5,6-dihydrocyclopenta[b]pyridine-3-carbonitrile —— C28H32N2S3
    (7E)-4-thiophen-2-yl-7-(thiophen-2-ylmethylidene)-2-(3,5,5-trimethylheptylsulfanyl)-5,6-dihydrocyclopenta[b]pyridine-3-carbonitrile
    —— N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-4,6-dimorpholin-4-yl-1,3,5-triazin-2-amine —— C24H25ClN8O4S
    N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]-4,6-dimorpholin-4-yl-1,3,5-triazin-2-amine
    —— (5Z)-3-benzyl-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-1,3-thiazolidine-2,4-dione —— C24H18N2O4S2
    (5Z)-3-benzyl-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-1,3-thiazolidine-2,4-dione
    —— 2,4-Dimethyl-6-(4-methylphenyl)sulfanylaniline —— C15H17NS
    2,4-Dimethyl-6-(4-methylphenyl)sulfanylaniline
    —— N-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]adamantane-1-carboxamide —— C28H27N3O4S3
    N-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-4-oxo-2-sulfanylidene-1,3-thiazolidin-3-yl]adamantane-1-carboxamide
    —— 3,5-Dimethyl-4-(4-methylphenyl)sulfanylaniline —— C15H17NS
    3,5-Dimethyl-4-(4-methylphenyl)sulfanylaniline
    —— 1-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]-3-prop-2-enylthiourea —— C18H18N4O2S2
    1-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]-3-prop-2-enylthiourea
    —— 1-[(1S,3R,7R,9S,11S)-11-benzyl-5,9-dimethyl-5-azatricyclo[5.3.2.03,9]dodecan-12-yl]-2-pyridin-3-ylsulfanylethanone —— C27H34N2OS
    1-[(1S,3R,7R,9S,11S)-11-benzyl-5,9-dimethyl-5-azatricyclo[5.3.2.03,9]dodecan-12-yl]-2-pyridin-3-ylsulfanylethanone
    —— 2-(4,5-dichloropyridin-2-yl)sulfanyl-N-[(Z)-pyridin-3-ylmethylideneamino]acetamide —— C13H10Cl2N4OS
    2-(4,5-dichloropyridin-2-yl)sulfanyl-N-[(Z)-pyridin-3-ylmethylideneamino]acetamide
    —— 2-[4-(difluoromethyl)-6-methylpyrimidin-2-yl]sulfanyl-N-(furan-2-ylmethyl)acetamide —— C13H13F2N3O2S
    2-[4-(difluoromethyl)-6-methylpyrimidin-2-yl]sulfanyl-N-(furan-2-ylmethyl)acetamide
    —— 1-[(1S,3R,7R,9S,11R)-11-benzyl-5-(2-methoxyethyl)-9-methyl-2-oxa-5-azatricyclo[5.3.2.03,9]dodecan-12-yl]-2-pyridin-2-ylsulfanylethanone —— C28H36N2O3S
    1-[(1S,3R,7R,9S,11R)-11-benzyl-5-(2-methoxyethyl)-9-methyl-2-oxa-5-azatricyclo[5.3.2.03,9]dodecan-12-yl]-2-pyridin-2-ylsulfanylethanone
    —— 1-[(1S,3R,7R,9S,11R)-11-benzyl-9-methyl-5-prop-2-enyl-2-oxa-5-azatricyclo[5.3.2.03,9]dodecan-12-yl]-2-pyridin-3-ylsulfanylethanone —— C28H34N2O2S
    1-[(1S,3R,7R,9S,11R)-11-benzyl-9-methyl-5-prop-2-enyl-2-oxa-5-azatricyclo[5.3.2.03,9]dodecan-12-yl]-2-pyridin-3-ylsulfanylethanone
    —— 1-[(1S,3R,7R,9S,11S)-11-benzyl-5-(2-methoxyethyl)-9-methyl-5-azatricyclo[5.3.2.03,9]dodecan-12-yl]-2-pyridin-3-ylsulfanylethanone —— C29H38N2O2S
    1-[(1S,3R,7R,9S,11S)-11-benzyl-5-(2-methoxyethyl)-9-methyl-5-azatricyclo[5.3.2.03,9]dodecan-12-yl]-2-pyridin-3-ylsulfanylethanone
    —— N-[(Z)-1-phenylethylideneamino]-2-phenylsulfanylacetamide —— C16H16N2OS
    N-[(Z)-1-phenylethylideneamino]-2-phenylsulfanylacetamide
    —— 1-[(1S,3R,7R,9S,11R)-11-benzyl-5-(cyclopropylmethyl)-9-methyl-2-oxa-5-azatricyclo[5.3.2.03,9]dodecan-12-yl]-2-pyridin-2-ylsulfanylethanone —— C29H36N2O2S
    1-[(1S,3R,7R,9S,11R)-11-benzyl-5-(cyclopropylmethyl)-9-methyl-2-oxa-5-azatricyclo[5.3.2.03,9]dodecan-12-yl]-2-pyridin-2-ylsulfanylethanone
    —— 1-[(1S,3R,7R,9S,11R)-11-benzyl-9-methyl-5-propan-2-yl-2-oxa-5-azatricyclo[5.3.2.03,9]dodecan-12-yl]-2-pyridin-3-ylsulfanylethanone —— C28H36N2O2S
    1-[(1S,3R,7R,9S,11R)-11-benzyl-9-methyl-5-propan-2-yl-2-oxa-5-azatricyclo[5.3.2.03,9]dodecan-12-yl]-2-pyridin-3-ylsulfanylethanone
    —— (2E)-2-[[4-(diethylamino)-2-hydroxyphenyl]methylidene]-1-benzothiophen-3-one —— C19H19NO2S
    (2E)-2-[[4-(diethylamino)-2-hydroxyphenyl]methylidene]-1-benzothiophen-3-one
    —— (NZ)-N-[2-(4,6-diaminopyrimidin-2-yl)sulfanylcyclooctylidene]hydroxylamine —— C12H19N5OS
    (NZ)-N-[2-(4,6-diaminopyrimidin-2-yl)sulfanylcyclooctylidene]hydroxylamine
    —— 1-[(1S,3R,7R,9S,11R)-11-benzyl-5,9-dimethyl-2-oxa-5-azatricyclo[5.3.2.03,9]dodecan-12-yl]-2-pyridin-3-ylsulfanylethanone —— C26H32N2O2S
    1-[(1S,3R,7R,9S,11R)-11-benzyl-5,9-dimethyl-2-oxa-5-azatricyclo[5.3.2.03,9]dodecan-12-yl]-2-pyridin-3-ylsulfanylethanone
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(4-ethylphenyl)methylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide —— C18H19N11O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-(4-ethylphenyl)methylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide
    —— (2R)-2-amino-3-methylbutane-1-thiol;hydrochloride —— C5H14ClNS
    (2R)-2-amino-3-methylbutane-1-thiol;hydrochloride
    —— (2R)-2-amino-4-methylpentane-1-thiolhydrochloride —— C6H16ClNS
    (2R)-2-amino-4-methylpentane-1-thiolhydrochloride
    —— (S)-2-Amino-butane-1-thiol; hydrochloride —— C4H11NS*ClH
    (S)-2-Amino-butane-1-thiol; hydrochloride
    —— (2R)-2-amino-3,3-dimethylbutane-1-thiol;hydrochloride —— C6H16ClNS
    (2R)-2-amino-3,3-dimethylbutane-1-thiol;hydrochloride
    —— (2R)-2-amino-3-methylbutane-1-thiol —— C5H13NS
    (2R)-2-amino-3-methylbutane-1-thiol
    —— 3-(2,5-Dimethylfuran-3-yl)sulfanylfuran-2-carboxylate —— C11H9O4S-
    3-(2,5-Dimethylfuran-3-yl)sulfanylfuran-2-carboxylate
    —— 2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1Z)-1-(2-hydroxyphenyl)ethylidene]acetohydrazide —— C19H17ClN4O2S3
    2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1Z)-1-(2-hydroxyphenyl)ethylidene]acetohydrazide
    —— 5-[[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylmethyl]-3-(1H-1,2,4-triazol-5-yl)-1,2,4-oxadiazole —— C14H12N8OS
    5-[[1-(pyridin-2-ylmethyl)imidazol-2-yl]sulfanylmethyl]-3-(1H-1,2,4-triazol-5-yl)-1,2,4-oxadiazole
    —— [5-(Difluoromethyl)-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl 2,2-dimethylpropanoate —— C10H15F2N3O2S
    [5-(Difluoromethyl)-4-methyl-1,2,4-triazol-3-yl]sulfanylmethyl 2,2-dimethylpropanoate
    —— N,N-dimethyl-5-(3-piperidin-1-ylpropylsulfanyl)-1,3,4-thiadiazol-2-amine —— C12H22N4S2
    N,N-dimethyl-5-(3-piperidin-1-ylpropylsulfanyl)-1,3,4-thiadiazol-2-amine
    —— 4-[5-[(2-Methylfuran-3-yl)sulfanylmethyl]-4,5-dihydro-1,3-thiazol-2-yl]morpholine —— C13H18N2O2S2
    4-[5-[(2-Methylfuran-3-yl)sulfanylmethyl]-4,5-dihydro-1,3-thiazol-2-yl]morpholine
    —— (Z)-6-((5-((4-chlorophenyl)thio)furan-2-yl)methylene)-2-(2-cyclohexylethyl)-5-imino-5H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7(6H)-one —— C24H23ClN4O2S2
    (Z)-6-((5-((4-chlorophenyl)thio)furan-2-yl)methylene)-2-(2-cyclohexylethyl)-5-imino-5H-[1,3,4]thiadiazolo[3,2-a]pyrimidin-7(6H)-one
    —— 3-(Ethoxymethylsulfanyl)-4-propan-2-yl-1,2,4-triazole —— C8H15N3OS
    3-(Ethoxymethylsulfanyl)-4-propan-2-yl-1,2,4-triazole
    —— 1-Cyclopropyl-3-(2-methylfuran-3-yl)sulfanylpyrazin-2-one —— C12H12N2O2S
    1-Cyclopropyl-3-(2-methylfuran-3-yl)sulfanylpyrazin-2-one
    —— N-[(6-methyl-2-pyrrolidin-1-ylpyridin-3-yl)methyl]-6-methylsulfanylpyrazin-2-amine —— C16H21N5S
    N-[(6-methyl-2-pyrrolidin-1-ylpyridin-3-yl)methyl]-6-methylsulfanylpyrazin-2-amine
    —— methyl 2-(2-fluorophenyl)-2-(2H-triazol-4-ylsulfanyl)acetate —— C11H10FN3O2S
    methyl 2-(2-fluorophenyl)-2-(2H-triazol-4-ylsulfanyl)acetate
    —— 1-(4-Acetylpiperazin-1-yl)-2-(2-methylfuran-3-yl)sulfanylpropan-1-one —— C14H20N2O3S
    1-(4-Acetylpiperazin-1-yl)-2-(2-methylfuran-3-yl)sulfanylpropan-1-one
    —— 2-Cyclohexyl-5-(ethoxymethylsulfanyl)-1,3,4-oxadiazole —— C11H18N2O2S
    2-Cyclohexyl-5-(ethoxymethylsulfanyl)-1,3,4-oxadiazole
    —— 2-[4-(6-Methylsulfanylpyrazin-2-yl)-1,4-diazepan-1-yl]ethanol —— C12H20N4OS
    2-[4-(6-Methylsulfanylpyrazin-2-yl)-1,4-diazepan-1-yl]ethanol
    —— 3-(3-Fluoropropylsulfanyl)-5,6-dimethylpyridazine-4-carbonitrile —— C10H12FN3S
    3-(3-Fluoropropylsulfanyl)-5,6-dimethylpyridazine-4-carbonitrile
    —— 3-[(1-Tert-butylimidazol-2-yl)sulfanylmethyl]-1-methylsulfonylpiperidine —— C14H25N3O2S2
    3-[(1-Tert-butylimidazol-2-yl)sulfanylmethyl]-1-methylsulfonylpiperidine
    —— (5E)-2-sulfanylidene-5-[[4-(trifluoromethylsulfanyl)phenyl]methylidene]-1,3-thiazolidin-4-one —— C11H6F3NOS3
    (5E)-2-sulfanylidene-5-[[4-(trifluoromethylsulfanyl)phenyl]methylidene]-1,3-thiazolidin-4-one
    —— (1S,2R,7S,9R)-5-benzyl-12-phenyl-7-phenylsulfanyl-3,8,11,13-tetraoxa-5-azatricyclo[7.4.0.02,6]tridecan-4-one —— C27H25NO5S
    (1S,2R,7S,9R)-5-benzyl-12-phenyl-7-phenylsulfanyl-3,8,11,13-tetraoxa-5-azatricyclo[7.4.0.02,6]tridecan-4-one
    —— 1-Bromo-3-iso-pentylthiobenzene —— C11H15BrS
    1-Bromo-3-iso-pentylthiobenzene
    —— (4-Chloro-3-fluorobenzyl)(4-chlorophenyl)sulfane —— C13H9Cl2FS
    (4-Chloro-3-fluorobenzyl)(4-chlorophenyl)sulfane
    —— (4-Chloro-3-fluorobenzyl)(phenyl)sulfane —— C13H10ClFS
    (4-Chloro-3-fluorobenzyl)(phenyl)sulfane
    —— 1-Bromo-2-n-heptylthiobenzene —— C13H19BrS
    1-Bromo-2-n-heptylthiobenzene
    —— 3-(2-n-Propylthiophenyl)-1-propene —— C12H16S
    3-(2-n-Propylthiophenyl)-1-propene
    —— (4-Chloro-2-fluorobenzyl)(3-chloro-4-fluorophenyl)sulfane —— C13H8Cl2F2S
    (4-Chloro-2-fluorobenzyl)(3-chloro-4-fluorophenyl)sulfane