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    首页 分子通 按分子结构分类 有机化合物 有机硫化合物

    有机硫化合物

    有机硫化合物是指含有硫原子的有机化合物。这些化合物在自然界中广泛存在，在医药、农药和材料科学等领域有着重要的应用。有机硫化合物因其化学性质独特，在药物设计、合成化学以及材料制备方面扮演着重要角色。

    1. 结构与分类

    有机硫化合物可以按硫的连接方式分为饱和和不饱和类，如二硫化物、噻吩衍生物、砜等。常见的结构类型有：

    • 二硫化物：含-S-S-键的化合物。
    • 硫醚（Thiols）：含有-R-S-H或-R-S-R 基团的化合物。
    • 磺酸酯（Sulfonates）与磺酸盐（Sulfonates）：带有-SO3H基团的化合物，广泛应用于合成和制药领域。
    • 噻吩及其衍生物：具有环状结构的有机硫化物。
    2. 生物学活性

    许多有机硫化合物在生物学上有重要功能或应用潜力。例如：

    • 某些硫醚类药物被用于抗真菌、抗菌以及抗癌治疗。
    • 硫代葡萄糖苷（Glycosinolate）是十字花科植物中的一种天然存在物质，具有生物活性。
    3. 合成方法

    有机硫化合物可通过多种途径合成：

    • 亲核取代反应：使用含硫试剂与卤化物进行反应。
    • 自由基加成法：采用氧化剂引发自由基形成，通过烯烃与H2S、R-S-H等反应制备。
    • 金属催化转化：利用钯、铜等催化剂促进特定硫化过程。
    4. 应用领域

    有机硫化合物的应用广泛：

    • 医药领域：用于开发抗菌剂、抗病毒药物及抗癌药物等。
    • 农学研究：某些有机硫化合物作为生物农药的有效成分，能够抑制病害的发生。
    • 材料科学与技术：在导电聚合物和塑料添加剂中有重要应用。
    5. 环境与安全性

    尽管有机硫化合物具有许多潜在益处，但其生产和使用也可能对环境造成影响。因此，在设计和合成这些化合物时需要考虑可持续性和环保性因素。

    以上是对有机硫化合物的简单介绍，包括它们的结构、生物学活性、合成方法及其应用领域等基本信息。

    下级分类

    中文名称 英文名称 CAS号 化学式 结构式图片
    —— 2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1Z)-1-phenylethylidene]acetohydrazide —— C19H17ClN4OS3
    2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)-N'-[(1Z)-1-phenylethylidene]acetohydrazide
    —— N'-[(1Z)-1-(4-bromophenyl)ethylidene]-2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide —— C19H16BrClN4OS3
    N'-[(1Z)-1-(4-bromophenyl)ethylidene]-2-({5-[(4-chlorobenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide
    —— [(E)-2-nitro-1-phenylsulfanylbut-1-enyl]benzene —— C16H15NO2S
    [(E)-2-nitro-1-phenylsulfanylbut-1-enyl]benzene
    —— 2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-1-thiophen-2-ylethylideneamino]acetamide —— C17H16N4OS4
    2-[(5-benzylsulfanyl-1,3,4-thiadiazol-2-yl)sulfanyl]-N-[(Z)-1-thiophen-2-ylethylideneamino]acetamide
    —— N-[(Z)-1-(4-fluorophenyl)ethylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C20H19FN4OS3
    N-[(Z)-1-(4-fluorophenyl)ethylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— N'-[(1Z)-1-(4-bromophenyl)ethylidene]-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide —— C20H19BrN4OS3
    N'-[(1Z)-1-(4-bromophenyl)ethylidene]-2-({5-[(4-methylbenzyl)sulfanyl]-1,3,4-thiadiazol-2-yl}sulfanyl)acetohydrazide
    —— [(E)-1-phenylhex-1-en-2-yl]sulfanylbenzene —— C18H20S
    [(E)-1-phenylhex-1-en-2-yl]sulfanylbenzene
    —— 1-oxido-2-[[(4R)-1,3,4-trimethyl-4,5-dihydroimidazol-1-ium-2-yl]sulfanyl]pyridin-1-ium —— C11H16N3OS+
    1-oxido-2-[[(4R)-1,3,4-trimethyl-4,5-dihydroimidazol-1-ium-2-yl]sulfanyl]pyridin-1-ium
    —— 1-oxido-2-[[(4S)-1,3,4-trimethyl-4,5-dihydroimidazol-1-ium-2-yl]sulfanyl]pyridin-1-ium —— C11H16N3OS+
    1-oxido-2-[[(4S)-1,3,4-trimethyl-4,5-dihydroimidazol-1-ium-2-yl]sulfanyl]pyridin-1-ium
    —— propan-2-yl (2E)-7-methyl-2-[(5-methylfuran-2-yl)methylidene]-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C24H24N2O4S2
    propan-2-yl (2E)-7-methyl-2-[(5-methylfuran-2-yl)methylidene]-5-(4-methylsulfanylphenyl)-3-oxo-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— (3Z,5E)-1,1-dimethyl-3,5-bis[(4-methylsulfanylphenyl)methylidene]piperidin-1-ium-4-one —— C23H26NOS2+
    (3Z,5E)-1,1-dimethyl-3,5-bis[(4-methylsulfanylphenyl)methylidene]piperidin-1-ium-4-one
    —— (5E)-5-{4-[(4-chlorophenyl)sulfanyl]benzylidene}-3-methyl-1,3-thiazolidine-2,4-dione —— C17H12ClNO2S2
    (5E)-5-{4-[(4-chlorophenyl)sulfanyl]benzylidene}-3-methyl-1,3-thiazolidine-2,4-dione
    —— 3-[(Z)-(3-octyl-4-oxo-2-thioxo-1,3-thiazolidin-5-ylidene)methyl]-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-4-one —— C26H27N3O2S3
    3-[(Z)-(3-octyl-4-oxo-2-thioxo-1,3-thiazolidin-5-ylidene)methyl]-2-(phenylsulfanyl)-4H-pyrido[1,2-a]pyrimidin-4-one
    —— propan-2-yl (2E)-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-2-[(1,2,5-trimethylpyrrol-3-yl)methylidene]-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C26H29N3O3S2
    propan-2-yl (2E)-7-methyl-5-(4-methylsulfanylphenyl)-3-oxo-2-[(1,2,5-trimethylpyrrol-3-yl)methylidene]-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— 4-Amino-3-phenylthio-3-penten-2-on 52687-69-1 C11H13NOS
    4-Amino-3-phenylthio-3-penten-2-on
    —— (2R)-N-(1-hydroxy-2-methylpropan-2-yl)-2,3-dihydro-1-benzothiophene-2-carboxamide —— C13H17NO2S
    (2R)-N-(1-hydroxy-2-methylpropan-2-yl)-2,3-dihydro-1-benzothiophene-2-carboxamide
    —— 2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-[(E)-2-methyl-3-phenylprop-2-enylidene]amino]acetamide —— C21H19ClN4OS3
    2-[[5-[(4-chlorophenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(Z)-[(E)-2-methyl-3-phenylprop-2-enylidene]amino]acetamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-[(E)-3-(furan-2-yl)-2-methylprop-2-enylidene]amino]triazole-4-carboxamide —— C20H17ClN8O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-[(E)-3-(furan-2-yl)-2-methylprop-2-enylidene]amino]triazole-4-carboxamide
    —— (2S)-2-[[(1R)-1-(4-methylsulfanylphenyl)ethyl]amino]propan-1-ol —— C12H19NOS
    (2S)-2-[[(1R)-1-(4-methylsulfanylphenyl)ethyl]amino]propan-1-ol
    —— (Z)-3-amino-2-[2-[[5-[(E)-4-amino-3-cyano-2-oxopent-3-enyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]but-2-enenitrile —— C14H14N6O2S3
    (Z)-3-amino-2-[2-[[5-[(E)-4-amino-3-cyano-2-oxopent-3-enyl]sulfanyl-1,3,4-thiadiazol-2-yl]sulfanyl]acetyl]but-2-enenitrile
    —— methyl (2E)-7-methyl-2-(4-methylbenzylidene)-5-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate —— C24H22N2O3S2
    methyl (2E)-7-methyl-2-(4-methylbenzylidene)-5-[4-(methylsulfanyl)phenyl]-3-oxo-2,3-dihydro-5H-[1,3]thiazolo[3,2-a]pyrimidine-6-carboxylate
    —— (5E)-5-[[4-(4-chlorophenyl)sulfanylphenyl]methylidene]-3-(oxolan-2-ylmethyl)-2-phenylimino-1,3-thiazolidin-4-one —— C27H23ClN2O2S2
    (5E)-5-[[4-(4-chlorophenyl)sulfanylphenyl]methylidene]-3-(oxolan-2-ylmethyl)-2-phenylimino-1,3-thiazolidin-4-one
    —— (5Z)-5-({4-bromo-5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-1-(3,5-dimethylphenyl)-2-thioxodihydropyrimidine-4,6(1H,5H)-dione —— C23H16BrClN2O3S2
    (5Z)-5-({4-bromo-5-[(4-chlorophenyl)sulfanyl]furan-2-yl}methylidene)-1-(3,5-dimethylphenyl)-2-thioxodihydropyrimidine-4,6(1H,5H)-dione
    —— 2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-1-phenylethylideneamino]acetamide —— C20H20N4OS3
    2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]-N-[(E)-1-phenylethylideneamino]acetamide
    —— (E)-3-[5-[[(2S)-oxolan-2-yl]methylsulfanyl]thiophen-2-yl]prop-2-enoic acid —— C12H14O3S2
    (E)-3-[5-[[(2S)-oxolan-2-yl]methylsulfanyl]thiophen-2-yl]prop-2-enoic acid
    —— (NE)-N-[(4Z)-8-phenylsulfanylcyclooct-4-en-1-ylidene]hydroxylamine —— C14H17NOS
    (NE)-N-[(4Z)-8-phenylsulfanylcyclooct-4-en-1-ylidene]hydroxylamine
    —— 5-[[(2S)-oxolan-2-yl]methylsulfanyl]thiophene-2-carbaldehyde —— C10H12O2S2
    5-[[(2S)-oxolan-2-yl]methylsulfanyl]thiophene-2-carbaldehyde
    —— N,N-dimethyl-1-[(E)-1-phenylsulfanylprop-1-en-2-yl]pyridin-1-ium-4-amine —— C16H19N2S+
    N,N-dimethyl-1-[(E)-1-phenylsulfanylprop-1-en-2-yl]pyridin-1-ium-4-amine
    —— 2-(4-methylphenyl)sulfanyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide —— C17H18N2OS2
    2-(4-methylphenyl)sulfanyl-N-[(Z)-(4-methylsulfanylphenyl)methylideneamino]acetamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(furan-2-yl)ethylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide —— C15H15N11O3S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-N-[(Z)-1-(furan-2-yl)ethylideneamino]-5-[(4-methyl-1,2,4-triazol-3-yl)sulfanylmethyl]triazole-4-carboxamide
    —— (4-methylphenyl) (E)-N-(2,2-dichloro-1-diphenylphosphorylethenyl)benzenecarboximidothioate —— C28H22Cl2NOPS
    (4-methylphenyl) (E)-N-(2,2-dichloro-1-diphenylphosphorylethenyl)benzenecarboximidothioate
    —— N-[(Z)-1-(furan-2-yl)ethylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide —— C18H18N4O2S3
    N-[(Z)-1-(furan-2-yl)ethylideneamino]-2-[[5-[(4-methylphenyl)methylsulfanyl]-1,3,4-thiadiazol-2-yl]sulfanyl]acetamide
    —— 1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]triazole-4-carboxamide —— C21H20ClN9O2S
    1-(4-amino-1,2,5-oxadiazol-3-yl)-5-[(4-chlorophenyl)sulfanylmethyl]-N-[(Z)-[4-(dimethylamino)phenyl]methylideneamino]triazole-4-carboxamide
    —— (3E)-4-(dimethylamino)-1,3-bis(phenylsulfanyl)but-3-en-2-one —— C18H19NOS2
    (3E)-4-(dimethylamino)-1,3-bis(phenylsulfanyl)but-3-en-2-one
    —— N-[(4-fluorophenyl)methyl]-2-[[2-[(3S)-3-methylpiperidin-1-yl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl]acetamide —— C20H22FN5OS2
    N-[(4-fluorophenyl)methyl]-2-[[2-[(3S)-3-methylpiperidin-1-yl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl]acetamide
    —— N-benzyl-2-[[2-[(3R)-3-methylpiperidin-1-yl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl]acetamide —— C20H23N5OS2
    N-benzyl-2-[[2-[(3R)-3-methylpiperidin-1-yl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl]acetamide
    —— N-[(2R)-butan-2-yl]-2-[[2-(4-methylpiperidin-1-yl)-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl]acetamide —— C17H25N5OS2
    N-[(2R)-butan-2-yl]-2-[[2-(4-methylpiperidin-1-yl)-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl]acetamide
    —— 2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(1Z)-1-(4-chlorophenyl)ethylidene]acetohydrazide —— C19H17ClN4OS3
    2-{[5-(benzylsulfanyl)-1,3,4-thiadiazol-2-yl]sulfanyl}-N'-[(1Z)-1-(4-chlorophenyl)ethylidene]acetohydrazide
    —— (E)-2-[(E)-1-cyano-2-ethoxyethenyl]sulfonyl-3-ethoxyprop-2-enenitrile —— C10H12N2O4S
    (E)-2-[(E)-1-cyano-2-ethoxyethenyl]sulfonyl-3-ethoxyprop-2-enenitrile
    —— Dilithium;ethane-1,2-disulfonoperoxoic acid —— C2H6Li2O8S2+2
    Dilithium;ethane-1,2-disulfonoperoxoic acid
    —— Ethane-1,2-disulfonoperoxoic acid —— C2H6O8S2
    Ethane-1,2-disulfonoperoxoic acid
    —— 2,2-Dimethylpropane-1-sulfonoperoxoic acid —— C5H12O4S
    2,2-Dimethylpropane-1-sulfonoperoxoic acid
    —— Sodium;2,2-dimethylpropane-1-sulfonoperoxoic acid —— C5H12NaO4S+
    Sodium;2,2-dimethylpropane-1-sulfonoperoxoic acid
    —— N-[2-(cyclohexen-1-yl)ethyl]-2-[[2-[(3R)-3-methylpiperidin-1-yl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl]acetamide —— C21H29N5OS2
    N-[2-(cyclohexen-1-yl)ethyl]-2-[[2-[(3R)-3-methylpiperidin-1-yl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl]acetamide
    —— 1-Tridecoxypropane-1-sulfonoperoxoic acid —— C16H34O5S
    1-Tridecoxypropane-1-sulfonoperoxoic acid
    —— N-[2-(cyclohexen-1-yl)ethyl]-2-[[2-[(3S)-3-methylpiperidin-1-yl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl]acetamide —— C21H29N5OS2
    N-[2-(cyclohexen-1-yl)ethyl]-2-[[2-[(3S)-3-methylpiperidin-1-yl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl]acetamide
    —— [(3R)-1-[6-(4-bromophenyl)sulfanylpyridazin-3-yl]piperidin-3-yl]-thiomorpholin-4-ylmethanone —— C20H23BrN4OS2
    [(3R)-1-[6-(4-bromophenyl)sulfanylpyridazin-3-yl]piperidin-3-yl]-thiomorpholin-4-ylmethanone
    —— 1-[3-(4-methylphenyl)sulfanylpyrazin-2-yl]-N-[2-[(2R)-2-methylpiperidin-1-yl]ethyl]piperidine-4-carboxamide —— C25H35N5OS
    1-[3-(4-methylphenyl)sulfanylpyrazin-2-yl]-N-[2-[(2R)-2-methylpiperidin-1-yl]ethyl]piperidine-4-carboxamide
    —— 2-[[2-[(3S)-3-methylpiperidin-1-yl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl]-N-[(2S)-4-phenylbutan-2-yl]acetamide —— C23H29N5OS2
    2-[[2-[(3S)-3-methylpiperidin-1-yl]-[1,3]thiazolo[4,5-d]pyrimidin-7-yl]sulfanyl]-N-[(2S)-4-phenylbutan-2-yl]acetamide
    —— N-[3-[(2R)-2-methylpiperidin-1-yl]propyl]-1-(3-phenylsulfanylpyrazin-2-yl)piperidine-4-carboxamide —— C25H35N5OS
    N-[3-[(2R)-2-methylpiperidin-1-yl]propyl]-1-(3-phenylsulfanylpyrazin-2-yl)piperidine-4-carboxamide