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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 3-{(Z)-[3-(2-ethylhexyl)-4-oxo-2-thioxo-1,3-thiazolidin-5-ylidene]methyl}-9-methyl-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-4-one —— C27H29N3O2S3
    3-{(Z)-[3-(2-ethylhexyl)-4-oxo-2-thioxo-1,3-thiazolidin-5-ylidene]methyl}-9-methyl-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-4-one
    —— N-[(Z)-(4-chlorophenyl)methylideneamino]-2-[[4-methyl-5-[(3-methylanilino)methyl]-1,2,4-triazol-3-yl]sulfanyl]acetamide —— C20H21ClN6OS
    N-[(Z)-(4-chlorophenyl)methylideneamino]-2-[[4-methyl-5-[(3-methylanilino)methyl]-1,2,4-triazol-3-yl]sulfanyl]acetamide
    —— 4-(5-octadecylsulfanylthiophen-3-yl)-N,N-dioctylaniline —— C44H77NS2
    4-(5-octadecylsulfanylthiophen-3-yl)-N,N-dioctylaniline
    —— 1-(3-Methylsulfanyl-1,2,4-triazin-6-yl)ethanethiol —— C6H9N3S2
    1-(3-Methylsulfanyl-1,2,4-triazin-6-yl)ethanethiol
    —— (E)-3-amino-2-[2-[[5-[(E)-4-amino-3-cyano-2-oxopent-3-enyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]but-2-enenitrile —— C14H14N6O2S3
    (E)-3-amino-2-[2-[[5-[(E)-4-amino-3-cyano-2-oxopent-3-enyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]but-2-enenitrile
    —— 2-(Ethyldisulfanyl)-2-methylpentane —— C8H18S2
    2-(Ethyldisulfanyl)-2-methylpentane
    —— 2-(Dimethylamino)-2-propan-2-ylsulfanylethane-1,1-diol —— C7H17NO2S
    2-(Dimethylamino)-2-propan-2-ylsulfanylethane-1,1-diol
    —— (7Z)-2-[(E)-2-butan-2-yl-3-ethyl-5-iminopent-2-enyl]sulfanyl-8-(trifluoromethyl)-4,5-dihydro-3H-azocin-6-one —— C19H27F3N2OS
    (7Z)-2-[(E)-2-butan-2-yl-3-ethyl-5-iminopent-2-enyl]sulfanyl-8-(trifluoromethyl)-4,5-dihydro-3H-azocin-6-one
    —— 2-(3-Aminophenyl)sulfanyl-2-methoxypropanamide —— C10H14N2O2S
    2-(3-Aminophenyl)sulfanyl-2-methoxypropanamide
    —— 2-Methyl-2-(oxan-2-yl)-4-propyl-1,3-oxathiane —— C13H24O2S
    2-Methyl-2-(oxan-2-yl)-4-propyl-1,3-oxathiane
    —— [4-[[4-[3-(Tert-butylamino)-2-hydroxypropoxy]-1,2,5-thiadiazol-3-yl]sulfanyl]-1-hydroxy-2,2,5,5-tetramethylpyrrolidin-3-yl]methyl nitrate —— C18H33N5O6S2
    [4-[[4-[3-(Tert-butylamino)-2-hydroxypropoxy]-1,2,5-thiadiazol-3-yl]sulfanyl]-1-hydroxy-2,2,5,5-tetramethylpyrrolidin-3-yl]methyl nitrate
    —— [4-[3-(Diheptylamino)phenyl]sulfanylphenyl] butanoate —— C30H45NO2S
    [4-[3-(Diheptylamino)phenyl]sulfanylphenyl] butanoate
    —— Ethane;1-methyl-3-(2,3,3,4,4-pentamethylpentan-2-ylsulfanyl)benzene —— C19H34S
    Ethane;1-methyl-3-(2,3,3,4,4-pentamethylpentan-2-ylsulfanyl)benzene
    —— N-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]-5-(trifluoromethyl)pyridin-2-amine —— C17H11F3N6O2S
    N-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]-5-(trifluoromethyl)pyridin-2-amine
    —— 2-thionitroso-1,4-dihydropyrazine —— C4H5N3S
    2-thionitroso-1,4-dihydropyrazine
    —— 5-Methyl-1,2,3-tris(tetracosylsulfanyl)benzene —— C79H152S3
    5-Methyl-1,2,3-tris(tetracosylsulfanyl)benzene
    —— 8-(2,5-dimethoxyphenyl)sulfanyl-3-[(4-nitrophenyl)methyl]-7H-purin-3-ium-6-amine —— C20H19N6O4S+
    8-(2,5-dimethoxyphenyl)sulfanyl-3-[(4-nitrophenyl)methyl]-7H-purin-3-ium-6-amine
    —— 1,3-Bis(icosylsulfanyl)-5-methylbenzene —— C47H88S2
    1,3-Bis(icosylsulfanyl)-5-methylbenzene
    —— N-[(Z)-1-(4-bromophenyl)ethylideneamino]-2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide —— C24H27BrN6OS
    N-[(Z)-1-(4-bromophenyl)ethylideneamino]-2-[[5-[(4-methylanilino)methyl]-4-prop-2-enyl-1,2,4-triazol-3-yl]sulfanyl]propanamide
    —— 1-[4-(4-Aminophenyl)sulfanyl-3-[(7-propan-2-yl-7,8-dihydropyrido[2,3-d]pyrimidin-4-yl)amino]phenyl]-3-[4-(4-aminophenyl)sulfanyl-3-[(7-propan-2-ylpyrido[2,3-d]pyrimidin-4-yl)amino]phenyl]urea —— C45H44N12OS2
    1-[4-(4-Aminophenyl)sulfanyl-3-[(7-propan-2-yl-7,8-dihydropyrido[2,3-d]pyrimidin-4-yl)amino]phenyl]-3-[4-(4-aminophenyl)sulfanyl-3-[(7-propan-2-ylpyrido[2,3-d]pyrimidin-4-yl)amino]phenyl]urea
    —— N-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]aniline —— C20H17N3O2S
    N-[(Z)-[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylideneamino]aniline
    —— 2-(1-Oxo-2-pyridylsulfanylmethyl)durene —— C16H19NOS
    2-(1-Oxo-2-pyridylsulfanylmethyl)durene
    —— N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]benzamide —— C20H14ClN3O3S
    N-[(Z)-[4-(4-chlorophenyl)sulfanyl-3-nitrophenyl]methylideneamino]benzamide
    —— (2E)-N-(3-chlorophenyl)-3-{5-[(4-chlorophenyl)sulfanyl]furan-2-yl}-2-cyanoprop-2-enamide —— C20H12Cl2N2O2S
    (2E)-N-(3-chlorophenyl)-3-{5-[(4-chlorophenyl)sulfanyl]furan-2-yl}-2-cyanoprop-2-enamide
    —— N-[4-[4-[(1-amino-3-iminobutylidene)amino]-6-[(3S)-3-(methylamino)pyrrolidin-1-yl]pyrimidin-2-yl]sulfanylphenyl]propanamide —— C22H30N8OS
    N-[4-[4-[(1-amino-3-iminobutylidene)amino]-6-[(3S)-3-(methylamino)pyrrolidin-1-yl]pyrimidin-2-yl]sulfanylphenyl]propanamide
    —— 2-Propenenitrile, 3-ethoxy-2-(propylsulfonyl)- —— C8H13NO3S
    2-Propenenitrile, 3-ethoxy-2-(propylsulfonyl)-
    —— N'-ethyl-N-[5-[2-[(4-ethylphenyl)methylsulfanyl]pyridin-3-yl]pentyl]-N-propylethanimidamide —— C26H39N3S
    N'-ethyl-N-[5-[2-[(4-ethylphenyl)methylsulfanyl]pyridin-3-yl]pentyl]-N-propylethanimidamide
    —— 6-Methyl-1-methylsulfanylhept-2-ene —— C9H18S
    6-Methyl-1-methylsulfanylhept-2-ene
    —— 1,1,1-Trifluoro-4-(2-methylbut-3-en-2-ylsulfanyl)octa-3,5-diene —— C13H19F3S
    1,1,1-Trifluoro-4-(2-methylbut-3-en-2-ylsulfanyl)octa-3,5-diene
    —— 5-Sulfonylpent-2-ene —— C5H8O2S
    5-Sulfonylpent-2-ene
    —— methyl N-methylbut-3-enimidothioate —— C6H11NS
    methyl N-methylbut-3-enimidothioate
    —— 2-(1,1-Difluoroethyl)-5-methylsulfanylpyridine —— C8H9F2NS
    2-(1,1-Difluoroethyl)-5-methylsulfanylpyridine
    —— 1-(1-Methyl-1-methylidenethiopyran-2-yl)ethanol —— C9H14OS
    1-(1-Methyl-1-methylidenethiopyran-2-yl)ethanol
    —— 2-(Disulfanyl)pent-2-ene —— C5H10S2
    2-(Disulfanyl)pent-2-ene
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide —— C17H16FN11O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(4-fluorophenyl)ethylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide
    —— 6-[(4-chlorophenyl)sulfanyl]imidazo[2,1-b][1,3]thiazole-5-carbaldehyde O-methyloxime —— C13H10ClN3OS2
    6-[(4-chlorophenyl)sulfanyl]imidazo[2,1-b][1,3]thiazole-5-carbaldehyde O-methyloxime
    —— 2-(2,2-dimethyl-5-oxo-1,3-dioxolan-4-ylidene)-N-[(4-fluoro-2-methylsulfanylphenyl)methyl]propanamide —— C16H18FNO4S
    2-(2,2-dimethyl-5-oxo-1,3-dioxolan-4-ylidene)-N-[(4-fluoro-2-methylsulfanylphenyl)methyl]propanamide
    —— [4-[3-[2-Phenylethylcarbamoyl(3-phenylpropyl)amino]phenyl]sulfanylphenyl] butanoate —— C34H36N2O3S
    [4-[3-[2-Phenylethylcarbamoyl(3-phenylpropyl)amino]phenyl]sulfanylphenyl] butanoate
    —— [4-[3-[Butylcarbamoyl(heptyl)amino]phenyl]sulfanylphenyl] butanoate —— C28H40N2O3S
    [4-[3-[Butylcarbamoyl(heptyl)amino]phenyl]sulfanylphenyl] butanoate
    —— 5-[[2-amino-3-[[2-amino-5-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-2H-1,3,4-thiadiazol-3-yl]disulfanyl]-2H-1,3,4-thiadiazol-5-yl]sulfanyl]-1,3,4-thiadiazol-2-amine —— C8H10N12S8
    5-[[2-amino-3-[[2-amino-5-[(5-amino-1,3,4-thiadiazol-2-yl)sulfanyl]-2H-1,3,4-thiadiazol-3-yl]disulfanyl]-2H-1,3,4-thiadiazol-5-yl]sulfanyl]-1,3,4-thiadiazol-2-amine
    —— (E)-6-(4-chlorobenzylthio)imidazo[2,1-b]thiazole-5-carbaldehyde O-methyl oxime —— C14H12ClN3OS2
    (E)-6-(4-chlorobenzylthio)imidazo[2,1-b]thiazole-5-carbaldehyde O-methyl oxime
    —— 2-[(E)-1,2-bis(ethylsulfonyl)-2-(5-methylpyridin-2-yl)sulfanylethenyl]sulfanyl-5-methylpyridine —— C18H22N2O4S4
    2-[(E)-1,2-bis(ethylsulfonyl)-2-(5-methylpyridin-2-yl)sulfanylethenyl]sulfanyl-5-methylpyridine
    —— 3-[2-[(2-Amino-5-benzylsulfanyl-[1,3]thiazolo[4,5-d]pyrimidin-7-yl)amino]phenyl]propan-1-ol —— C21H21N5OS2
    3-[2-[(2-Amino-5-benzylsulfanyl-[1,3]thiazolo[4,5-d]pyrimidin-7-yl)amino]phenyl]propan-1-ol
    —— 5H-1,4-benzothiazepin-2-one —— C9H7NOS
    5H-1,4-benzothiazepin-2-one
    —— N-[(Z)-[(Z)-2-chloro-3-phenylprop-2-enylidene]amino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide —— C17H17ClN4OS
    N-[(Z)-[(Z)-2-chloro-3-phenylprop-2-enylidene]amino]-2-(4,6-dimethylpyrimidin-2-yl)sulfanylacetamide
    —— N-(3-methylphenyl)-2-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]acetamide —— C26H21N3O5S2
    N-(3-methylphenyl)-2-[(5Z)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2,4-dioxo-1,3-thiazolidin-3-yl]acetamide
    —— [Ethyl(ethylsulfanylsulfonyl)amino]ethane —— C6H15NO2S2
    [Ethyl(ethylsulfanylsulfonyl)amino]ethane
    —— N-[2-[2-(octadeca-9,12-dienylamino)ethyldisulfanyl]ethyl]octadeca-9,12-dien-1-amine —— C40H76N2S2
    N-[2-[2-(octadeca-9,12-dienylamino)ethyldisulfanyl]ethyl]octadeca-9,12-dien-1-amine
    —— 1-(1,1,2,2,2-Pentafluoroethylsulfanyl)propane —— C5H7F5S
    1-(1,1,2,2,2-Pentafluoroethylsulfanyl)propane
    —— 2-Methyl-4-[2-[[2-methyl-4-(2-sulfanylethoxymethoxy)butan-2-yl]disulfanyl]ethoxymethoxy]butane-2-thiol —— C16H34O4S4
    2-Methyl-4-[2-[[2-methyl-4-(2-sulfanylethoxymethoxy)butan-2-yl]disulfanyl]ethoxymethoxy]butane-2-thiol