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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-(4,5-diethyl-3H-thiophen-2-ylidene)-5-methoxy-N-methyl-1,3-dithiolan-4-imine —— C13H19NOS3
    2-(4,5-diethyl-3H-thiophen-2-ylidene)-5-methoxy-N-methyl-1,3-dithiolan-4-imine
    —— N-benzyl-N-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]aniline —— C24H19N5O2S
    N-benzyl-N-[(Z)-(3-nitro-4-pyrimidin-2-ylsulfanylphenyl)methylideneamino]aniline
    —— 2,3,5-Trimethyl-4-(sulfanylmethyl)hex-5-enal —— C10H18OS
    2,3,5-Trimethyl-4-(sulfanylmethyl)hex-5-enal
    —— N-ethyl-3-methyl-N-propan-2-ylbutanethioamide —— C10H21NS
    N-ethyl-3-methyl-N-propan-2-ylbutanethioamide
    —— (3Z)-3-(11,12-dihydrobenzo[d][1]benzothiocin-5-ylidene)-N,N-dimethylpropan-1-amine —— C20H23NS
    (3Z)-3-(11,12-dihydrobenzo[d][1]benzothiocin-5-ylidene)-N,N-dimethylpropan-1-amine
    —— N-benzyl-4-(3-hydroxyphenyl)sulfanylpentanamide —— C18H21NO2S
    N-benzyl-4-(3-hydroxyphenyl)sulfanylpentanamide
    —— [(Z)-[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]urea —— C12H10ClN3O2S
    [(Z)-[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]urea
    —— 3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine-1-carboximidamide —— C15H19N5S
    3-(2-methylsulfanylphenyl)-4,5,6,7-tetrahydro-2H-pyrazolo[3,4-b]azepine-1-carboximidamide
    —— 1-Sulfanylpentan-2-ylideneazanium;chloride —— C5H12ClNS
    1-Sulfanylpentan-2-ylideneazanium;chloride
    —— 1-Fluoro-2-methylsulfonylethene —— C3H5FO2S
    1-Fluoro-2-methylsulfonylethene
    —— N-[[2-chloro-6-(5,6-dihydro-1,4,2-dioxazin-3-yl)phenyl]methyl]-4-methyl-3-methylsulfanyl-5-oxo-1,2,4-triazole-1-carboxamide;methanol;4-methyl-3-methylsulfanyl-1H-1,2,4-triazol-5-one —— C20H27ClN8O6S2
    N-[[2-chloro-6-(5,6-dihydro-1,4,2-dioxazin-3-yl)phenyl]methyl]-4-methyl-3-methylsulfanyl-5-oxo-1,2,4-triazole-1-carboxamide;methanol;4-methyl-3-methylsulfanyl-1H-1,2,4-triazol-5-one
    —— (7Z)-8-methyl-2-(1,3-thiazol-4-ylmethylsulfanyl)-4,5-dihydro-3H-azocin-6-one —— C12H14N2OS2
    (7Z)-8-methyl-2-(1,3-thiazol-4-ylmethylsulfanyl)-4,5-dihydro-3H-azocin-6-one
    —— (E)-3-(4-bromo-5-phenylsulfanylfuran-2-yl)-2-cyano-N-(3-cyano-4,5,6,7-tetrahydro-1-benzothiophen-2-yl)prop-2-enamide —— C23H16BrN3O2S2
    (E)-3-(4-bromo-5-phenylsulfanylfuran-2-yl)-2-cyano-N-(3-cyano-4,5,6,7-tetrahydro-1-benzothiophen-2-yl)prop-2-enamide
    —— 3-(4-Chlorocyclohexa-2,4-dien-1-yl)sulfonyl-3-(3,6-difluoro-6-methylcyclohexa-2,4-dien-1-yl)-1-prop-2-enylcyclobutane-1-carbonitrile —— C21H22ClF2NO2S
    3-(4-Chlorocyclohexa-2,4-dien-1-yl)sulfonyl-3-(3,6-difluoro-6-methylcyclohexa-2,4-dien-1-yl)-1-prop-2-enylcyclobutane-1-carbonitrile
    —— Bis(methylsulfonyl)methanimine —— C3H7NO4S2
    Bis(methylsulfonyl)methanimine
    —— methyl (Z)-2-chloro-3-(4-chlorophenyl)sulfanylprop-2-enoate —— C10H8Cl2O2S
    methyl (Z)-2-chloro-3-(4-chlorophenyl)sulfanylprop-2-enoate
    —— [4-[3-[2-Phenylethyl(2-phenylethylcarbamoyl)amino]phenyl]sulfanylphenyl] butanoate —— C33H34N2O3S
    [4-[3-[2-Phenylethyl(2-phenylethylcarbamoyl)amino]phenyl]sulfanylphenyl] butanoate
    —— 2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C16H18N4OS2
    2-(4,6-dimethylpyrimidin-2-yl)sulfanyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— 2-Methyl-1-sulfanylideneguanidine —— C2H5N3S
    2-Methyl-1-sulfanylideneguanidine
    —— N-[(3R,4S)-1-azabicyclo[2.2.1]heptan-3-yl]-2-phenylsulfanyl-1,3-thiazole-5-carboxamide —— C16H17N3OS2
    N-[(3R,4S)-1-azabicyclo[2.2.1]heptan-3-yl]-2-phenylsulfanyl-1,3-thiazole-5-carboxamide
    —— 4-[1-(4-Methylsulfanylphenyl)-3-(trifluoromethyl)-1,2,4-triazol-1-ium-1-yl]pyridine —— C15H12F3N4S+
    4-[1-(4-Methylsulfanylphenyl)-3-(trifluoromethyl)-1,2,4-triazol-1-ium-1-yl]pyridine
    —— 3-[(3,3-dimethoxy-2-methylpropyl)disulfanyl]-1,1-dimethoxy-2-methylpropane —— C12H26O4S2
    3-[(3,3-dimethoxy-2-methylpropyl)disulfanyl]-1,1-dimethoxy-2-methylpropane
    —— 2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(1Z)-1-(2-hydroxyphenyl)ethylidene]acetohydrazide —— C19H18N4O2S3
    2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(1Z)-1-(2-hydroxyphenyl)ethylidene]acetohydrazide
    —— methyl 2-(5-tert-butylsulfanyl-4-oxo-1H-pyridin-2-yl)acetate —— C12H17NO3S
    methyl 2-(5-tert-butylsulfanyl-4-oxo-1H-pyridin-2-yl)acetate
    —— 2,2-dioxo-1H-2lambda6,4,1-benzodithiazine-3-carbaldehyde —— C8H7NO3S2
    2,2-dioxo-1H-2lambda6,4,1-benzodithiazine-3-carbaldehyde
    —— [5-Phenylsulfanyl-4-propan-2-yl-1-(pyridin-2-ylmethyl)imidazol-2-yl]methyldiazene —— C19H21N5S
    [5-Phenylsulfanyl-4-propan-2-yl-1-(pyridin-2-ylmethyl)imidazol-2-yl]methyldiazene
    —— 4,5-bis(pyrimidin-2-ylsulfanyl)-4H-pyridazin-3-one —— C12H8N6OS2
    4,5-bis(pyrimidin-2-ylsulfanyl)-4H-pyridazin-3-one
    —— 4-[(3-methoxyphenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-methyloxime —— C15H14N2O4S
    4-[(3-methoxyphenyl)sulfanyl]-3-nitrobenzenecarbaldehyde O-methyloxime
    —— 5,6-Dihydro-7h-[1,2,4]triazolo[5,1-b][1,3]thiazin-7-one —— C5H5N3OS
    5,6-Dihydro-7h-[1,2,4]triazolo[5,1-b][1,3]thiazin-7-one
    —— 3-(2,5-dihydroxy-1-propylpyrrol-3-yl)sulfanyl-N-[2-[2-(2-ethoxyethoxy)ethoxy]ethyl]propanamide —— C18H32N2O6S
    3-(2,5-dihydroxy-1-propylpyrrol-3-yl)sulfanyl-N-[2-[2-(2-ethoxyethoxy)ethoxy]ethyl]propanamide
    —— 3-Ethylidene-1-benzothiophene —— C10H10S
    3-Ethylidene-1-benzothiophene
    —— N-[(Z)-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylideneamino]benzamide —— C19H13N3O2S2
    N-[(Z)-[5-(1,3-benzothiazol-2-ylsulfanyl)furan-2-yl]methylideneamino]benzamide
    —— N-[(4-chlorophenyl)methyl]-6-(3-hydroxypropyl)-1-methylthieno[2,3-e][1,3,4]thiadiazine-3-carboxamide —— C17H18ClN3O2S2
    N-[(4-chlorophenyl)methyl]-6-(3-hydroxypropyl)-1-methylthieno[2,3-e][1,3,4]thiadiazine-3-carboxamide
    —— (E)-2-(1H-benzimidazol-2-yl)-3-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]prop-2-enenitrile —— C21H13N5OS
    (E)-2-(1H-benzimidazol-2-yl)-3-[5-(1H-benzimidazol-2-ylsulfanyl)furan-2-yl]prop-2-enenitrile
    —— 5-Amino-1-(4-methylpentyl)-2-(1-propan-2-ylbenzimidazol-2-yl)sulfanylimidazole-4-carboxamide —— C20H28N6OS
    5-Amino-1-(4-methylpentyl)-2-(1-propan-2-ylbenzimidazol-2-yl)sulfanylimidazole-4-carboxamide
    —— 9-chloro-3,4-dihydro-2H-pyrimido[1,2-b][1,4,2]benzodithiazine —— C10H9ClN2S2
    9-chloro-3,4-dihydro-2H-pyrimido[1,2-b][1,4,2]benzodithiazine
    —— (5Z)-3-(2-methylphenyl)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one —— C24H18N2O3S3
    (5Z)-3-(2-methylphenyl)-5-[[4-(4-methylphenyl)sulfanyl-3-nitrophenyl]methylidene]-2-sulfanylidene-1,3-thiazolidin-4-one
    —— (1-Bromo-2,2,2-trifluoroethyl)-[2-chloro-4-methyl-5-(2,2,2-trifluoroethylsulfanyl)phenyl]diazene —— C11H8BrClF6N2S
    (1-Bromo-2,2,2-trifluoroethyl)-[2-chloro-4-methyl-5-(2,2,2-trifluoroethylsulfanyl)phenyl]diazene
    —— 2-[5-(3,4-dichlorophenyl)sulfanyl-4-propan-2-yl-7,8-dihydro-6H-pyrido[3,4-b]pyrrolizin-8-yl]butanoic acid —— C23H24Cl2N2O2S
    2-[5-(3,4-dichlorophenyl)sulfanyl-4-propan-2-yl-7,8-dihydro-6H-pyrido[3,4-b]pyrrolizin-8-yl]butanoic acid
    —— [3-[3-[Cyclohexylcarbamoyl(2-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate —— C31H36N2O3S
    [3-[3-[Cyclohexylcarbamoyl(2-phenylethyl)amino]phenyl]sulfanylphenyl] butanoate
    —— 1-Methylsulfinylpentan-3-ol —— C6H14O2S
    1-Methylsulfinylpentan-3-ol
    —— (3E,5E)-1,1-dimethyl-3,5-bis[(4-methylsulfanylphenyl)methylidene]piperidin-1-ium-4-one —— C23H26NOS2+
    (3E,5E)-1,1-dimethyl-3,5-bis[(4-methylsulfanylphenyl)methylidene]piperidin-1-ium-4-one
    —— 3-Methyl-7-propylsulfanylhept-1-ene —— C11H22S
    3-Methyl-7-propylsulfanylhept-1-ene
    —— 3-[2-(2-Aminoethylsulfanylmethyl)pyridin-3-yl]sulfanyl-1-azabicyclo[4.2.0]oct-2-en-8-one —— C15H19N3OS2
    3-[2-(2-Aminoethylsulfanylmethyl)pyridin-3-yl]sulfanyl-1-azabicyclo[4.2.0]oct-2-en-8-one
    —— 3-(2-ethylphenyl)sulfanyl-2-methyl-1H-indole —— C17H17NS
    3-(2-ethylphenyl)sulfanyl-2-methyl-1H-indole
    —— Isothiocyanatoethane;sulfanylidenephosphane —— C3H6NPS2
    Isothiocyanatoethane;sulfanylidenephosphane
    —— 2-Ethylsulfanyl-2,5-dimethylhexane —— C10H22S
    2-Ethylsulfanyl-2,5-dimethylhexane
    —— 1-[(Z)-[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]-3-ethylthiourea —— C14H14ClN3OS2
    1-[(Z)-[5-(4-chlorophenyl)sulfanylfuran-2-yl]methylideneamino]-3-ethylthiourea
    —— 3-Cyclohexyliminopropanethioamide —— C9H16N2S
    3-Cyclohexyliminopropanethioamide
    —— 3-[2-[6-[3-(2-carboxyethyl)-4-hydroxy-2-sulfanylidene-1,3-thiazol-5-yl]hexa-2,4,5-trienylidene]-5,6-bis(methylsulfanyl)-3H-1-benzothiophen-3-yl]propanoic acid —— C25H25NO5S5
    3-[2-[6-[3-(2-carboxyethyl)-4-hydroxy-2-sulfanylidene-1,3-thiazol-5-yl]hexa-2,4,5-trienylidene]-5,6-bis(methylsulfanyl)-3H-1-benzothiophen-3-yl]propanoic acid